(Luận văn) nghiên cứu tổng hợp và xác định cấu trúc các phức chất của phối tử (n, n dialkylthiourea) benzamidine ba càng chứa hợp phần alanine với các ion cu2+ và zn2+

BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC QUY NHƠN NGUYỄN THỊ THU HÂN lu an va n NGHIÊN CỨU TỔNG HỢP VÀ XÁC ĐỊNH CẤU tn to p ie gh TRÚC CÁC PHỨC CHẤT CỦA PHỐI TỬ (N,N-DIALKYLTHIOUREA)BENZAMIDINE nl w BA CÀNG CHỨA HỢP PHẦN ALANINE d oa VỚI CÁC ION Cu2+ VÀ Zn2+ oi lm ul nf va an lu at nh LUẬN VĂN THẠC SĨ HÓA HỌC z z gm @ om l.c an Lu Bình Định - Năm 2019 n va ac th si BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC QUY NHƠN NGUYỄN THỊ THU HÂN lu an n va NGHIÊN CỨU TỔNG HỢP VÀ XÁC ĐỊNH CẤU to p ie gh tn TRÚC CÁC PHỨC CHẤT CỦA PHỐI TỬ (N,N-DIALKYLTHIOUREA)BENZAMIDINE BA CÀNG CHỨA HỢP PHẦN ALANINE nl w d oa VỚI CÁC ION Cu2+ VÀ Zn2+ oi lm ul nf va an lu : 44 01 13 at Mã số nh Chun ngành : HĨA VƠ CƠ z z gm @ om l.c an Lu Người hướng dẫn: TS LÊ CẢNH ĐỊNH n va ac th si i LỜI CAM ĐOAN Tôi xin cam đoan, luận văn cơng trình nghiên cứu tơi Các số liệu, kết luận văn trung thực chưa công bố trước lu an n va p ie gh tn to d oa nl w oi lm ul nf va an lu at nh z z gm @ om l.c an Lu n va ac th si ii LỜI CẢM ƠN Để hồn thành luận văn này, tơi chân thành bày tỏ lòng biết ơn sâu sắc đến cá nhân tập thể tạo điều kiện giúp đỡ suốt q trình thực luận văn Trước hết tơi xin trân trọng gửi lời cảm ơn sâu sắc đến TS Lê Cảnh Định, người hướng dẫn khoa học, tận tình hướng dẫn, quan tâm bảo ln động viên tơi suốt q trình Xin gửi lời cảm ơn chân thành tới TS Phạm Chiến Thắng thầy cô lu giáo tổ mơn Hóa vơ Trường Đại học Khoa học Tự Nhiên - Đại học an Quốc Gia Hà Nội tạo điều kiện thuận lợi nhiệt tình hỗ trợ tơi xun suốt n va q trình làm thực nghiệm gh tn to Tôi chân thành cảm ơn sâu sắc PGS.TS Vũ Thị Ngân, anh, p ie chị, em Phịng thí nghiệm Hóa học tính tốn Mơ tận tình giúp đỡ tạo điều kiện cho thực đề tài nl w Cuối cùng, xin gửi lời cảm ơn gia đình, bạn bè ln bên cạnh động d oa viên giúp đỡ để tơi hồn thành khóa luận tốt nghiệp an lu nf va Bình Định, ngày 24 tháng năm 2019 oi lm ul Học viên at nh z Nguyễn Thị Thu Hân z gm @ om l.c an Lu n va ac th si iii MỤC LỤC LỜI CAM ĐOAN i LỜI CẢM ƠN ii MỤC LỤC iii DANH MỤC CÁC KÝ HIỆU VÀ CHỮ VIẾT TẮT vii DANH MỤC HÌNH VẼ viii DANH MỤC BẢNG xi MỞ ĐẦU lu Lý chọn đề tài an n va Mục đích nghiên cứu to Đối tượng phạm vi nghiên cứu gh tn 3.1 Đối tượng nghiên cứu p ie 3.2 Phạm vi nghiên cứu nl w Phương pháp nghiên cứu oa Ý nghĩa khoa học thực tiễn đề tài d CHƯƠNG - TỔNG QUAN lu va an 1.1 Giới thiệu kim loại khả tạo phức chất chúng lm ul nf 1.1.1 Giới thiệu Đồng oi 1.1.1.1 Tính chất chung nh at 1.1.1.2 Khả tạo phức chất Cu(II) z 1.1.1.3 Vai trò sinh học Đồng z @ gm 1.1.2 Giới thiệu Kẽm om l.c 1.1.2.1 Tính chất chung an Lu 1.1.2.2 Khả tạo phức chất Zn(II) 10 1.1.2.3 Vai trò sinh học Kẽm 12 n va ac th si iv 1.2 Giới thiệu benzamidine phức chất chúng 13 1.2.1 Benzamidine hai phức chất chúng 13 1.2.2 Benzamidine ba phức chất chúng 20 1.2.3 Benzamidine ba chứa hợp phần α-amino acid phức chất chúng 30 Chương PHƯƠNG PHÁP THỰC NGHIỆM VÀ TÍNH TỐN 35 2.1 Tổng quan phương pháp nghiên cứu thực nghiệm 36 lu 2.1.1 Phân tích hàm lượng ion kim loại chuẩn độ complexon III 36 an n va 2.1.1.1 Xác định hàm lượng ion Cu2+ phức chất 36 tn to 2.1.1.2 Xác định hàm lượng ion Zn2+ phức chất 37 p ie gh 2.1.2 Phương pháp phổ hồng ngoại IR 38 2.1.3 Phương pháp phổ khối lượng ESI-MS 39 nl w 2.1.4 Phương pháp nhiễu xạ tia X đơn tinh thể 40 oa d 2.2 Phương pháp tính tốn lý thuyết sử dụng phần mềm Gaussian 43 an lu 2.3 Các kỹ thuật kết tinh phức chất 44 va lm ul nf 2.3.1 Phương pháp bay dung môi 44 oi 2.3.2 Phương pháp làm lạnh chậm dung dịch 45 nh 2.3.3 Khuếch tán dung môi 45 at z 2.3.4 Khuếch tán 45 z @ gm 2.3.5 Thăng hoa chân không 45 om l.c 2.4 Dụng cụ hóa chất 46 2.4.1 Dụng cụ 46 Lu an 2.4.2 Hóa chất 46 n va ac th si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an v 2.4.3 Chuẩn bị hóa chất 47 2.5 Tổng hợp phối tử HA 47 2.5.1 Giai đoạn 1: Tổng hợp N,N-diethyl-N’-benzoylthiourea 47 2.5.2 Giai đoạn 2: Tổng hợp phức chất bis(N,N-diethyl-N’benzoylthioureato)nickel(II) 48 2.5.3 Giai đoạn 3: Tổng hợp N,N-(diethylcarbamothioyl)benzimidoyl chloride48 2.5.4 Giai đoạn 4: Tổng hợp phối tử (N,N-diethylthiourea)benzamidine ba lu chứa hợp phần alanine (HA) 49 an n va 2.6 Tổng hợp phức chất 49 tn to 2.6.1 Tổng hợp phức chất Zn(II)-HA 49 p ie gh 2.6.2 Tổng hợp phức chất Cu(II)-HA 50 2.7 Điều kiện thực nghiệm tính tốn 50 oa nl w Chương KẾT QUẢ VÀ THẢO LUẬN 52 d 3.1 Thảo luận trình tổng hợp nghiên cứu phối tử HA 52 lu va an 3.1.1 Thảo luận trình tổng hợp HA 52 ul nf 3.1.2 Nghiên cứu cấu trúc phối tử HA 54 oi lm 3.1.2.1 Nghiên cứu phối tử phương pháp IR 54 at nh 3.1.2.2 Nghiên cứu phối tử phương pháp khối phổ ESI-MS 55 z 3.1.2.3 Nghiên cứu phối tử phương pháp nhiễu xạ tia X đơn tinh thể z gm @ 56 om l.c 3.2 Thảo luận trình tổng hợp nghiên cứu phức chất 60 3.2.1 Thảo luận trình tổng hợp phức chất 60 an Lu 3.2.2 Nghiên cứu cấu trúc hai phức chất 61 n va ac Stt.010.Mssv.BKD002ac.email.ninhd 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an vi 3.2.2.1 Xác định hàm lượng ion kim loại phức chất 61 3.2.2.2 Nghiên cứu phức chất phương pháp phổ IR 62 3.2.2.3 Nghiên cứu phức chất phương pháp khối phổ ESI-MS- 63 3.2.2.4 Nghiên cứu phức chất phương pháp tính tốn lý thuyết sử dụng phần mềm Gaussian 65 3.2.2.5 Nghiên cứu phức chất phương pháp nhiễu xạ tia X đơn tinh thể 68 lu KẾT LUẬN 74 an n va TÀI LIỆU THAM KHẢO a A-TÀI LIỆU TIẾNG VIỆT a tn to B-TÀI LIỆU TIẾNG ANH a p ie gh PHỤ LỤC i QUYẾT ĐỊNH GIAO ĐỀ TÀI LUẬN VĂN (bản sao) p d oa nl w oi lm ul nf va an lu at nh z z gm @ om l.c an Lu n va ac Stt.010.Mssv.BKD002ac.email.ninhd 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an vii DANH MỤC CÁC KÝ HIỆU VÀ CHỮ VIẾT TẮT lu DFT : Density Functional Theory (thuyết phiếm hàm mật độ) HA : (Z)-(((diethylcarbamothioyl)imino)(phenyl)methyl)alanine (HA) IR : Infared Reflectance (Phổ hồng ngoại) ESI-MS : (Electrospray ionization massspectrometry) Phổ khối lượng m : mạnh rm : mạnh tb : trung bình y : yếu an n va p ie gh tn to d oa nl w oi lm ul nf va an lu at nh z z gm @ om l.c an Lu n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an viii DANH MỤC HÌNH VẼ Hình 1.1 Sự tách mức lượng orbital d xếp electron ion Cu2+(d9) trường đối xứng bát diện, bát diện lệch vuông phẳng Hình 1.2 Cấu trúc phức chất Cu(Hdmg)2 [51] Hình 1.3 Một số cấu trúc phức chất Zn(II) [7], [21], [30], [52] 11 Hình 1.4 Sơ đồ điều chế benzimidoyl clorua 13 Hình 1.5 Sơ đồ điều chế benzamidine hai 13 Hình 1.6 Một số dạng tautome benzamidine hai dung dịch 14 lu Hình 1.7 Cấu trúc tinh thể (N,N-diethylthiourea)benzamidine C12H17N3S an [13] 14 n va Hình 1.8 Cấu trúc phân tử phức chất {chloro-[N-(p-nitrobenzoyl)-N’,N’- to gh tn diethyl-thioureato-κO,κS]-dimerthylsulphoxide-κS}-platinum(II) (1) [28] 16 p ie Hình 1.9 Cấu trúc phân tử phức chất [chloro-(N-benzoyl-N’,N’-diphenyl- thioureato-κO,κS)-dimerthylsulphoxide-κS]-platinum(II) (2) [28] 17 oa nl w Hình 1.10 Cấu trúc phân tử phức chất {chloro-[N-(o-chlorbenzoyl)-N’,N’diethyl-thioureato-κO,κS]-dimerthylsulphoxide-κS}-platinum(II) (3) [28] 17 d an lu Hình 1.11 Cấu trúc cis trans phức chất 19 nf va Hình 1.12 Chloro(N-diethylaminothicarbonylbenzamidine)gold(I) [13] 19 lm ul Hình 1.13 Bis[N-(diethylaminothiocarbonyl)-benzamidine]silver(I)-nitrate [14] oi 20 at nh Hình 1.14 Benzamidine ba dẫn xuất từ 2-aminophenol (1), z 2-(aminomethyl)pyridine (2), anthranilic acid (3), benzoylindrazine (4) z @ thiosemicacbazide (5) 20 gm Hình 1.15 Sơ đồ tổng quát điều chế benzamidine ba 21 om l.c Hình 1.16 Cấu trúc phân tử H2L3 [42] 21 Hình 1.17 Cấu trúc (N,N-diethylthiourea)benzamidine ba dẫn xuất từ Lu an benzoylhydrazine (H2L4) [34] 23 n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an c derivatives Antifungal activity", Journal of Inorganic Biochemistry 69, pp 113-119 [17] Criado, J J.; Rodrıǵ uez-Fernández, E.; Garcıá , E.; Hermosa, M R.; Monte, E (1988), "Thiourea derivatives of a-aminoacids Synthesis and characterization of Ni(II), Cu(II) and Pt(II) complexes with L-valinate derivatives Antifungal activity", J Inorg Biocheme 69, pp 113 [18] Del Campo, R.; Criado, J J.; Garcia, E.; Hermosa, M R.; JimenezSanchez, A.; Manzano, J L.; Monte, E.; Rodriguez-Fernandez, E.; Sanz, lu F (2002), "Thiourea derivatives and their nickel(II) and platinum(II) an complexes: antifungal activity", J Inorg Biochem 89 (1-2), pp 74-82 va n [19] Dolomanov, O V.; Bourhis, L J.; Gildea, R J.; Howard, J A K.; to refinement and analysis program", J Appl Cryst 42, pp 339-341 p ie gh tn Puschmann, H.; (2009), "Olex2: a complete structure solution, [20] Douglass, I B.; Dains, F B (1934), "Some Derivatives of Benzoyl and oa nl w Furoyl Isothiocyanates and their Use in Synthesizing Heterocyclic Compounds", J Am Chem Soc 56, pp 719-721 d an lu [21] El Aamrani, F Z.; Garcia-Raurich, J.; Sastre, A.; Beyer, L.; Florido, A nf va (1999), "PVC membranes based on silver(I)–thiourea complexes", ul Analytica Chimica Acta 402(1-2), pp 129-135 lm oi [22] Feltham, H L.; Klower, F.; Cameron, S A.; Larsen, D S.; Lan, Y.; at nh Tropiano, M.; Faulkner, S.; Powell, A K.; Brooker, S (2011), "A family z of 13 tetranuclear zinc(II)-lanthanide(III) complexes of a [3+3] Schiff- z Dalton Trans 40 (43), pp 11425-11432 gm @ base macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene", om l.c [23] Geissinger, M.; Magull, J (1996), "Thioureato Brigded Binuclear Complexes of the Lanthanides Synthesis and Crystal Structure of Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an d [{PhC(NPh)NC(S)NEt2}{Et2NC(S)NH}LnBr(thf)]2 (Ln = Gd, Sm)", Zeitschrift fuer Anorganische und Allgemeine Chemie, pp 622, 734 [24] Guillon, E.; Dechamps-Olivier, I.; Mohamadou, A.; Barbier, J-P (1998), "Synthesis and spectroscopic characterization of copper, nickel and cobalt complexes with N-(N″,N″-disubstituted-aminothiocarbonyl)-N′substituted benzamidines", Inorg Chim Acta, pp 268, 213 [25] Hartung J.; Weber, G.; Beyer, L.; Szargan, R (1985), "Complex Formation of N-(Thiocarbamoyl) benzamidines", Zeitschrift fuer lu Anorganische und Allgemeine Chemie 523, pp 153-160 an [26] Haynes W M L., D R.; Bruno,T J (2005), Bond Lengths and Angles in va n Gas-Phase Molecules, CRC Handbook of Chemistry and Physics, 86th to gh tn Edition, pp 9-19 p ie [27] Hernandez W S., E.; Vega, A.; Richter, R.; Griebel, J.; Kirmse, R.; Schröder, U.; and Beyer, L (2004), "Cis-transIsomerism in Copper(II) oa nl w Complexeswith N-acylThioureaLigands", Z Anorg Allg Chem.(630), pp 1381_1386 d an lu [28] Hernández, W.; Spodine, E.; Richter, R.; Hallmeier, K.; Schröder, U.; nf va Beyer, L (2003), "Platinum(II) Mixed Ligand Complexes with Thiourea ul Derivatives, Dimerthyl Sulphoxide and Chloride: Syntheses, Molecular lm oi Structures, and ESCA Data", Z Anorg Allg Chem 629, pp 2559-2565 z Books-Doubleday, New York at nh [29] Holden, A.; Singer, P.1960), "Crystals and Crystal Growing", Anchor z gm @ [30] Hui, Y.; Feng, W.; Wei, T.; LüX Q.; Song, J.; Zhao, S.; Wong, W K.; Jones, R A (2011), "Adjustment of coordination environment of Ln(III) om l.c ions tomodulate near-infrared luminescent properties of Ln(III) complexes", Inorg.Chem Commun(14), pp 200-204 Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an e [31] Irving, A.; Koch, K R.; Matoetoe, M (1993), "Inorg Chim Acta", pp 206, 193 [32] Maia, P I.; Nguyen, H H.; Ponader, D.; Hagenbach, A.; Bergemann, S.; Gust, R.; Deflon, V M.; Abram, U (2012), "Neutral gold complexes with tridentate SNS thiosemicarbazide ligands", Inorg Chem 51 (3), pp 1604-1613 [33] Masa, W (2003), "Crystal Structure Deternation", Springer [34] Nguyen, H H.; Abram, U.(2009), "Rhenium and technetium complexes lu with tridentate S,N,O ligands derived from benzoylhydrazine", an Polyhedron 28, pp 3945–3952 va n [35] Nguyen, H H.; Deflon ,V M.; Abram, U (2009), "Mixed-Ligand to and Bidentate Benzoylthioureas", Eur J Inorg Chem(21), pp 3179- p ie gh tn Complexes of Technetium and Rhenium with Tridentate Benzamidines 3187 oa nl w [36] Nguyen, H H.; Hazin, K.; Abram, U (2011), "Synthesis and Characterization of Unusual Oxidorhenium(V) Cores", Eur J Inorg d an lu Chem, pp 78 - 82 S.; U Biological "Synthesis, Evaluation oi and (2009), lm Characterization, Abram, ul Bergemann, nf va [37] Nguyen, H H.; Jegathesh, J J; Maia, P.; Deflon, M V.; Gust, R.; of Structural Oxorhenium(V) at nh Complexes with a Novel Type of Thiosemicarbazones Derived from NChlorides", Inorg z gm @ Chem 48, pp 9356-9364 benzimidoyl z [N',N'-Dialkylamino(thiocarbonyl)] [38] Nguyen H H.; Le, C D.; Pham, C T.; Trieu, T N.; Hagenbach, A.; om l.c Abram, U (2012), "Ni(II), Pd(II) and Cu(II) complexes with N(dialkylthiocarbamoyl)-N′-picolylbenzamidines: Structure and activity Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an f against human MCF-7 breast cancer cells", Polyhedron 48 (1), pp 181188 [39] Nguyen, H H.; Maia, P.; Deflon, M V.; Abram, U (2009), "Oxotechnetium(V) Complexes with a Novel Class of Tridentate Thiosemicarbazide Ligands", Inorg Chem 48, pp 25-27 [40] Nguyen H H.; Trieu, T N.; Abram U., (2011), "Syntheses and Structures of Nitridorhenium(V) and Nitridotechnetium(V) Complexes with N,N-[(Dialkylamino)(thiocarbonyl)]-N'-(2- lu hydroxyphenyl)benzamidines", Z Anorg Allg Chem, pp 637 an [41] Nguyen, T B Y.; Pham, C T.; Trieu, T N.; Abram, U.; Nguyen, H H va n (2015), "Syntheses, structures and biological evaluation of some to metal complexes with a tetradentate benzamidine/thiosemicarbazone ligand", Polyhedron 96, 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an h semi and thiosemicarbazide ligands derived from diketo hydrazide”, Polyhedron, pp 81, 749 [53] Yousef, T A.; El-Gammal, O A.; Ahmed, S F.; Abu El-Reash, G M (2014), “Structural, DFT and biological studies on Co(II) complexes of semi and thiosemicarbazide ligands derived from diketo hydrazide”, J Mol Struct, 1076, pp.1227 lu an va n to p ie gh tn oa nl w d ul nf va an lu oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an i PHỤ LỤC Bảng Thông tin hệ phức [CuA(OAc)] [CuA(OAc)] tối ưu hóa mức lý thuyết B3LYP/631-G(d) [CuA(OAc)] -0.66113100 -2.43650000 -0.15042200 S 0.93934400 -2.19692500 -0.81412400 N -1.60167200 -1.50972200 0.03649300 N -1.04140000 -3.71688200 0.10197900 C -2.41741900 -4.05072800 0.46440000 H -2.74139700 -4.91935900 -0.11964700 H -3.06098400 -3.19963800 0.25421100 C -0.13132600 -4.85234700 -0.01092500 H -0.47474600 -5.63712100 0.66907900 H -0.11393500 -5.25365700 -1.03266400 nl w -1.49072100 -0.18304900 0.05214000 N -0.37252400 0.50818100 0.22579800 lu C an va n to p ie gh tn C oa an lu -0.42177500 1.95011800 0.48216000 0.87727700 2.54020700 -0.03862000 nf va C d C 1.82639200 1.85177200 -0.40545100 O 0.89953100 3.86394000 -0.03983200 C 2.13748300 4.48622700 -0.46341300 H 2.34556500 4.23212300 -1.50483300 H 1.96989700 5.55634900 -0.35057800 H 2.96125200 4.14805600 0.16810400 C -2.82638400 0.49720400 -0.10440700 C -3.83803800 0.28295200 0.84072800 C -3.09628000 1.29606000 -1.22458700 ul O oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an j -5.08901000 0.87945000 0.68267300 H -3.63895600 -0.35880000 1.69391000 C -4.35338100 1.87922400 -1.38923200 H -2.32815500 1.43981600 -1.98061800 C -5.34985800 1.67868000 -0.43231800 H -5.86321900 0.71299900 1.42681600 H -4.55480800 2.48534200 -2.26829700 H -6.32691900 2.13681600 -0.55871300 C -0.57338200 2.25669600 1.98781600 H -0.54819800 3.33526400 2.16923000 H -1.53244200 1.86410000 2.33673100 H 0.22755100 1.77729400 2.56033800 H -1.23734200 2.44663900 -0.05231600 O 3.09371800 -0.41910300 0.77914000 C nl w 4.30922300 -0.35296700 0.27181500 O 5.30371300 -0.15510900 0.95123800 lu C an va n to p ie gh tn oa d 4.40275600 -0.55454700 -1.24244100 3.96744800 -1.51896000 -1.52969800 nf va H an lu C 3.84527400 0.22974600 -1.76930300 H 5.44772800 -0.52191200 -1.55741500 Cu 1.43055900 -0.17065400 0.05159800 ul H oi lm at nh -2.51526652 -4.40301219 1.96036849 H -3.44710961 -4.04959417 2.34980932 H -2.45780660 -5.46460269 2.08129813 H -1.70886826 -3.93960848 2.48940425 C 1.30005970 -4.43453949 0.37400599 H 1.82381386 -4.10873372 -0.50031213 z C z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an k H 1.25949681 -3.63514088 1.08408803 H 1.81140224 -5.26944922 0.80569402 [Zn(AOAc)] S 0.97304200 -2.02101700 -1.29294900 N -1.39847100 -1.58908400 0.11431700 N -0.66117000 -3.73212700 -0.05327300 C -1.89029800 -4.19146100 0.59385800 H -1.69725000 -4.46278800 1.63959600 H -2.63197300 -3.39666600 0.56288600 C 0.27437500 -4.79283300 -0.41404700 H 0.04013800 -5.21375900 -1.40058900 H 1.29465800 -4.41233200 -0.43110200 C nl w -1.42154800 -0.25657600 0.23852700 N -0.35371900 0.50169500 0.39689200 an va n to p ie gh tn oa -0.44698100 -2.41418300 -0.30398700 lu C d 0.54528900 2.46539100 -0.64524800 nf va C -0.40126500 1.95667900 0.44318000 an lu C 1.39646500 1.76602100 -1.19213000 O 0.37589500 3.74758800 -0.92718300 C 1.28385800 4.32374300 -1.89613500 H 1.17838300 3.81464800 -2.85636500 H 0.98880000 5.36911300 -1.97538700 H 2.31317200 4.23369400 -1.54309300 C -2.82062200 0.29822700 0.24759800 C -3.31508500 1.04600000 1.32483500 C -3.66977300 0.01592100 -0.83185100 ul O oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an l lu an va n to -4.63012300 1.51411600 1.31657700 H -2.67962800 1.23935100 2.18404300 C -4.97664800 0.49995700 -0.84784800 H -3.29710400 -0.58678900 -1.65466100 C -5.46083500 1.24936600 0.22725400 H -5.00468500 2.08125900 2.16433800 H -5.62088400 0.28478600 -1.69605500 H -6.48289800 1.61812900 0.21879700 C 0.08222700 2.49436700 1.80907900 H 0.11586500 3.58814200 1.80366600 H -0.60789800 2.16935300 2.59268800 H 1.07655500 2.09942600 2.04123200 H -1.39542000 2.35655600 0.21992500 O 2.81669200 0.26414800 1.08464200 C 4.12716800 0.09179400 1.06893800 oa 1.46466500 -0.12019200 -0.12923800 Zn nl w p ie gh tn C d 4.68498300 -0.65703100 -0.14522100 nf va C 4.86244500 0.50000500 1.95152600 an lu O 4.20108700 -1.63456000 -0.25800300 H 4.49608200 -0.08920300 -1.06571800 H 5.76198600 -0.79771500 -0.03433800 C -2.41199068 -5.43582742 -0.14842831 H -1.81420563 -6.28385650 0.11310508 H -3.42912585 -5.61691293 0.13003908 H -2.35511519 -5.27130470 -1.20417328 C 0.16551729 -5.91245778 0.63770885 H -0.43134185 -6.71066768 0.24845299 ul H oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an m H 1.14332359 -6.27915964 0.87078521 H -0.29106475 -5.52546676 1.52465349 Bảng Vị trí giá trị U(eq) nguyên tử phối tử HA lu an va n to p ie gh tn y oa nl w d nf va an lu oi lm at z z U(eq) 44.8(2) 47.8(3) 60.4(8) 42.6(7) 41.8(6) 67.5(8) 36.7(6) 43.9(7) 41.1(6) 60.8(10) 71.2(9) 35.7(7) 76.1(9) 37.5(7) 44.7(8) 35.2(6) 39.2(7) 42.0(8) 45.5(8) 47.8(8) 44.1(8) 52.4(9) 41.0(7) 58.1(10) 52.1(9) 62.2(11) 69.5(12) 68.0(13) 71.0(13) gm @ z 5297.1(7) -279.0(7) 2396(2) 688(2) 1811(2) 2451(2) 1060(2) 4560(2) 4050(2) 3235(2) 2842(2) 690(2) 2366(2) 4558(2) 2197(3) 925(2) 4141(2) 1028(3) 279(3) 2863(3) 4049(3) 4792(3) 5140(3) 795(4) 2845(3) 1809(3) 5327(4) 3167(4) 6555(4) om l.c Lu 689.2(7) 5993.2(7) 6780(2) 8386(2) 6103(2) 1850(3) 7012(2) 3117(2) 1846(2) 982(3) 8103(3) 7932(3) 3258(3) 2695(3) 7607(3) 6398(2) 1211(3) 7832(3) 8560(3) 2631(3) 2612(3) 3309(3) 3282(3) 8573(3) 6489(3) 5388(4) 3872(4) 266(4) 4399(4) nh x 6651.6(9) 3334.8(9) 9082(3) 6495(3) 4252(3) 976(3) 5462(3) 3565(3) 4610(3) 5764(4) 8100(3) 5371(3) 2112(3) 4702(3) 8298(3) 4361(3) 5667(3) 7753(3) 4122(3) 1813(3) 2279(3) 7001(4) 5965(3) 3253(4) 5141(4) 3202(4) 8153(4) 6761(5) 7249(4) ul Atom S001 S002 O003 N004 N005 O006 N007 N008 N009 N00A O00B C00C O00D C00E C00F C00G C00H C00I C00J C00K C00L C00M C00N C00O C00P C00Q C00R C00S C00T an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an n lu an va n to 6103(4) 8268(4) 8790(4) 2088(5) 9782(5) 1225(4) 3820(4) 1936(5) 6212(5) 1802(5) 2660(5) 338(6) 8069(6) 4639(10) 4941(10) 3993(14) 5212(15) 3833(3) 4418(4) 8443(4) 9156(4) 6498(5) 3136(4) 9146(4) 5951(6) 5742(5) 9722(5) 9728(4) 1813(6) 768(5) 1286(7) 2359(9) 1246(13) 1750(12) 6033(3) 6208(4) 771(4) 407(5) 3490(4) 4366(4) -618(4) 1722(4) 3427(4) -489(6) -993(5) 1318(4) 3307(5) 2209(6) 1950(7) 1565(11) 2306(9) 54.8(9) 75.6(14) 73.3(14) 83.4(16) 87.4(17) 72.7(13) 65.4(12) 93(2) 88.8(17) 99(2) 90.1(18) 102(2) 93.7(18) 52(3) 69(3) 90(5) 57(3) p ie gh tn C00U C00V C00W C00X C00Y C00Z C010 C011 C012 C013 C014 C015 C016 C017 C018 C1 C2 Bảng Vị trí giá trị U(eq) nguyên tử phức chất [CuA*]n nl w Table Anisotropic Displacement Parameters (Å2×103) for CuAlaMe oa d The Anisotropic displacement factor exponent takes the form: - oi lm at z z gm om l.c U13 2.7(2) -19.5(7) -16.6(17) -9.1(16) -4.2(16) -9.8(18) -1.8(16) 1.9(18) -3(2) -13(2) 2(2) 3.1(19) Lu an U23 -10.0(2) -20.4(7) -10.7(15) -14.7(16) -8.8(14) -3.0(17) -8.4(15) -5.9(17) -5.6(18) 10(2) -9.8(19) -6.9(17) @ U33 31.1(3) 48.3(7) 38.9(17) 47.3(18) 28.1(18) 38(2) 29.2(18) 30(2) 26(2) 49(3) 28(2) 29(2) nh U22 32.2(3) 53.8(8) 39.3(17) 32.5(18) 30.8(19) 39(2) 32.5(19) 27(2) 29(2) 40(3) 41(3) 35(2) ul U11 40.5(3) 77.0(9) 55(2) 53(2) 37(2) 40(2) 32(2) 24(2) 37(3) 54(3) 41(3) 32(2) nf Atom Cu01 S002 O003 O004 N005 N006 N007 C008 C009 C00A C00B C00C va an lu 2π2[h2a*2U11+2hka*b*U12+…] U12 3.1(2) 34.0(8) -1.9(16) 2.7(17) 2.6(16) 2.1(19) 2.8(16) -4.7(17) 0.5(19) 0(3) -4(2) -1(2) n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an o C00D C00E C00F C00G C00H C00I C00J C00K C00L C00M 48(3) 78(5) 48(3) 99(6) 52(3) 57(3) 67(4) 46(3) 92(5) 83(5) 32(2) 44(3) 37(3) 32(3) 36(3) 64(4) 50(3) 64(4) 58(3) 124(6) 29(2) 57(3) 60(3) 64(4) 57(3) 62(3) 44(3) 124(6) 38(3) 55(4) -8.6(18) -9(3) 6(2) -2(3) -6(2) 2(3) -15(2) 27(4) 3(2) -37(4) -7(2) -7(3) 12(3) -10(4) 0(3) 12(3) -25(3) -20(4) -8(3) 0(4) -1(2) 28(3) 5(3) 0(3) -4(2) 26(4) 8(3) 7(4) -26(4) 14(5) lu an va n to p ie gh tn oa nl w d ul nf va an lu oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 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