Elements that share the same period have the same num- ber of electron shells. Common Elements Some elements are frequently encountered in biologi- cally important molecules and everyday life. Below you will find a list of common elements, their symbols, and common uses. H—Hydrogen: involved in the nuclear process that produces energy in the sun He—Helium: used to make balloons fly C—Carbon: found in all living organisms; pure car- bon exists as graphite and diamonds N—Nitrogen: used as a coolant to rapidly freeze food O—Oxygen: essential for respiration (breathing) and combustion (burning) Si—Silicon: used in making transistors and solar cells Cl—Chlorine: used as a disinfectant in pools and as a cleaning agent in bleach Ca—Calcium: necessary for bone formation Fe—Iron: used as a building material; carries oxygen in the blood Cu—Copper: a U.S. penny is made of copper; good conductor of electricity I—Iodine: lack in the diet results in an enlarged thy- roid gland, or goiter Hg—Mercury: used in thermometers; ingestion can cause brain damage and poisoning Pb—Lead: used for X-ray shielding in a dentist office Some elements exist in diatomic form (two atoms of such an element are bonded), and are technically mole- cules. These elements include hydrogen (H 2 ), nitrogen (N 2 ), oxygen (O 2 ), fluorine (F 2 ), chlorine (Cl 2 ), bromine (Br 2 ), and iodine (I 2 ). Structure and Properties of Matter Matter has weight and takes up space. The building blocks of matter are atoms and molecules. Matter can interact with other matter and with energy. These inter- actions form the basis of chemical and physical reactions. Molecules Molecules are composed of two or more atoms. Atoms are held together in molecules by chemical bonds. Chemical bonds can be ionic or covalent. Ionic bonds form when one atom donates one or more electrons to another. Covalent bonds form when electrons are shared between atoms. The mass of a molecule can be calculated by adding the masses of the atoms of which it is com- posed. The number of atoms of a given element in a molecule is designated in a chemical formula by a sub- script after the symbol for that element. For example, the glucose (blood sugar) molecule is represented as C 6 H 12 O 6. This formula tells you that the glucose mole- cule is contains six carbon atoms (C), twelve hydrogen atoms (H), and six oxygen atoms (O). Organic and Inorganic Molecules Molecules are often classified as organic or inorganic. Organic molecules are those that contain both carbon and hydrogen. Examples of organic compounds are methane (natural gas, CH 4 ), glycine (an amino acid, NH 2 CH 2 COOH), and ethanol (an alcohol, C 2 H 5 OH). Inorganic compounds include sodium chloride (table salt, NaCl), carbon dioxide (CO 2 ), and water (H 2 O). States of Matter Matter is held together by intermolecular forces—forces between different molecules. Three common states of matter are solid, liquid, and gas. Matter is an atom, a molecule (compound), or a mixture. Examples of mat- ter in solid form are diamonds (carbon atoms), ice (water molecules), and metal alloys (mixtures of differ- ent metals). A solid has a fixed shape and a fixed volume. The molecules in a solid have a regular, ordered arrange- ment and vibrate in place, but are unable to move far. Examples of matter in liquid form are mercury (mer- cury atoms), vinegar (molecules of acetic acid), and per- fume (a mixture of liquids made of different molecules). Liquids have a fixed volume, but take the shape of the container they are in. Liquids flow, and their density (mass per unit volume) is usually lower than the density of solids. The molecules in a liquid are not ordered and can move by sliding past one another through a process called diffusion. – PHYSICAL SCIENCE– 225 Examples of matter in gaseous form include helium gas used in balloons (helium atoms), water vapor (mol- ecules of water), and air (mixture of different molecules including nitrogen, oxygen, carbon dioxide, and water). Gases take the shape and volume of their container. They can be compressed when pressure is applied. The mole- cules in gases are completely disordered and move very quickly. Gas density is much lower than the density of a liquid. Phase Changes Change of phase involves the transition from one state of matter into another. Freezing water to make ice for cool- ing your drink, condensation of water vapor as morning dew, and sublimation of dry ice (CO 2 ) are examples of phase change. A phase change is a physical process. No chemical bonds are formed or broken. Only the inter- molecular (physical) forces are affected. Freezing is the process of changing a liquid into a solid by removing heat. The opposite process whereby heat energy is added to the solid until it changes into a liquid is called melting. Boiling is the change of phase from a liquid to a gas and also requires the input of energy. Con- densation is the change from gas to liquid. Some sub- stances sublime—change directly from the solid phase to the gas phase without forming the liquid state first. Car- bon dioxide is such a substance. Solid carbon dioxide, called dry ice, evaporates into the gas phase when heated. When gas changes directly into a solid, the process is called deposition. Phase changes between the three states of matter The stronger the intermolecular forces are, the easier it is for the molecule to exist in one of the condensed states (liquid or gas). Molecules in which intermolecular forces are strong tend to have high boiling points, since more energy is needed to turn the molecules into the gaseous state where molecular interactions are low. Compounds and Mixtures A compound is a homogeneous substance composed of two or more elements, united chemically. Examples of compounds include carbon dioxide (a product of respi- ration), sucrose (table sugar), seratonin (a human brain chemical), and acetic acid (a component of vinegar). In each of these compounds, there is more than one type of atom, chemically bonded to other atoms in definite pro- portion. Compounds are made of molecules. A mixture is a physical combination of its compo- nents. In a homogeneous mixture, the components can’t be visually separated. Homogeneous mixtures also have the same composition (ratio of components) through- out their volume. An example is a mixture of a small amount of salt in water. A uniform mixture is often called a solution. In a solution, one substance (solute) is dissolved in another (solvent). In the salt and water mix- ture, the salt is the solute, and the water is the solvent. In a heterogeneous mixture, the components can often be visually identified, and the composition may vary from one point of the mixture to another. A collection of dimes and pennies is a heterogeneous mixture. A mix- ture of sugar and flour is also heterogeneous. While both components (sugar and flour) are white, the sugar crys- tals are larger and can be identified. Miscibility is the term used to describe the ability of two substances to form a homogeneous mixture. Water and alcohol are miscible. They can be mixed in such a way that the mixture will be uniform throughout the sample. At each point, it will look, smell, and taste the same. Oil and water are not miscible. A mixture of these two substances is not homogeneous, since the oil floats on water. In a mixture of oil and water, two layers con- taining the two components are clearly visible. Each layer looks, smells, tastes, and behaves differently. Gas Liquid Vaporization Solid Sublimation Deposition Condensation Melting Freezing – PHYSICAL SCIENCE– 226 Chemical Reactions Removing stains from clothes, digesting food, and burning wood in a fireplace are all examples of chemical reactions. Chemical reactions involve changes in the chemical arrangement of atoms. In a chemical reaction, the atoms of reactants combine, recombine, or dissociate to form products. The number of atoms of a particular element remains the same before and after a chemical reaction. The total mass is also preserved. Similarly, energy is never created or destroyed by a chemical reaction. If chemical bonds are broken, energy from those bonds can be liberated into the surroundings as heat. However, this liberation of energy does not consti- tute creation, since the energy only changes form—from chemical to heat. Writing Chemical Reactions A chemical reaction can be represented by a chemical equation; the reactants are written on the left side and the products on the right side of an arrow, indicating the direction in which the reaction proceeds. The chemical equation below represents the reaction of glucose (C 6 H 12 O 6 ) with oxygen (O 2 ) to form carbon dioxide (CO 2 ) and water (H 2 O). Your body runs this reaction all the time to obtain energy. (C 6 H 12 O 6 ) + 6 (O 2 ) → 6 (CO 2 ) + 6 (H 2 O) The numbers in front of the molecular formulas indi- cate the proportion in which the molecules react. No number in front of the molecule means that one mole- cule of that substance is reacting. In the reaction above, one molecule of glucose is reacting with six molecules of oxygen to form six molecules of carbon dioxide and six molecules of water. In reality, there are many molecules of each of the substances and the reaction tells you in what proportion the molecules react. So if you had ten molecules of glucose react with 60 molecules of oxygen, you would obtain 60 molecules of carbon dioxide and 60 molecules of water. In many ways, chemical equations are like food recipes. 2 Bread + 1 Cheese + 2 Tomato → Sandwich With two slices of bread, one slice of cheese, and two slices of tomato, you can make one sandwich. If you had six slices of bread, three slices of cheese, and six slices of tomato, you could make three sandwiches. The same principles of proportion apply in chemical reactions. Heat of Reaction (Enthalpy) Breaking molecular bonds releases energy stored in those bonds. The energy is released in the form of heat. Simi- larly, forming new bonds requires an input of energy. Therefore, a chemical reaction will either absorb or give off heat, depending on how many and what kind of bonds are broken and made as a result of that reaction. A reaction that absorbs energy is called endothermic. A container in which an endothermic reaction takes place gets cold, because the heat of the container is absorbed by the reaction. A reaction that gives off energy is called exothermic. Burning gasoline is an exothermic reaction—it gives off energy. Increase in Disorder (Entropy) Disorder, or entropy, is the lack of regularity in a system. The more disordered a system, the larger its entropy. Dis- order is much easier to come by than order. Imagine that you have 100 blue beads in one hand and 100 red beads in the other. Now place all of them in a cup and shake. What are the chances that you can pick out 100 beads in each hand so that they are separated by color, without looking? Not very likely! Entropy and chaos win. There is only one arrangement that leads to the ordered sepa- ration of beads (100 blue in one hand, 100 red in the other), and many arrangements that lead to mixed-up beads (33 blue, 67 red in one hand, 33 red and 67 blue in the other; 40 blue, 60 red in one hand, 60 blue, 40 red in the other . . .). The same is true of atoms. Sometimes, arrangement and order can be achieved. Atoms and mol- ecules in solids, such as snowflakes, have very regular, ordered arrangements. But given enough time (and tem- perature), the snow melts, forming less ordered liquid water. So, although reactions that lead to a more ordered state are possible, the reactions that lead to disorder are more likely. The overall effect is that the disorder in the universe keeps increasing. – PHYSICAL SCIENCE– 227 Catalysts Often, a reaction needs help getting started. Such help can come from a catalyst. A catalyst is a substance or form of energy that gets a reaction going, without being changed or used up in the reaction. A catalyst acts by lowering what is called the activation energy of a reaction. The activation energy is often illustrated as a hill sepa- rating two valleys that needs to be crossed in order to get from one valley to the other (one valley representing the reactants, and the other the products). The catalyst acts by making the hill lower. A catalyst acts by lowering the activation energy barrier (Ea) to product formation. In the diagram, the top hill represents a high activation energy. The catalyst acts to make the hill smaller, so that the bottom hill represents the activation energy in the presence of a catalyst. Light is a catalyst for the photosynthesis reaction. In living systems, reactions are catalyzed by special protein molecules called enzymes. Reversible and Irreversible Reactions Some reactions can proceed in both directions—reac- tants can form products, which can turn back into reactants. These reactions are called reversible. Other reactions are irreversible, meaning that reactants can form products, but once the products form, they can not be turned back into reactants. While wood can burn (react with oxygen) to produce heat, water, and carbon dioxide, these products are unable to react to form wood. You can better understand reversibility if you look at the activation energy diagram in the previous section. The hill that needs to be crossed by reactants to form prod- ucts is much lower than the hill that needs to be crossed by products to form reactants. Most likely, such a reac- tion will be irreversible. Now look at the diagram below. The hill that needs to be crossed is almost the same for reactants and for products, so the crossing could take place from both sides—the reaction would be reversible. The activation energies (Ea) for the forward reaction (reac- tants forming products) and for the reverse reaction (prod- ucts forming reactants) are about the same. Such a reaction is reversible. Motions, Forces, and Conservation of Energy A force is a push or a pull. Objects move in response to forces acting on them. When you kick a ball, it rolls. A force is also required to stop motion. The ball stops rolling because of the frictional force. What happens here? First, your body breaks the chemical bonds in the food you have eaten. This supplies your body with energy. You use up some of that energy to kick the ball. You apply a force, and as a result, the ball moves, carry- ing the energy your foot supplied it with. But some of that energy is transferred from the ball to the ground it rolls on in the form of heat, through frictional force. As energy is lost this way, the ball slows down. When all the energy is used up through friction, the ball stops moving. This example illustrates the concept of conservation of energy, as well as Newton’s first law—the Law of Inertia. Law of Inertia The velocity of an object does not change unless a force is applied. For velocity of motion to change, either the speed and/or the direction must change and a net or unbal- anced force must be applied. To summarize, an object at rest (whose speed is zero) remains at rest, unless some force acts on it—a person pushes it, the wind blows it away, gravity pulls it down . . . A moving object contin- ues to move at the same speed in the same direction, unless some force is applied to it to slow it down, speed it up, or change its direction. The amount of speed an object gains (acceleration) or loses (deceleration) is directly proportional to the force applied. The harder reactants products Ea for forward reaction Ea for reverse reaction reactants products Ea with a catalyst Ea without a catalyst – PHYSICAL SCIENCE– 228 you kick the ball, the faster it will move. The mass of the ball will also determine how much it will accelerate. Kick a soccer ball. Now kick a giant ball made of lead with the same force (watch your foot!).Which ball moves faster as a result of an equal kick? These observations constitute Newton’s second law—the Law of Acceleration. Law of Acceleration The acceleration of an object depends on its mass and on the force applied to it. The greater the force, the greater the acceleration. The greater the mass, the lower the acceleration. Or, mathematically, force = mass × acceleration. A good way to learn about the laws of motion is to shoot pool. What happens to billiard balls if you miss and fail to hit any of them? Nothing. They stay at rest. What happens when you hit the cue ball with the cue? It moves in the direction you hit it in. The harder you hit it, the faster it moves. Now, what happens when the cue ball collides with another ball? The other ball starts moving. The cue ball slows down. The energy is trans- ferred from the cue ball to the ball it collided with. When an object exerts a force on a second object, the second object exerts an equal force in the opposite direction on the first object. This is Newton’s third law—the Law of Interaction. Law of Interaction For every action, there is an equal and opposite reaction. Types of Forces Newton’s laws do not depend on the type of force applied. Some types of forces include gravitational, elec- tromagnetic, contact, and nuclear. G RAVITATIONAL FORCE Gravitation is an attractive force that each object with mass exerts on any other object with mass. The strength of the gravitational force depends on the masses of the objects and on the distance between them. When we think of gravity, we usually think of Earth’s gravity, which prevents us from jumping infinitely high, keeps our homes stuck to the ground, and makes things thrown upward fall down. We, too, exert a gravitational force on the Earth, and we exert forces on one another, but this is not very noticeable because our masses are very small in comparison with the mass of our planet. The greater the masses involved, the greater the gravita- tional force between them. The sun exerts a force on the Earth and the Earth exerts a force on the sun. The moon exerts a force on the Earth, and the Earth on the moon. The gravitational force of the moon is the reason there are tides. The moon’s gravity pulls the water on Earth. The sun also exerts a force on our water, but this is not as apparent because the sun, although more massive than the moon, is very far away. As the distance between two objects doubles, the gravitational force between them decreases four times. Gravitation Gravitation is an attractive force that exists between all objects. It is proportional to the masses of the objects and inversely propor- tional to the square of the distance between them. ELECTROMAGNETIC FORCE Electricity and magnetism are two aspects of a single electromagnetic force. Moving electric charges produce magnetic forces, and moving magnets produce electric forces. The electromagnetic force exists between any two charged or magnetic objects, such as a proton and an electron or two electrons. Opposite charges attract (an electron and a proton), while like charges repel (two pro- tons or two electrons). The strength of the force depends on the charges and on the distance between them. The greater the charges, the greater the force. The closer the charges are to each other, the greater the force between them. – PHYSICAL SCIENCE– 229 CONTACT FORCE Contact forces are forces that exist as a result of an inter- action between objects that are physically in contact with one another. They include frictional forces, tensional forces, and normal forces. The friction force opposes the motion of an object across a surface. For example, if a glass moves across the surface of the dinner table, there exists a friction force in the direction opposite to the motion of the glass. Friction is the result of attractive intermolecular forces between the molecules of the surface of the glass and the surface of the table. Friction depends on the nature of the two surfaces. For example, there would be less friction between the table and the glass if the table was moistened or lubricated with water. The glass would glide across the table more easily. Friction also depends on the degree to which the glass and the table are pressed together. Air resistance is a type of frictional force. Tension is the force that is transmitted through a rope or wire when it is pulled tight by forces acting at each end. The tensional force is directed along the rope or wire and pulls on the objects on either end of the wire. The normal force is exerted on an object in contact with another stable object. For example, the dinner table exerts an upward force on a glass at rest on the surface of the table. NUCLEAR FORCE Nuclear forces are very strong forces that hold the nucleus of an atom together. If nuclei of different atoms come close enough together, they can interact with one another and reactions between the nuclei can occur. Forms of Energy Energy is defined as the ability to do work. We have already stated that energy can’t be created or destroyed; it can only change form. Forms of energy include poten- tial energy and kinetic energy. Potential energy is stored energy. Kinetic energy is the energy associated with motion. Look at the following illustration. As the pendulum swings, the energy is con- verted from potential to kinetic, and back to potential. When the hanging weight is at one of the high points, the gravitational potential energy is at the maximum, and kinetic energy is at the minimum. At the low point, the kinetic energy is maximized, and gravitational potential energy is minimized. The change of potential energy into kinetic energy, and kinetic energy into potential energy, in a pendulum Examples of potential energy include nuclear energy and chemical energy—energy is stored in the bonds that hold atoms and molecules together. Heat, hydrodynamic energy, and electromagnetic waves are examples of kinetic energy—energy associated with the movement of molecules, water, and electrons or photons (increments of light). Interactions of Energy and Matter Energy in all its forms can interact with matter. For example, when heat energy interacts with molecules of water, it makes them move faster and boil. Waves— including sound and seismic waves, waves on water, and light waves—have energy and can transfer that energy when they interact with matter. Consider what happens if you are standing by the ocean and a big wave rolls in. Sometimes, the energy carried by the wave is large enough to knock you down. Waves Energy is also carried by electromagnetic waves or light waves. The energy of electromagnetic waves is related to their wavelengths. Electromagnetic waves include radio waves (the longest wavelength), microwaves, infrared radiation (radiant heat), visible light, ultraviolet radia- tion, X-rays, and gamma rays. The wavelength depends on the amount of energy the wave is carrying. Shorter wavelengths carry more energy. When a wave hits a smooth surface, such as a mirror, it is reflected. Sound waves are reflected as echoes. Mat- ter can also refract or bend waves. This is what happens when a ray of light traveling through air hits a water sur- face. A part of the wave is reflected, and a part is refracted into the water. Maximum Potential Energy Maximum Potential Energy Maximum Kinetic Energy – PHYSICAL SCIENCE– 230 . reverse reaction reactants products Ea with a catalyst Ea without a catalyst – PHYSICAL SCIENCE– 2 28 you kick the ball, the faster it will move. The mass of the ball will also determine how much