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ADVANCED MAGNETICMATERIALS EditedbyLeszekMalkinski Advanced Magnetic Materials Edited by Leszek Malkinski Published by InTech Janeza Trdine 9, 51000 Rijeka, Croatia Copyright © 2012 InTech All chapters are Open Access distributed under the Creative Commons Attribution 3.0 license, which allows users to download, copy and build upon published articles even for commercial purposes, as long as the author and publisher are properly credited, which ensures maximum dissemination and a wider impact of our publications. After this work has been published by InTech, authors have the right to republish it, in whole or part, in any publication of which they are the author, and to make other personal use of the work. Any republication, referencing or personal use of the work must explicitly identify the original source. As for readers, this license allows users to download, copy and build upon published chapters even for commercial purposes, as long as the author and publisher are properly credited, which ensures maximum dissemination and a wider impact of our publications. Notice Statements and opinions expressed in the chapters are these of the individual contributors and not necessarily those of the editors or publisher. No responsibility is accepted for the accuracy of information contained in the published chapters. The publisher assumes no responsibility for any damage or injury to persons or property arising out of the use of any materials, instructions, methods or ideas contained in the book. Publishing Process Manager Romina Skomersic Technical Editor Teodora Smiljanic Cover Designer InTech Design Team First published May, 2012 Printed in Croatia A free online edition of this book is available at www.intechopen.com Additional hard copies can be obtained from orders@intechopen.com Advanced Magnetic Materials, Edited by Leszek Malkinski p. cm. ISBN 978-953-51-0637-1 Contents Preface IX Chapter 1 Rapidly Solidified Magnetic Nanowires and Submicron Wires 1 Tibor-Adrian Óvári, Nicoleta Lupu and Horia Chiriac Chapter 2 M-Type Barium Hexagonal Ferrite Films 33 Mingzhong Wu Chapter 3 Tailoring the Interface Properties of Magnetite for Spintronics 61 Gareth S. Parkinson, Ulrike Diebold, Jinke Tang and Leszek Malkinski Chapter 4 Biomedical Applications of Multiferroic Nanoparticles 89 Armin Kargol, Leszek Malkinski and Gabriel Caruntu Chapter 5 Micro-Fabrication of Planar Inductors for High Frequency DC-DC Power Converters 119 Elias Haddad, Christian Martin, Bruno Allard, Maher Soueidan and Charles Joubert Chapter 6 Fe-Al Alloys’ Magnetism 133 F. Plazaola, E. Apiñaniz, D. Martin Rodriguez, E. Legarra and J. S. Garitaonandia Chapter 7 Magnetic Material Characterization Using an Inverse Problem Approach 171 Ahmed Abouelyazied Abdallh and Luc Dupré Chapter 8 The Everett Integral and Its Analytical Approximation 203 Jenõ Takács Preface Recent progress in information technology, wireless communication, biotechnology and microelectronicsrequiresadvanced technologies and newmagnetic materials to meetdemandsofmoderndevices.Thiscollectionofeightchaptersprovidesanup‐to‐ date review of recent trends and developments in technology, characterization methods, theoryandapplicationsofmodernmagneticmaterials withoriginal,never publishedcontributionsfromtherenownedscientistsinthefieldofmagnetism. The bookisaddressedtoadiversegroupofreaderswhichincludestudents,engineersand researchers in the fields of physics, chemistry, bioengineering, electronics and materials science, who wish to enrich their knowledge about advanced magnetics. Depending onthedisciplinerepresented bythereaderstheyareinvitedtoreadentire book or select chapters of particular interest. In order to help with the choice of appropriatechaptersbelowIsummarizetheircontent: Chapter 1. The first chapter reports on fabrication method of amorphous magnetic nanowires with the glass coating using rapid solidification of the melt. The original measurementmethodsandmagneticpropertiesofthenanowireswiththediameters rangingfrom 90nmto13μmarepresented.Inparticular,thearticletargetstheeffect of fabrication conditions and post‐fabrication treatment on mobility and velocity of domain walls in the nanowires, which can be used in future racetrack memories, magnetic domain wall logic devices, domain wall diodes and oscillators, and other devices. Chapter 2. Future microwavedevicesforwirelesscommunicationsrequire extended frequency range. This chapter treats about new developments in technology and application of a new microwave material‐barium hexagonal ferrite films with extremely high anisotropy, large saturation magnetization and low losses in the microwaverange.Theauthordemonstratesoriginalresultsregardingprototypenotch filtersandphaseshiftersoperatingatmillimeterrangewavelengthswhichemploythe hexagonalferritefilms. Chapter3.Spinelectronics(orspintronics)isanemerging fieldofsciencewhichtakes advantage of magnetic moments to build nonvolatile random access memories and otherdigitaldevices.Inordertocompeteandeventuallyreplacesemiconductor‐based electronics, the spintronic devices must use materials with nearly 100% spin X Preface polarization. The magnetite is one of the best candidates for the spintronic applications. However, its performance in existing devices is drastically reduced by the atomic structure at the surface which differs from that of the bulk. This chapter presentsstudiesofsurface reconstructionofthemagnetiteanddescribesmethodsfor increasing spinefficiencyinspintronicdevicesbypreservingtheFe3O4structureofthe surface. Chapter 4. Multiferroic composites consisting of ferromagnetic and ferroelectric materials provide a unique way of converting magnetic field into electricfield.This processinvolvesstressesattheinterfacebetweenthesematerialsandtakesadvantage ofthepiezoelectricityoftheferroelectricandthemagnetostrictionoftheferromagnetic phase.Thischapterdescribesoriginal methodsofsynthesisofmultiferroiccore‐shell nanoparticles and indicates entirely new biomedical applications of such nanoparticles.Usingexternalalternatingmagneticfieldsitispossibletoproducelocal electricfieldsnearmultiferroicnanoparticleswhichcancontrolopeningandclosingof voltage‐gated ion channels in mammalian cells. Ion channels are involved in generation and propagation of actionpotentialsin nervesandtheirmalfunctioncan lead to multiple diseases such as cystic fibrosis, diabetes, cardiac arrhythmias, neurological disorders or hypertension. The proposed mechanism has also potential foranewmethodofcancertreatment. Chapter 5. One of challenges in the design of portable electronic devices is the optimization of on‐chip inductorsfor the powerconversion.This optimization takes intoaccountmultiplefactors,suchassize,achoiceoffabricationsmethod,frequency rangeofoperation,energylossesandcostofthedevice.Thischapterprovidesdetailed discussion about theory, design, fabrication methods and measurementsof essential parameters characterizing electroplated micro‐inductors for DC‐DC conversion operatingwiththeswitchingfrequencyupto100MHz. Chapter6.Thefocusofthischapterisontherelationbetweenmagneticpropertiesand disorderinthe Fe‐Alsystem.Dependingonthecompositionandthemicrostructure, differentmagneticandstructuralorderscanexistinthissystemincludingaspin‐glass order. Detailed experimental studies based on magnetometry, the Mössbauer effect and X‐raydiffractometry,aswellas theoreticalmodelsofthissystemshow thatthe atomicdisorder,whichcanbecontrolledbya mechanicaltreatmentoranannealing, leadstosignificantincreaseinthelatticeparametersandthemagnetizationcompared tothoseintheordered structures.Thecontributionofdisordertothemagnetismof thesealloysdependsontheFecontentofthealloyandisthelargestclosetotheequi‐ atomic FeAl alloy, but in Fe75Al25 alloy it is similar to the one given by the volume change. Chapter 7. Direct characterization of the magnetic material parameters based on measurementsofmagneticdeviceswithcomplicatedgeometryisacomplexproblem. This chapter proposes the state‐of‐the‐art methodology to extract materials characteristics from the measurements of electromagnetic devices. This original
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