organic nanostructures, 2008, p.371

[...]... across the molecular sciences The focus is on the ‘ organic ’ (loosely applied) since it is generally carbon-based building blocks that are the most versatile molecular components that can be induced to link into nanoscale structures As chapters by Mohammed Eddaoudi and Lee Cronin show, however, hybrid organic inorganic materials and well-defined inorganic building blocks as just as capable of assembling... Nanostructures Based on Metal Organic Frameworks (MOFs): En Route to Zeolite-like Metal Organic Frameworks (ZMOFs) 251 Mohamed Eddaoudi and Jarrod F Eubank Introduction 251 Historical Perspective 252 Metal–Cyanide Compounds 252 Werner Complexes 254 Expanded Nitrogen-donor Ligands 255 Carboxylate-based Ligands 258 Single-metal Ion-based Molecular Building Blocks 261 Discrete, 2D and 3D Metal Organic Assemblies... Introduction 275 Background and Classes of Polyoxometalates 277 Wells–Dawson {M18O54} Capsules 278 Isopolyoxometalate Nanoclusters 280 Keplerate Clusters 282 Surface-Encapsulated Clusters (SECs): Organic Nanostructures with Inorganic Cores 285 Perspectives 287 References 287 Nano-capsules Assembled by the Hydrophobic Effect 291 Bruce C Gibb Introduction 291 Synthesis of a Water-soluble, Deep-cavity Cavitand 292... Conclusions 302 References 303 13 Opportunities in Nanotechnology via Organic Solid-state Reactivity: Nanostructured Co-crystals and Molecular Capsules 305 Dejan-Kre4imir Bu4ar, Tamara D Hamilton, and Leonard R MacGillivray s c Introduction 305 Template-controlled [2 þ 2] Photodimerization in the Solid State 305 Nanostructured Co-crystals 307 Organic Nanocrystals and Single Crystal-to-single Crystal Reactivity... 7.3.2 7.3.3 7.4 7.5 7.6 8 8.1 8.2 8.3 8.4 8.4.1 8.4.2 8.4.3 8.4.4 8.4.5 8.4.6 8.4.7 8.5 9 9.1 9.2 Nanoporous Coordination Network Crystals for Uptake/Release of Small Molecules 156 Hybrid Organic organometallic and Inorganic-organometallic Co-crystals 161 Crystal Isomers and Crystal Polymorphs 167 Dynamic Crystals – Motions in the Nano-world 170 Conclusions 172 References 173 Supramolecular Architectures... contributions from the solid-state materials community as in Dario Braga’s perspective on the crystal engineering or organic nanostructures and from experts in discrete molecular assemblies such as Dimitry Rudkevich, Kay Severin, Thomas Rauchfuss and Bruce Gibb Of course, nanostructures are not Organic Nanostructures Edited by Jerry L Atwood and Jonathan W Steed Copyright Ó 2008 WILEY-VCH Verlag GmbH & Co... Bologna Dipartimento di Chimica “G Ciamician” Via Selmi 2 40126 Bologna Italy Michał J Chmielewski University of Oxford Department of Chemistry Inorganic Chemistry Laboratory South Parks Road Oxford OX1 3QR UK Paul D Beer University of Oxford Department of Chemistry Inorganic Chemistry Laboratory South Parks Road Oxford OX1 3QR UK Dario Braga Università di Bologna Dipartimento di Chimica “G Ciamician” Via... Reactivity 308 Self-assembled Capsules Based on Ligands from the Solid State 309 Summary and Outlook 312 References 313 13.1 13.2 13.3 13.3.1 13.4 13.5 14 14.1 14.2 14.3 14.4 14.5 14.6 14.7 14.8 14.9 Organic Nanocapsules 317 Scott J Dalgarno, Nicholas P Power, and Jerry L Atwood Introduction 317 First Generation Nanocapsules 317 Second Generation Nanocapsules 320 Third Generation Nanocapsules 323 Fourth... Complexes 254 Expanded Nitrogen-donor Ligands 255 Carboxylate-based Ligands 258 Single-metal Ion-based Molecular Building Blocks 261 Discrete, 2D and 3D Metal Organic Assemblies 262 Zeolite-like Metal Organic Frameworks (ZMOFs) 264 sod-ZMOF 265 rho-ZMOF 266 Conclusion 270 References 271 10.1 10.2 10.2.1 10.2.2 10.2.3 10.2.4 10.3 10.3.1 10.3.2 10.3.2.1 10.3.2.2 10.4 11 11.1 11.2 11.3 11.4 11.5 11.6 11.7... 40126 Bologna Italy Alberto Credi Università di Bologna Dipartimento di Chimica “G Ciamician” Via Selmi 2 40126 Bologna Italy Leroy Cronin University of Glasgow Department of Chemistry Glasgow G12 8QQ UK Organic Nanostructures Edited by Jerry L Atwood and Jonathan W Steed Copyright Ó 2008 WILEY-VCH Verlag GmbH & Co KGaA, Weinheim ISBN: 978-3-527-31836-0 XVI List of Contributors Marco Curzi Università di . approx. 220 figures and approx. 20 tables Softcover ISBN: 978-3-527-31531-4 Zehetbauer, M. J., Zhu, Y. T. (eds.) Bulk Nanostructured Materials approx. 750 pages with approx. 250 figures and approx shows a space-filling image illustrating the packing of the ligands in the optically pure cage complex [Zn 4 (L o-Phà ) 6 (ClO 4 )](ClO 4 ) 7 and is adapted from Figure 9.5 with the permission. not specifically marked as such, are not to be considered unprotected by law. Typesetting Thomson Digital, Noida, India Printing Strauss GmbH, Mörlenbach Binding Litges & Dopf GmbH, Heppenheim Printed