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Chapter 8: ARENES potx

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1 ORGANIC CHEMISTRY Dr Nam T. S. Phan Faculty of Chemical Engineering HCMC University of Technology Office: room 211, B2 Building Phone: 8647256 ext. 5681 Email: ptsnam@hcmut.edu.vn 2 Chapter 8: ARENES Benzene 3 CRITERIA FOR AROMATICITY To be classified as aromatic, a compound must meet both of the following criteria: • It must have an un-interrupted cyclic π cloud above & below the plane of the molecule • The π cloud must contain (4n + 2) π electrons (n = 0, 1, 2…) un-interrupted cyclic π cloud 6 π e = 4 x 1 + 2 4 Aromatic: (-) (+) (+) N H O S 5 NOT aromatic: (+) (.) (.) (-) 4 π e 5 π e 7 π e 8 π e NOT (4n + 2) π e Interrupted cyclic π cloud 6 NOMENCLATURE OF MONOSUBSTITUTED BENZENES Name of substituent + benzene 7 Names have to be memorized: 8 NOMENCLATURE OF DI- & POLYSUBSTITUTED BENZENES Alphabetical order, 1-position for the 1 st stated substituent 9 1 of the substituents can be incorporated into a name: Names incorporating 2 substituents 10 Alphabetical order Lowest possible numbers . Technology Office: room 211, B2 Building Phone: 8647256 ext. 5681 Email: ptsnam@hcmut.edu.vn 2 Chapter 8: ARENES Benzene 3 CRITERIA FOR AROMATICITY To be classified as aromatic, a compound must meet

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