Chemical kinetics fundamentals and new developments docx

[...]... chemical kinetics Chapter 1 General ideas of chemical kinetics 1.1 Subject o f chemical kinetics The chemical process of transformation of reactants into products is the subject of studying of chemical kinetics One can say against it that the chemical reaction is also the subject of studying of several other chemical disciplines, such as synthetic and analytical chemistry, chemical thermodynamics and. .. Chemistry and Chemical Kinetics of the Institute of Problems of Chemical Physics (from 1974 up now) His scientific interests lie in the following fields of chemical kinetics: elementary reactions of free radicals in solutions and polymeric matrix and the kinetics of oxidation and inhibiting action of antioxidants Prof Denisov is author of 17 monographs and 390 papers on chemistry of oxidation and free... Endeavors in 1991 and International Academy of Sciences in 1994 From 1979 to 1989 he was a member of IUPAC Commission on physicochemical symbols, terminology, and units and in 1989-1991 the Chairman of Commission on Chemical Kinetics Prof Denisov was the Chairman of the Kinetic Section of the Scientific Council on Structure and Chemical Kinetics of the Academy of Sciences of Russia (1972-1997), and he is Chairman... of chemical kinetics in combination with its modern applications in chemistry, technology, and biochemistry A brief historical note is given below The material is traditionally divided into formal kinetics and kinetics in the gaseous phase The main concepts of chemical kinetics were formulated during the end of the 19th century when C Guldberg and P Waage formulated the law of action mass (1867) and. .. on chemical kinetics In this monograph, chemical kinetics was presented as simple chemical reactions It was in the beginning of the 20 th century that researchers faced complicated mechanisms of chemical reactions and during the period 1910-1935, chain reactions were discovered (M Bodenstein, N Semenov, S Hinshelwood) In this period, chemical kinetics was transformed into the science of complex chemical. .. molecules and radicals In turn, results of the chemical kinetics compose the scientific foundation for the synthetic chemistry and chemical technology The methods for affecting the reaction developed in the kinetics are used for controlling the chemical process and creation of kinetic methods for the selective preparation of chemical compounds The methods for retardation (inhibition) of chemical processes... "tough" chemical problems under mild conditions: hydrolysis peptides, substrate oxidation, nitrogen fixation, long-distance electron transfer conversion of light energy to chemical energy, etc.; and 7) Chemical modeling of enzymes: achievements and problems This monograph is intended for scientists working in various areas of chemistry and chemical and biotechnology, as well as for instructors, graduate and. .. their precise specificity, selectivity, high rate, and capacity to be regulated Classical and modern physical chemistry, chemical kinetics, organic, inorganic and vi quantum-chemistry provide a variety of physical methods and establish a basis for investigation of structure and action mechanisms of enzymes The general properties of enzymes, the "ideal" chemical catalysts, are the formation of intermediates,... the Professor of Chemistry and vice director at N.N Semenov Institute of Chemical Physics of the Russian Academy of Sciences and the Professor at the Faculty of Molecular and Biological Physics of Moscow Institute of Physics and Technology He is the author of more than 200 publications His scientific interests: kinetics and dynamics of elementary reactions, laser spectroscopy, and photochemistry Gertz... reactions in gaseous and liquid phases Simultaneously, the theory of the elementary act of monomolecular and bimolecular reactions was advanced The absolute rate theory was developed in the 1930s by S Glasstone, K Laidlerand and H Eyring New advancements in the theory of chemical reactions began with the appearance and development of quantum chemistry The advanced theory of electron and proton transfer . chemistry, and heterogeneous catalysis. 1.2. History of the appearance of chemical kinetics Chemical kinetics is a rather young science among other chemical. Vant-Hoff was the first monograph on chemical kinetics. In this monograph, chemical kinetics was presented as simple chemical reactions. It was in the beginning