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NITRITECURING
OF
MEAT
The N-NitrosamineProblemand
Nitrite Alternatives
RONALD
B.
PEGG, Ph.D.
Saskatchewan Food Product Innovation Program
Department of Applied Microbiology and Food Science
University of Saskatchewan, Saskatoon,
SK,
S7N
5A8
Canada
and
FEREIDOON SHAHIDI, Ph.D.
FACS, FCIC, FCIFST, FRSC
University Research Professor
Department
of
Biochemistry
Memorial University of Newfoundland
St.
John's,
NF, A1B
3x9
Canada
FOOD
&
NUTRITION
PRESS,
INC.
TRUMBULL, CONNEXTICUT
06611
USA
[...]... respectively, on 4 NITRITECURING OF MEATthe outer surface ofthe netted hams (Fiddler et al 1997) Therefore, caution must be exercised to avoid accidental formation of N-nitrosamines in products Benefits and Drawbacks of Nitrite: New Trends and Prospects In response to the nitrite- nitrosamine problem, the industry reduced the level ofnitrite used in preparation of a variety of products The current trends,... production of low -nitrite, low-fat, low- salt, and all -meat products In addition, all -meat emulsion-type products are being introduced into the market Although theN-nitrosamine scare has died down, nonetheless, nitrite- free curingofmeat might still be attractive in view ofthe fact that many ofthe effects ofnitrite can be easily duplicated by the presence of adjuncts, together with refrigeration The. .. different effects on the rate of production and level of these carcinogens in products The interest in studying the formation and occurrence of N-nitrosa- 3 INTRODUCTION mines in cured meats and other foods stems from the absolute nature ofthe U.S Food and Drug Regulations and other regulatory agencies in Canada and Europe which prohibit the use of any food additive, that is either in itself carcinogenic... nitrate and/ or nitrite to solid cuts ofmeat such as ham Thecuring agents are rubbed in dry form over the surface of pieces of meatThemeat is then placed in a cooler at 2-4°C and permitted to cure No water is added; hence, thecuring agents are solubilized in the original moisture present in the muscle tissue With time, slow penetration of the cure into themeat (cu 2.5 c d w e e k ) and micrococcal... Nitrates, nitrites and N-nitroso compounds: a review ofthe occurrence in food and diet andthe toxicological implications Food Addit Contarn I , 717-768 CHAPTER 2 HISTORY OFTHECURING PROCESS The preservation ofmeat by way ofcuring is based in part upon the art as practiced through eons of time and perhaps to a far greater extent upon sound scientific principles developed since the turn ofthe century... pieces ofmeatand encourage their cohesion During cooking, the protein matrix denatures and coagulates It has been proposed that juiciness results from the coagulation ofthe salt-soluble proteins which in turn entrap moisture within particles ofmeat Other researchers have suggested that the myofibrillar proteins immobilize the water 10 NITRITECURINGOFMEATand reduce evaporation during thermal... attributes that nitrite imparts to meat, and ramifications and possible alternatives to its usage are discussed in the remaining chapters of this book REFERENCES Binkerd, E.F and Kolari, O.E 1975 The history and use of nitrate andnitrite in thecuringofmeat Food Cosmet Toxicol 13, 655-661 Doran, G.F 1917 Art ofcuring meats U.S Patent 1,212,614 Flores, J , Biron, C., Izquierdo, L and Nieto, P 1988... Spices and other flavorings were added to achieve a distinctive brand flavor Toward the end ofthe nineteenth century, significant changes in meatcuring had occurred Various methods of curing, namely dry, wet or pickle cures and combinations ofthe two, were commonplace Dry curing is the oldest technique and involves applying uniform and quantitated mixtures of salt, sugar, spices and sodium nitrate and/ or... to the preservation ofmeat For example, certain spices and herbs possess antioxidant properties and thereby reduce the rate of oxidative rancidity development (Nakatani 1997).A list of some ofthe common spices used in meat products, their origin, and some typical examples of their use in processed meats are presented in Table 2.2 (Hedrick er al 1994) Of all the aforementioned additives to cured meats,... color and special flavor in meat It was nitrate impurities in the rock salt, which upon incorporation into themeat matrix and after reduction to nitrite by the postmortem reducing activity ofthe muscle tissue, that were truly responsible for thecuring effect 8 NITRITECURINGOFMEAT By medieval times, treating meat with salt, saltpeter and smoke was commonplace, and saltpeter’s effect to “fix” the . alt=""
NITRITE CURING
OF
MEAT
The N-Nitrosamine Problem and
Nitrite Alternatives
F
N~
PUBLICATIONS IN
FOOD SCIENCE AND NUTRITION
Books
NITRITE CURING. a review of the history of the curing process. Issues on
how curing began, techniques used then and today, and the discovery of nitrite
as the active