phân tích eclectron trong hóa phân tích phần 10 pdf

lo ° • 10 -+ ¢:: o 10 .= 0 L. (D m ] 10 "3 10 .4 10 .5 [] Included point " • Excluded point _ CX I = 0.74 - O • _ au= 0.91 T # = 0.80 - • M w T = 235 °C -P = 1.48 MPa, H2/CO = 1.0 • O • i O SV =,2.0 Nl/g-cat,h - I I I ,_,, , , , I I , I , I I , , ,,t I 0 6 12 18 24 80 36 42 48 54 Carbon number Pig.r~" 32. A.,letson-Schldz-Plory piol. for r.n PA-O3-1308-1, Lobtl products exel.dinB .ntecovered w~x. 0 ~ I ' ' "' ' I l ' ~ ' ' ~ I ' ' ' " ' I ' ' ' ' J I ' ' ' ' ' I ' ' ' ' ' I I! ' Included point I [] • Excluded point I L __ | 10" 10 "~ 10"' O0 O T = 235 °C P - 1.48 MPa i H2/CO = 0.69 SV = 2.0 NI/g-cat,h 0 c< l 0.79 ocnl= 0.91 = 0.62 8 12 18 24 30 36 42 Carbon number go 48 -i .i 54 Figure 33. An,l~r~n-$eht,lz-Rory plot for r,n P^-03-1308-4. total products rxcl,di,g unre¢overrd ~'ax. i°° l+'" '"' '"'~'"' '"+ " '+"'"""" " '"+ ' '+ ' ' ' ' ""'" ','' "+~- I-, ,. [] Included point 10" 10" m ~ 10 .3 113 .+ 10"' _=~ • Excluded point . ",i, : o. o ; = ; i 235 °C P = 1,48 MPa | m H2/CO = 1.0 SV = 2.0 NI/g-cat,h , , _, . ! I , , , . I . , , , I , , , , I ., _' , , I _, _. , , ! , , , , I , , , , 0 5 10 15 20 25 30 35 40 e , Carbon number 45 l"igure 34. Anderson-SdmlT,-Flory plot I'or r I,'A-t}~-I,lOS-x, tc;tnl prod.¢t.~ exclmling unre¢overe(! wnx, z C]0 ~D c: O m O~ Q) :> c- O O O + o4 3: 0< 60 70 00 60 40 8O 20 0 ,ll " k'' I Oo I " ' I' 1"' • FA-15-1698 (100 Fell.0 Cu/0.2 K) • FA-15-1768 235 °C 1.48 MPa 2.0 NI/g-cst.h (H2/CO) = 0.67 O O l • I , , • I , , , L,, * I 60 100 150 Time on stream (h) 200 Pig,r,. 3~. SL,iI)ility ploi. (II~-I-CO) conversion vers,IA time on stfesm, for r,ns F^-I 5-1098 and l.'A-15- 1768. 70 - ~ ' ; - ~" i " ' ~ - • - | • • ±' • I ,L• , , I II II , n,~ln,ll,,I | n • • ~ | • . • t "~ 05 8O r- 0 m 55 > C 0 O 50 0 0 + cq 45 "r- 4O 85 80 O• 4ca, (H2/CO) = 0.67 (H2/CO) = 1.0 e~~ o ~ • ~ ~. ~ oaPaV 0 FB-99-1588 (Ruhrohemle LP 33/81) 250 °C , 1.48 MPa 2,0 NI/g-cat.h • _, 0 _, _1 , ,_., , I , j • I , ! ,. , , I , • • , I , , , . , 0 100 200 800 400 500 600 Time on stream (h) 700 PigLzre 30. SL~l)ility plof (llz4-CO) ronversion vers,s tiz,e on streams For r.n Fn-90-1588. , I 60.0- 5OO 30.0 O.O 71 167 263 36O 42"7 528 623 "////////~ 1' I 0-~ C2-C4 C5-~il C12+ .g 3; &O &O 50 4Q 2_0 1~) (10 71 167 263 380 427 ,528 623 Tin~ on S~ (h) I I (:;2 C3 C4 C8 I C10 Figure 37. Effec~ of time on stream cn Ruhrchem]e LP 33/81 selectivity for rm~ FB 99-15S8:250 =C, 1.48 MPa, 2 ]v'l/g-cat.h, (H2/CO) = 0.67 (71-427 h) amd 1.0 (528, 623 h). • o 91 i 3: •E} m 3E:~ i 2gO 1DO O,O E~ 2 SA-3 F'B 5 SA-12 I I O44 C2-C4 C5 Cll C12÷ E: 7n 60 50 4.D 30 23 1.0 O0 F'B-2 SA-3 ~-6 SA-12 I I C2 C3 C7777~ C# C8 I' i C10 Fig, u~e 38. Comparison offixecl bed a~cl slur~' reactor select3v]ty wi¢]~ tL~hrchemie I.P 33/81 cata]ys~ (FB = TB-99-1588, SA = 5A-99-0888): 250 °C, 1.48 MPa, 2.0 ~'l/g-cat-h, (H2/CO) = 0.67 (FB-2 amd SA-3) and 1.0 (PB-6 a~d SA-12). 92 e ® Reproduced by ,-> U National Technical Information Service '~ ~ Springfield, VA 22161 ~ ~ This report was printed specifically for your order ~ from nearly 3 million titles available in our collection. R ~1= ~) g For economy and efficiency, NTIS does not maintain stock of its O vast collection of technical reports. Rather, most documents are custom reproduced for each order. 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Easy Access tO U~ U.S. Government Information Assets U.S. DEPARTMENT OF COMMERCE Tech~ogy ~mini~afion National Technical Information Se~ce Sp~ingfield, VA 22161 (703) 605-6000 IIIIIIII111111111MIIlllllllllllllllllllUlllll ~DE92'.016986 ~ IIIIIIIlUllll III *BA ~ BIN: M17 11-06-03 INVOICE: 1300066 SHIPTO: 1"852037 PAYMENT: CSH~A . lo ° • 10 -+ ¢:: o 10 .= 0 L. (D m ] 10 "3 10 .4 10 .5 [] Included point " • Excluded point _ CX I = 0.74 -. ""'" ','' "+~- I-, ,. [] Included point 10& quot; 10& quot; m ~ 10 .3 113 .+ 10& quot;' _=~ • Excluded point . ",i, : o. o ; = ; i 235. ' ' ' I I! ' Included point I [] • Excluded point I L __ | 10& quot; 10 "~ 10& quot;' O0 O T = 235 °C P - 1.48 MPa i H2/CO = 0.69 SV = 2.0 NI/g-cat,h