TABLE E.6 Wrought-Bronzes—Standard Designations for Wrought Bronzes (Composition as Maximum % Unless Indicated as Range or Minimum) (Continued) Part 3. Copper-phosphorus and copper-silver-phosphorus alloys (brazing alloys) Alloy Cu Ag P C55180 Rem. 4.8–5.2 C55181 Rem. 7.0–7.5 C55280 Rem. 1.8–2.2 6.8–7.2 C55281 Rem. 4.8–5.2 5.8–6.2 C55282 Rem. 4.8–5.2 6.5–7.0 C55283 Rem. 5.8–6.2 7.0–7.5 C55284 Rem. 14.5–15.5 4.8–5.2 Part 4. Copper-aluminum alloys (aluminum bronzes) Alloy Pb Fe Sn Zn Al Mn Si Ni (ϩCo) Other C60800 0.1 0.1 5.0–6.5 .02–.35As C61000 0.02 0.5 0.2 6.0–8.5 0.1 C61300 0.01 2.0–3 .20–0.5 0.1 6.0–7.5 0.2 0.1 0.15 .015P C61400 0.01 1.5–3.5 0.2 6.0–8 1 .015P C61500 0.015 7.7–8.3 1.8–2.2 C61550 0.05 0.2 0.05 0.8 5.5–6.5 1 1.5–2.5 .8Zn C61800 0.02 .50–1.5 0.02 8.5–11 0.1 C61900 0.02 3.0–4.5 0.6 0.8 8.5–10 C62200 0.02 3.0–4.2 0.02 11.0–12 0.1 C62300 2.0–4 0.6 8.5–10 0.5 0.25 1 C62400 2.0–4.5 0.2 10.0–11.5 0.3 0.25 C62500 3.5–5.5 12.5–13.5 2 C62580 0.02 3.0–5 0.02 12.0–13 0.04 C62581 0.02 3.0–5 0.02 13.0–14 0.04 C62582 2 3.0–5 0.02 14.0–15 0.04 C63000 2.0–4 0.2 0.3 9.0–11 1.5 0.25 4.0–5.5 C63010 2.0–3.5 0.2 0.3 9.7–10.9 1.5 4.5–5.5 1076 0765162_AppE_Roberge 9/1/99 8:18 Page 1076 C63020 0.03 4.0–5.5 0.25 0.3 10.0–11 1.5 4.2–6 .20Co C63200 0.02 3.5–4.3 8.7–9.5 1.2–2 0.1 4.0–4.8 C63280 0.02 3.0–5 8.5–9.5 .6–3.5 4.0–5.5 C63380 0.02 2.0–4 0.15 7.0–8.5 11.0–14 0.1 1.5–3 C63400 0.05 0.15 0.2 0.5 2.6–3.2 .25–0.45 0.15 .15As C63600 0.05 0.15 0.2 0.5 3.0–4 .7–1.3 0.15 .15As C63800 0.05 0.2 0.8 2.5–3.1 0.1 1.5–2.1 0.2 .25–.55Co C64200 0.05 0.3 0.2 0.5 6.3–7.6 0.1 1.5–2.2 0.25 .15As C64210 0.05 0.3 0.2 0.5 6.3–7 0.1 1.5–2 0.25 .15As Part 5. copper-silicon alloys (silicon bronzes) Alloy Cu (ϩAg) Pb Fe Sn Zn Mn Si Ni (ϩCo) Other C64700 Rem. 0.1 0.1 0.5 .40–8 1.6–2.2 C64710 95.0 min. .20–0.5 0.1 .50–9 2.9–3.5 C64725 95.0 min. 0.01 0.25 .20–.8 .50–1.5 .20–.8 1.3–2.7 .01Ca, .20Mg, .20Cr C64730 93.5 min. 1.0–1.5 .20–0.5 0.1 .50–9 2.9–3.5 C64740 95.0 min. .10max 1.5–2.5 .20 .05–.50 1.0–2 .01Ca, .05Mg C64900 Rem. 0.05 0.1 1.2–1.6 0.2 .8–1.2 0.1 .10Al C65100 Rem. 0.05 0.8 1.5 0.7 .8–2.0 C65400 Rem. 0.05 1.2–1.9 0.5 2.7–3.4 .01–.12Cr C65500 Rem. 0.05 0.8 1.5 .50–1.3 2.8–3.8 0.6 C65600 Rem. 0.02 0.5 1.5 1.5 1.5 2.8–4 .01Al C66100 Rem. .20–8 0.25 1.5 1.5 2.8–3.5 1077 0765162_AppE_Roberge 9/1/99 8:18 Page 1077 TABLE E.6 Wrought-Bronzes—Standard Designations for Wrought Bronzes (Composition as Maximum % Unless Indicated as Range or Minimum) (Continued) Part 4. Copper-aluminum alloys (aluminum bronzes) Alloy Pb Fe Sn Zn Al Mn Si Ni (ϩCo) Other TABLE E.6 Wrought-Bronzes—Standard Designations for Wrought Bronzes (Composition as Maximum % Unless Indicated as Range or Minimum) (Continued) Part 6. Other copper-zinc alloys Alloy Cu (ϩAg) Pb Fe Sn Zn Ni (ϩCo) Al Mn Si Other C66300 84.5–87.5 0.05 1.4–2.4 1.5–3 Rem. .35–.20Co C66400 Rem. 0.015 1.3–1.7 0.05 11.0–12 .30–.7Co C66410 Rem. 0.015 1.8–2.3 0.05 11.0–12 C66420 Rem. .50–1.5 12.0–17 C66700 68.5–71.5 0.07 0.1 Rem. .8–1.5 C66800 60.0–63 0.5 0.35 0.3 Rem. 0.25 0.25 2.0–3.5 .50 C66900 62.5–64.5 0.05 0.05 Rem. 11.5–12.5 C67000 63.0–68 0.2 2.0–4 0.5 Rem. 3.0–6 2.5–5 C67300 58.0–63 .40–3 0.5 0.3 Rem. 0.25 0.25 2.0–3.5 .50–1.5 C67400 57.0–60.0 0.5 0.35 0.3 Rem. 0.25 .50–2 2.0–3.5 .50–1.5 C67420 57.0–58.5 .25–8 .15–55 0.35 Rem. 0.25 1.0–2 1.5–2.5 .25–7 C67500 57.0–60 0.2 .8–2.0 .50–1.5 Rem. 0.25 .05–0.5 C67600 57.0–60 .50–1 .40–1.3 .50–1.5 Rem. .05–.50 C68000 56.0–60 0.05 .25–1.25 .75–1.1 Rem. .20–8 0.01 .01–0.5 .04–0.15 C68100 56.0–60 0.05 .25–1.25 .75–1.1 Rem. 0.01 .01–.50 .04–.15 C68700 76.0–79 0.07 0.06 Rem. 1.8–2.5 .02–.06As C68800 Rem. 0.05 0.2 21.3–24.1 3.0–3.8 .25–.55Co C69050 70.0–75 Rem. .50–1.5 3.0–4 .10–0.6 .01–.20Zr C69100 81.0–84 0.05 0.25 0.1 Rem. .8–1.4 .7–1.2 .10 min. .8–1.3 C69400 80.0–83 0.3 0.2 Rem. 3.5–4.5 C69430 80.0–83 0.3 0.2 Rem. 3.5–4.5 .03–.06As C69700 75.0–80 .50–1.5 0.2 Rem. 0.4 2.5–3.5 C69710 75.0–80 .50–1.5 0.2 Rem. 0.4 2.5–3.5 .03–.06As 1078 0765162_AppE_Roberge 9/1/99 8:18 Page 1078 TABLE E.7 Wrought Copper-Nickel Alloys—Standard Designations for Wrought Copper-Nickel Alloys (Composition as Maximum % Unless Indicated as Range or Minimum) Alloy Cu (ϩAg) Pb Fe Zn Ni Sn Mn Other C70100 Rem. 0.05 0.25 3.0–4.0 0.5 C70200 Rem. 0.05 0.1 2.0–3.0 0.4 C70250 Rem. 0.05 0.2 1 2.2–4.2 0.1 .05–.30Mg, .25–1.2Si C70260 Rem. 1.0–3.0 .20–.7Si, .005P C70400 Rem. 0.05 1.3–1.7 1 4.8–6.2 .30–.8 C70500 Rem. 0.05 0.1 0.2 5.8–7.8 0.15 C70600 Rem. 0.05 1.0–1.8 1 9.0–11.0 1 C70610 Rem. 0.01 1.0–2.0 10.0–11.0 .50–1.0 .05S,.05C C70620 86.5 min. 0.02 1.0–1.8 0.5 9.0–11.0 1 .05C, .02P, 02S C70690 Rem. 0.001 0.005 0.001 9.0–11.0 0.001 C70700 Rem. 0.05 9.5–10.5 0.5 C70800 Rem. 0.05 0.1 0.2 10.5–12.5 0.15 C71000 Rem. 0.05 1 1 19.0–23.0 1 C71100 Rem. 0.05 0.1 0.2 22.0–24.0 0.15 C71300 Rem. 0.05 0.2 1 23.5–26.5 1 C71500 Rem. 0.02 .40–1.0 1 29.0–33.0 1 C71520 65.0 min. .40–1.0 0.5 0.5 29.0–33.0 1 .05C, .02P, .02S C71580 Rem. 0.05 0.5 0.05 29.0–33.0 0.3 C71581 Rem. 0.02 .40–.7 29.0–32.0 1 C71590 Rem. 0.001 0.15 0.001 29.0–31.0 0.001 0.5 C71640 Rem. 0.01 1.7–2.3 29.0–32.0 1.5–2.5 .03S, .06C C71700 Rem. .40–1.0 29.0–33.0 .30–.7Be C71900 Rem. 0.015 0.5 0.05 28.0–33.0 .20–1.0 2.2–3.0Cr, .02–.35Zr, .01–.20Ti, .04C, .25Si, .015S, .02P C72150 Rem. 0.05 0.1 0.2 43.0–46.0 0.05 .10C, .50Si C72200 Rem. 0.05 .50–1.0 1 15.0–18.0 1 .30–.7Cr, .03Si, .03Ti C72420 Rem. 0.02 .7–1.2 0.2 13.5–16.5 0.1 3.5–5.5 1.0–2.0Al, .50Cr, .15Si. .05Mg, .15S, .01P, .05C C72500 Rem. 0.05 0.6 0.5 8.5–10.5 1.8–2.8 0.2 C72650 Rem 0.01 0.1 0.1 7.0–8.0 4.5–5.5 0.1 C72700 Rem. 0.02 0.5 0.5 8.5–9.5 5.5–6.5 .05–.30 .10Nb, .15Mg C72800 Rem. 0.005 0.5 1 9.5–10.5 7.5–8.5 .05–.30 .10Al, .001B, .001Bi, .10–.30Nb, .005–.15Mg, .005P, .0025S, .02Sb, .05Si, .01Ti C72900 Rem. 0.02 0.5 0.5 14.5–15.5 7.5–8.5 0.3 .10Nb, .15Mg C72950 Rem. 0.05 0.6 20.0–22.0 4.5–5.7 0.6 1079 0765162_AppE_Roberge 9/1/99 8:18 Page 1079 TABLE E.8 Wrought Nickel-Silvers—Standard Designations for Wrought Nickel-Silver Alloys (Composition as Maximum % Unless Indicated as Range or Minimum) Alloy Cu (ϩAg) Pb Fe Zn Ni (ϩCo) Mn Other C73500 70.5–73.5 0.1 0.25 Rem. 16.5–19.5 0.5 C74000 69.0–73.5 0.1 0.25 Rem. 9.0–11.0 0.5 C74300 63.0–66.0 0.1 0.25 Rem. 7.0–9.0 0.5 C74500 63.5–66.5 0.1 0.25 Rem. 9.0–11.0 0.5 C75200 63.5–66.5 0.05 0.25 Rem. 16.5–19.5 0.5 C75400 63.5–66.5 0.1 0.25 Rem. 14.0–16.0 0.5 C75700 63.5–66.5 0.05 0.25 Rem. 11.0–13.0 0.5 C76000 60.0–63.0 0.1 0.25 Rem. 7.0–9.0 0.5 C76200 57.0–61.0 0.1 0.25 Rem. 11.0–13.5 0.5 C76400 58.5–61.5 0.05 0.25 Rem. 16.5–19.5 0.5 C76700 55.0–58.0 Rem. 14.0–16.0 0.5 C77000 53.5–56.5 0.05 0.25 Rem. 16.5–19.5 0.5 C77300 46.0–50.0 0.05 Rem. 9.0–11.0 .01Al, .25P, .04–.25Si C77400 43.0–47.0 0.2 Rem. 9.0–11.0 C78200 63.0–67.0 1.5–2.5 0.35 Rem. 7.0–9.0 0.5 C79000 63.0–67.0 1.5–2.2 0.35 Rem. 11.0–13.0 0.5 C79200 59.0–66.5 .8–1.4 0.25 Rem. 11.0–13.0 0.5 C79800 45.5–48.5 1.5–2.5 0.25 Rem. 9.0–11.0 1.5–2.5 C79830 45.5–47.0 1.0–2.5 0.45 Rem. 9.0–10.5 .15–.55 1080 0765162_AppE_Roberge 9/1/99 8:18 Page 1080 TABLE E.9 Cast Coppers and High Coppers—Standard Designations for Cast Coppers and High Coppers (Composition as Maximum % Unless Indicated as Range or Minimum) Alloy Cu (ϩAg) P Be Co Si Ni Fe Al Sn Pb Zn Cr C80100 99.95 C80410 99.9 0.1 C81100 99.7 C81200 99.9 .045–.065 C81400 Rem. .02–.10 .6–1.0 C81500 Rem. 0.15 0.1 0.1 0.1 0.02 0.1 .40–1.5 C81540 95.1 min. .40–.8 2.0–3.0 0.15 0.1 0.1 0.02 0.1 .10–.6 C82000 Rem. .45–.8 2.40–2.70 0.15 0.2 0.1 0.1 0.1 0.02 0.1 0.1 C82200 Rem. .35–.8 0.3 1.0–2.0 C82400 Rem. 1.60–1.85 .20–.65 0.2 0.2 0.15 0.1 0.02 0.1 0.1 C82500 Rem. 1.90–2.25 .35–.70 .20–.35 0.2 0.25 0.15 0.1 0.02 0.1 0.1 C82510 Rem. 1.90–2.15 1.0–1.2 .20–.35 0.2 0.25 0.15 0.1 0.02 0.1 0.1 C82600 Rem. 2.25–2.55 .35–.65 .20–.35 0.2 0.25 0.15 0.1 0.02 0.1 0.1 C82700 Rem. 2.35–2.55 0.15 1.0–1.5 0.25 0.15 0.1 0.02 0.1 0.1 C82800 Rem. 2.50–2.85 .35–.70 .20–.35 0.2 0.25 0.15 0.1 0.02 0.1 0.1 1081 0765162_AppE_Roberge 9/1/99 8:18 Page 1081 TABLE E.10 Cast Brasses Part 1. Copper-tin-zinc and copper-tin-zinc-lead alloys (red and leaded red brasses) Alloy Cu Sn Pb Zn Fe Sb As Ni S P Al Si C83300 92.0–94.0 1.0–2.0 1.0–2.0 2.0–6.0 C83400 88.0–92.0 0.2 0.5 8.0–12.0 0.25 0.25 1 0.08 0.03 0.005 0.005 C83450 87.0–89.0 2.0–3.5 1.5–3.0 5.5–7.5 0.3 0.25 .8–2.0 0.08 0.03 0.005 0.005 C83500 86.0–88.0 5.5–6.5 3.5–5.5 1.0–2.5 0.25 0.25 .50–1.0 0.08 0.03 0.005 0.005 C83600 84.0–86.0 4.0–6.0 4.0–6.0 4.0–6.0 0.3 0.25 1 0.08 0.05 0.005 0.005 C83800 82.0–83.8 3.3–4.2 5.0–7.0 5.0–8.0 0.3 0.25 1 0.08 0.03 0.005 0.005 C83810 Rem. 2.0–3.5 4.0–6.0 7.5–9.5 0.5 2 0.005 0.1 Part 2. Copper-tin-zinc and copper-tin-zinc-lead alloys (semi-red and leaded semi-red brasses) Alloy Cu Sn Pb Zn Fe Sb Ni S P Al Si Bi C84200 78.0–82.0 4.0–6.0 2.0–3.0 10.0–16.0 0.4 0.25 0.8 0.08 0.05 0.005 0.005 C84400 78.0–82.0 2.3–3.5 6.0–8.0 7.0–10.0 0.4 0.25 1 0.08 0.02 0.005 0.005 C84410 Rem. 3.0–4.5 7.0–9.0 7.0–11.0 1 0.01 0.2 0.05 C84500 77.0–79.0 2.0–4.0 6.0–7.5 10.0–14.0 0.4 0.25 1 0.08 0.02 0.005 0.005 C84800 75.0–77.0 2.0–3.0 5.5–7.0 13.0–17.0 0.4 0.25 1 0.08 0.02 0.005 0.005 Part 3. Copper-zinc and copper-zinc-lead alloys (yellow and leaded yellow brasses) Alloy Cu Sn Pb Zn Fe Sb Ni Mn As S P Al Si C85200 70.0–74.0 .7–2.0 1.5–3.8 20.0–27.0 0.6 0.2 1 0.05 0.02 0.005 0.05 C85400 65.0–70.0 .50–1.5 1.5–3.8 24.0–32.0 0.7 1 0.35 0.05 C85500 59.0–63.0 0.2 0.2 Rem. 0.2 0.2 0.2 C85700 58.0–64.0 .50–1.5 .8–1.5 32.0–40.0 0.7 1 0.8 0.05 C85800 57.0 min. 1.5 1.5 31.0–41.0 0.5 0.05 0.5 0.25 0.05 0.05 0.01 0.55 0.25 1082 0765162_AppE_Roberge 9/1/99 8:18 Page 1082 Part 4. Manganese bronze and leaded manganese bronze alloys (high-strength and leaded high-strength yellow brasses) Alloy Cu Sn Pb Zn Fe Ni Al Mn Si C86100 66.0–68.0 0.2 0.2 Rem. 2.0–4.0 4.5–5.5 2.5–5.0 C86200 60.0–66.0 0.2 0.2 22.0–28.0 2.0–4.0 1 3.0–4.9 2.5–5.0 C86300 60.0–66.0 0.2 0.2 22.0–28.0 2.0–4.0 1 5.0–7.5 2.5–5.0 C86400 56.0–62.0 .50–1.5 .50–1.5 34.0–42.0 .40–2.0 1 .50–1.5 .10–1.5 C86500 55.0–60.0 1 0.4 36.0–42.0 .40–2.0 1 .50–1.5 .10–1.5 C86550 57.0 min. 1 0.5 Rem. .7–2.0 1 .50–2.5 .10–3.0 0.1 C86700 55.0–60.0 1.5 .50–1.5 30.0–38.0 1.0–3.0 1 1.0–3.0 .10–3.5 C86800 53.5–57.0 1 0.2 Rem. 1.0–2.5 2.5–4.0 2 2.5–4.0 Part 5. Copper-silicon alloys (silicon bronzes and silicon brasses) Alloy Cu Sn Pb Zn Fe Al Si Mn Mg Ni S Other C87300 94.0 min. 0.2 0.25 0.2 3.5–4.5 .8–1.5 C87400 79.0 min. 1 12.0–16.0 0.8 2.5–4.0 C87500 79.0 min. 0.5 12.0–16.0 0.5 3.0–5.0 C87600 88.0 min. 0.5 4.0–7.0 0.2 3.5–5.5 0.25 C87610 90.0 min. 0.2 3.0–5.0 0.2 3.0–5.0 0.25 C87800 80.0 min. 0.25 0.15 12.0–16.0 0.15 0.15 3.8–4.2 0.15 0.01 0.2 0.05 .01P Part 6. Copper-bismuth and copper-bismuth-selenium alloys (high-strength and leaded high-strength yellow brasses) Alloy Cu Sn Pb Zn Fe Sb Ni S P Al Si Bi Se Other C89320 87.0–91 5.0–7 0.09 1 0.2 0.35 1 0.08 0.3 0.005 0.005 4.0–6 C89510 86.0–88 4.0–6 0.25 4.0–6 0.3 0.25 1 0.08 0.05 0.005 0.005 .50–1.5 .35–0.7 C89520 85.0–87 5.0–6 0.25 4.0–6 0.3 0.25 1 0.08 0.05 0.005 0.005 1.9–2.2 .8–1.2 Ϫ64 C89550 58.0–64 .50–1.5 0.2 32.0–40 0.7 1 .30–0.7 .7–2 .07–0.25 C89844 83.0–86 3.0–5 0.2 7.0–10 0.3 0.25 1 0.08 0.05 0.005 0.005 2.0–4 C89940 64.0–68.0 3.0–5 0.01 3.0–5 .7–2 0.1 20.0–23 0.05 .10–0.15 0.005 0.15 4.0–5.5 .20Mn 1083 0765162_AppE_Roberge 9/1/99 8:18 Page 1083 TABLE E.10 Cast Brasses Continued TABLE E.11 Part 1. Copper-tin alloys (tin bronzes) Alloy Cu Sn Pb Zn Fe Sb Ni S P Al Si Mn C90200 91.0–94.0 6.0–8.0 0.3 0.5 0.2 0.2 0.5 0.05 0.05 0.005 0.005 C90300 86.0–89.0 7.5–9.0 0.3 3.0–5.0 0.2 0.2 1 0.05 0.05 0.005 0.005 C90500 86.0–89.0 9.0–11.0 0.3 1.0–3.0 0.2 0.2 1 0.05 0.05 0.005 0.005 C90700 88.0–90.0 10.0–12.0 0.5 0.5 0.15 0.2 0.5 0.05 0.3 0.005 0.005 C90710 Rem. 10.0–12.0 0.25 0.05 0.1 0.2 0.1 0.05 .05–1.2 0.005 0.005 C90800 85.0–89.0 11.0–13.0 0.25 0.25 0.15 0.2 0.5 0.05 0.3 0.005 0.005 C90810 Rem. 11.0–13.0 0.25 0.3 0.15 0.2 0.5 0.05 .15–.8 0.005 0.005 C90900 86.0–89.0 12.0–14.0 0.25 0.25 0.15 0.2 0.5 0.05 0.05 0.005 0.005 C91000 84.0–86.0 14.0–16.0 0.2 1.5 0.1 0.2 0.8 0.05 0.05 0.005 0.005 C91100 82.0–85.0 15.0–17.0 0.25 0.25 0.25 0.2 0.5 0.05 1 0.005 0.005 C91300 79.0–82.0 18.0–20.0 0.25 0.25 0.25 0.2 0.5 0.05 1 0.005 0.005 C91600 86.0–89.0 9.7–10.8 0.25 0.25 0.2 0.2 12–2.0 0.05 0.3 0.005 0.005 C91700 84.0–87.0 11.3–12.5 0.25 0.25 0.2 0.2 1.2–2.0 0.05 0.3 0.005 0.005 Part 2. Copper-tin-lead alloys (leaded tin bronzes) Alloy Cu Sn Pb Zn Fe Sb Ni S P Al Si Mn C92200 86.0–90.0 5.5–6.5 1.0–2.0 3.0–5.0 0.25 0.25 1 0.05 0.05 0.005 0.005 C92210 86.0–89.0 4.5–5.5 1.7–2.5 3.0–4.5 0.25 0.2 .7–1.0 0.05 0.03 0.005 0.005 C92220 86.0–88.0 5.0–6.0 1.5–2.5 3.0–5.5 0.25 .50–1.0 0.05 C92300 85.0–89.0 7.5–9.0 .30–1.0 2.5–5.0 0.25 0.25 1 0.05 0.05 0.005 0.005 C92310 Rem. 7.5–8.5 .30–1.5 3.5–4.5 1 0.005 0.005 0.03 C92400 86.0–89.0 9.0–11.0 1.0–2.5 1.0–3.0 0.25 0.25 1 0.05 0.05 0.005 0.005 C92410 Rem. 6.0–8.0 2.5–3.5 1.5–3.0 0.2 0.25 0.2 0.005 0.005 0.05 C92500 85.0–88.0 10.0–12.0 1.0–1.5 0.5 0.3 0.25 .8–1.5 0.05 0.3 0.005 0.005 C92600 86.0–88.5 9.3–10.5 .8–1.5 1.3–2.5 0.2 0.25 0.7 0.05 0.03 0.005 0.005 C92610 Rem. 9.5–10.5 .30–1.5 1.7–2.8 0.15 1 0.005 0.005 0.03 C92700 86.0–89.0 9.0–11.0 1.0–2.5 0.7 0.2 0.25 1 0.05 0.25 0.005 0.005 C92710 Rem. 9.0–11.0 4.0–6.0 1 0.2 0.25 2 0.05 0.1 0.005 0.005 1084 0765162_AppE_Roberge 9/1/99 8:18 Page 1084 Cast Bronzes (Continued) C92800 78.0–82.0 15.0–17.0 4.0–6.0 0.8 0.2 0.25 0.8 0.05 0.05 0.005 0.005 C92810 78.0–82.0 12.0–14.0 4.0–6.0 0.5 0.5 0.25 0.8–1.2 0.05 0.05 0.005 0.005 C92900 82.0–86.0 9.0–11.0 2.0–3.2 0.25 0.2 0.25 2.8–4.0 0.05 0.5 0.005 0.005 Part 3. Copper-tin-lead alloys (high-leaded tin bronzes) Alloy Cu Sn Pb Zn Fe Sb Ni S P Al Si C93100 Rem. 6.5–8.5 2.0–5.0 2 0.25 0.25 1 0.05 0.3 0.005 0.005 C93200 81.0–85.0 6.3–7.5 6.0–8.0 1.0–4.0 0.2 0.35 1 0.08 0.15 0.005 0.005 C93400 82.0–85.0 7.0–9.0 7.0–9.0 0.8 0.2 0.5 1 0.08 0.5 0.005 0.005 C93500 83.0–86.0 4.3–6.0 8.0–10.0 2 0.2 0.3 1 0.08 0.05 0.005 0.005 C93600 79.0–83.0 6.0–8.0 11.0–13.0 1 0.2 0.55 1 0.08 0.15 0.005 0.005 C93700 78.0–82.0 9.0–11.0 8.0–11.0 0.8 0.7 0.5 0.5 0.08 0.1 0.005 0.005 C93720 83.0 min. 3.5–4.5 7.0–9.0 4 0.7 0.5 0.5 0.1 C93800 75.0–79.0 6.3–7.5 13.0–16.0 0.8 0.15 0.8 1 0.08 0.05 0.005 0.005 C93900 76.5–79.5 5.0–7.0 14.0–18.0 1.5 0.4 0.5 0.8 0.08 1.5 0.005 0.005 C94000 69.0–72.0 12.0–14.0 14.0–16.0 0.5 0.25 0.5 .50–1.0 0.08 0.05 0.005 0.005 C94100 72.0–79.0 4.5–6.5 18.0–22.0 1 0.25 0.8 1 0.08 0.05 0.005 0.005 C94300 67.0–72.0 4.5–6.0 23.0–27.0 0.8 0.15 0.8 1 0.08 0.08 0.005 0.005 C94310 Rem. 1.5–3.0 27.0–34.0 0.5 0.5 0.5 .25–1.0 0.05 C94320 Rem. 4.0–7.0 24.0–32.0 0.35 C94330 68.5–75.5 3.0–4.0 21.0–25.0 3 0.7 0.5 0.5 0.1 C94400 Rem. 7.0–9.0 9.0–12.0 0.8 0.15 0.8 1 0.08 0.5 0.005 0.005 C94500 Rem. 6.0–8.0 16.0–22.0 1.2 0.15 0.8 1 0.08 0.05 0.005 0.005 Part 4. Copper-tin-nickel alloys (tin-nickel bronzes) Alloy Cu Sn Pb Zn Fe Sb Ni Mn S P Al Si C94700 85.0–90.0 4.5–6.0 0.1 1.0–2.5 0.25 0.15 4.5–6.0 0.2 0.05 0.05 0.005 0.005 C94800 84.0–89.0 4.5–6.0 .30–1.0 1.0–2.5 0.25 0.15 4.5–6.0 0.2 0.05 0.05 0.005 0.005 C94900 79.0–81.0 4.0–6.0 4.0–6.0 4.0–6.0 0.3 0.25 4.0–6.0 0.1 0.08 0.05 0.005 0.005 1085 0765162_AppE_Roberge 9/1/99 8:18 Page 1085 TABLE E.11 Part 2. Copper-tin-lead alloys (leaded tin bronzes) Alloy Cu Sn Pb Zn Fe Sb Ni S P Al Si Mn Cast Bronzes (Continued) [...]... 1HCuO2Ϫ 1 eϪ ϩ 1Cu2ϩ ϭ 1Cuϩ 1 eϪ ϩ 3H ϩ ϩ 1HCuO2Ϫ ϭ 1Cuϩ ϩ 2H2O 1 eϪ ϩ 4H ϩ ϩ 1CuO 22 ϭ 2H2Oϩ1Cuϩ 2 eϪ ϩ 2H ϩ ϩ 1Cu2O ϭ 1H2Oϩ2Cu 2 eϪ ϩ 2H ϩ ϩ 1Cu(OH )2 ϭ 2H2Oϩ1Cu 2 eϪ ϩ 2H ϩ ϩ 2Cu(OH )2 ϭ 3H2Oϩ1Cu2O 2H ϩ ϩ 1Cu2O ϭ 1H2Oϩ2Cuϩ 2H ϩ ϩ 1Cu(OH )2 ϭ 2H2Oϩ1Cu2ϩ 2H ϩ ϩ 1CuO 22 ϭ 1Cu(OH )2 1 eϪ ϩ 1Cuϩ ϭ 1Cu 2 eϪ ϩ 1Cu2ϩ ϭ 1Cu 2 eϪ ϩ 3H ϩ ϩ 1HCuO2Ϫ ϭ 2H2Oϩ1Cu 2 eϪ ϩ 4H ϩ ϩ 1CuO 22 ϭ 2H2Oϩ1Cu 2 eϪ ϩ 1H2O ϩ 2Cu2 ϩ ϭ 2H... 2H2O 1 eϪ ϩ 4H ϩ ϩ 1CuO 22 ϭ 2H2Oϩ1Cuϩ 2 eϪ ϩ 2H ϩ ϩ 1Cu2O ϭ 1H2Oϩ2Cu 2 eϪ ϩ 2H ϩ ϩ 1CuO ϭ 1H2Oϩ1Cu 2 eϪ ϩ 2H ϩ ϩ 2CuO ϭ 1H2Oϩ1Cu2O 2H ϩ ϩ 1Cu2O ϭ 1H2Oϩ2Cuϩ 2H ϩ ϩ 1CuO ϭ 1H2Oϩ1Cu2 ϩ 1H ϩ ϩ 1HCuO2Ϫ ϭ 1H2Oϩ1CuO 1 eϪ ϩ 1Cuϩ ϭ 1Cu 2 eϪ ϩ 1Cu2 ϩ ϭ 1Cu 2 eϪ ϩ 3H ϩ ϩ 1HCuO2Ϫ ϭ 2H2Oϩ1Cu 2 eϪ ϩ 4H ϩ ϩ 1CuO 22 ϭ 2H2Oϩ1Cu 2 eϪ ϩ 1H2Oϩ2Cu2 ϩ ϭ 2H ϩ ϩ 1Cu2O 2 eϪ ϩ 4H ϩ ϩ 2HCuO2Ϫ ϭ 3H2Oϩ1Cu2O 2 eϪ ϩ 6H ϩ ϩ 2CuO 22 ... 3Mn(OH)ϩ ϩ 1H2O 2 eϪ ϩ 1Mn3O4 ϩ 2H2O ϭ 3HMnO2Ϫ ϩ 1H ϩ 2 eϪ ϩ 1Mn2O3 ϩ 6H ϩ ϭ 2Mn2ϩ ϩ 3H2O 2 eϪ ϩ 1MN2O3 ϩ 4H ϩ ϭ 2Mn(OH)ϩ ϩ 1H2O 2 eϪ ϩ 1Mn2O3 ϩ 1H2O ϭ 2HMnO2Ϫ 2 eϪ ϩ 1MnO2 ϩ 4H ϩ ϭ 1Mn2 ϩ ϩ 2H2O 2 eϪ ϩ 1MnO2 ϩ 3H ϩ ϭ 1Mn(OH)ϩ ϩ 1H2O 2 eϪ ϩ 1MnO2 ϩ 1H ϩ ϭ 1HMnO2Ϫ 1 eϪ ϩ 1MnO2 ϩ 4H ϩ ϭ 1Mn3ϩ ϩ 2H2O 3 eϪ ϩ 1MnO4Ϫ ϩ 4H ϩ ϭ 1MnO2 ϩ 2H2O 2 eϪ ϩ 1MnO 42 ϩ 4H ϩ ϭ 1MnO2 ϩ 2H2O 2 eϪ ϩ 1MnOϩ2H ϩ ϭ 1Mnϩ1H2O 2 eϪ ϩ... Species O2 H2 H2O Cu Cu2O CuO Cu(OH )2 G0 (29 8 K), JиmolϪ1 S0 (29 8 K), JиmolϪ1 0 0 23 7,000 0 147 ,904 Ϫ 127 ,905 Ϫ358,987 20 5 131 69.9 33 .2 92. 4 42. 6 87 A 29 .96 27 .28 75 .27 22 .635 62. 62 42. 32 87.91 B ϫ 103 4.184 3 .26 3 0 6 .27 6 0 0 0 Cϫ 10Ϫ5 Ϫ1.674 0.5 02 0 0 0 0 0 ˇ S0 (29 8 K), JиmolϪ1 Hϩ Cuϩ Cu2 ϩ Cu(OH)ϩ Cu2(OH )22 ϩ Cu3ϩ HCuO2Ϫ CuO 22 CuO2Ϫ 0 50, 626 65,689 Ϫ 129 ,704 28 0, 328 303,340 25 8,571 Ϫ183,678 Ϫ1 12, 550... Reactions in the Mn-H2O System Equilibria 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 eϪ 2H ϩ 2 ϩ ϭ 1H2 4 eϪ ϩ 1O2 ϩ 4H ϩ ϭ 2H2O 1Mn(OH)ϩ ϩ 1H ϩ ϭ 1Mn2ϩ ϩ 1H2O 1HMnO2Ϫ ϩ 3H ϩ ϭ 1Mn2ϩ ϩ 2H2O 1HMnO2Ϫ ϩ 2H ϩ ϭ 1Mn(OH)ϩ ϩ 1H2O 1MnOϩ2H ϩ ϭ 1Mn2ϩ ϩ 1H2O 1MnOϩ1H ϩ ϭ 1Mn(OH)ϩ 1HMnO2Ϫ ϩ 1H ϩ ϭ 1MnOϩ1H2O 2 eϪ ϩ 1Mn3O4 ϩ 8H ϩ ϭ 3Mn2ϩ ϩ 4H2O 2 eϪ ϩ 1Mn3O4 ϩ... 0 .2 0.3 0.5 0.5 0 .2 0.5 0 .2 0.4 0 .2 0.5 0 .2 0.5 0 .2 0.6 0 .2 0.6 0 .2 0.5 0.35–0.75 0.35–0.75 0.35–0.75 0.35–0.75 0.4 8–10 18 22 26 –30 26 –30 26 –30 19 23 24 28 26 –30 24 28 28 – 32 19 23 13–17 17 21 10 14 15–19 25 2 4 4–7 8–11 9– 12 11 14 14–18 18 22 18 22 23 27 33–37 37–41 58– 62 64–68 35 Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem Rem 1099 07651 62_ AppE_Roberge 1100 UNS 1 2 3 5 7 9 11 12 16... Species G0 (29 8 K), JиmolϪ1 S0 (29 8 K), JиmolϪ1 O2 H2 H2O Ni Ni(OH )2 NiO Ni3O4 Ni2O3 NiO2 0 0 23 7,000 0 Ϫ453,130 21 5,940 Ϫ711,910 Ϫ469,740 21 5 ,140 20 5 131 69.9 30. 12 79.5 38.58 146 .44 94 .14 52. 3 B ϫ 103 A 29 .96 27 .28 75 .27 16.99 0 20 .88 129 .03 98 .28 69.45 ˇ S0 (29 8 K), JиmolϪ1 Hϩ Ni2ϩ HNiO2Ϫ 0 0 Ϫ46,4 42 20 1.3 Ϫ349 ,21 8 62. 76 20 .9 24 3 .14 41.84 4.184 3 .26 3 0 29 4.55 0 157 .23 71.46 77. 82 10 .21 C ϫ 10Ϫ5... 4H2O 1 eϪ ϩ 1CrO2Ϫ ϩ 2H ϩ ϭ 1CrOϩ1H2O 2CrO2Ϫ ϩ 2H ϩ ϩ 1Cr2O3 ϩ 1H2O 1CrO3 ϩ 1H2O ϭ 1CrO 42 ϩ 2H ϩ 1CrO3 ϩ 1H2O ϭ 1HCrO4Ϫ ϩ 1H ϩ 1CrOϩ2H ϩ ϭ 1Cr2 ϩ ϩ 1H2O 3 eϪ ϩ 1Cr3ϩ ϭ 1Cr 3 eϪ ϩ 1CrO33Ϫ ϩr ϩ 3H2O 1 eϪ ϩ 1CrO33Ϫ ϩ 4H ϩ ϭ 1CrOϩ2H2O 1 eϪ ϩ 1CrO2 ϩ 4H ϩ ϭ 1Cr3ϩ ϩ 2H2O 2 eϪ ϩ 1HCrO4Ϫ ϩ 3H ϩ ϭ 1CrO2 ϩ 2H2O 2 eϪ ϩ 1CrO 42 ϩ 4H ϩ ϭ 1CrO2 ϩ 2H2O 1Cr2O3 ϩ 6H ϩ ϭ 2Cr3ϩ ϩ 3H2O 1Cr2O3 ϩ 3H2O ϭ 2CrO33Ϫ ϩ 6H ϩ 2. .. 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 eϪ 2 ϩ 1CrOϩ2H ϩ ϭ 1Cr ϩ 1H2O Ϫ ϩ 1Cr O ϩ 2H ϩ ϭ 2CrOϩ1H O 2e 2 3 2 6 eϪ ϩ 1Cr2O3 ϩ 6H ϩ ϭ 2Cr ϩ 3H2O 2 eϪ ϩ 2CrO2 ϩ 2H ϩ ϭ 1Cr2O3 ϩ 1H2O 6 eϪ ϩ 2CrO3 ϩ 6H ϩ ϭ 1Cr2O3 ϩ 3H2O 2 eϪ ϩ 1CrO3 ϩ 2H ϩ ϭ 1CrO2 ϩ 1H2O 2 eϪ ϩ 1Cr2ϩ ϭ 1Cr 3 eϪ ϩ 1CrO2Ϫ ϩ 4H ϩ ϭ 1Cr ϩ 2H2O 6 eϪ ϩ 1HCrO4Ϫ ϩ 7H ϩ ϭ 1Cr ϩ 4H2O 6 eϪ ϩ 1CrO 42 ϩ 8H ϩ... 1HCrO4Ϫ ϩ 3H ϩ ϭ 1CrO2Ϫ ϩ 2H2O 1Cr2O3 ϩ 4H ϩ ϭ 2Cr(OH )2 ϩ ϩ 1H2O 1Cr2O3 ϩ 1H2Oϩ2H ϩ ϭ 2Cr(OH )2 1 eϪ ϩ 1CrO2 ϩ 3H ϩ ϭ 1Cr(OH )2 ϩ 1H2O 1Cr(OH )2 ϩ ϩ 1H ϩ ϭ 1Cr3ϩ ϩ 1H2O 1Cr(OH )2 ϩ 1H ϩ ϭ 1Cr(OH )2 ϩ 1H2O 1CrO2Ϫ ϩ 2H ϩ ϭ 1Cr(OH )2 1 eϪ ϩ 1Cr(OH )2 ϩ 1H ϩ ϭ 1Cr2 ϩ ϩ 1H2O 1 eϪ ϩ 1Cr(OH )2 ϩ 2H ϩ ϭ 1Cr2 ϩ ϩ 2H2O 3 eϪ ϩ 1CrO 42 ϩ 7H ϩ ϭ 1Cr(OH )2 ϩ ϩ 3H2O 3 eϪ ϩ 1CrO 42 ϩ 7H ϩ ϭ 1Cr(OH )2 ϩ ϩ 3H2O 3 eϪ ϩ 1HCrO4Ϫ . 1.0–1 .2 .20 –.35 0 .2 0 .25 0.15 0.1 0. 02 0.1 0.1 C 826 00 Rem. 2. 25 2. 55 .35–.65 .20 –.35 0 .2 0 .25 0.15 0.1 0. 02 0.1 0.1 C 827 00 Rem. 2. 35 2. 55 0.15 1.0–1.5 0 .25 0.15 0.1 0. 02 0.1 0.1 C 828 00 Rem. 2. 50 2. 85. 0 .25 C 625 00 3.5–5.5 12. 5–13.5 2 C 625 80 0. 02 3.0–5 0. 02 12. 0–13 0.04 C 625 81 0. 02 3.0–5 0. 02 13.0 14 0.04 C 625 82 2 3.0–5 0. 02 14. 0–15 0.04 C63000 2. 0–4 0 .2 0.3 9.0–11 1.5 0 .25 4.0–5.5 C63010 2. 0–3.5. 66.0–68.0 0 .2 0 .2 Rem. 2. 0–4.0 4.5–5.5 2. 5–5.0 C8 620 0 60.0–66.0 0 .2 0 .2 22. 0 28 .0 2. 0–4.0 1 3.0–4.9 2. 5–5.0 C86300 60.0–66.0 0 .2 0 .2 22. 0 28 .0 2. 0–4.0 1 5.0–7.5 2. 5–5.0 C86400 56.0– 62. 0 .50–1.5