fundamentals of electrochemistry 2ed 2006 - bagotsky

[...]... 1197 3-5 000, E-mail: jmcbreen@ bnl.govChapter 27 DR KLAUS MĩLLER (retired from Battelle, Geneva, Switzerland), D-85560 Ebersberg, Germany, E-mail: Klaus-mueller-ebersberg@freenet.deChapter 25 PROF ALVIN J SALKIND, Bioengineering Division, University of Medicine and Dentistry of New Jersey, Piscataway, NJ 0885 4-3 635, E-mail: Alvin salkind@umdnj.eduSection 24.5 PROF ZDENEK SAMEC, J Heyrovský Institute of. .. Chemistry, Academy of Sciences of the Czech Republik, CZ-182 23 Prague, Czech Republic, E-mail: zdenek.samec@jh-inst.cas.czChapter 32 DR ALEXANDER M SKUNDIN, A N Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskij Prospekt 31, 119071 Moscow, Russia, E-mail: askundin@mail.ruSections 24.1 to 24.4 PROF ULRICH STIMMING, Physik-Department E-19, Technische Universitọt... The main topic of electrochemistry is investigation of the properties of ionic conductors and of electric circuits containing ionic conductors, and investigation of phenomena occurring during passage of an electric current through such circuits Aqueous solutions of acids, bases, and salts are the ionic conductors used most widely and studied most thoroughly The importance of other types of ionic conductors... beyond electrochemistry as such; they can be found in practically all spheres of human activity They are of exceptional importance in the Fundamentals of Electrochemistry, Second Edition, By V S Bagotsky Copyright â 2006 John Wiley & Sons, Inc 3 C01.qxd 10/29/2005 4 11:55 AM Page 4 ELECTRIC CURRENTS IN IONIC CONDUCTORS form of intracellular uids in the biological and physiological processes of all... eect of motion of positive ions is exactly the same as that of the motion of negative ions, and the total current density is the sum of the partial currents due to transport of each type of ion: i ij F E zjcjuj (1.11) We can see when comparing Eqs (1.4) and (1.11) that a conductors conductivity depends on the concentrations and the mobilities of all types of ions: F zjcjuj (1.12) The fraction of. .. this case the term base electrolyte is used for the set of remaining solution components Often, a base electrolyte is actually added to the solutions to raise their conductivity The concentration of ions of type j in the solution can be stated in terms of the number of moles nj of these ions per unit of the volume V: cj nj / V The electric charge Qj of an ion can be described as Qj Q0zj, where Q0 1.62... VLADIMIR S BAGOTSKY (retired from the A N Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskij Prospekt 31, 119071 Moscow, Russia), Mountain View, CA 94043, E-mail: vbag@mail.rumain author DR LEONID S KANEVSKY, A N Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskij Prospekt 31, 119071 Moscow, Russia, E-mail:... E-mail: c/o askundin@mail.ruSection 33.2 PROF ALEXANDER M KUZNETSOV, A N Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskij Prospekt 31, 119071 Moscow, Russia, E-mail: theor@elchem.ac.ruChapter 34 PROF EZEQUIEL P M LEIVA, INFIQC-Facultad de Ciencias Quớmicas, Universidad Nacional de Cúrdoba, 5000 Cúrdoba, Argentina, E-mail: eleiva@mail.fcq.unc edu.arChapters... electrostatic eld of eld strength E is applied, each type j of ion carrying charge zjF (per mole) nds itself under the eect of an electric driving force fdr zjFE, causing the ions to move in a direction given by the eld This motion under the eect of a eld is called the migration of ions Migration is superimposed on the thermal motion of the ions The ux density Jj of migrating ions (the number of moles crossing... insulators: for example, by electric discharge in the gas phase (electrochemistry of gases) or upon irradiation of liquid and solid dielectrics (radiation chemistry) At the same time, electrochemistry deals with certain problems often associated with other elds of science, such as the structure and properties of solid electrolytes and the kinetics of ionic reactions in solutions This book seeks essentially . index. ISBN-13 97 8-0 -4 7 1-7 005 8-6 (cloth : alk. paper) ISBN-10 0-4 7 1-7 005 8-4 (cloth : alk. paper) 1. Electrochemistry I. Title. QD553.B23 2005 541Ј.37—dc22 2005003083 Printed in the United States of America 10987654321 ffirs.qxd. web site at www.wiley.com. Library of Congress Cataloging-in-Publication Data: Bagotsky, V. S. (Vladimir Sergeevich) Fundamentals of electrochemistry / V. S. Bagotsky 2nd ed. p. cm. Includes bibliographical. class="bi x0 y0 w0 h1" alt="" FUNDAMENTALS OF ELECTROCHEMISTRY Second Edition V. S. BAGOTSKY A. N. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences Moscow, Russia A