Thiết kế bài giảng hóa học 12 tập 1

CAO CM GIAC (Chii bi^n) Thiet ke bdi giang H6A HOC 12 TAP M O T N H A X U A T B A N H A N0I TS CAO CU" GlAC (Chu bi^n) - ThS H THANH THUY THI£T K£ BAI GIANG HOAHOC > ^ T^PM^ NHA XUAT BAN HA NOI J-cfi noi dau Di hd trg cho viec dgy - hoc mon Hod hoc 12 theo chuang trinh sdch gido khoa (SGK) mai dp dung tic ndm hoc 2008 - 2009, chung tdi biin sogn cuon Thiit ki bdi gidng Hod hgc 12 tap 1, Sdch giai thieu cdch thiet ki bdi gidng theo tinh thdn ddi mai phucmg phdp dgy hoc nhdm phdt huy tinh tich cue nhdn thuc ciia hoc sinh (HS) Ve ngi dung: Sdch bdm sdt ngi dung SGK Hod hoc 12 theo chuang trinh chudn cua Bo Gido due vd Ddo tgo ban hdnh O mdi tiit dgy diu chi ro muc tieu ve kien thicc, ki ndng, thdi do, cdc cdng viec cdn chudn bi cita gido viin (GV) vd hoc sinh (HS), cdc phuang tiin trg gidng cdn thiit nhdm dam bdo chdt lugng timg bdi, tiing tiet lin lap Ngodi sdch cdn ma rgng, bo sung thim mot sd ngi dung liin quan den bdi gidng bdng nhieu hogt do/ig nhdm cung cdp them tu lieu de cdc thdy, co gido tham khdo, van dung theo doi tugng vd muc dich dgy hoc Ve phucmg phdp dgy - hoc: Sdch duac trien khai theo huang tich cue hod hogt dong cua HS, lay ca sd cua mdi hogt dong Id nhicng viec lam cua HS dual su huang ddn, ggi ma cua thdy, cd gido Sdch ciing dua nhieu hlnh thicc hogt dong hdp ddn, phii hgp vai dgc trung mdn hoc nhu: thi nghiem, quan sdt vdt that hay md hlnh, thdo ludn, thuc hdnh, nhdm phdt huy tinh dgc lap, tu gidc ciia HS Ddc biit sdch rdt chii tai khdu thuc hdnh bdi hoc, dong tthai ciing chi ro tieng hogt dgng cu the ciia GV vd HS mot tien trinlh DAY -HOC, coi day Id.hai hogt dgng ciing cd HS vd GV deu Id chu the Chung toi hi vong cuon sdch ndy se Id tdi lieu tham khdo hiru ich, gdp phdn ho trg cdc thdy, co gido dang tr.uc tiep gidng dgy mon Hod hoc 12 trdng viec ndng cao chdt lugng bdi gicing ciia minh Rdt mong nhgn dugc y kien ddng gdp ciia cdc thdy, co gid'O vd bgn dgc gdn xa de cuon sdch dugc hodn thien hem CAC TAC GlA ON TAP D A U NAM A MUG TIEU BAI HOC Ki§n thu'c On tap he thong hoa kien thuc ve: • Sir dien li, khai niem axit-baza, pH cua dung dich va phan ung trao d6i ion dung dich dien H, nhom nita-photpho, nhom cacbon-silic • Cac khai niem: Chat huu ca, cong thiic va cku tnic phan tii, danh phap cac hop chat hOxi ca, cac loai phan ling huu ca ca ban (phan ung thS, phan ling cong, phan ung tach ), dong dang, dong phan c4u tao va d6ng phan lap thg • Hieu dugc moi quan he giiia cau tao ciia hgp ch4t hiru ca vai nhiing tinh chat vat li, tinh chat hoa hpc • Khac sau dugc nhiing tinh chat vat li, tinh chSt hoa hoc, bilt nhung ling dung va phuang phap dieu che cac loai hgp chat hiru ca chuang trinh hoa hgc lap 11 • Khac sau nhung quy tac, quy luat hoa huu ca nhu: Quy tac Mac-copnhi-cop, quy tac the vao nhan tham, quy tac tach Zai-xep de chuan bj kien thiic nghien ciiu cac hgp chat hiiu ca phiic tap han (hoa hgc 12) KT nang • Ren luyen kT nang dua vao cau tao cua chat de suy tinh chat va ling dung cua chat va ngugc lai tu tinh chat cua chat de du doan cau tao cua cac chat • Bilt van dung li thuyet hoa hgc de giai quyet mgt so van de dan gian dai song, san xuat • Phat trien kT nang tu hgc, biet lap bang tong ket kien thiic, biet each tom tat cac ngi dung chinh bai, timg chuang • Ren luyen kT nang giai bai tap xac dinh cong thiic phan tir cua hgp chat Tinh cam, thai • Thong qua viec ren luyen tu bien chiing viec xet moi quan he nhan qua giira cdu tao va tinh chat cua chat, lam cho HS thu hgc tap va yeu thich mon hoa hgc han • Ren thai lam viec khoa hgc, nghiem tiic B C H U A N • • B! Q U A GVVA HS GV: May tinh, may chieu, he thong bai tap va cac cau hoi ggi y HS: On tap cac kien thiic thong qua boat dgng giai bai t ^ C TI^N TRJNH DAY - HOC GV t6 chiic cac nhom HS thao luan cac ngi dung cin on tap a lop U duoi dang cac bai tap trac nghiem khach quan Hogt dgng SUDlfiN LI Cho dung dich HCl va CH3COOH co ciing n6ng CM SO sanh pH cua dung dich nhan thay: A HCl < CH3COOH B HCl > CH3COOH C bang D khong so sanh dugc Ddp dn A Cho 9,6 gam Cu va 100ml dung dich hon hgp HNO3 1,5M va HCl 2M thi sinh V lit NO (dktc) Gia tri cua V la B 2,24 lit C 2,68 lit D 4,48 lit A 1,97 lit Ddp dn B Khang dinh nao sau day la diing? A Chat dien ly la chat tan dugc nuac B Do dien li a cang lan thi hang so can bang K cang tang va chat dien li cang manh C Do dien li a cang lan dung dich chat dien li cang loang D Trong dung dich chat dien li chi ton tai cac ion Ddp dn C Chat phai them vao dung dich nuac de lam pH thay doi tir 12 xuong 101a A Nuac cat B Natri hidroxit C Hidro clorua D Natri axetat Ddp dn C Khi CO can hoac pha loang dung dich: A Nong mol cac chat ti le thuan vai the tich B Nong mol cac chat ti le nghich vai the tich C Khoi lugng chat tan va khoi lugng dung dich khong thay d6i D Nong cac chat khong thay doi Ddp dn B Doi vai dung dich axit yeu HNO2 0,1M neu bo qua sir dien li cua nuac thi danh gia nao sau day la diing? A p H > l , B pH=l,0 C [H1 > [NO2-] Ddp dn A D [H"] < [NO2"] Do dien li a cua axit yeu tang theo pha loang dung dich Khi gia tri hang so phan li axit Ka thay d6i nhu thi nao? A Tang B Giam C Khong d6i D Khong xac dinh Ddp dn C Do dien li a cua CH3COOH se thay d6i nhu the nao nho vai gigt dung dich NaOH vao dung dich axit axetic? A Tang B Giam C Khong doi D Khong xac djnh Ddp dn A Trgn V, lit dung dich HCl (pH = 5) vai V2 lit dung dich NaOH (pH = 9) thu dugc dung djch co pH = Ti le ViA'2 la A 1/3 B 3/1 C 9/11 D 11/9 Ddp dn C 10 Xac dinh pH cua dung dich CH3COOH 0,01M? A pH = 2,0 B p H > , C pH < 2,0 D Khong xac dinh Ddp dn B 11 Co cac dung dich dien li manh cimg nong mol: NaHC03, NaOH, Na2C03, Ba(0H)2 Hay sap xep cac dung dich theo chieu pH cua dung dich tang dan? A NaHC03 < NaOH < Ba(0H)2 < Na2C03 B NaHCOs < Na2C03 < Ba(0H)2 < NaOH C NaHC03 < Na2C03 < NaOH = Ba(0H)2 D NaHC03 < Na2C03 < NaOH < Ba(0H)2 Ddp dn D 12 Co bao nhieu gam KCIO3 tach khoi dung dich lam lanh 350 gam dung dich KCIO3 bao hoa a 80"C xu6ng 20°C? Bilt tan cua KCIO3 a 80°C va 20°C lan lugt la 40g/100g nuac va 8g/100g nuac A 95 gam Ddp dn B B 80 gam C 60 gam D 115 gam 13 Muoi nao sau day bi thiiy phan? A.NH4CI Ddp dn A B Ba(N03)2 C.CaCl2 D MgS04 14 Chat nao sau day la luang tinh? A NaHS04, Na2C03, CHjCOONa B NaHS04, NaHC03,NaHS C NaHC03, (NH4)2C03, CH3COONH4 D Zn(0H)2, AI2O3, Al Ddp dn C 15 Mgt dung dich co chira cac ion: Na"^: 0,1 mol; K"": 0,05 mol; Ba^"": 0,05 mol; Cl": 0,1 mol; N03~: x mol Khoi lugng mu6i c6 dung dich X la: A 23,95 gam B 18,25 gam C 42,00 gam D 36,25 gam Ddp dn A 16 De bao quan dung dich muoi Fe2(S04)3 tranh bi thuy phan, nguoi ta thuang them vao vai gigt: A Dung dich NaOH B Dung dich BaCh C Dung djch NH3 D Dung dich H2SO4 Ddp dn D 17 Dung dich dien li dan dugc dien la do: A Su chuyen dich cua cac electron B Su chuyen dich cua cac cation C Sir chuyen dich cua cac phan tir hoa tan D Su chuyen djch cua cac ion Ddp dn D 18 Phan img nao sau day tao dugc ket tua? A FeS04 + KMn04 + H2SO4 -^ B Fe2(S04)3 + KI ^ C Fe(N03)3 + Fe ^ D Fe(N03)3 + KOH -^ Ddp dn D 19 Trgn 100 ml dung dich co pH = g6m HCl va HNO3 vai 100 ml dung dich NaOH nong a (mol/1) thu dugc 200 ml dung dich co pH = 12 Gia tri cua a la A 0,15 Ddp dn D B 0,30 C 0,03 D 0,12 20 Nhung chat nao sau day co thi t6n tai ddng thai mgt dung dich A A\^\ Na^ K^ c r C03^' C Na^ c r , H\ NO3", C03^" B Ba^^ CP K^ NO3", S04^" D Na^ NH4'' Ca^^ NO3" Cl" Ddp dn D Hogt dgng NITO - PHOTPHO Cau hinh electron lop ngoai ciing cua cac nguyen to nhom VA dugc bieu dien tong quat la A ns^np'* B ns^np^ C ( n - l ) d " ' n s V Ddp dn B D ( n - l ) d ' " n p ' Trong nhom Nita (VA), di tir nito den bitmut, phat bieu nao sau day diing? A Do am dien cua cac nguyen to tang dan B Ban kinh nguyen tir cua cac nguyen to giam dan C Bitmut the hien tinh kim loai trgi han tinh phi kim D Asen the hien tinh kim loai trgi han tinh phi kim Ddp dn C Trong cong nghiep nita dugc san xuat theo phuang phap nao sau day? A Chung cat phan doan khong long B Nhiet phan dung dich NH4NO2 bao hoa C Diing photpho de dot chay oxi khong D Cho khong di qua bgt dong nung nong Ddp dn A nhiet cao (1000°C), N2 tac dung vai Al (dang bgt) tao hgp chat X Cong thiic diing cua X la: A.AI2N3 B.AI3N2 CAIN D.AI5N3 Ddp dn C Thanh phan chinh co chiia P cua quang Apatit la A Ca3(P04)2 Ddp dn A B.NH4H2PO4 C Ca(H2P04)2 D CaHP04 Cho phuang trinh hoa hgc ciia phan ung tong hgp amoniac N2 (k) + 3H2 (k) < '"'" > 2NH3 (k) Khi tang nong ciia hidro len lan, toe phan ling thuan A tang len lan B tang len lan C tang len lan D giam di Idn Ddp dn A Hap thu X mol NO2 vao dung dich chiia x mol NaOH thi dung dich thu dugc CO A pH = 7" B p H > C p H < D pH = Ddp dn B Khi thuc hien phan ling dot chay NH3 O2 co mat xac tac Pt a 850 - 900°C, phan irng nao sau day xay ra? A 4NH3 + 3O2 -> 2N2 + 6H2O B 4NH3 + 4O2 -^ 2N0 + N2 + 6H2O C 4NH3 + 5O2 ^ 4N0 + 6H2O D 2NH3 + 2O2 -> N2O + 3H2O Ddp dn C Tong he so (cac so nguyen, toi gian) ciia tat ca cac chat phuang trinh phan ling giOa Cu vai dung dich PINO3 dac, nong la A 10 B C D 11 Ddp dn A 10 Kim loai Cu tan dugc dung dich nao sau day? A dung dich NH3 B dung dich KNO3 C dung dich KNO3 + NH3 D dung dich KNO3 + HCl Ddp dn D 11 Khi nho tir tir dung dich NH3 den du vao dung dich CUSO4 thi san phdm co mau xanh tham cua: A Cu(0H)2 B [Cu(NH3)4]S04 C [Cu(NH3)4](0H)2 D [Cu(NH3)4]^^ Ddp dn D 10 12 Cho NH3 vao nuac dung dich thu dugc la: A NH4OH B NH4^NH3, OH" C NH4OH, NH3 D NH4\NH40H, OH" Ddp dn B 13 De dieu che HNO3 phong thi nghiem, cac hoa chat can sir dung la: A Dung dich NaNOs va dung dich H2SO4 dac B Tinh thi NaNOs va dung dich H2SO4 dac C Dung dich NaN03 va dung dich HCl dac D Tinh the NaNOs va dung dich HCl dac Ddp dn B 14 De nhan biet ion P04^" dung dich muoi, nguai ta thuang dimg thuoc thii AgN03 bai vi: A Phan iing tao mau nau B Phan img tao dung dich c6 mau vang C Phan ung tao ket tua co mau vang D Phan iing tao khong mau hoa nau khong Ddp dn C 15 Co dung dich rieng biet AICI3, ZnCb, FeCh, CuCb N I U them dung dich KOH du roi them tilp dung dich NH3 du vao dung dich tren thi so chat ket tua thu dugc la A B C D Ddp dn D 16 Nung mgt kh6i lugng Cu(N03)2 say mgt thai gian dimg lai, lam ngugi, roi can thdy khoi lugng giam 0,54 gam Vay khIi lugng Cu(N03)2 da bi nhiet phan la A n.^4aam B 0,74 gam C 0,94 gam D 0,47 gam Ddp dn C 17 Khi 1amlf>i nghiem vai photpho trang can chu y nao sau day A Cam P trang bang tay co deo gang B Tranh cho P trang tiep xiic vai nuac C Co the de P tiing ngoai khong 11 Gia sir phan iing xay hoan toan thi V cd gia tri la A 12,375 ml B 13,375 ml C 14,375 ml Ddp dn C 2.21 Saccarit nao sau day khong bi thuy phan ? A Glucozo B Saccarozo C Mantoza Ddp dn A D 24,735 ml D Tinh bgt 2.22 De phan biet glucoza va fructoza, ta cd the dimg thudc thir la A Nude vdi B Nude brom C AgN03/NH3 Ddp dn B D dung dich NaOH 2.23 Cho m gam tinh bdt len men de san xuat ancol etylic, toan bd lugng CO2 sinh cho di qua dung dich Ca(0H)2 thu dugc 200 gam ket tua, dun ndng dung dich nude lgc thu dugc, them 200 gam kit tua Biet hieu suat mdi giai doan len men la 75%) Khdi lugng m da dung la A 860 gam B 880 gam C 869 gam D 864 gam Ddp dn D 1.14 Phan iing nao sau, day khong dung de chiing minh dac diem cau tao phan tvr glucoza? A Phan iing vdi NaOH de chiing minh phan tir cd nhdm OH B Hoa tan Cu(0H)2 de chiing minh phan tir cd nhieu nhgm OH ke C Phan ling vdi phan tii CH3COOH de chimg minh cd nhdm OH D Phan iing vdi Ag20 NH3 de chiing minh phan tu cd nhdm CHO Ddp dn A 2.25: Mudn xet nghiem sir cd mat cua dudng nude tilu khong thi dimg nude thudc thir nao sau day? A Thudc thir Fehlinh ( phiii: Cu^"*^ vdi ion tactarat) B Thudc thir tolen ( phiic Ag"^ vdi NH3 ) C Cu(0H)2 D Dung dich vdi sira Ddp dn A 235 2.26: Chgn phat bieu dung ve Cacbohidrat: A Cacbohidrat la mdt loai hidrocacbon B Cacbohidrat la hgp chat tap chiic cd chiia nhilu nhdm -OH va cd nhdm >C0 phan tir C Cacbohidrat la hgp chat da chiic cd chiia nhilu nhdm - O H va cd nhdm >C0 phan tir D Cacbohidrat la hgp chat cd cdng thiic chung la Cn(H20)n Ddp dn B 2.27 Cho cac dung dich, khdng mau: HCOOH, CH3COOH, Glucoza(C6Hi206), glixerol, C2H5OH, CH3CHO Diing nhiing cap chat nao cd the nhan bilt dugc ca chat? A Cu(0H)2, quy tim, AgNOs dung dich NH3 B Quy tim, NaOH va AgNOs dung dich NH3 C Cu(0H)2, AgN03 dung djch NH3 va NaOH D Quy tim, AgN03 dung dich NH3 va H2SO4 Ddp dn A 2.28 Cho m gam hdn hgp glucoza, mantoza tac dung hoan toan vdi dung dich AgN03/NH3 thu dugc 32,4 gam Ag Cho m gam hon hgp Glucozo, mantoza vao dung dich H2SO4 loang den thuy phan hoan toan Trung boa het axit sau dd cho san pham tac dung hoan toan vdi dung dich AgN03/NH3 thu dugc 45,36 gam Ag Khdi lugng Glucoza m gam hon hgp la A 10,8 gam B 14,58 gam C 16,2gam D 20,52gam Ddp dn C 2.29: Khdi lugng glucoza diing de dieu che lit ancol etylic vdi hieu suat 80% (khdi lugng rieng cua ancol etylic la 0,8 g/ml) la A 2,504kg B 3,130 kg C 2,003 kg D 3,507 kg Ddp dn B 2.30 Xenluloza diaxetat (X) dugc diing de san xuat phim anh hoac to axetat Cdng thirc don gian nhat (cdng thiic thuc nghiem) cua X la A C3H4O2 Ddp dn B 236 B C,oH,407 C C,2H,407 D C,2H,405 Chirang III AMIN-AMINO AXIT-P,ROTEIN 3.1 Cdng thirc nao dudri day la cdng thiic chung cua day ddng dang amin thom (chura mdt vdng benzen), don chiic, bac nhat? A.C„H2n-7NH2 (n>6) B.C„H2n+iNH2 (n>6) C.C6H5NHC„H2n.i(n>l) D C„H2n-3NHC„H2n-4 (n>3) Ddp dn A 3.2 Phan tich dinh lugng hgp chdt hiiu co X ta thdy ti le khdi lugng giira nguyen to C, H, O, N la mc: mn: mo: mN = 4,8: 1: 6,4: 2,8 Ti khdi hoi ciia X so vdi He bang 18,75 Cdng thiic phan tii cua X la A C2H5O2N B C3H7O2N C C4H10O4N2 D C2Hg02N2 Ddp dn A 3.3 Ldy 9,1 gam hgp chdt A cd cdng thiic phan tir la C3H9O2N tac dung vdi dung dich NaOH du, dun ndng, cd 2,24 lit (do d dktc) B thoat lam xanh gidy qui tim dm Ddt chay hit 1/2 lugng B ndi tren, thu dugc 4,4 gam CO2 Cdng thiic cau tao ciia A va B la A HCOONH3C2H5; C2H5NH2 B CH3COONH3CH3; CH3NH2 C HCOONH3C2H3; C2H3NH2 D CH2=CHCOONH4; NH3 Ddp dn A 3.4 Cho cac dung dich cua cac hgp chat sau: NH2-CH2-COOH (I); CIH3N-CH2-COOH (2); NH2-CH2-COONa (3); NH2-(CH2)2CH(NH2)-COOH (4); HOOC-(CH2)2CH(NH2)-COOH (5) Cac dung dich lam quy tim boa dd la A.(l),(3) B.(3),(4) C(2),(5) D.(l),(4) Ddp dn C 3.5 Cho hon hgp hai amino axit deu chiia nhdm amino va nhdm cacboxyl vao 440 ml dung dich HCl 1M dugc dung dich X De tac dung bet vdi dung djch X cdn 840 ml dung dich NaOH IM Vay tao dung dich X thi A Amino axit va HCl ciing het B Du amino axit C Du HCl D Khdng xac dinh dugc Ddp dn C 237 3.6 Day chat nao sau day dugc xIp theo chilu tang ddn bac cua amin? A CH3CH2NHCH3, CH3T^H2, (CH3)2NCH2CH3 B C2H5NH2, (CH3)2CHNH2, (CH3)3CNH2 C CH3NH2, CH3CH2NHCH3, (CH3)2NCH2CH3 D CH3NH2, (CH3)2NCH2CH3, CH3CH2NHCH3 Ddp dn C 3.7 Cho so dd phan iing: CH3NH2 ^^"^' > A ^"^' > B Cac chdt A, B so dd tren lan lugt la A (CH3)2NH, CH3CH2NH3CI B (CH3)2NH, (CH3)2NH2C1 C C2H5NH2, C2H5NH3CI D (CH3)2NH, CH3NH3CI Ddp dn B 3.8 Cac chdt sau dugc sdp xIp theo thii tu tinh bazo tang dan: A C6H5NH2, NH3, CH3NH2, C2H5NH2, CH3NHCH3 B CH3NH2, C6H5NH2, NH3, C2H5NH2 C NH3, C6H5NH2, CH3NH2, CH3NHCH3 D NH3, C2H5NH2, CH3NHC2H5, CH3NHCH3 Ddp dn A 3.9 Hgp chdt X luong tinh cd cdng thiic phan tii la C3H9O2N Cho X tac dung vdi dung dich NaOH thi thu dugc etyl amin Cdng thiic cau tao cua X la A CH3COONH3CH3 B HCOONH3C2H5 C HCOONH2(CH3)2 D C2H5COONH4 Ddp dn B 3.10 Sd ddng phan amin bac cd cdng thiic phan tu C4H1 iN la A B.3 C.4 D.5 Ddp dn B 3.11 Hgp chat X cd cdng thirc phan tir la C9H17O4N, cd cau tao ddi xung Hgp chat Y cd cdng thiic phan tir la C5H704NNa2 cd so dd chuyen boa: V + dung dich N a O H A • ^ > + dung djch HCl Cdng thirc cau tao cua X la A C2H500CCH2CH(NH2)CH2COOC2H5 238 r^ ij r\ XT/^I * L,5rlioC4rNCl B CH3COOCH2CH(NH2)CH200CC3H7 C CH3COOCH2CH2CH(NH2)CH2CH200CCH3 D C2H500CCH2CH2CH(NH2)COOC2H5 Ddp dn A 3.12 E)6t chay hoan toan m gam mgt amin don chiic thu dugc 0,2 mol CO2 va 0,35 mol H2O Cdng thiic phan tir ciia amin la A C4H7N B C2H7N C C4H,4N D C2H5N Ddp dn B 3.13 De tdng hgp cac protein tir cac amino axi4:, ngudi ta dimg phan iing: A Trimg hgp B Trimg ngung C Trung boa D Este hoa Ddp dn B 3.14 Day gdm cac chat deu cd kha nang lam ddi mau qui tim la A C6H5OH, C2H5NH2,CH3COOH B CH3NH2, C2H5NH2, CH3COOH C C6H5NH2 va CH3NH2, C2H5NH2 D (C6H5)2NH, (CH3)2NH, NH2CH2COOH Ddp dn B 3.15 Hgp chat hiiu co A chiia cac nguyen td C,H,0,N dd N chiem 15,73 % ve khdi lugng Chat A tac dung dugc vdi NaOH va HCl va deu theo ty le 1:1 ve sd mol Chat A cd san thien nhien va tdn tai d trang thai ran Cdng thiic cau tao cua A cd the la A NH2CH2CH2COOH B CH2=CHCOONH4 C HCOOCH2CH2NH2 D NH2CH2COOCH3 Ddp dn A 3.16 Cho so bien hoa C 2^2 H "^ B -D C6H5NH2 Cac chdt A, B, D ldn lugt la A C6H6, C6H5NO2, C6H5NH3CI B C6H6, C6H5CI, C6H5NO2 C C6H,2, C6H6, C6H5NO2 D CeHs, C6H5NO2, C6H4(N02)2 Ddp dn A 239 3.17 Cho cac hgp chdt hiiu co: phenyl metyl ete, toluen, anilin, phenol Trong sd cac chdt da cho, nhirng chdt cd thi lam mdt mau dung dich brom la A Toluen, anilin, phenol B Phenyl metyl ete, toluen, anilin, phenol C Phenyl metyl ete, anilin, phenol D Phenyl metyl ete, toluen, phenol Ddp dn A 3.18 Hay sdp xIp cac chdt sau day theo trat tu tang ddn tinh bazo: NH3, CH3NH2, C6H5NH2; (CH3)2NH va (C6H5)2NH: A (C6H5)2NH, NH3, C6H5NH2, (CH3)2NH, CH3NH2 B (C6H5)2NH, C6H5NH2, NH3, CH3NH2, (CH3)2NH C (CH3)2NH, CH3NH2, NH3, C6H5NH2, (C6H5)2NH D NH3, CH3NH2, C6H5NH2, (CH3)2NH, (C6H5)2NH Ddp dn B 3.19 Hgp chdt nao sau day khong phai la amino axit ? A NH2CH2COOH B HOOCCH2CHNH2COOH C CH3NHCH2COOH D CH3CH2CONH2 Ddp dn D 3.20 Cho X la mdt amino axit Khi cho 0,01mol X tac dung vdi HCl thi dung het 80ml dung dich HCl 0,125M va thu dugc 1,835gam muoi khan Cdn cho 0,0Imol X tac dung vdi dung dich NaOH thi cdn dung 25gam NaOH 3,2% Cdng thiic cdu tao cua X la A NH2C3H6COOH B C1NH3C3H3(C00H)2 C NH2C3H5(COOH)2 D (NH2)2C3H5COOH Ddp dn C 3.21 Cd thi tach rieng cac chdt tir hon hgp ldng gdm benzen va anilin bang nhiing chat nao? A Dung dich NaOH, dung dich brom B Dung dich HCl, dung dich NaOH C H2O, dung dich brom D Dung dich NaCl, dung dich brom Ddp dn B 240 3.22 De phan biet cac dung dich glucoza, glixerol, andehit axetic, ancol etylic va ldng trang triing ta dimg: A.NaOH Ddp dn C B AgN03/NH3 C Cu(0H)2 D HNO3 3.23 Trong cac chat: metyl benzoat, natri phenolat, ancol benzylic, phenyl amoni clorua, glixerin, protein Sd chat tac dung dugc vdi dung dich NaOH la A Ddp dn A 3.24 Trong cac chat: B C D P-NO2-C6H4-NH2; P-CH3O-C6H4-NH2; P-NH2-C6H4-CHO; C6H5-NH2 Chat cd tinh bazo manh nhat la A P-NO2-C6H4-NH2 B P-CH3O-C6H4-NH2 C P-NH2-C6H4-CHO D C6H5-NH2 ' Ddp dn B 3.25 C4H1 iN cd sd ddng phan amin bac la A B.3 C.4 D.5 Ddp dn C 3.26 Cho 14,7 gam mdt amino axit X (cd nhdm NH2) tac dung vdi NaOH du thu dugc 19,1 gam mudi Mat khac ciing lugng amino axit tren phan img vdi HCl du tao 18,35 gam mudi Cdng thirc cau tao cua X cd the la A NH2-CH2-COOH B CH3-CH(NH2)COOH C NH2-(CH2)6 -COOH D HOOC-CH2-CH2-CH(NH2)COOH Ddp dn D 3.21 Trong cac chdt: C6H5NH2, CH3CH2NHCH3, CH3CH2CH2NH2, CH3NH2 chdt cd tinh bazo manh nhat la A C6H5NH2 B CH3NH2 C CH3CH2NHCH3 D CH3CH2CH2NH2 Ddp dn C 3.28 Cho so dd C8H,504N + 2NaOH -^ C5H704NNa2 + CH4O + C2H6O Bilt C5H7()4NNa2 cd mach cacbon khdng phan nhanh, cd -NH2 tai C" thi C8H15O4N cd sd cdng thiic cau tao phii hgp la A B C D Ddp dn B 241 3.29 Hgp chat hiiu co cd cdng thirc phan tir C3H9O2N Sd ddng phan cd tinh chat ludng tinh (vira tac dung vdi dung dich NaOH va dung dich HCl) la A.l B.2 C.3 D.4 Ddp dn D 3.30 Ddt chay hoan toan 10,4 gam hai amin no, don chiic, ddng dang lien tiep thu dugc 11,2 lit CO2 (dktc) Hai amin cd cdng thirc phan tir la A CH4N va C2H7N B C2H5N va C3H9N C C2H7N va C3H7N D C2H7N va C3H9N Ddp dn D Chu'O'ng IV POLIME VA VAT LIEU POLIME 4.1 Khai niem dung ve polime la A Polime la hgp chat dugc tao tir cac phan tir ldn B Polime la hgp chat dugc tao tir cac phan 4ir cd phan tu khdi nhd ban C Polime la san pham nhat ciia phan triing hgp hoac triing ngung D Polime la hgp chat cao phan tir gdm n mdt xich tao Ddp dn D 4.2 Trong cac chat sau day chdt nao khong phai la polime A Tri stearat glixerol B Nhua bakelit C Cao su D Tinh bdt Ddp dn A 4.3 Chat nao dudi day khong thi tham gia phan ung triing hgp A Propilen Ddp dn D B Stiren C Propin D Toluen 4.4 San phdm -^C2H4-0-CO-C6H4-CO^ dugc tao tir phan iing nao sau day A C2H5OH + HOOC-C6H4-COOH-^ B C2H5-COOH + HO-C6H4-OH^ C CH2=CH-C00H + HOOC-C6H4-COOH-> D HO-C2H4-OH + HOOC-C6H4-COOH^ Ddp dn D 242 4.5 Chat cd cdng thiic cdu tao sau dugc tao tir phan iing - t C H - CH=CH-CH2-CH2-CHis CeHs A CH3-CH=CH-CH3 va CH2=CH-C6H5 B CH2=CH2 va CH2=CH-CH2-CH2-C6H5 C CH2=CH-CH3 va CH2=CH-CH2-C6H5 D CH2=CH-CH=CH2 va CH2=CH-C6H5 Ddp dn D 4.6 To nilon-6 thudc loai to thudc loai to nao sau day A To nhan tao B To tu nhien C To poliamit D To polieste B To tdng hgp C To nhan tao D To poliamit Ddp dn C 4.7 Xenluloza triaxetat dugc xem la A Chat deo Ddp dn C 4.8 Khdi lugng ciia mdt doan mach to nilon-6,6 la 27346 u va cua mdt doan mach to capron la 17176 u Sd lugng mat xich doan mach nilon-6,6 va capron neu tren lan lugt la A 113 va 152 B I 13 v a i 14 C 121 va 152 D 121 v a i 14 Ddp dn C 4.9 Khi triing ngung a gam axit aminoaxetic vdi hieu suat 80%), ngoai aminoaxit du ngudi ta cdn thu dugc m gam polime va 2,88 gam nude Gia tri ciia m la A 7,296 gam B 11,40 gam C 11,12 gam D 9,120 gam Ddp dn D 4.10 Tir 15kg metyl metacrylat cd the dieu che dugc bao nhieu gam thuy tinh hiiu CO cd hieu suat 90%)? A 13500n (kg) B 13500 g C 150n (kg) D 13,5 (kg) Ddp dn B 4.11 Khi dot chay polime X chi thu dugc CO2 va hoi nude vdi ti le sd mol tuong img la 1: X la polime nao dudi day ? A Polipropilen B Tinh bdt C Polivinyl clorua (PVC) D Polistiren (PS) Ddp dn A 243 4.12 Polime dugc trimg hgp tir etilen Hdi 280g polietilen da dugc tning hgp tir tdi thieu bao nhieu phan tir etilen? A 3,01.10^^ Ddp dn B B 6,02.10^^ C 6,02.10^^ D 10 4.13 Ddt chay hoan toan mdt lugng polietilen, san phdm chay cho di qua binh dung dung dich Ca(0H)2 du thdy xudt hien 10 gam kit tua Khdi lugng binh thay ddi nhu the nao? A Tang4,4g B Tang 6,2g C Giam 3,8g D Giam 5,6g Ddp dn B 4.14 Cho san pham triing hgp mol etilen d dieu kien thich hgp tac dung vira dii I6g Brom Hieu suat phan iing triing hgp va khdi lugng PE thu dugc la A 80%; 22,4 g B 90%; 25,2 g C 20%; 25,2 g D 10%; 28 g Ddp dn B 4.15 Tien hanh phan iing triing hgp 5,2 gam stiren, sau phan img ta them 400 ml dung dich nude brom 0,125M, khuay deu cho phan iing hoan toan thay du 0,04 mol Br2 Khdi lugng polime sinh la A 4,16 gam B 5,20 gam C 1,02 gam D 2,08 gam Ddp dn A 4.16 Mdt loai polime cd cau tao khdng phan nhanh nhu sau -CH2-CH2 -CH2-CH2 -CH2-CH2 -CH2-CH2Cdng thiic mdt mat xich cua polime la A -CH2- B -CH2-CH2-CH2- C - CH2-CH2- D -CH2-CH2-CH2-CH2- Ddp dn C 4.17 Polime X cd phan tir khdi la 280000 va he so tning hgp n=10000 Vay X la A.-eCH2-CH2-tn B.tCF2-CF2l-n C.-eCH2-CH(Cl)1-n Ddp dn A D.tCH2-CH(CH3)1s 4.18: Qua nghien ciiu thuc nghiem cho thdy cao su thien nhien la polime cua monome A buta-1,3-dien va stiren B 2-metylbuta-l ,3-dien C buta-1,3-dien D buta-1,2-dien Ddp dn B 244 4.19 Chi rd monome cua san pham triing hgp cd ten ggi poli propilen (P.P) A.-eCH2-CH2ls B CH2=CH-CH3 C CH2=CH2 D.t-CH2-CH(CH3)^ Ddp dn D 4.20: Cii 2,62g cao su buna-S phan iing vira hit vdi 1,6 gam brom CCI4 Hdi ti le sd mat xich butadien va stiren cao su buna-S la bao nhieu ? A 2/3 B 1/3 C 1/2 D 3/5 Ddp dn C 4.21 San pham triing hgp ciia buta-1,3-dien vdi CH2=CH-CN cd ten ggi thdng thudng: A Cao su B Cao su buna C Cao su buna - N D Cao su buna - S Ddp dn C 4.22 Giai trimg hgp polime -f CH2-CH(CH3)-CH(C6H5)-CH2 •% ta se dugc monome nao sau day ? A 2-metyl-3-phenylbut-2-en B 2-metyl-3-phenylbutan C Propilen va stiren D Isopren va toluen Ddp dn C 4.23 Dung poli(vinylaxetat) cd the lam dugc vat lieu nao sau day? A Chdt deo B Polime C To D Cao su Ddp dn A 4.24 Nhan xet ve tinh chat vat li chung cua polime nao dudi day khong diing ? A Hau bet la nhirng chat ran, khdng bay hoi B Hau het polime deu ddng thdi cd tinh deo, tinh dan hdi va cd the keo sgi dai, ben C Da sd ndng chay d mdt khoang nhiet rdng, hoac khdng ndng chay ma bi phan buy dun ndng D Da sd khdng tan cac dung mdi thdng thudng, mdt sd tan dung mdi thich hgp tao dung dich nhdt Ddp dn B 245 4.25 Hai chat nao dudi day tham gia phan iing triing ngung vdi tao to nilon- 6.6 A Axit adipic va etylen glicol B Axit picric va hexametylendiamin C Axit adipic va hexametylendiamin D Axit glutamic va hexaetylendiamin Ddp dn C 4.26 Polime nao sau day cd ten ggi "to nilon" hay "olon" dugc diing det may quan ao am? A Poli(metyl metacrylat) B Poliacrilonitrin C Poli(vinyl clorua) D Poli(phenol-fomandebit) Ddp dn B 4.27 Poli (vinyl axetat) la polime dugc dieu che tir san pham trung hgp monome nao sau day: A CH2=CH-C00CH3 B CH2=CH-C00H C CH2=CH-C00C2H5 D CH2=CH-OCOCH3 Ddp dn D 4.28 Trong sd cac polime tdng hgp sau day: nhua PVC (1), caosu isopren (2), nhua bakelit (3), thuy tinh hiiu co (4), to nilon-6,6 (5) Cac polime la san pham triing ngung gdm: A (l)va(5) B ( l ) v a ( ) C (3) va (4) D (3) va (5) Ddp dn D 4.29 De giat ao bang len ldng ciru can dung loai xa phdng cd tinh chat nao sau day?' A Xa phdng cd tinh bazo B Xa phdng cd tinh axit C Xa phdng trung tinh D Loai nao ciing dugc Ddp dn C 4.30 Khi dun ndng, cac phan tir alanin (axit a-aminopropionic) cd thi tao san pham nao sau day: 246 A t HN-CH2-CO % B tHN-CH(NH2)C0 tn C -\ HN-CH(CH3)-C0 tn Ddp dn C D t H N - C H ( C 0 H ) - C H tn MUC LUC LOI NOI DAU O N T A P D A U NAM Chu'O'ng ESTE - LIPIT 36 Bai ESTE 36 Bai LIPIT 46 Bai KHAI NIEM V& XA PHONG VA C H A T TAY R\JA T O N G HOP 56 Bai LUYEN TAP: ESTE VA C H A T BEO 63 Chipcng CACBOHIDRAT Bai GLUCOZO 73 , Bai SACCAROZO, TINH BQT VA XENLULOZO Bai LUYEN TAP: CAU TAO VA TJNH C H A T CUA CACBOHIDRAT 73 92 108 Bai THUC H A N H ; O I ^ U Che, TINH C H A T HOA HOC CUA ESTE VA CACBOHIDRAT Chu-cngS AMIN, AMINO AXIT VA PROTEIN: 120 128 Bai AMIN 128 Bai 10 AMINO AXIT 142 Bai 11 PEPTIT VA PROTEIN 152 Bai 12 LUYEN TAP: CAU TAO VA TINH C H A T CUA AMIN, AMINO AXIT VA PROTEIN Chu-cng POLIME VA VAT LIEU POLIME 165 175 Bai 13 DAI CUONG v e POLIME 175 Bai 14 VAT LIEU POLIME 188 Bai 15 LUYEN TAP: POLIME VA VAT LIEU POLIME 202 Bai 16 THUC H A N H : M Q T SO T I N H CHAT C O A PROTEIN vA VAT LIEU POLIME 210 ON TAP HOC Ki I 218 247 Thiet ke bai giang HOAHpC12-TAPMpT TS CAO CU G I A C (Chu bien) NHA XUXT BAN HA NOI Chiu trdch nhiem xudt bdn: NGUYfiN K H A C O A N H Bien tap: PHAM QUOC TUAN Vebia: NGUYfiN TUAN Trinh bdy: THAI SON - SON LAM Sua bdn in: PHAM QUOC TUAN In 2000 cuon, kho' 17 x 24 cm, tai Cdng ty TNHH in Ha Anh Giay phep xuat ban so: 217 - 2008/CXB/100 p TK - 05/HN In xong va nop luu chieu nam 2008 Sach lien ket v6i Cong ty CO phan In va Phat hanh sach Viet Nam ^ • INPHAVI Phat hanh tai Cong ty co phan In va Phat hanh sach Viet NaniJuft k#BGHaahocl2Tl Dia chi : 78 - Dong Cac - Dong Da - Ha Noi DT : 104) 5.115921 - Fax : (04) 5.115921 '"^T; ll|i!ii illlll Illlll iill ' 02 iSIIIIII II III Jl5:584 3.000 D Gid: 33.000d ; [...]... Ddp dn B 16 Khi clo hoa hoan toan mgt ancol A thu dugc ddn xudt B chira clo Bilt MB MA = 2 01 A la ankan nao sau day? A.CH4 Ddp dn B B C2H6 C C3H8 D C4H10 17 Crackinh 560 lit C4H10 (dktc) xay ra cac phan img C4H,o^CH4+C3H6 (1) C4H,o^C2H6+C2H4 (2) C4H,o -^ H2 + C4H8 (3) Thu dugc 10 10 lit (dktc) hon hgp khi X The tich C4Hio(dktc) chua phan iing la A 11 0 lit B 55 lit C 16 5 lit D 80 lit Ddp dn A 18 Trong... hai muoi la A 0 ,10 mol B 0, 01 mol C 0,05 mol D 0,5 mol Ddp dn B 16 Hoa tan hoan toan 4 gam hon hgp MCO3 va RCO3 vao dung dich HCl thdy thoat ra V lit khi (dktc) Dung dich thu dugc dem co can thu dugc 5 ,1 gam muoi khan V co gia tri la A 1 ,12 lit Ddp dn B 14 B 2,24 lit C 3,36 lit D 4,48 lit 17 Tac nhan chu yeu gay mua axit la A SO2 va NO2 B CH4 va NH3 C CO va CH4 D CO va CO2 Ddp dn A 18 Phan irng nao... dugc 12 gam ket tiia Khi di ra khoi dung dich phan img vira dii vai 16 gam brom va con lai khi Z Dot chay hoan toan khi Z thu dugc 2,24 lit khi CO2 (a dktc) va 4,5 gam nuac Gia tri ciia V bang A 5,60 B 13 ,44 C 11 ,2 D 8,96 Ddp dn C 4 Hon hgp X co ti khoi so vai H2 la 21, 2 gom propan, propen va propin Khi dot chay hoan toan 0 ,1 mol X, tong khoi lugng cua CO2 va H2O thu dugc la A 20,40 gam B 18 ,96 gam C 16 ,80... but-l-en D xiclobutan, cis-but-2-en, but-l-en, but-l-in Ddp dn C 10 Dun hdn hgp gdm 0 ,1 mol C2H2 va 0 ,1 mol H2 vdi chat xiic tac thich hgp thu dugc hdn hgp X ddt hoan toan X thu dugc: A 0,2 mol CO2 va 0,2 mol H2O B 0 ,1 mol CO2 va 0 ,1 mol H20" C 0 ,15 mol CO2 va0 ,15 mol H2O D 0,2 mol CO2 va 0,3 mol H2O Ddp dn A 23 11 Mdt hdn hgp gdm C2H2 va H2 co V = 13 ,44 lit (dktc) Cho hon hgp di qua Ni nung nong, phan iing... lit, V2=8,96 lit B Vi=l ,12 lit, V2 =12 , 32 lit C V,=2,24 lit, V2=l 1, 2 lit D V,=l 1, 2 lit, V2=2,24 lit Ddp dn C 12 Cho hdn hgp X gdm 0,02 mol C2H2 va 0,03mol H2 di qua bdt Ni, t" Ddn san pham tir tir qua dung dich brom du, co 0,02 mol hon hgp khi Z di ra khdi binh Ti khdi cua Z ddi vai hidro bang 4,5 Khdi lugng binh brom tang: A 0,4 gam B 0,58 gam C 0,62 gam D 0,76 gam Ddp dn A 13 Cho hon hgp propen va... 7,84 lit CO2 (dktc) va 8 ,1 gam H2O Tong so mol hai hidrocacbon dem dot la A 0 ,1 mol B 0,05 mol C 0,2 mol D 0 ,15 mol Ddp dn A 10 Crackinh 20 lit butan thu dugc 36 lit h6n hgp khi g6m C4H10, C2H4, C2H6, C3H6, CH4 (cac khi do a cimg dilu kien) theo 2 phuang trinh hoa hgc C4H10 -» C2H4 + C2H6 C4H,o ^ CH4 + C3H6 Hieu suat qua trinh crac kinh la: A 60% B 70% C 80% D 90% Ddp dn C 11 Hidrocacbon X tac dung... metyltoluen D.p- metyUoluen Ddp dn D 11 Clo hda toluen bang clo cd mat anh sang thu dugc san pham nao dudd day? A Benzylclorua B o- clotoluen C m- clo toluen Ddp dn A D p - clotoluen 12 San pham chinh cua phan ung hidro hda benzen bang H2, xiic tac Ni dudi ap sudt 10 atm, 15 00°C la chdt nao sau day? A Xiclohexadien- 1, 3 B Xiclohexen C Xiclohexan D Hexan Ddp dn C 13 De dieu che m-clonitrobenzen tir benzen... m la A 16 ,20 B 6,48 C 8 ,10 D 10 ,12 Ddp dn B Cho 0 ,1 mol andehit X tac dung vdi lugng du AgN03 trong dung djch NH3, dun ndng thu dugc 43,2 gam Ag Hidro hoa X thu dugc Y, biet 0 ,1 mol Y phan img vira du vdi 4,6 gam Na Cdng thirc cau tao thu ggn cua X la A CH3CHO B HCHO C CH3CH(0H)CH0 D OHC-CHO Ddp dn D Cho 2,9 gam mdt andehit phan iing hoan toan vdi lugng du AgN03 trong dung dich NH3 thu dugc 21, 6 gam... vdi 500 ml dung dich gdm KOH 0 ,12 M va NaOH 0 ,12 M Cd can dung dich thu dugc 8,28 gam hdn hgp chat ran khan Cdng thirc phan tir ciia X la A C2H5COOH Ddp dn B B CH3COOH C HCOOH D C3H7COOH 18 Oxi hoa 1, 2 gam CH3OH bang CuO nung ndng, sau mdt thdi gian thu dugc hon hop san phdm X (gdm HCHO, H2O va CH3OH du) Cho toan bd X tac dung vdi lugng du AgN03 trong dung dich NH3, dugc 12 , 96 gam Ag Hieu suat cua phan... A 18 Butan C4H10 co the co cac dang dong phan nao sau day? A Dong phan cau tao ve nhom chirc B Dong phan cau tao ve mach cacbon C Dong phan cau tao ve vi tri nhom chirc D Dong phan hinh hgc Ddp dn B 19 Phan iing cua /err-butylbromua vai H2O chay theo ca che nao, biet mgt so dir lieu thuc nghiem sau day: (CH3)3CBr + H2O -> (CH3)3COH + HBr Thi nghiem [(CH3)3CBr] [H2O] Toe do tuang doi 1 0, 01 0, 01 1 2