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[...]... materials Case studies are presented and, in some instances, conclusions and projections for optimal design procedures ofnanoparticlesandporousmaterials are offered The scope of this volume is inherently multidisciplinary from the viewpoint of usage ofmaterials The common factor, however, is that their surface chemical behavior mates, and thus, unification of purpose and scope becomes a reality The... Heat of Adsorption of Pure Gas and Multicomponent Gas Mixtures on Microporous Adsorbents 501 Shivaji Sircar and Madhukar B Rao art 111 Adsorption from the Liquid Phase onto NanoparticlesandPorous Solids 20 Surface Chemistry of Activated Carbon Materials: State of the Art and Implications for Adsorption 529 Ljubisa R Radovic 21 Charge Regulation at the Surface of a Porous Solid Boris V Zhrnud and Lennart... sections, each of which addresses fundamental and practical realization of the production of nanostructured materials The first section deals with the preparation, characterization, and transport properties of this unique class ofmaterials Structural and chemical heterogeneity are the result of preparation protocols, and various spectroscopies can be used to characterize these properties Transport of adsorbates... The purpose of this volume, therefore, is to collect state -of- the-art procedures for construction and design ofnanoparticlesandporous materials, where their applications might be most appropriate To that end, synthesis and characterization procedures are presented The ultimate test is their practical utilization in world" environments that exist at the gas and liquid interfaces of these materials. .. Equilibria and Kinetics: Rationalizations of the Elovich Equation 355 WladyslawRudzinski and Tornasz Panczyk 16 Single- and Multicomponent Adsorption Equilibria of Hydrocarbons on Activated Carbon: The Role of Micropore Size Distribution 391 K and D Do 17 Surface and Structural Properties of Modified Porous Silicas Michal Kruk and Mietek Jaroniec 443 18 Nanodimensional Magnetic Assembly of Confined... gas-solid and liquid-solid interfaces ofporousmaterials have been the focus of many studies, over decades In recent years, materials have become the focus of many researchers Such materials have interesting properties, but they d o not definitively promise to change the state of science or technology What might change is our use of design strategies for converting theoretical materials into practical materials. .. sections are quite diverse, which is a reflection of the versatility ofnanoparticlesandporousmaterials in technologies that demand superior performance, yet still require latitude for optimization strategies Each of the contributions has been peer-reviewed and we feel confident that the information contained is complete and can be used by seasoned researchers and newcomers Copyright 1999 by Marcel Dekker... Magnetic Carrier Technology 31 Zhenghe Xu, Qingxia Liu ,and James A Finch Acid-Base Behavior ofSurfacesofPorousMaterials Cristian I Contescu and James A Schirarz Electro-Optical Spectroscopy of Colloidal Systems Maria Stoimenova and Tsuneo Okuho 51 103 N M R Studies of Colloidal Oxides 125 Edisson Morgado, Jr., Sonia Maria Cabral de Menezes, and Carlos Roberto Nogueira Pacheco Polymer Surface Dynamics... high surface-to-volume ratio ofnanoparticlesand microporous materials When familiar materials become mainly surface, they acquire new optical, magnetic, electrical, chemical, and transport properties Thus, dispersions tend to agglomerate, fine particles show increased mechanical strength, and microporous solids develop tremendous sorption and molecular sieving properties Materials with a high surface-to-volume... to control and use for our benefit all kinds of special properties developed at the extended surface that characterizes the objects of the nanoworld depends on our understanding of phenomena at and across the interfaces Nanoparticlesandporousmaterials exist essentially as an extended surface The line of structural similitude, however, ends at this point Nanoparticles derive their properties from their . Edition, Revised and Expanded, edited by Hiroyuki and Kunio 77. Polymer - Surfactant Systems, edited by Jan T. Kwak 78. Surfaces of Nanoparticles and Porous Materials, edited by James A. and I. 79. Surface. gas and liquid interfaces of these materials. Case studies are presented and, in some instances, conclusions and projections for opti - mal design procedures of nanoparticles and porous materials. things, and show the tracks of knowledge. from De (On The Nature of Things) BC) In the world of nanoparticles and microporous materials, the interaction forces between nanosized particles and molecules