[...]... therapy adenosine-5′-triphosphate bacteriochlorophyll back electron transfer 4-[ 4-( 2,2′-bipyridin-4-yl)phenyl ]-2 ,2′-bipyridine 2-( 4′-benzyloxy-phenyl)imidazo[4,5-f ]-1 ,10-phenanthroline 2,2′-bipyridine 4-( 4′-methyl-2,2′-bipyridin-4-yl)butanamide 2,2′-bipyrazine carotenoid conduction band crystal field theory chlorophyll chrysene-5,6-diylidenediamine 2-( 2-chloro-5-nitrophenyl)imidazo[4,5-f ]-1 ,10-phenanthroline... therapy 3-( pyridine-2-yl)-as-triazino[5,6-f ]acenaphthylene 3-( pyridine-2-yl )-5 ,6-diphenyl-as-triazine 3-( pyridine-2-yl)-as-triazino[5,6-f ]phenanthroline photoinduced electron transfer phenyl or phosphorescence 1,4,5,8,9,10,17,18-octaazaphenanthro[9,10-b]triphenylene 1,10-phenanthroline pheophytin phenanthrene-9,10-diylidenediamine benzo[a]phenazine-5,6-diylidenediamine 2-phenylimidazo[4, 5- 2 2f ]-1 ,10-phenanthroline... hole 1,2-diaminoethane 1,4,5,8,9,12-hexaazatriphenylene haemoglobin 2-( 2-hydroxy-l-naphthyl)imidazo[4,5-f ]-1 ,10-phenanthroline 2-( 2-hydroxy-5-nitrophenyl)imidazo[4, 5-f ]-1 ,10-phenanthroline highest occupied molecular orbital 2-( 2-hydroxyphenyl)imidazo[4,5-f ]-1 ,10-phenanthroline humic substance internal conversion interfacial electron transfer intra-ligand charge transfer imidazo[4,5-f ]-1 ,10-phenanthroline... ]-1 ,10-phenanthroline particle-to-metal charge transfer xvi Abbreviations POM poq-Nmet ppip PQ PSI PSII PTT pydppz qdppz QD qpy RC RNOS ROS SCF SEM Sens SOD SP SPE SSCT T tap TAP TEOA tex TON tmtp TPE tpp tpy (terpy) tren TS U UV VB VR XOD polyoxometallate 2 - {2 - [(7 - chloroquinolin - 4 - yl)methylamino]ethylsulfanyl} - N [1,10]-phenantrolin-5-yl-acetamide 2-( 4′-phenoxy-phenyl)-imidazo-1,10-phenantroline plastoquinone... pdta pdtb pdtp PET Ph phehat phen Pheo phi phzi pip PMCT lowest unoccupied molecular orbital metal-to-band charge transfer metal centred 11,12-dimethyl-4,5,9,14-tetraazabenzo[b]triphenylene N-(1,10-phenanthrolin-4-ylmethyl)guanidine metal-to-ligand charge transfer metal-to-metal charge transfer metal-to-particle charge transfer nitromerocyanine magnetic resonance imaging messenger ribonucleic acid the... therapy 3-( pyrid-2′-yl)dipyrido[3,2-a:2′,3′-c]phenazine naptho[2,3-a]dipyrido[3,2-h:29,39-f ]phenazine-5,18-dione quantum dot 2,2′:4′,4″:2″,2″′-quaterpyridine reaction centre reactive NO species reactive oxygen species supercritical fluid semiconductor sensitizer superoxide dismutase nitrosporopyran single-photon excitation second-sphere charge transfer thymine pyrazino[2,3-f ]quinoxaline 1,4,5,8-tetraazaphenanthrene... (Figure 3.1) [3]: (1) (2) (3) (4) ligand-centred, strongly s-bonding orbitals (sL) ligand-centred, p-bonding orbitals (pL) metal-centred p-bonding orbitals (pM), predominantly metal d-orbitals (t2g) metal-centred s-antibonding orbitals (σ * ), predominantly metal d-orbitals M (eg) References 23 (5) ligand-centred p-antibonding orbitals (π *) L (6) metal-centred, strongly s-antibonding (σ * ) orbitals M Accordingly,... The radiation energy effective Bioinorganic Photochemistry Grazyna Stochel, Malgorzata Brindell, Wojciech Macyk, Zofia Stasicka, Konrad Szacilowski © 2009 Grazyna Stochel, Malgorzata Brindell, Wojciech Macyk, Zofia Stasicka, Konrad Szacilowski ISBN: 97 8-1 -4 0 5-1 617 2-5 4 Philosophy of Bioinorganic Photochemistry Figure 1.1 Bioinorganic photochemistry connects inorganic photochemistry with biological,... 4,7-diphenyl-1,10-phenanthroline 4,4′-dimethyl-2,2′-bipyridine dimethyl sulfoxide 2,3-bis(2-pyridyl)benzo[g]quinoxaline 2,3-dipyridin-2-ylpyrazine dipyrido[3,2-a:2′,3′-c]phenazine dipyrido[3,2-d:2′,3′-f ]quinoxaline ethylenediaminetriacetate ethylenediaminetetraacetate 1,2-diaminoethane electron spin resonance electron transfer flavine adenine dinucleotide Förster resonant energy transfer tetrakis(4-trifluoromethylphenyl)porphyrin... phenomena Grazyna Stochel, Małgorzata Brindell, Wojciech Macyk, Zofia Stasicka, Konrad Szaciłowski Abbreviations [12]aneN4 8-oxo-G A ACT ADP AETE AM AOP AOT APDT ATP BChl bet bphb bpip bpy bpy′ bpz Car CB CFT Chl chrysi cnoip COX Cp CT CTTS cyclam cyt ddz 1,4,7,10-tetraazacyclotetradecane 7,8-dihydro-8-oxoguanine adenine antimicrobial chemotherapy adenosine-5′-diphosphate absorption/energy-transfer/emission . pdta 3 - (pyridine - 2 - yl) - as - triazino[5,6 - f ]acenaphthylene pdtb 3 - (pyridine - 2 - yl) - 5,6 - diphenyl - as - triazine pdtp 3 - (pyridine - 2 - yl) - as - triazino[5,6 - f ]phenanthroline. Hb haemoglobin hnaip 2 - (2 - hydroxy - l - naphthyl)imidazo[4,5 - f ] - 1,10 - phenanthroline hnoip 2 - (2 - hydroxy - 5 - nitrophenyl)imidazo[4, 5 - f ] - 1,10 - phenanthroline HOMO highest. adenosine - 5 ′ - triphosphate BChl bacteriochlorophyll bet back electron transfer bphb 4 - [4 - (2,2 ′ - bipyridin - 4 - yl)phenyl] - 2,2 ′ - bipyridine bpip 2 - (4 ′ - benzyloxy - phenyl)imidazo[4,5