GavashelidzePetre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi, State University, I.. GurgenishviliPetre Melikishvili Institute of Physical an
CHEMICAL ENGINEERING OF POLYMERS Production of Functional and Flexible Materials CHEMICAL ENGINEERING OF POLYMERS Production of Functional and Flexible Materials Edited by Omari V Mukbaniani, DSc Marc J M Abadie, DSc Tamara N Tatrishvili, PhD Apple Academic Press Inc Apple Academic Press Inc 3333 Mistwell Crescent Spinnaker Way Oakville, ON L6L 0A2 Waretown, NJ 08758 Canada USA © 2018 by Apple Academic Press, Inc No claim to original U.S Government works Printed in the United States of America on acid-free paper International Standard Book Number-13: 978-1-77188-445-7 (Hardcover) International Standard Book Number-13: 978-1-315-36598-5 (eBook) All rights reserved No part of this work may be reprinted or reproduced or utilized in any form or by any electronic, mechanical or other means, now known or hereafter invented, including photocopying and re- cording, or in any information storage or retrieval system, without permission in writing from the publisher or its distributor, except in the case of brief excerpts or quotations for use in reviews or critical articles This book contains information obtained from authentic and highly regarded sources Reprinted material is quoted with permission and sources are indicated Copyright for individual articles remains with the authors as indicated A wide variety of references are listed Reasonable efforts have been made to publish reliable data and information, but the authors, editors, and the publisher cannot assume responsibility for the validity of all materials or the consequences of their use The authors, editors, and the publisher have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained If any copyright material has not been acknowl- edged, please write and let us know so we may rectify in any future reprint Library of Congress Control Number: 2017952488 Trademark Notice: Registered trademark of products or corporate names are used only for explanation and identification without intent to infringe Library and Archives Canada Cataloguing in Publication International Caucasian Symposium on Polymers and Advanced Materials (4th : 2015 : Batumi, Georgia) Chemical engineering of polymers : production of functional and flexible materials / edited by Omari V Mukbaniani, DSc, Marc J M Abadie, DSc, Tamara N Tatrishvili, PhD Papers presented at the 4th International Caucasian Symposium on Polymers and Advanced Materials held at Batumi Black sea beach, Georgia July 1-4, 2015 Includes bibliographical references and index Issued in print and electronic formats ISBN 978-1-77188-445-7 (hardcover). ISBN 978-1-315-36598-5 (PDF) Polymers Congresses Chemical engineering Congresses I Mukbaniani, Omari V., editor II Abadie, Marc J M., editor III Tatrishvili, Tamara N, editor IV Title TP1081.I58 2017 668.9 C2017-905795-2 C2017-905796-0 CIP data on file with US Library of C o ngress Apple Academic Press also publishes its books in a variety of electronic formats Some content that appears in print may not be available in electronic format For information about Apple Academic Press products, visit our website at www.appleacademicpress.com and the CRC Press website at www.crcpress.com CONTENTS List of Contributors ix List of Abbreviations xvii About the Editors xxi Preface xxiii PART I: SYNTHESIS AND APPLICATION 1 Copolymerization of Aniline P-Phenylenediamine in an Acetic Acid Medium A H Durgaryan, NA Durgaryan, R H Arakelyan, and N A Miraqyan Free-Radical Frontal Polymerization of Acrylamide in the Presence of Nano and Micro Additives .15 A O Tonoyan and S P Davtyan Influence of Ph on the Structuring of Zetag 9014® Type of Cationic Polymers .23 E Alvarenga, L Hayrapetyan, S Hayrapetyan, G Pirumyan, E Govasmark, and B Salbu Aromatic Azides and Pentazenes in Multistep Radical Polymerization .41 V G Syromyatnikov, D G Vyshnevsky, and A Yu Kolendo Synthesis and Adsorption Properties of 4-Aminostyrene and Methacrylic Acid Copolymer, Immobilized in Situ on Silica Surface .49 E Yanovska, L Vretik, D Sternik, O Kychkiruk, O Nikolaeva, and M Melnyk Synthesis of Polyarylates Containing Ether Bonds in Macromolecules 61 G Papava, N Dokhturishvili, N Gelashvili , M Gurgenishvili, K Papava, I Chitrekashvili, and Z Tabukashvili vi Contents Synthesis of Polyarylates on the Base of Nucleus Bisphenols in High Boiling Solvents 73 G Papava, N Maisuradze, E Gavashelidze, Sh Papava, M Gurgenishvili, I Chitrekashvili, and V Sherozia PART II: COMPOSITES AND NANOPARTICLES .85 Structure and Properties of the Polystyrene/Fullerene Composite Films 87 O Alekseeva, N Bagrovskaya, and A Noskov Composites on the Basis of Sawdust with Some Organic and Inorganic Binders 103 O Mukbaniani, J Aneli, G Buzaladze, E Markarashvili, and T Tatrishvili 10 Aging Process of Gold Nanoparticles Synthesized In Situ in Aqueous Solutions of Polyacrylamides 119 Nataliya Kutsevol, Vasyl Chumachenko, Yuliia Harahuts, and Andriy Marinin 11 Microscale Temperature Visualization in Silver Nanoparticle Doped Polymer Nanocomposite 129 N Ponjavidze and G Petriashvili 12 Polyaniline-Co3O4 Nanocomposites: Synthesis, Structural, Morphological, Optical and Electrical Properties 139 Z Hesari and B Shirkavand Hadavand 13 Strategy for Nanohybridized Synthesis of MAMBOX Systems 147 M Donadze and T Agladze 14 New Composite Polymer Electrolyte Based on PVDF with the Addition of TiO2 165 G S Askarova, K A Ablayeva, A P Kurbatov, and Ye S Sivokhina 15 Dextran-Polyacrylamide as Nanocarrier for Targeted Delivery of Anticancer Drugs into Tumor Cells .183 P Telegeeva, N Kutsevol, S Filipchenko, and G Telegeev 16 Investigation Photothermal and Photooptical Energy Conversions in Silver and Gold Nanoparticles Doped Nanocomposites for the Modeling of Cancer Cells Visualization and Photothermal Cancer Therapy 195 K Chubinidze and M Chubinidze Contents vii 17 Synthesis and Characterization of Conductive Polyurethane Composites Containing Polyaniline–CuO Nanocomposites 207 Z Hesari and B Shirkavand Hadavand PART III: MATERIALS AND PROPERTIES .213 18 Fundamentals and Challenges in Curing Process 215 Marc J M Abadie 19 New Polymer Metal Complexes Based β-Diketone and Lanthanides for OLEDs 231 I Savchenko, A Berezhnytska, and Ya Fedorov 20 Intergel Systems: Highly Effective Instruments for Rare Earth Elements Extraction from Industrial Solutions 267 T K Jumadilov, Zh A Abilov, and R G Kondaurov 21 Investigation of a Complex Formation Process of Copper with Fulvic Acids .281 T Makharadze, G Supatashvili, and G Makharadze 22 HgBa2Ca2Cu3Oy Superconductor Prepared by Vapor Diffusion Process .287 T Lobzhanidze, I Metskhvarishvili, G Dgebuadze, B Bendeliani, M Metskhvarishvili, and V Gabunia 23 Study of Temperature Dependence of Specific Resistance of Nickel- Tungsten Coating on Copper 295 T Marsagishvili, G Mamniashvili, G Tatishvili, N Ananiashvili, M Gachechiladze, and J Metreveli 24 Topology of Formation of Latexes in Heterogeneous Static Monomer-Water Systems 301 A A Hovhannisyan, M Khaddazh, N G Grigoryan, G K Grigoryan, and O A Zhuravleva 25 Synthesis and Research of Some Phtalocyaninic Dyes with Cu, Zn for Testing in the Systems of Solar Cells Type 309 S Robu, G Dragalina, A Popusoi, N Nasedkina, A Covali, and T Potlog 26 Polymeric Recording Media Based on Carbazole Containing Copolymers and Benzoxyphthalocyanines of Transition Metals 319 S Robu, M Abadie, I Andries, A Chirita, N Nasedchina, A Ivancic, and O Corsac viii Contents 27 Buckminsterfullerene-Pyrrolidines as Promising Antioxidants in Polymer Materials 329 Eldar B Zeynalov and Matanat Ya Magerramova 28 Design and Photocatalytic Properties of Semiconductor/Dye//Polymer Thin Film Photocatalysts 345 O Linnik, O Nadtoka, N Chorna, N Smirnova, and V Syromyatnikov 29 Graded Zone Stretching of the Linear Polymers 361 L Nadareishvili, N Topuridze, L Sharashidze, and I Pavlenishvili 30 Possibilities of Current Carrying Superconducting Polymer-Ceramic Nanocomposites Obtainment .371 S P Davtyan and A O Tonoyan PART IV: GREEN CHEMISTRY AND RECYCLING 385 31 The Influence of Rubber Recyclate Morphology on the Properties of Rubber-Asphalt Composite 387 M Sienkiewicz, H Janik, K Borzedowska, and Sz Konkel 32 Degradation of Modified TPS in the Natural and Industrial Compost 397 H Janik, M Sienkiewicz, M Wawrowska, K Wiecierzycka, and A Przybytek 33 Renewable Resources for Polyurethanes and Polyurethane Composites: A Review 407 J T Haponiuk, A Hejna, Ł Piszczyk, J Datta, and K Formela 34 Modification of Polyethylene Films via Photochemical Reaction 433 V Smokal, O Krupka, A Kolendo, and V Syromyatnikov Index 443 LIST OF CONTRIBUTORS Marc J M Abadie Institute Charles Gerhardt of Montpellier – Agreggates, Interfaces and Materials for Energy (ICGM – AIME, UMR CNRS 5253), University Montpellier, Place Bataillon, 34095 Montpellier Cedex 5, France, E-mail: abadie@univ-montp2.fr & marc@ntu.edu.sg Zh A Abilov Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave, 71, Almaty, Republic of Kazakhstan K A Ablayeva Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan T Agladze Georgian Technical University, Kostava Str., 77, 0175, Tbilisi, Georgia, E-mail: tamazagladze@emd.ge O Alekseeva G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo, 153045, Russia, E-mail: avn@isc-ras.ru E Alvarenga NIBIO, Norwegian Institute of Bioeconomy Research, Pb 115, N-1431, Ås, Norway, E-mail: Emilio.Alvarenga@nibio.no N Ananiashvili Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia I Andries Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova R H Arakelyan Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia G S Askarova Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan N Bagrovskaya G A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo, 153045, Russia B Bendeliani Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia A Berezhnytska V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine A Chirita Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova