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Energy & Air
Pollution
Introduction
Fossil Fuels: Oil & Gas
Fossil Fuels: Coal
Nuclear Energy
Alternative Energy Resources
Air Pollution
Summary
At the heart of modern society lies an economy driven by energy use.
Unfortunately, the same energy that brings us comfort, convenience, and
prosperity also brings us pollution, impoverishment, and global warming.
Our challenge is to maximize the benefits gained from energy
consumption while minimizing the costs incurred.
Douglas Foy
A fuming smokestack is the perfect symbol of our national dilemma. On
the one hand, it means the jobs and products we need. On the other, it
means pollution.
American Gas Association ad, 1991
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Introduction
• Fossil fuels (oil, gas, coal) makeup most of the energy
consumed in the U.S.
• Energy use increases with increasing population, land area,
and industrial activity and energy use per capita is greatest
in large, sparsely populated states.
• Fossil fuels are non-renewable resources with limited life
span and their combustion contributes to global warming.
• Alternative energy sources such as solar and wind power
are renewable and hold the promise of a sustainable energy
future.
U.S. Energy Use
Current U.S. energy use is weighted heavily toward fossil fuels
(oil, natural gas, and coal) that account for approximately 90%
of all energy used in the nation (Fig. 1). Environmental
concerns over airpollution and the potential for global
warming may encourage wider access to alternative energy
sources such as nuclear power and wind or solar energy.
Nuclear power accounts for about a fifth of U.S. electricity
generation but only 5% of total energy consumption.
Alternative energy sources (hydroelectric, wind, solar,
geothermal) generate 5% of U.S. energy production but may
expand that share in the decades ahead.
Energy use within the U.S. varies with population size and
character of energy demand (Fig. 2). States with large
populations, large land area (greater distances to travel), and
Figure 1. U.S. energy
consumption per
energy type, 1949 to
1995.
Graph courtesy
of the Energy
Information
Administration.
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energy-intensive industries (e.g., oil refining, chemicals),
typically use the most energy. Large sparsely populated states
such as Wyoming and Alaska rate highly in energy use per
person because transportation consumes large volumes of fuel.
Fossil fuels form from decayed organic material through a
series of chemical reactions that occur gradually over millions
of years under specific physical conditions in a select group of
rocks. These conditions make it possible to predict where oil
and gas may be found but also highlight the fact that fossil
fuels are non-renewable resources that will not be replaced
once used. Reserves of oil and natural gas will probably be
stretched out for another century but we must face the
inevitable conclusion that these finite resources will have to be
replaced with an alternative form of energy in the next 50
years. The inevitable decrease in the availability of fossil fuels
will be felt most acutely in transportation because there is no
viable inexpensive replacement for the refined petroleum
products that fuel automobiles and airplanes.
Coal represents an alternative fossil fuel with a potentially
longer life span than either oil or gas but it has the unfortunate
distinction of generating more pollution than the other fossil
fuels. Furthermore, coal produces more carbon dioxide during
combustion than either oil or gas, but all three have been
fingered as the primary sources of the greenhouse gas that is
the culprit for global warming.
Advocates of a nuclear future have seized the potential threat
of global warming and the nation's dependence on foreign oil
to advance the nuclear cause. Fifty years ago, scientists
working in the fledgling U.S. nuclear power industry (Fig. 3)
predicted that electricity would be virtually free by the end of
the century because of the electrical benevolence of nuclear
energy. Today, only 17% of the world’s electricity is generated
by nuclear power and that number is unlikely to grow because
of concerns about the safety of nuclear reactors and anxiety
over how to dispose of highly radioactive waste produced
Figure 2. Distribution
of U.S. energy use.
Energy use at home
and industry is
typically in the form of
electricity generated
by burning coal.
Transportation is
almost exclusively
fueled by forms of
gasoline refined from
petroleum.
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during power generation. Rarely has a technology shown such
early promise only to fall so rapidly from grace.
Alternative energy resources (hydroelectric, wind, solar,
biomass, geothermal) generate less than 10% of U.S. energy
but have few of the drawbacks of fossil fuels or nuclear power
and hold promise of a sustainable energy future. A veritable
chorus of Pollyannas has sung the praises of alternative energy
since the 1970s but their potential remains ambiguous because
of uncertainties over the rate of technological development and
operating costs. Some of these renewable energy sources have
greater potential than others with solar energy and wind power
holding the most hope for the future.
The industrial airpollution that was once proudly viewed as a
by-product of economic growth is now largely a thing of the
past. No longer will thousands of people die during a weekend
of lethal airpollution as they did in London in 1952. Air
pollution is still widespread but its effects are muted, hidden
among reports of greater incidence of asthma and other
respiratory ailments and studies of acid rain downwind from
industrial centers. The burning of fossil fuels represents a
major source of air pollutants and cleaner air will therefore be
an indirect by-product of any change in energy production in
the years ahead.
Figure 3. Perry
nuclear reactor, 35
miles northwest of
Cleveland, Ohio.
Lake Erie is on the
left of the image.
Image courtesy of the
Nuclear Regulatory
Commission (NRC).
Think about it . . .
1. Predict which of the following states consumes the
most energy.
a) California b) Illinois c) New York d) Texas
2. Examine the partially completed graph found at the
end of the chapter that plots gross domestic product
(GDP) per capita vs. energy consumption per capita.
Label the points that represent where you think the
eight named nations would plot on the graph.
3. Draw a time line for energy use before you read any
further in this chapter. Label the time line to indicate
how energy consumption has changed/will change
from 1850 to 2050. Differentiate between domestic
and industrial energy sources and transportation
energy sources.
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Fossil Fuels: Oil & Gas
• Time and a specific temperature range are necessary for the
generation of oil and gas.
• As hydrocarbons become mature they progress from heavy
oils to light oils to natural gas.
• Hydrocarbons become concentrated in sedimentary rocks.
• The volume of the world’s oil reserves is approximately
1,070 billion barrels.
• The U.S. uses 25% of the world’s oil.
• Two-thirds of the world’s oil reserves are located in the
Middle East.
Fossil fuels form from decayed organic material. Oil, coal, and
natural gas are the most common products of this process. Oil
and gas form from organic material in microscopic marine
organisms, whereas coal forms from the decayed remains of
land plants. Tar (oil) sands and oil shale are less common
forms of fossil fuels and are less widely used because
extraction of oil from these deposits is more expensive than
producing other forms of fossil fuels.
Generation and Production of Oil and Gas
The two principal requirements in the generation of oil and gas
(also known as hydrocarbons - chemical compounds of
carbon and hydrogen) are time and a specific range of
temperature. The steps in the process are:
1. Organic-rich sediments are deposited and gradually
buried to greater depths and converted to sedimentary rock
(e.g., shale).
2. Chemical reactions occur during burial under conditions
of increasing temperature and pressure. The reactions occur
at temperatures of 50 to 100
o
C, higher temperatures "boil
off" the hydrocarbons; lower temperatures are not sufficient
to drive the chemical reactions.
3. The reactions change the organic molecules to hydrocarbon
molecules. With increasing time (millions of years) the
hydrocarbons become more mature changing from heavy
oils to lighter oils to natural gas. Fossil fuels are considered
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non-renewable resources because they are consumed much
faster than they can be replaced.
Oil and gas migrate upward through fractures and pore spaces
in permeable rocks and/or sediments. Some hydrocarbons
escape at Earth’s surface through features such as oil seeps.
Others collect below the surface in sedimentary rocks when
their path is blocked by low-permeability rocks (Fig. 4). Rock
structures such as faults and folds may serve to juxtapose
permeable and impermeable units. Oil and gas are trapped in
the permeable rocks and will migrate upward to lie at the
highest elevation in the rock unit.
When an oil field is first drilled the oil is driven into the well
by pressures within the rocks. This primary recovery will
extract about 25% of the oil. Additional oil can be extracted
using enhanced recovery techniques that make it easier for the
oil to enter the well. Such techniques may include artificially
fracturing the rock to create passages for oil migration or
pumping wastewaters from drilling operations into nearby
wells to drive the oil toward the producing well.
Oil Reserves
Oil and gas are not distributed uniformly within Earth's crust
(Fig. 5). Hydrocarbons are initially formed as organic-rich
sediments and the oil and gas subsequently migrate upward,
into younger rocks that are also of sedimentary origin.
Consequently, oil and gas reserves are generally absent in areas
underlain by igneous or metamorphic rocks such as volcanic
island chains like Japan or Hawaii. Even in areas where
sedimentary rocks are present, they must fall within a specific
age range to ensure that the rocks are mature enough to contain
hydrocarbons but not so old that oil and gas would have long
ago escaped.
Oil reserves steadily increased since the first commercial oil
well was drilled in Titusville, Pennsylvania, in 1859 but
estimates of global reserves have remained relatively uniform
Figure 4. Oil and gas
will migrate through
permeable rocks to
the highest available
elevation. Examples
of traps include folds
(left), and faults
(right).
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at around a billion barrels over the last decade. Oil reserves
remained stable despite the fact that global population has
doubled in the last thirty years. Reserves haven't declined
because of:
• Exploration of geologic formations in increasingly remote
areas of the world, including the seafloor, using an array of
new methods that utilize satellites and geophysical
instruments to unravel the geology in regions where few
rocks are visible.
• Improved technology used by oil companies to extract
greater volumes of oil through enhanced recovery
techniques.
• Greater efficiency in energy use as a result of higher fuel
prices and stricter pollution standards that caused
manufacturers to build more energy-efficient appliances
and engines.
Further improvements in energy efficiency will continue to
delay the inevitable decline in oil reserves. For example,
recently introduced combination gas-electric cars can be driven
112 km (70 miles) on a gallon of gas. However, even with the
best management and environmental stewardship we must
anticipate that a world that continues to rely on oil will see this
finite resource decline toward the second half of this century.
Known world oil reserves are approximately 1,030 billion
barrels (one barrel is equivalent to 42 gallons). These reserves
would last for nearly 40 years at current global consumption
Figure 5. Locations of
principal North
American oil fields
(left) and other
hydrocarbon
resources (right).
Most oil shales and
oil sands are not
economically viable
now but may play a
more significant role
in energy production
as supplies decrease.
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rates. The U.S. Geological Survey recently issued a more
optimistic estimate that there actually may be double those
reserves left to be discovered with a potential life span until the
end of this century.
The U.S. uses 25% of the world's oil, much more than any
other nation, and imports over half of the oil it consumes.
Consequently we are vulnerable to disruptions in oil supplies.
Current fluctuations in gasoline prices that result from
relatively modest changes in supply and demand will become
much more exaggerated as the available reserves of oil decline.
The future success of the U.S. economy may rely on the state
of our political relationships with the relatively few nations that
have abundant oil reserves.
The majority of the oil and other petroleum products currently
imported into the U.S. come from just four nations, Venezuela,
Mexico, Canada, and Saudi Arabia. However, as two-thirds of
all the world's oil reserves are located in the Middle East (Fig.
6), countries such as Saudi Arabia, Kuwait, Iran, and Iraq may
play an increasingly important role in U.S. oil supply in the
decades ahead.
Figure 6. Distribution
of global oil and gas
reserves expressed
as a percentage of
global reserves. Two-
thirds of the world’s
oil and one-third of all
natural gas reserves
are located in the
Middle East. Russia
has 33% of the
world's natural gas
and Saudi Arabia has
25% of the world's oil.
Think about it . . .
1. Use the Venn diagram found at the end of the chapter
to compare and contrast the similarities and
differences between the characteristics of oil and coal
resources.
. . . continued on next page
9
Fossil Fuels: Coal
• The carbon content and heat content of coal increase with
increasing maturity.
• The volume of ash residue after burning decreases with
increasing coal maturity.
• The two principal regions of coal production in the U.S. are
the Appalachian basin and the Great Plains.
• Sulfur content of coal is lower in the Great Plains and
higher in the Appalachian basin.
• Air pollution, medical expenses, and landfill fees are
external costs of coal use.
Coal, the carbon-rich residue of plants, can be classified by
rank or carbon content. Coal matures by increasing rank with
increasing burial pressure (Fig. 7).
2. Similar organic-rich source rocks are present in two
locations. Oil deposits formed in the overlying rocks at
the first location but did not form at the second
location. Which of the following is the best explanation
for this difference?
a) The first location was more deeply buried than the
second.
b) The first location was subjected to lower
temperatures than the second.
c) The first location contains younger rocks than the
second.
d) Rocks at the first location had lower permeability
than rocks at the second site.
Figure 7. Progression
of coal rank (maturity)
from carbon-poor
peat to carbon-rich
anthracite. The
relative proportion of
U.S. coal production
by rank is anthracite
2%, bituminous 53%,
sub-bituminous 36%,
and lignite 9%.
10
Peat is the least-mature form of coal, containing a large volume
of fibrous plant matter. With increasing compaction, water is
driven out and carbon becomes increasingly concentrated. Both
carbon content and the amount of heat released during
burning increase with maturity. The carbon content ranges
from around 30% in peat to 99% for anthracite. The higher the
carbon content, the more heat that is released when the coal is
burned. Small amounts of high-carbon coals produce the same
heat as large volumes of low-carbon coal. The volume of ash
that remains after burning decreases with increasing rank. The
ash must be disposed off in a landfill thus increasing expense.
Figure 8. Coal-
bearing areas of the
U.S.
Image courtesy of
Energy Information
Administration.
[...]... inversion occurs when cold air lies below warm air Under normal conditions, the temperature of air decreases with increasing altitude A parcel of warm air will rise through the overlying colder air, diluting pollution as it is carried higher in the atmosphere Pollutants become concentrated below a blanket of warm air when cold air lies immediately above the ground surface The cold air remains trapped near... is restricted by location to sites in sparsely populated areas of the West Solar and wind energy represent the greatest potential for technological advances and increasing energy production among renewable energy sources Solar Energy Solar energy accounts for approximately 1% of all U.S energy use Passive solar energy refers to using the heat from sunlight to warm buildings (Fig 25) and was first used... resources 2 The graph located at chapter end compares projected plots of the generation of wind energy vs time (19852025) with nuclear energy capacity vs time (19602000) Make some predictions on the future of wind energy using the evolution of nuclear power as a model 27 AirPollution • • • • • Toxic air pollution killed thousands in the relatively recent past Industrial emissions are recorded annually... they will increase their share of U.S energy significantly in the future Passive solar energy requires that structures be oriented to receive light and heat from sunlight and active solar energy converts solar radiation to electricity Wind energy accounts for 0.5% of all U.S energy but could generate up to 20% Future energy must come from one of the three principal energy sources currently in use Approximately... standards National air quality is improving despite increases in population, transportation, and economic growth In addition to various health effects, airpollution also causes acid rain and can reduce visibility Air quality diminished in big cities following the Industrial Revolution and declined further as the popularity of the automobile increased during the last century Air pollution at Earth's... sources currently in use Approximately 80% of the nation's current energy needs are supplied by fossil fuels (oil, gas, coal) that carry with them the threat of potential energy shortages as well as associated environmental degradation from airpollution and concerns about global warming Nuclear power supplies less than 10% of total U.S energy and is 21 unlikely to undergo a resurgence any time soon in... proportion of U.S energy from renewable sources from its current level (Fig 19; less than 10%) to at least 30% of total energy use Figure 19 Proportion of U.S energy generated by renewable energy vs fossil fuels and nuclear power Controls on Renewable Energy Unlike fossil fuels, renewable energy must often be used relatively close to where it is generated Transmission lines may conduct electricity up to... (renewable) energy sources (hydroelectric power, biomass) account for the 31 remainder of electricity generation and approximately 10% of all U.S energy consumption 2 What factors influence energy use in different locations? States with large populations, large land area (greater distances to travel), and energy- intensive industries (e.g oil refining, chemicals), typically use the most energy Texas... to generate electricity High-sulfur bituminous coals contribute to air pollution but yield more heat per ton of coal than low sulfur sub-bituminous coal Utility companies must balance the cost of guarding against pollution with the extra cost of transporting more low-grade coals that generate more waste (ash) following combustion Air pollution represents an external cost associated with the combustion... wind energy hold hope for the future as they have few of the drawbacks associated with other energy sources (pollution, safety) However, renewable energy sources will be limited by climate and have little potential for replacing petroleum as the energy source of choice for transportation 11 How is nuclear energy generated? Uranium ore contains is a small fraction of the uranium isotope (U235) The radioactive . Energy & Air
Pollution
Introduction
Fossil Fuels: Oil & Gas
Fossil Fuels: Coal
Nuclear Energy
Alternative Energy Resources
Air Pollution
Summary
At. Alternative energy sources such as solar and wind power
are renewable and hold the promise of a sustainable energy
future.
U.S. Energy Use
Current U.S. energy