Volume 03 - Alloy Phase Diagrams Part 10 pdf

(Zn) 100 hP2 P6 3 /mmc Other reported phases LaZn 5 70.1 hP6 P6/mmm La 3 Zn 22 78 tI100 I4 1 /amd LaZn 11 83.9 tI48 I4 1 /amd Li (Lithium) Binary Alloy Phase Diagrams Introduction THIS ARTICLE includes systems where lithium is the first-named element in the binary pair. Additional binary systems that include lithium are provided in the following locations in this Volume: • “Ag-Li (Silver - Lithium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.” • “Al-Li (Aluminum - Lithium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.” • “Au-Li (Gold - Lithium)” in the article “Au (Gold) Binary Alloy Phase Diagrams.” • “Ba-Li (Barium - Lithium)” in the article “Ba (Barium) Binary Alloy Phase Diagrams.” • “Bi-Li (Bismuth - Lithium)” in the article “Bi (Bismuth) Binary Alloy Phase Diagrams.” • “Ca-Li (Calcium - Lithium)” in the article “Ca (Calcium) Binary Alloy Phase Diagrams.” • “Cd-Li (Cadmium - Lithium)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams.” • “Cu-Li (Copper - Lithium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.” • “Ga-Li (Gallium - Lithium)” in the article “Ga (Gallium) Binary Alloy Phase Diagrams.” • “Ge-Li (Germanium - Lithium)” in the article “Ge (Germanium) Binary Alloy Phase Diagrams.” • “Hg-Li (Mercury - Lithium)” in the article “Hg (Mercury) Binary Alloy Phase Diagrams.” • “In-Li (Indium - Lithium)” in the article “In (Indium) Binary Alloy Phase Diagrams.” Li-Mg (Lithium - Magnesium) A.A. Nayeb-Hashemi, A.D. Pelton, and J.B. Clark, 1988 Li-Mg phase diagram Li-Mg crystallographic data Phase Composition, wt% Li Pearson symbol Space group (Mg) 0 to 6 hP2 P6 3 /mmc ( Li) 8.5 to 100 cI2 Im m ( Li) (a) 100 hP2 P6 3 /mmc Cold worked stabilized phase (b) ( Li) 100 cF4 Fm m (a) Below -193 °C. (b) Nonequilibrium Li-Na (Lithium - Sodium) C.W. Bale, 1989 Li-Na phase diagram Li-Na crystallographic data Phase Composition, wt% Na Pearson symbol Space group ( Li) 0 cI2 Im m ( Li) (a) 0 hP2 P6 3 /mmc ( Na) 100 cI2 Im m ( Na) 100 hP2 P6 3 /mmc (a) Below -193 °C Li-Pb (Lithium - Lead) From [Hansen] 6 Li-Pb phase diagram Li-Pb crystallographic data Phase Composition, wt% Pb Pearson symbol Space group ( Li) 0 cI2 Im m ( Li) (a) 0 hP2 P6 3 /mmc Li 4 Pb 88 . . . . . . Li 10 Pb 3 89.7 to 90.2 cP52 P 3m Li 3 Pb 91 cF16 Fm m Li 5 Pb 2 92.3 . . . . . . LiPb <96 to 96.8 cP2 Pm m LiPb <96 to 96.8 hR2 R m (Pb) 99.9 to 100 cF4 Fm m Other reported phases Li 22 Pb 5 87.1 cF432 F23 Li 7 Pb 2 89.5 hP9 P321 Li 8 Pb 3 91.8 mC22 C2/m (a) Below -193 °C Reference cited in this section 6. [Hansen]: M. Hansen and K. Anderko, Constitution of Binary Alloys, McGraw- Hill, New York or General Electric Co., Business Growth Services, Schenectady, New York (1958). Li-Pd (Lithium - Palladium) J. Sangster and A.D. Pelton, 1992 Li-Pd phase diagram Li-Pd crystallographic data Phase Composition, wt% Pd Pearson symbol Space group ( Li) 0 cI2 Im m ( Li) (a) 0 hP2 P6 3 /mmc Li 5 Pd (b) 75.5 (b) cF* . . . Li 15 Pd 4 80.4 cI76 I 3d Li 3 Pd 84 cF16 Fm m Li 2 Pd 88.4 hP3 P6/mmm Li 3 Pd 2 90.9 to 91.5 cP2(?) Pm m LiPd 92.7 to 94.3 hP2 P LiPd 2 94 to 98 mP8 P2/m LiPd 7 99.1 cF32 Fm m (Pd) 99.7 to 100 cF4 Fm m (a) Below -193 °C. (b) Approximate composition Li-S (Lithium - Sulfur) H. Okamoto, unpublished Li-S phase diagram Li-S crystallographic data Phase Composition, wt% S Pearson symbol Space group ( Li) 0 cI2 Im m ( Li) (a) 0 hP2 P6 3 /mmc Li 2 S 69.8 cF12 Fm m ( S) 100 mP48 P2 1 /a ( S) 100 oF128 Fddd (a) Below -193 °C Li-Se (Lithium - Selenium) P.T. Cunningham, S.A. Johnson, and E.J. Cairns, 1971 Li-Se phase diagram Li-Se crystallographic data Phase Composition, wt% Se Pearson symbol Space group ( Li) 0 cI2 Im m ( Li) 0 hP2 P6 3 /mmc Li 2 Se 85.0 cF12 Fm m (Se) 100 hP3 P3 1 21 (a) Below -193 °C Li-Si (Lithium - Silicon) H. Okamoto, 1990 Li-Si phase diagram Li-Si crystallographic data Phase Composition, wt% Si Pearson symbol Space group ( Li) 0 cI2 Fm m ( Li) (a) 0 hP2 P6 3 /mmc Li 22 Si 5 47.9 cF432 F23 Li 13 Si 4 55.4 oP24 Pbam Li 7 Si 3 63 hR7 R m Li 12 Si 7 70.2 oP152 Pnma (Si) 100 cF8 Fd m Questionable phases Li 4 Si 50 oP250 ? Li 7 Si 2 53.6 oP36 Pbam Li 10 Si 3 54.9 cF416 ? Li 2 Si 66.9 mC12 C2/m Li 13 Si 7 69 oP160 Pnma (a) Below -193 °C Li-Sn (Lithium - Tin) From [Moffatt] 11 Li-Sn phase diagram Li-Sn crystallographic data Phase Composition, Pearson Space [...]... Binary Alloy Phase Diagrams. ” “Ba-Mg (Barium - Magnesium)” in the article “Ba (Barium) Binary Alloy Phase Diagrams. ” “Bi-Mg (Bismuth - Magnesium)” in the article “Bi (Bismuth) Binary Alloy Phase Diagrams. ” “Ca-Mg (Calcium - Magnesium)” in the article “Ca (Calcium) Binary Alloy Phase Diagrams. ” “Cd-Mg (Cadmium - Magnesium)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams. ” “Ce-Mg (Cerium - Magnesium)”... (Gold) Binary Alloy Phase Diagrams. ” “B-Mn (Boron - Manganese)” in the article “B (Boron) Binary Alloy Phase Diagrams. ” “Bi-Mn (Bismuth - Manganese)” in the article “Bi (Bismuth) Binary Alloy Phase Diagrams. ” “C-Mn (Carbon - Manganese)” in the article “C (Carbon) Binary Alloy Phase Diagrams. ” “Ce-Mn (Cerium - Manganese)” in the article “Ce (Cerium) Binary Alloy Phase Diagrams. ” “Co-Mn (Cobalt - Manganese)”... Binary Alloy Phase Diagrams. ” “Cr-Mn (Chromium - Manganese)” in the article “Cr (Chromium) Binary Alloy Phase Diagrams. ” “Cu-Mn (Copper - Manganese)” in the article “Cu (Copper) Binary Alloy Phase Diagrams. ” “Dy-Mn (Dysprosium - Manganese)” in the article “Dy (Dysprosium) Binary Alloy Phase Diagrams. ” “Er-Mn (Erbium - Manganese)” in the article “Er (Erbium) Binary Alloy Phase Diagrams. ” “Fe-Mn (Iron - Manganese)”... Binary Alloy Phase Diagrams. ” “Cu-Mg (Copper - Magnesium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams. ” “Eu-Mg (Europium - Magnesium)” in the article “Eu (Europium) Binary Alloy Phase Diagrams. ” “Ga-Mg (Gallium - Magnesium)” in the article “Ga (Gallium) Binary Alloy Phase Diagrams. ” “Gd-Mg (Gadolinium - Magnesium)” in the article “Gd (Gadolinium) Binary Alloy Phase Diagrams. ” “Ge-Mg (Germanium... Binary Alloy Phase Diagrams. ” “Ga-Mn (Gallium - Manganese)” in the article “Ga (Gallium) Binary Alloy Phase Diagrams. ” “Gd-Mn (Gadolinium - Manganese)” in the article “Gd (Gadolinium) Binary Alloy Phase Diagrams. ” “Ge-Mn (Germanium - Manganese)” in the article “Ge (Germanium) Binary Alloy Phase Diagrams. ”> “Hf-Mn (Hafnium - Manganese)” in the article “Hf (Hafnium) Binary Alloy Phase Diagrams. ” “Ho-Mn... - Manganese)” in the article “Ho (Holmium) Binary Alloy Phase Diagrams. ” “In-Mn (Indium - Manganese)” in the article “In (Indium) Binary Alloy Phase Diagrams. ” “La-Mn (Lanthanum - Manganese)” in the article “La (Lanthanum) Binary Alloy Phase Diagrams. ” “Mg-Mn (Magnesium - Manganese)” in the article “Mg (Magnesium) Binary Alloy Phase Diagrams. ” Mn-Mo (Manganese - Molybdenum) From [Molybdenum] 12 Mn-Mo... Diagrams. ” “Ge-Mg (Germanium - Magnesium)” in the article “Ge (Germanium) Binary Alloy Phase Diagrams. ” “Hg-Mg (Mercury - Magnesium)” in the article “Hg (Mercury) Binary Alloy Phase Diagrams. ” “In-Mg (Indium - Magnesium)” in the article “In (Indium) Binary Alloy Phase Diagrams. ” “La-Mg (Lanthanum - Magnesium)” in the article “La (Lanthanum) Binary Alloy Phase Diagrams. ” “Li-Mg (Lithium - Magnesium)” in the... (Lithium) Binary Alloy Phase Diagrams. ” Mg-Mn (Magnesium - Manganese) A.A Nayeb-Hashemi and J.B Clark, 1988 Mg-Mn phase diagram Mg-Mn crystallographic data Phase Composition, wt% Mn Pearson symbol Space group (Mg) 0 to 2.2 hP2 P63/mmc ( Mn) 100 cI58 I 3m ( Mn) 100 cP20 P4132 ( Mn) 100 cF4 Fm m ( Mn) 100 cI2 Im m Mg-Ni (Magnesium - Nickel) A.A Nayeb-Hashemi and J.B Clark, 1991 Mg-Ni phase diagram Mg-Ni crystallographic... to 100 ( Sm) cI2 Im m ( Sm) 100 hP2 P63/mmc ( 100 hR3 R m Sm) Mg-Sn (Magnesium - Tin) A.A Nayeb-Hashemi and J.B Clark, 1988 Mg-Sn phase diagram Mg-Sn crystallographic data Phase Composition, wt% Sn Pearson symbol Space group (Mg) 0 to 14.48 hP2 P63/mmc Mg2Sn 70.9 cF12 Fm m ( Sn) 100 tI4 I41/amd ( Sn) 100 cF8 Fd m High-pressure phases Mg2Sn 70.9 h** SnII 100 tI2 SnIII 100 cI2 Mg-Sr (Magnesium - Strontium)... magnesium is the first-named element in the binary pair Additional binary systems that include magnesium are provided in the following locations in this Volume: • • • • • • • • • • • • • • • • • “Ag-Mg (Silver - Magnesium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams. ” “Al-Mg (Aluminum - Magnesium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams. ” “Au-Mg (Gold - Magnesium)” in the . Binary Alloy Phase Diagrams. ” • “Al-Li (Aluminum - Lithium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams. ” • “Au-Li (Gold - Lithium)” in the article “Au (Gold) Binary Alloy Phase Diagrams. ”. Alloy Phase Diagrams. ” • “Ga-Li (Gallium - Lithium)” in the article “Ga (Gallium) Binary Alloy Phase Diagrams. ” • “Ge-Li (Germanium - Lithium)” in the article “Ge (Germanium) Binary Alloy Phase. “Au-Mg (Gold - Magnesium)” in the article “Au (Gold) Binary Alloy Phase Diagrams. ” • “Ba-Mg (Barium - Magnesium)” in the article “Ba (Barium) Binary Alloy Phase Diagrams. ” • “Bi-Mg (Bismuth -