seymour carraher’s polymer chemistry, seventh edition

[...]... Polymerization (Addition Polymerization) 6.1 Initiators for Free Radical Chain Polymerization 6.2 Mechanism for Free Radical Chain Polymerization 6.3 Chain Transfer 6.4 Polymerization Techniques 6.4.1 Bulk Polymerization 6.4.2 Suspension Polymerization 6.4.3 Solution Polymerization 6.4.4 Emulsion Polymerization 6.5 Fluorine-Containing Polymers 6.6 Polystyrene 6.7 Poly(vinyl chloride) 6.8 Poly(methyl methacrylate)... Inorganic Reaction Mechanisms 11.3 Condensation Organometallic Polymers 11.3.1 Polysiloxanes 11.3.2 Organotin and Related Condensation Polymers 11.4 Coordination Polymers 11.4.1 Platinum-Containing Polymers 11.5 Addition Polymers 11.5.1 Ferrocene-Containing and Related Polymers 11.5.2 Polyphosphazenes and Related Polymers 11.5.3 Boron-Containing Polymers 11.6 Ion-Exchange Resins 11.7 Summary Glossary Exercises... Table of Contents Chapter 1 Introduction to Polymers 1.1 History of Polymers 1.2 Why Polymers? 1.3 Today’s Marketplace 1.4 Summary Glossary Exercises Further Reading General Encyclopedias and Dictionaries Chapter 2 Polymer Structure (Morphology) 2.1 Stereochemistry of Polymers 2.2 Molecular Interactions 2.3 Polymer Crystals 2.4 Amorphous Bulk State 2.5 Polymer Structure–Property Relationships 2.6... Poly(acrylonitrile) 6.11 Solid State Irradiation Polymerization 6.12 Plasma Polymerizations 6.13 Summary Glossary Exercises Further Reading 173 173 177 183 185 185 187 187 187 190 193 194 197 199 200 201 202 203 203 204 205 Chapter 7 Copolymerization 7.1 Kinetics of Copolymerization 7.2 The Q–e Scheme 7.3 Commercial Copolymers 7.4 Block Copolymers 7.5 Graft Copolymers 7.6 Elastomers 7.7 Thermoplastic Elastomers... Stepwise Polymerization 4.21 Summary Glossary Exercises Further Reading 83 83 88 88 92 94 100 103 109 110 110 113 114 117 119 120 122 122 123 127 128 130 131 133 134 Chapter 5 Ionic Chain-Reaction and Complex Coordination Polymerization (Addition Polymerization) 5.1 Chain-Growth Polymerization—General 5.2 Cationic Polymerization 5.3 Anionic Polymerization 5.4 Stereoregularity and Stereogeometry 5.5 Polymerization... Polypropylene 5.9 Polymers from 1,4-Dienes 5.10 Polyisobutylene 5.11 Metathesis Reactions 5.12 Zwitterionic Polymerization 5.13 Isomerization Polymerization 5.14 Precipitation Polymerization 5.15 Summary ß 2006 by Taylor & Francis Group, LLC 135 136 137 143 148 148 150 153 158 162 164 165 165 166 167 167 Glossary Exercises Further Reading 168 169 170 Chapter 6 Free Radical Chain Polymerization (Addition Polymerization)... given polymer, you might look up molecular weight determinations for that polymer since most molecular weight determinations require the polymer be dissolved Following is a longer version that can be used if hard copy or electronic version of CA is available In searching, polymers from a single monomer are indexed as the monomer name with the term ‘‘homopolymer’’ cited in the modification Thus, polymers... ‘‘homopolymer’’ cited in the modification Thus, polymers of 1-pentene are listed under the monomer 1-Pentene homopolymer Polymers formed from two or more monomers such as condensation polymers and copolymers, as well as homopolymers are indexed at each inverted monomer name with the modifying term ‘ polymer with’’ followed by the other monomer names in uninverted alphabetical order The preferential listing... Examples are: 1-Pentene polymer with 1-hexene 2,5-Furandione polymer with 1,4-butanedisulfonic acid Silane, dichlorodiethylpolymer with dichlorodiphenylsilane While the percentage composition of copolymers (i.e., the ratio of comonomers) is not given, copolymers with architecture other than random or statistical are identified as ‘‘alternating, block, graft, etc.’’ Random or statistical copolymers are not... introduction to polymer molecules, the emphasis is often on concepts although all the aspects are important ß 2006 by Taylor & Francis Group, LLC 1 1 Introduction to Polymers 1.1 HISTORY OF POLYMERS Since most chemists, biochemists, and chemical engineers are now involved in some phase of polymer science or technology, some have called this the polymer age Actually, we have always lived in a polymer age . w0 h0" alt="" Polymer Chemistry Seventh Edition Seymour/ Carraher’s ß 2006 by Taylor & Francis Group, LLC. ß 2006 by Taylor & Francis Group, LLC. Polymer Chemistry Seventh Edition Charles. infringe. Library of Congress Cataloging-in-Publication Data Carraher, Charles E. Seymour/ Carraher’s polymer chemistry. Seventh edition / by Charles E. Carraher, Jr. p. cm. Includes bibliographical references. and technology in polymer science institutes, which concentrate entirely on the scienc e and technologies of polymers. This seventh edition addresses the important subject of polymer science and