Đề ôn thi đại học môn Hóa số 16

Trang 1/6 - 899 SỞ GD&ĐT BẮC NINH TRƯỜNG THPT CHUYÊN BẮC NINH Tổ: Hóa học (Đề thi gốm 06 trang) ĐỀ THI THI THỬ ĐẠI HỌC LẦN 3 NĂM 2014 MÔN: HÓA HỌC Thời gian làm bài: 90 phút; (60 câu trắc nghiệm) (Ngày 03/03/2014) Mã đề thi 899 Họ, tên thí sinh: Số báo danh:  H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Ni = 58,7; Cu = 64; Zn = 65; Br = 80; Ag = 108; Sn = 119; Ba = 137; Pb = 207. I. PHẦN CHUNG CHO TẤT CẢ THÍ SINH (40 câu, từ câu 1 đến câu 40) Câu 1:  6 H 10 O 5  X + 2NaOH  Ct 0 2Y + H 2 O; Y + HCl   Z + NaCl   2 ? A. 0,15 mol. B. 0,075 mol. C. 0,1 mol. D. 0,2 mol. Câu 2: sai  A.   B.  C.  D.  Câu 3:  -  2  -    A. C 2 H 4  2 H 2 B. C 3 H 6  3 H 4 C. C 4 H 8  4 H 6 D. C 3 H 6  4 H 6 Câu 4:       2 O) sau: H 2 N-CH 2 -COOH; HOOC-CH 2 -CH 2 -CH(NH 2 )- COOH;H 2 N-CH 2 -COOK; HCOOH; ClH 3 N-CH 2 - A. 4 B. 3 C. 6 D. 5 Câu 5:   A. MgCO 3 + CO 2 + H 2 O  Mg(HCO 3 ) 2 B. Ca(HCO 3 )  CaCO 3 + CO 2 + H 2 O C. CaCO 3 + CO 2 + H 2 O  Ca(HCO 3 ) 2 D. CaO + CO 2  CaCO 3 Câu 6:  A.  B.  C.  D.  Câu 7:  C 4 H 6 O 2 C 4 H 6 O 4 C 7 H 12 O 4 C 10 H 18 O 4 X 2 + Y 1 + Y 2  1  ; Y 2 không  A. X 1  B. X 3  C. X 2  D. X 4  Câu 8:   A.  B.  C.  D.  O 2 , xt +Y 1 , xt H 2 SO 4 +Y 2 , xt H 2 SO 4 +H 2 O, xt H + X 1 X 2 X 3 X 4 Trang 2/6 - 899 Câu 9:  Ni 2+   dm 2  3 . A. 0,066cm. B. 0,033cm. C. 0,066mm. D. 0,033mm. Câu 10:  2 O 3 , Fe 3 O 4   2 SO 4   2   A.  B.  C.  D.  Câu 11:  2 , Cu(OH) 2 , Ni(OH) 2 , Zn(OH) 2 , Al(OH) 3   3  A. 3. B. 5. C. 4. D. 2. Câu 12:  - A. 6 B. 7 C. 8 D. 9 Câu 13:  A.  3  2 SO 4 - B. -  C.  D. -bromanilin.  A. 2. B. 3. C. 5. D. 4. Câu 14:  2 SO 4   4  A.  B.  C.  2  D.  Câu 15:   -amino-4- -Val-  A. 7 B. 9 C. 6 D. 8 Câu 16: Este X no,   mch       bc.   0,1 mol X          dung  c  trong  cha 0,22 mol Ca(OH) 2 th vc k ph X  dung dch NaOH thu c 2 ch hu       t  nhau.    ng c oxi trong  A. 37,21%. B. 53,33%. C. 43,24%. D. 36,36%. Câu 17:   2 , MgCl 2 , Na 2 SO 4 , MgSO 4 , CaSO 4 .  A. dd CaCl 2 ; dd (NH 4 ) 2 CO 3 . B. dd (NH 4 ) 2 CO 3 ; dd BaCl 2 . C. dd BaCl 2 ; dd Na 2 CO 3 . D. dd BaCl 2 ; dd (NH 4 ) 2 CO 3 . Câu 18: Cho 400 g 3   3   A. 0,27M. B. 1,2M. C. 0,7M. D. 0,13M. Câu 19:  + ; 0,5 mol Ca 2+ ; 0,3 mol Mg 2+ ; 1,5 mol HCO 3 - ; 0,4 mol Cl -  A. Na 2 CO 3 . B. HCl. C. Ca(OH) 2 . D. Na 2 SO 4 . Câu 20:  H 2 N-CH(CH 3 )-CO-NH-CH 2 -CO-NH-CH 2 -CH 2 -CO-NH-CH(C 6 H 5 )-CO-NH-CH(CH 3 )-COOH.  A.  Trang 3/6 - 899 B.  C.  D.   -amino ax Câu 21:   3 /NH 3  0,35 gam H 2 .  A. 8,66 gam. B. 4,95 gam. C. 6,93 gam. D. 5,94 gam. Câu 22:  3 O 4   3    A. 268,2gam. B. 368,1gam. C. 423,2gam. D. 266,9gam. Câu 23: t    x gam    hai axit cacboxylic hai ch mch   u m  kt i C=C trong  t thu c V   CO 2   y mol H 2 O. Bi   i      A. 28/55(x-30y) B. V=28/95(x-62y) C. V=28/55(x+30y) D. V=28/95(x+62y) Câu 24:  +  -    +  -   A.  B.  C.  D.  Câu 25:  amoniclorua, ancol benzylic, p-  A. 7 B. 5 C. 6 D. 4 Câu 26:   A.   B.  C.   D.  Câu 27:      3 COOH, CH 2 =CHCOOH, CH 2 =CHOOCCH 3 , CH 2 OH-CH 2 OH, C 2 H 5 OH, HOOC(CH 2 ) 4   A.  B.  C.  D.  Câu 28:  3 ) 2 , Fe(NO 3 ) 3 , Mg(NO 3 ) 2    A. 12,88 gam. B. 18,68 gam. C. 31,44 gam. D. 23,32 gam. Câu 29:  2 S 2 O 3  2 SO 4   2 S 2 O 3  2    2 S 2 O 3  A. 10 -2  B. 10 -1  C. 2,5.10 -3 ). D. 2,5.10 -2  Câu 30:   A. Cu(OH) 2  B.  3  C. du 3 /NH 3  4 . D. Cu(OH) 2  Trang 4/6 - 899 Câu 31:  : Al, S, O 2 , Cl 2 , SO 2 , Fe 2+ , Cu 2+ , HCl, HNO 3   A. 7. B. 6. C. 5. D. 4. Câu 32:  n H 2n-2 O 2 không  A.  B.  C.  D.   Câu 33: đúng? A.  2 H 5 Br, KOH, C 2 H 5  B.  2 H 5   C.  2 H 5 OH, CH 3 CH 2 CH 2 OH, CH 3 CH 2 CH 2 CH 2  D. Cho HNO 3  Câu 34:  A. NO 2 , CO. B. SO 2 , HCl. C. N 2 O, CO 2 . D. CO 2 , SO 2 . Câu 35:                A. 6 B. 7 C. 8 D. 5 Câu 36:   2  2   3 trong NH 3   A. 64,8g B. 16,2g C. 32,4. D. 21,6g Câu 37:  2  2 CO 3   2   A.  B.  C.  D.  Câu 38:   2  2   A. C 3 H 8 O 2  C 3 H 6 O 2 B. C 3 H 8  3 H 6 O 2 C. C 3 H 8  3 H 2 O 2 D. C 3 H 8 O 2  3 H 4 O 2 Câu 39:  2 SO 4 0,1M; Cu(NO 3 ) 2 0,1M, Fe(NO 3 ) 3 0,1M .  , 0,69 ,    ( ).        A. 20   78,5 gam. B. 20   55,7 gam. C. 25,8   78,5 gam. D. 25,8   55,7 gam. Câu 40:    2  2   2  2  2: A.  B.  C.  D.  II. PHẦN RIÊNG [10 câu] Thí sinh chỉ được làm một trong hai phần (phần A hoặc B) A. Theo chương trình Chuẩn (10 câu, từ câu 41 đến câu 50) Câu 41: H  M gm axit cacboxylic X, ancol Y     mol X  hai   mol  este Z c  ra t X  Y. Cho m ng M      dung dch  0,2 m mu h A. HC 3 H 7 OH. B. HC 3 OH. C. CH 3 COOH  2 H 5 OH. D. CH 3 COOH  3 OH. Trang 5/6 - 899 Câu 42:      2  A. . B. . C. . D. . Câu 43:  2  2 2b   2  2 b   A. 0,2 B. 0,1 C. 0,05 D. 0,8 Câu 44:  A. Hai ion Mg 2+  +   +  2+ B.   C.  2+ , Ca 2+ , Ba 2+ , Cl -  3 -   2 CO 3  D.  3  3  Câu 45:            propanal, isopren, axit metacrylic, phenylamin, m-crezol, cumen, stiren, xiclopropan.   A. 9. B. 10. C. 8. D. 7. Câu 46:  3 H 6 O 3   2  không  A. . B. . C.  D. . Câu 47:  A. Sn + O 2  2 . B. Ag 2 S + O 2  2 C. Fe 2 O 3  3 + 3H 2 O D.  2 + H 2 Câu 48:  45 o   ? A. 0,294. B. 7,440. C. 0,930 . D. 0,744. Câu 49:  4 2- ; 0,1 mol NO 3 - ; 0,08 mol Na + ; 0,05 mol H +  + .   A. 15,62 gam. B. 11,67 gam . C. 12,47 gam. D. 13,17 gam. Câu 50: Cho p ⇌  2    C = 2,25.  M      1                 ? A. 75%. B. 50%. C. 60%. D. 65%. B. Theo chương trình Nâng cao (10 câu, từ câu 51 đến câu 60) Câu 51:  5 H 10   X  C 5 H 9 Br  C 5 H 9 Br 3  C 5 H 12 O 3  Y(C 8 H 12 O 6 ).          3 / NH 3 , t 0 ; Cu(OH) 2 /dd NaOH,t 0 ; NaOH, t 0 ; CH 3 COOH (xt H 2 SO 4  0 ); CH 3 OH (xt H 2 SO 4  0 ); NaHCO 3   ? A. 6. B. 3. C. 4. D. 5. Câu 52: sai? A. Khi cho C 2 H 2 - B. . R   2 -m -- C.  3  D.  +  Trang 6/6 - 899 Câu 53:    2  A. 33,33%. B. 24,23%. C.26,50%. D. 24,30%. Câu 54:  2 CO 3  3  H 2 SO 4  2  2    A. 34,95 gam. B. 66,47 gam. C. 74,35 gam. D. 31,52 gam. Câu 55:  3  ch AgNO 3 /NH 3   A. 21,6. B. 35,95. C. 54,75. D. 40,4. Câu 56:  2  H 2 SO 4   1  1   3  2  A. 2,24. B. 11,2. C. 8,96. D. 1,12. Câu 57:      3 COOCH 2 CH 2 Cl, ClH 3 N-CH 2 COOH, C 6 H 5  HCOOC 6 H 5  6 H 5 COOCH 3 -C 6 H 4 -CH 2  3 CCl 3 , CH 3 COOC(Cl 2 )-CH 3 , HCOOC 6 H 4    A. 7. B. 5. C. 6. D. 4. Câu 58:  2 O 3             A. C 3 H 7 OH. B. C 4 H 9 OH. C. C 5 H 11 OH. D. C 3 H 5 OH. Câu 59:  aF 2  2 SO 4 .  2 .  .  2 SO 4     A. 2. B. 3. C. 4. D. 5. Câu 60:  (1) Na 2 CO 3 + dd FeCl 3  (2) H 2 SO 4  3 (PO 4 ) 2  3 + NaCl (3) ZnS + dd HCl (7) Cl 2 + O 2 (4) Ca 3 (PO 4 ) 2 + H 3 PO 4 (8) Si + dd NaOH  A. 6. B. 7. C. 4. D. 5. HẾT Các thí sinh làm đúng thời gian, không được sử dụng tài liệu gì liên quan tới Hóa học. . BẮC NINH Tổ: Hóa học (Đề thi gốm 06 trang) ĐỀ THI THI THỬ ĐẠI HỌC LẦN 3 NĂM 2014 MÔN: HÓA HỌC Thời gian làm bài: 90 phút; (60 câu trắc nghiệm) (Ngày 03/03/2014) Mã đề thi 899 Họ,.  A. 6. B. 7. C. 4. D. 5. HẾT Các thí sinh làm đúng thời gian, không được sử dụng tài liệu gì liên quan tới Hóa học. . 03/03/2014) Mã đề thi 899 Họ, tên thí sinh: Số báo danh:  H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5;