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C 04 01 phan ung oxi hoa khu 1

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electron 0 0 VD1: Cl2 , N2 , Cu, Fe 2O2, 2 Na2O2) 2 VD2: CuO, H NO3 , H2 S O4 , H2 O VD3: = – Trong NH3: x + 3.(+1) = x = –3 – Trong HNO3: (+1) + x + 3.(-2) = x = +5 HNO3 VD4: +, – VD5: Ca2+, Cl– x =+5 2(SO4)3 21 – 2.1e +2 + CuO H2 trình oxi hóa +2e +1 Cu + H2O H2 oxi hóa cho – O 2, NH3, N2O, NO, NO2, NH4NO3 2S, SO2, S, H2SO4, Na2SO4 4, KMnO4, K2Cr2O7 – , Chú ý 3O2 ↽ ⇀ 2O3 SO42–, NH4+, PO43– (1) 2SO2 + O2 SO3 (2) Fe2O3 + CO 2FeO + CO2 (3) 2H2S + SO2 3S + 2H2O (4) MnO2 + 4HCl MnCl2 + Cl2 + H2O (5) 2H2O2 2H2O + O2 (6) 2KClO3 2KCl + 3O2 (7) P2O5 + 3H2O 2H3PO4 (8) KOH + CO2 KHCO3 (9) Fe + 4HNO3 Fe(NO3)3 + NO + H2O (10) 2Al + Fe2O3 Al2O3 + Fe (A) (B) (C) (D) 08): (1) Ca(OH)2 + Cl2 CaOCl2 + H2O (2) 2H2S + SO2 3S + 2H2O (3) 2NO2 + 2NaOH NaNO2 + NaNO3 + H2O (4) 4KClO3 (5) O3 to KCl + 3KClO4 O2 + O A) B) (1) 4HCl + MnO2 C) D) + Cl2 + 2H2O + H2 (3) 14HCl + K2Cr2O7 + 3Cl2 + 7H2O + 3H2 (5) 16HCl + 2KMnO4 + 5Cl2 + 8H2O A) (a) 4HCl + PbO2 (b) HCl + NH4HCO3 (c) 2HCl + 2HNO3 A) B) C) D) C) D) + Cl2 + 2H2O 4Cl + CO2 + H2O + Cl2 + 2H2O + H2 B) 3 – – – – VD6: Chú ý 2O3 + H2 Fe + H2O 0 Fe2 O3 + H2 phi kim Fe + H2 O oxi Fe2 6e 2Fe H2 - 2e H2 Chú ý Fe2 6e cách nhân chéo H2 - 2e Fe2O3 + 3H2 2Fe H2 x1 x3 2Fe + 3H2O 41 VD7: + HCl Mn Chú ý KCl + MnCl2 + Cl2 + H2O Mn x 5e 2Cl - 2e x5 Cl2 Cl2 2Mn 10e 2Mn Cl 10 Cl - 10e MnCl2, KCl) – B4: 2KMnO4 + HCl 5Cl2 KCl + 2MnCl2 + 5Cl2 + H2O Cl 2KMnO4 + HCl 2KCl + 2MnCl2 + 5Cl2 + H2O 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + H2O 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + 8H2O VD8: – B1, B2, B3: Al(NO3)3 + N2 + H2O 3 Al 3e x 10 Al 2N - 10e x3 N2 10Al 30e N - 30e 10Al + 36HNO3 10Al 3N2 10Al(NO3)3 + 3N2 + 18H2O KL + HNO3 (H2SO4) KL HNO3 (H2SO4 HNO3 (H2SO4) 2O H2O Chú ý – VD9: Cl+5 -2 to – B1, B2, B3: to K ClO3 K Cl O2 2O 4e O2 x Cl + 6e x2 Cl 6O 12e 3O2 2Cl + 12e 2Cl to 2KClO3 Chú ý KCl + O2 2KCl + 3O2 2, VD10: – B1, B2, B3: Cl2 + KOH to Cl x5 x1 Cl Cl - 5e Cl 5Cl + 5e 3Cl2 + 6KOH Cl + 1e KCl + KClO3 + H2O K Cl + K ClO3 + H2O Cl - 5e t + KOH Br2… o to 5Cl 5KCl + KClO3 + 3H2O 6 6FeSO4 + K2Cr2O7 + 7H2SO4 3Fe2(SO4)3 + Cr2(SO4)3 + K2SO4 + 7H2O (A) K2Cr2O7 FeSO4 (C) H2SO4 FeSO4 (B) K2Cr2O7 H2SO4 (D) FeSO4 K2Cr2O7 a MnO2 + HCl b Cu + H2SO4 c KMnO4 MnCl2 + Cl2 + H2O CuSO4 + SO2 + H2O to d Cl2 + NaOH K2MnO4 + MnO2 + O2 NaCl + NaClO + H2O a Cu + HNO3 Cu(NO3)2 + NO + H2O b Fe + HNO3 Fe(NO3)3 + NO2 + H2O c Mg + HNO3 Mg(NO3)2 + N2O + H2O d Al + HNO3 Al(NO3)3 + NH4NO3 + H2O MgSO4 + S + H2O e Mg + H2SO4 to f Al + H2SO4 to g Mg(NO3)2 h AgNO3 t Al2(SO4)3 + SO2 + H2O MgO + NO2 + O2 o Ag + NO2 + O2 i Cl2 + Ca(OH)2 CaOCl2 + H2O k Br2 + H2O ↽ ⇀ HBr + HBrO l NH4NO3 to N2O + H2O (1) 3I2 + 3H2O HIO3 + 5HI (2) 2HgO 2Hg + O2 (3) 2H2O2 2H2O + O2 (A) (B) (4) NH4NO3 N2O + 2H2O (5) 2KClO3 2KCl + 3O2 (6) 3NO2 + H2O 2HNO3 + NO (C) (D) A 2) A) B) C) D) B (A) 10 cFe(NO3)3 + dNO + eH2O (B) 14 (C) 16 (D) 18 C H2O2 + KMnO4 + H2SO4 O2 + K2SO4 + MnSO4 + H2O (A) (B) 10 (C) 12 (D) 15 D K2Cr2O7 + HCl (A) 3/14 CrCl3 + Cl2 + KCl + H2O (B) 4/7 (C) 1/7 (D) 3/7 E Cl2 + KOH (A) : F KCl + KClO3 + H2O (B) : + 6KOH (C) : to (D) : 5KCl + KClO3 + 3H2O (A (C (B (D G NH4NO2 (A) (B) to N2 + H2O (C) 10 (D) 11 Câu Câu D C A A D B C A C B A D D A E B F B G A –3 +1 +2 +4 –3 +5 a N2, NH3, N2O, NO, NO2, NH4NO3 +1 –2 +4 –2 +1 +6 –2 +1 +6 –2 b H2S, SO2, S, H2SO4, Na2SO4 +1 –1 +1 +7 –2 +1 +7 –2 +1 +6 –2 c NaCl, HClO4, KMnO4, K2Cr2O7 +3 –2 +6 –2 –3 +1 +5 –2 d NO2–, SO42–, NH4+, PO43– a MnO2 + Cl2 + H2O b Cu + 2H2SO4 c 2KMnO4 to + SO2 + 2H2O K2MnO4 + MnO2 + O2 d Cl2 2O a 3Cu + 8HNO3 3)2 b Fe + 6HNO3 3)3 + 2NO + 4H2O + 3NO2 + 3H2O c 4Mg + 10HNO3 3)2 d 8Al + 30HNO3 3)3 + N2O + 5H2O + 3NH4NO3 + 9H2O e 3Mg + 4H2SO4 to f 2Al + 6H2SO4 to g 2Mg(NO3)2 h 2AgNO3 i to Cl2 + Ca(OH)2 + S + 4H2O Al2(SO4)3 + 3SO2 + 6H2O 2MgO + 4NO2 + O2 2Ag + 2NO2 + O2 + H2O k Br2 + H2 l NH4NO3 to N2O + 2H2O

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