heat capacities liquids, solutions and vapours

[...]... Non-electrolytes 5.5 Heat Capacities of Non-electrolyte Mixtures 5.6 Modeling of Heat Capacities of Mixtures References Chapter 6 86 87 89 90 100 106 107 Heat Capacities and Related Properties of Vapours and Vapour Mixtures Christopher J Wormald 112 6.1 Pioneering Measurements of the Heat Capacity of Gases 6.2 The Heat Capacity of Gases and Related Quantities 6.3 The Temperature Dependence of the Ideal Gas Heat Capacity... Contents 7.4 Studies of Apparent Molar Heat Capacities and Standard Partial Molar Heat Capacities of Aqueous Electrolyte Solutions 7.5 Calorimetry and Pressure Effects References Chapter 8 148 149 150 153 154 160 180 182 Speed of Sound Measurements and Heat Capacities of Gases Anthony R H Goodwin and J P Martin Trusler 185 9.1 Introduction 9.2 Heat Capacity 9.3 Measurement of the Speed of Sound 9.4... For instance, as a classical example, consider the standard entropies of liquids at T ¼ 298.15 K They are evaluated from experimental heat capacities at constant pressure from low temperatures to 298.15 K and entropies of phase changes in between (assuming applicability of Heat Capacities: Liquids, Solutions and Vapours Edited by Emmerich Wilhelm and Trevor M Letcher r The Royal Society of Chemistry... constructed by Smith-Magowan and Wood,30 with improved versions being due to White et al.,31 and Carter and Wood.32 However, comparison of heat capacities measured by different types of flow calorimeters and differential thermopile conduction calorimeters shows small differences in measured heat capacities, which are attributed to conductive and convective heat losses Conductive heat losses, the principal... Introduction 8.2 Scanning Transitiometry 8.3 Heat Capacities of Liquids under High Pressures 8.4 Conclusions References Chapter 9 Scanning Transitiometry and its Use to Determine Heat Capacities of Liquids at High Pressures Stanislaw L Randzio 185 186 191 196 209 209 Speed-of-Sound Measurements and Heat Capacities of Liquid Systems at High Pressure Toshiharu Takagi and Emmerich Wilhelm 218 10.1 10.2 Introduction... the monograph on Heat Capacities of Liquids: Volumes I and II Critical Review and Recom´ mended Values, authored by Zabransky et al (1996),39 with Supplement I of ´ 2001.40 This monograph also contains a valuable survey of calorimetric techniques for determining heat capacities of liquids, and useful comments on terminology and criteria for the classification of calorimeters As concerns heat capacity data... References Chapter 18 Heat Capacity in Liquid Crystals M Marinelli, F Mercuri and U Zammit 367 370 373 376 378 381 386 Heat Capacities and Phase Transitions for the Dynamic Chemical Systems: Conformers, Tautomers, Plastic Crystals, and Ionic Liquids Gennady Kabo, Eugene Paulechka and Michael Frenkel 18.1 18.2 18.3 18.4 18.5 Introduction Practical Calculations of Heat Capacity for Gases and Liquids by Statistical... References Chapter 5 Heat Capacities and Related Properties of Liquid Mixtures Emmerich Wilhelm and Jean-Pierre E Grolier 54 4.1 Introduction 4.2 Experiment 4.3 Selected Results and Discussion 4.4 Concluding Remarks References Chapter 4 49 50 52 54 58 61 74 75 Heat Capacity of Non-electrolyte Solutions Amr Henni 86 5.1 Introduction 5.2 Fundamentals 5.3 Experimental Arrangements 5.4 Heat Capacities of Aqueous... The measured heat capacity of an organic compound can usually be extrapolated to 0 K by fitting a Debye heat capacity function to the experimental values at, say, 10 K The nature and the size of this monograph’s topic make it impractical to cover the entire subject in one volume As indicated in the title, the focus will be on heat capacities of chemically non-reacting liquids, solutions and vapours/ gases... the Heat Capacity of Gases 6.5 The Enthalpy of Mixing of Gases at High Pressures 6.6 Heat Capacities of Gases at High Pressures References Chapter 7 112 113 116 121 126 127 129 Heat Capacity of Electrolyte Solutions Andrew W Hakin and Mohammad M.H Bhuiyan 132 7.1 7.2 7.3 132 133 140 Introduction Experimental Approaches Some Theoretical Considerations xi Contents 7.4 Studies of Apparent Molar Heat Capacities .