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I And Petroleum
Engineering
enw’-u
?N
McGraw-Hill Chemical Engineering Series
Editorial Advisory Board
James J. Carberry,
Professor
of
Chemical Engineering, University
of
Notre Dame
James
R
Fair,
Professor of Chemical Engineering, University
of
Texas, Austin
William P. Schowalter,
Dean, School
of
Engineering, University
of
Illinois
Matthew
Tipell,
Professor
of
Chemical Engineering, University
of
Minnesota
James
Wei,
Professor
of
Chemical Engineering, Massachusetts Institute
of
Technology
Max S. Peters,
Emeritus, Professor
of
Chemical Engineering, University
of
Colorado
Building the Literature of a Profession
Fifteen prominent chemicalengineers first met in New York more than 60 years
ago to plan a continuing literature for their rapidly growing profession. From
industry came such pioneer practitioners as Leo H. Baekeland, Arthur D. Little,
Charles L. Reese, John V. N. Dorr, M. C. Whitaker, and R. S. McBride. From
the universities came such eminent educators as William H. Walker, Alfred H.
White, D. D. Jackson, J. H. James, Warren K. Lewis, and Harry A. Curtis. H. C.
Parmelee, then editor of Chemicaland Metallu~cal Engineering, served as
chairman and was joined subsequently by S. D. Kirkpatrick as consulting editor.
After several meetings, this committee submitted its report to the
McGraw-Hill Book Company in September 1925. In the report were detailed
specifications for a correlated series of more than a dozen texts and reference
books which have since become the McGraw-Hill Series in Chemical Engineer-
ing and which became the cornerstone of the chemical engineering curriculum.
From this beginning there has evolved a series of texts surpassing by far
the scope and longevity envisioned by the founding Editorial Board. The
McGraw-Hill Series in Chemical Engineering stands as a unique historical
record of the development of chemical engineering education and practice. In
the series one finds the milestones of the subject’s evolution: industrial chem-
istry, stoichiometry, unit operations and processes, thermodynamics, kinetics,
and transfer operations.
Chemical engineering is a dynamic profession, and its literature continues
to evolve. McGraw-Hill, with its editor, B. J. Clark and consulting editors,
remains committed to a publishing policy that will serve, and indeed lead, the
needs of the chemical engineering profession during the years to come.
The Series
Bailey and Ollis: Biochemical Engineering Fundamentals
Bennett and Myers: Momentum, Heat, and Mass Transfer
Beveridge and Schechter: Optimization: Theory and Practice
Brudkey and
Hershey: Transport
Phenomena: A Unified Approach
Carberry: Chemicaland Catalytic Reaction Engineering
Constantinides: Applied Numerical Methodr with Personal Computers
Coughanowr and Koppel: Process Systems Analysis and Control
’ .
Douglas: Conceptual Design
of
Chemical Processes
Edgar and Himmelblau: Optimization
of
Chemical Processes
Gates, Katzer, and Schuit: Chemistry
of
Catalytic Processes
Holland: Fundamentals
of
Multicomponent Distillation
Holland and Liapis: Computer Methods
for
Solving Dynamic Separation Problems
Katz and
Lee:
Natural Gas Engineering: Production and Storage
King: Separation Processes
Lee: Fundamentals
of
Microelectronics Processing
*
Luybeo: Process Modeling, Simulation, and Control
for
Chemical Engineers
McCabe, Smith, J. C., and Harriott: Unit Operations
of
Chemical Engineering
Mickley, Sherwood, and Reed: Applied Mathematics in Chemical Engineering
Nelson: Petroleum Refinery Engineering
Perry and Green (Editors): Chemical Engineers’ Handbook
Peters: Elementary Chemical Engineering
Peters and Timmerhaus: PlantDesignandEconomics
for
Chemical Engineers
Reid, Prausoitz, and Rolling: The Properties
of
Gases and Liquids
Sherwood, Pigford, and Wilke: Mass Transfer
Smith, B. D.: Design
of
Efluilibrium Stage Processes
Smith, J. M.: Chemical Engineering Kinetics
Smith, J. M., and Van Ness: Introduction to Chemical Engineering Thermodynamics
Treybal: Mass Transfer Operations
Valle-Riestra: Project Evolution in the Chemical Process Industries
’
Wei, Russell, and Swartzlander: The Structure
of
the Chemical Processing Industries
Weotz: Hazardous Waste Management
S
+ CH,-CH, + Cl,
CH2CICH,CI
+
S
Ddhn
Ethykne chlorioc
Ethykne
dichlorii DolLn
(C.
F.
Bruun
and
Co.)
‘Ike
complete
plant-the complete economic process. Here is the
design
en@neer’s
goal.
PLANT DESIGN AND
ECONOMICS FOR
CHEMICAL ENGINEERS
Fourth Edition
Max S. Peters
Klaus D. Timmerhaus
Professors
of
Chemical Engineering
University
of
Colorado
I,
:’
’
:
!‘.
J.
, $
McGraw-Hill, Inc.
New York St. Louis San ijranciko Auckland Bogotfi Caracas ‘Hamburg
Lisbon London Madrid Mexico Milan Montreal New Delhi Paris
San Juan
SHo
Paula Singapore Sydney Tokyo Toronto
PLANT DESIGNANDECONOMICSFORCHEMICAL ENGINEERS
INTERNATIONAL EDITION 1991
Exclusive rights by McGraw-Hill Book Co.
-
Singapore
for manufacture and export. This book cannot be reexported
from the countty to which it is consigned by McGraw-Hill.
234567890CMOPMP95432
Copyright
0
1991, 1980, 1968, 1958 by McGraw-Hill, Inc. All
rights reserved. Except as permitted under the United States
Copyright Act of 1976, no part of this publication may be
reproduced or distributed in any form or by any means, or stored
in a data base or retrieval system, without the prior written
permission of the publisher.
This book was set in Times Roman by Science Typographers. Inc.
The editors were B.J. Clark and$hn M. Morriss;
the production supervisor was Richard Ausburn.
The cover was designed by Carla Bauer
Project supervision was done by Science Typographers, Inc.
Library of Congress Cataloging-in-Publication Data
Peters, Max Stone, (date)
Plantdesign andeconomicsforchemical engineers/Max S. Peters.
Klaus D. Timmerhaus.4th ed.
P.
cm (McGraw-Hill chemical engineering series)
Includes bibliographical references.
ISBN 0-07-0496137
1. Chemical plants Designand construction.
I. Timmerhaus,
Klaus
D. II. Title. III. Series.
TP155.5P4 1991
660’2Mc20
89-77497
When ordering this title me ISBN 0-97-100871-3
Printed in Singapore
ABOUTTHEAUTHORS
MAX S. PETERS is currently Professor Emeritus of Chemical Engineering and
Dean Emeritus of Engineering’ at the University of Colorado at Boulder. He
received his B.S. and M.S. degrees in chemical engineering from the Pennsylva-
nia State University, worked for the Hercules Power Company and the Treyz
Chemical Company, and returned to Penn State for his Ph.D. Subsequently, he
joined the faculty of the University of Illinois, and later came to the University
of Colorado as Dean of the College of Engineering and Applied Science and
Professor of Chemical Engineering. He relinquished the position of Dean in
1978 and became Emeritus in 1987.
Dr. Peters has served as President of the American Institute of Chemical
Engineers, as a member of the Board of Directors for the Commission on
Engineering Education, as Chairman of the President’s Committee on the
National Medal of Science, and as Chairman of the Colorado Environmental
Commission. A Fellow of the American Institute of Chemical Engineers. Dr.
Peters is the recipient of the George Westinghouse Award of the American
Society for Engineering Education, the Lamme Award of the ASEE, the Award
of Merit of the American Association of Cost Engineers, the Founders
Award of the American Institute of Chemical Engineers, and the W. K. Lewis
Award of the AIChE. He is a member of the National Academy of Engineering.
KLAUS D. TIMMERHAUS is currently Professor of
.Chemical
Engineering
and Presidential Teaching Scholar at the University of Colorado at Boulder. He
received his B.S., M.S., and Ph.D. degrees in Chemical Engineering from the
University of Illinois. After serving as a process design engineer for the
California Research Corporation, Dr. Timmerhaus joined the faculty of
the University of Colorado, College of Engineering, Department of Chemical
Engineering. He was subsequently appointed Associate Dean of the College of
Engineering and Director of the Engineering Research Center. This was fol-
lowed by a term as Chairman of the Chemical Engineering Department. The
vii
. . .
VII1
ABOUT THE AUTHORS
author’s extensive research publications have been primarily concerned with
cryogenics, energy, and heat and mass transfer, and he has edited 25 volumes of
Advances in Cryogenic Engineering and co-edited 24 volumes in the International
Cqvogenics Monograph Series.
He is past President of the American Institute of Chemical Engineers,
past President of Sigma Xi, current President of the International Institute of
Refrigeration, and has held offices in the Cryogenic Engineering Conference,
the Society of Sigma Xi, the American Astronautical Society, the American
Association for the Advancement of Science, the American Society for Engi-
neering Education-Engineering Research Council, the Accreditation Board
for Engineering and Technology, and the National Academy of Engineering.
A Fellow of AIChE and AAAS Dr. Timmerhaus has received the ASEE
George Westinghouse Award, the AIChE Alpha Chi Sigma Award, the AIChE
W. K. Lewis Award, the AIChE Founders Award, the USNC/IIR W. T.
Pentzer Award, the NSF Distinguished Service Award, the University of
Colorado Stearns Award, and the Samuel C. Collins Award, and has been
elected to the National Academy of Engineering and the Austrian Academy
of Science.
CONTENTS
Preface
Prologue-The International System of Units
(SI)
1
Introduction
2 Process Design Development
3 General Design Considerations
4
Computer-Aided
Design
5 Cost and Asset Accounting
6
Cost Estimation
7 Interest and Investment Costs
8 Taxes and Insurance
9 Depreciation
10 Profitability, Alternative Investments,
and Replacements
11
Optimum DesignandDesign Strategy
12
Materials Selection and Equipment Fabrication
Xi
xv
1
13
47
110
137
150
216
253
267
295
341
421
ix
X CONTENTS
13
14
15
16
17
A
B
C
D
The Design Report
Materials Transfer, Handling, and Treatment
Equipment-Design and Costs
Heat-Transfer Equipment-Design and Costs
Mass-Transfer and Reactor Equipment-Design
and Costs
Statistical Analysis in Design
Appendixes
The International System of Units 61)
Auxiliary, Utility, andChemical Cost Data
Design Problems
Tables of Physical Properties and Constants
Indexes
Name Index
893
Subject Index
897
452
478
579
649
740
778
800
817
869
[...]... pilot -plant data are necessary, and a program to obtain this information may be initiated Process development ,on,a pilot -plant or semiworks scale is usually desirable in order to -obtain accurate design data.- 16 PLANTDESIGNANDECONOMICS FOR CHEMICALENGINEERS Valuable information on material and energy balances can be obtained, and process conditions can be examined to supply data on temperature and. .. necessary for a detailed-estimate design The following factors should be tSee Chap 13 for assistance in preparing more concise and clearer de&n rebrts 18 PLANTDESIGNANDECONOMICS FOR CHEMICALENGINEERS established within narrow limits before a detailed-estimate design is developed: 1 Manufacturing process 2 Material and energy balances 3 Temperature and pressure ranges 4 Raw-material and product... problem A plant- design project moves to completion through a series of stages such as is shown in the following: 1 Inception 2 Preliminary evaluation of economicsand market 3 Development of data necessary for final design 4 Final economic evaluation 5 Detailed engineering design 6 Procurement 7 Erection 8 Startup and trial runs 9 Production t ’ I 1 - 2 PLANTDESIGNANDECONOMICS FOR CHEMICAL ENGINEERS. .. arrangements, and other information required for the actual construction of the plant The final stage * I _ 4 PLANTDESIGNANDECONOMICS FOR CHEMICALENGINEERS consists of procurement of the equipment, construction of the plant, startup of the plant, overall improvements in the operation, and development of standard operating procedures to give the best possible results The development of a design project proceeds... process designs (or detailed designs) can be prepared for purchasing and construction from a detailed-estimate design Detailed drawings are made for the fabrication of special equipment, and specifications are prepared for purchasing standard types of equipment and materials A complete plant layout is prepared, and blueprints and instructions for construction are developed Piping diagrams and other... gives descriptive and background information for the SI units along with a detailed set of rules for SI usage and lists of conversion factors presented in various forms which should be of special value forchemical engineering usage Chemicalengineers in design must be totally familiar with SI and its rules Reading of Appendix A is recommended for those readers who have not worked closely and extensively... Fundamentals, Industrial and Engineering Chemistry Process Designand Development, Journal of the American Chemical Society, Journal tAbstracts of general engineering articles are available in the En@etik Inks a 20 PLANTDESIGNANDECONOMICSFORCHEMICALENGINEERS of Physical Chemistv, Hydrocarbon Processing, Engineering News-Record, Oil and Gas Journal, and Canadian Journal of Chemical Engineering A... the design of individual pieces of equipment or to develop the strategy for a full plantdesign This application of computer usage in design is designated as computer-aided designand is the subject of Chap 4 Record keeping and accounting procedures are also important factors in general design considerations, and it is necessary that the design engineer be familiar with the general terminology and. .. engineer be led to believe that plants are designed around computers They are used to determine design data and are used as models for optimization once a design is established They are also used to maintain operating plants on the desired operating conditions The latter function is a part of designand supplements and follows process design The general approach in any plantdesign involves a carefully... process -design phase is ready to begin All the design details are worked out in this phase including controls, services; piping layouts, firm price quotations, specifications and designs for individual pieces of equipment, and all the other design information necessary for the construction of the final plant A complete construction design is then made with elevation drawings, plant- layout arrangements, and . Engineering Perry and Green (Editors): Chemical Engineers Handbook Peters: Elementary Chemical Engineering Peters and Timmerhaus: Plant Design and Economics for Chemical Engineers Reid, Prausoitz, and Rolling:. CONTENTS 13 14 15 16 17 A B C D The Design Report Materials Transfer, Handling, and Treatment Equipment -Design and Costs Heat-Transfer Equipment -Design and Costs Mass-Transfer and Reactor Equipment -Design and Costs Statistical. - I 1 2 PLANT DESIGN AND ECONOMICS FOR CHEMICAL ENGINEERS This brief outline suggests that the plant- design project involves a wide variety of skills. Among these are research, market analysis, design