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THÔNG TIN TÀI LIỆU
Cấu trúc
Advanced Nanomaterials
Contents
Preface
List of Contributors
Volume 1
1: Phase-Selective Chemistry in Block Copolymer Systems
1.1 Block Copolymers as Useful Nanomaterials
1.1.1 Introduction
1.1.2 Self-Assembly of Block Copolymers
1.1.3 Triblock Copolymers
1.1.4 Rod–Coil Block Copolymers
1.1.5 Micelle Formation
1.1.6 Synthesis of Block Copolymers Using Living Polymerization Techniques
1.1.6.1 Anionic Polymerization
1.1.6.2 Stable Free Radical Polymerizations
1.1.6.3 Reversible Addition–Fragmentation Chain Transfer (RAFT) Polymerization
1.1.6.4 Atom Transfer Radical Polymerization
1.1.6.5 Ring-Opening Metathesis Polymerization
1.1.6.6 Group Transfer Polymerization
1.1.7 Post-Polymerization Modifications
1.1.7.1 Active-Center Transformations
1.1.7.2 Polymer-Analogous Reactions
1.2 Block Copolymers as Lithographic Materials
1.2.1 Introduction to Lithography
1.2.2 Block Copolymers as Nanolithographic Templates
1.2.2.1 Creation of Nanoporous Block Copolymer Templates
1.2.3 Multilevel Resist Strategies Using Block Copolymers
1.3 Nanoporous Monoliths Using Block Copolymers
1.3.1 Structure Direction Using Block Copolymer Scaffolds
1.3.2 Nanopore Size Tunability
1.3.3 Functionalized Nanoporous Surfaces
1.4 Photo-Crosslinkable Nano-Objects
1.5 Block Copolymers as Nanoreactors
1.5.1 Polymer–Metal Solubility
1.5.2 Cluster Nucleation and Growth
1.5.3 Block Copolymer Micelle Nanolithography
1.6 Interface-Active Block Copolymers
1.6.1 Low-Energy Surfaces Using Fluorinated Block Copolymers
1.6.2 Patterning Surface Energies
1.6.3 Photoswitchable Surface Energies Using Block Copolymers Containing Azobenzene
1.6.4 Light-Active Azobenzene Block Copolymer Vesicles as Drug Delivery Devices
1.6.5 Azobenzene - Containing Block Copolymers as Holographic Materials
1.7 Summary and Outlook
References
2: Block Copolymer Nanofibers and Nanotubes
2.1 Introduction
2.2 Preparation
2.2.1 Nanofiber Preparation
2.2.2 Nanotube Preparation
2.3 Solution Properties
2.4 Chemical Reactions
2.4.1 Backbone Modification
2.4.2 End Functionalization
2.5 Concluding Remarks
Acknowledgements
3: Smart Nanoassemblies of Block Copolymers for Drug and Gene Delivery
3.1 Introduction
3.2 Smart Nanoassemblies for Drug and Gene Delivery
3.3 Endogenous Triggers
3.3.1 pH-Sensitive Nanoassemblies
3.3.1.1 Drug Delivery
3.3.1.2 Gene Delivery
3.3.2 Oxidation- and Reduction-Sensitive Polymeric Nanoassemblies
3.3.3 Other Endogenous Triggers
3.4 External Stimuli
3.4.1 Temperature
3.4.2 Light
3.4.3 Ultrasound
3.5 Future Perspectives
4: A Comprehensive Approach to the Alignment and Ordering of Block Copolymer Morphologies
4.1 Introduction
4.1.1 Motivation
4.1.2 Organization of the Chapter
4.2 How to Help Phase Separation
4.3 Orientation by External Fields
4.3.1 Mechanical Flow Fields
4.3.2 Electric and Magnetic Fields
4.3.3 Solvent Evaporation and Thermal Gradient
4.4 Templated Self-Assembly on Nanopatterned Surfaces
4.5 Epitaxy and Surface Interactions
4.5.1 Preferential Wetting and Homogeneous Surface Interactions
4.5.2 Epitaxy
4.5.3 Directional Crystallization
4.5.4 Graphoepitaxy and Other Confining Geometries
4.5.5 Combination of Directional Crystallization and Graphoepitaxy
4.5.6 Combination of Epitaxy and Directional Crystallization
4.6 Summary and Outlook
Acknowledgments
5: Helical Polymer-Based Supramolecular Films
5.1 Introduction
5.2 Helical Polymer-Based 1-D and 2-D Architectures
5.2.1 Formation of Various 1-D Architectures of Helical Polysilanes on Surfaces
5.2.1.1 Direct Visualization of 1-D Rod, Semi-Circle and Circle Structures by AFM
5.2.1.2 Driving Force for the Formation of 1-D Architectures
5.2.2 Formation of Mesoscopic 2-D Hierarchical Superhelical Assemblies
5.2.2.1 Direct Visualization of a Single Polymer Chain
5.2.2.2 Formation of Superhelical Assemblies by Homochiral Intermolecular Interactions
5.2.3 Formation of 2-D Crystallization of Poly(b-L-Glutamates) on Surfaces
5.2.3.1 Direct Visualization of 2-D Self-Organized Array by AFM
5.2.3.2 Orientation in 2-D Self-Organized Array
5.2.3.3 Intermolecular Weak van der Waals Interactions in 2-D Self-Organized Arrays
5.2.3.4 Comparison of Structures between a 2-D Self-Organized Array and 3-D Bulk Phase
5.2.4 Summary of Helical Polymer-Based 1-D and 2-D Architectures
5.3 Helical Polymer-Based Functional Films
5.3.1 Chiroptical Memory and Switch in Helical Polysilane Films
5.3.1.1 Memory with Re-Writable Mode and Inversion “-1” and “+1” Switch
5.3.1.2 Memory with Write-Once Read-Many (WORM) Mode
5.3.1.3 On-Off “0” and “+1” Switch Based on Helix–Coil Transition
5.3.2 Chiroptical Transfer and Amplification in Binary Helical Polysilane Films
5.3.3 Summary of Helical Polymer-Based Functional Films
6: Synthesis of Inorganic Nanotubes
6.1 Introduction
6.2 General Synthetic Strategies
6.3 Nanotubes of Metals and other Elemental Materials
6.4 Metal Chalcogenide Nanotubes
6.5 Metal Oxide Nanotubes
6.5.1 SiO2 Nanotubes
6.5.2 TiO2 Nanotubes
6.5.3 ZnO, CdO, and Al2O3 Nanotubes
6.5.4 Nanotubes of Vanadium and Niobium Oxides
6.5.5 Nanotubes of other Transition Metal Oxides
6.5.6 Nanotubes of other Binary Oxides
6.5.7 Nanotubes of Titanates and other Complex Oxides
6.6 Pnictide Nanotubes
6.7 Nanotubes of Carbides and other Materials
6.8 Complex Inorganic Nanostructures Based on Nanotubes
6.9 Outlook
7: Gold Nanoparticles and Carbon Nanotubes: Precursors for Novel Composite Materials
7.1 Introduction
7.2 Gold Nanoparticles
7.3 Carbon Nanotubes
7.4 CNT–Metal Nanoparticle Composites
7.5 CNT–AuNP Composites
7.5.1 Filling of CNT s with AuNPs
7.5.2 Deposition of AuNPs Directly on the CNT Surface
7.5.3 Interaction Between Modified AuNPs and CNTs
7.5.3.1 Covalent Linkage
7.5.3.2 Supramolecular Interaction Between AuNPs and CNTs
7.6 Applications
7.7 Merits and Demerits of Synthetic Approaches
7.8 Conclusions
8: Recent Advances in Metal Nanoparticle-Attached Electrodes
8.1 Introduction
8.2 Seed-Mediated Growth Method for the Attachment and Growth of AuNPs on ITO
8.3 Electrochemical Applications of AuNP-Attached ITO
8.4 Improved Methods for Attachment and Growth of AuNPs on ITO
8.5 Attachment and Growth of AuNPs on Other Substrates
8.6 Attachment and Growth of Au Nanoplates on ITO
8.7 Attachment and Growth of Silver Nanoparticles (AgNPs) on ITO
8.8 Attachment and Growth of Palladium Nanoparticles PdNPs on ITO
8.9 Attachment of Platinum Nanoparticles PtNPs on ITO and GC
8.10 Electrochemical Measurements of Biomolecules Using AuNP/ ITO Electrodes
8.11 Nonlinear Optical Properties of Metal NP-Attached ITO
8.12 Concluding Remarks
9: Mesoscale Radical Polymers: Bottom-Up Fabrication of Electrodes in Organic Polymer Batteries
9.1 Mesostructured Materials for Energy Storage Devices
9.2 Mesoscale Fabrication of Inorganic Electrode-Active Materials
9.3 Bottom-Up Strategy for Organic Electrode Fabrication
9.3.1 Conjugated Polymers for Electrode-Active Materials
9.3.2 Mesoscale Organic Radical Polymer Electrodes
9.4 Conclusions
10: Oxidation Catalysis by Nanoscale Gold, Silver, and Copper
10.1 Introduction
10.2 Preparations
10.2.1 Silver Nanocatalysts
10.2.2 Copper Nanocatalysts
10.2.3 Gold Nanocatalysts
10.3 Selective Oxidation of Carbon Monoxide (CO)
10.3.1 Gold Catalysts
10.3.2 Silver Catalysts
10.3.3 Gold–Silver Alloy Catalysts
10.3.4 Copper Catalysts
10.4 Epoxidation Reactions
10.4.1 Gold Catalysts
10.4.2 Silver Catalysts
10.5 Selective Oxidation of Hydrocarbons
10.5.1 Gold Catalysts
10.5.2 Silver Catalysts
10.5.3 Copper Catalysts
10.6 Oxidation of Alcohols and Aldehydes
10.6.1 Gold Catalysts
10.6.2 Silver Catalysts
10.7 Direct Synthesis of Hydrogen Peroxide
10.8 Conclusions
11: Self-Assembling Nanoclusters Based on Tetrahalometallate Anions: Electronic and Mechanical Behavior
11.1 Introduction
11.2 Preparation of Key Compounds
11.3 Structure of the [(A(18C6))4(MX 4)] [BX4] 2 · nH2O Complexes
11.4 Structure of the [(Na(15C5))4Br] [TlBr4]3 Complex
11.5 Spectroscopy of the Cubic F 23 [(A(18C6))4 (MX4)] [BX4]2 · nH2O
11.6 Unusual Luminescence Spectroscopy of Some Cubic [(A(18C6))4 (MnX4)] [TlCl4]2 · nH2O Compounds
11.7 Luminescence Decay Dynamics and 18C6 Rotations
11.8 Conclusions
12: Optically Responsive Polymer Nanocomposites Containing Organic Functional Chromophores and Metal Nanostructures
12.1 Introduction
12.2 Organic Chromophores as the Dispersed Phase
12.2.1 Nature of the Organic Dye
12.2.2 Polymeric Indicators to Mechanical Stress
12.2.2.1 Oligo(p-Phenylene Vinylene) as Luminescent Dyes
12.2.2.2 Bis(Benzoxazolyl) Stilbene as a Luminescent Dye
12.2.2.3 Perylene Derivatives as Luminescent Dyes
12.2.3 Polymeric Indicators to Thermal Stress
12.2.3.1 Oligo(p-Phenylene Vinylene) as Luminescent Dyes
12.2.3.2 Bis(Benzoxazolyl) Stilbene as Luminescent Dye
12.2.3.3 Anthracene Triaryl Amine-Terminated Diimide as Luminescent Dye
12.3 Metal Nanostructures as the Dispersed Phase
12.3.1 Optical Properties of Metal Nanoassemblies
12.3.2 Nanocomposite-Based Indicators to Mechanical Stress
12.3.2.1 The Use of Metal Nanoparticles
12.3.2.2 The Use of Metal Nanorods
12.4 Conclusions
13: Nanocomposites Based on Phyllosilicates: From Petrochemicals to Renewable Thermoplastic Matrices
13.1 Introduction
13.1.1 Structure of Phyllosilicates
13.1.1.1 Clays
13.1.2 Morphology of Composites
13.1.3 Properties of Composites
13.2 Polyolefin-Based Nanocomposites
13.2.1 Overview of the Preparation Methods
13.2.2 Organophilic Clay and Compatibilizer: Interactions with the Polyolefin Matrix
13.2.3 The One-Step Process
13.3 Poly(Ethylene Terephthalate)-Based Nanocomposites
13.3.1 In Situ Polymerization
13.3.2 Intercalation in Solution
13.3.3 Intercalation in the Melt
13.4 Poly(Lactide) (PLA)-Based Nanocomposites
13.4.1 Overview of Preparation Methods
13.4.1.1 In Situ Polymerization
13.4.1.2 Intercalation in Solution
13.4.1.3 Intercalation in the Melt
13.5 Conclusions
Volume 2
14: Amphiphilic Poly(Oxyalkylene)-Amines Interacting with Layered Clays: Intercalation, Exfoliation, and New Applications
14.1 Introduction
14.2 Chemical Structures of Clays and Organic-Salt Modifications
14.2.1 Natural Clays and Synthetic Layered-Double-Hydroxide (LDH)
14.2.2 Low-Molecular-Weight Intercalating Agents and X-Ray Diffraction d-Spacing
14.3 Poly(Oxyalkylene)-Polyamine Salts as Intercalating Agents, and Their Reaction Profiles
14.3.1 Poly(Oxyalkylene)-Polyamine Salts as Intercalating Agents
14.3.2 Critical Conformational Change in Confinement During the Intercalating Profile
14.3.3 Correlation between MMT d-Spacing and Intercalated Organics
14.4 Amphiphilic Copolymers as Intercalating Agents
14.4.1 Various Structures of the Amphiphilic Copolymers
14.4.2 Colloidal Properties
14.5 New Intercalation Mechanism Other than the Ionic-Exchange Reaction
14.5.1 Amidoacid and Carboxylic Acid Chelating
14.5.2 Intercalation Involving Intermolecular Hydrogen Bonding
14.6 Self-Assembling Properties of Organoclays
14.7 Exfoliation Mechanism and the Isolation of Random Silicate Platelets
14.7.1 Thermodynamically Favored Exfoliation of Na+-MMT by the PP-POP Copolymers
14.7.2 Zigzag Mechanism for Exfoliating Na+-MMT
14.8 Isolation of the Randomized Silicate Platelets in Water
14.9 Emerging Applications in Biomedical Research
14.10 Conclusions
15: Mesoporous Alumina: Synthesis, Characterization, and Catalysis
15.1 Introduction
15.2 Synthesis of Mesoporous Alumina
15.2.1 Experimental Techniques
15.2.1.1 Synthesis
15.2.1.2 Characterization
15.2.2 Examples of Synthesis
15.2.2.1 Neutral Surfactant Templating
15.2.2.2 Anionic Surfactant Templating
15.2.2.3 Cationic Surfactant Templating
15.2.2.4 Nonsurfactant Templating
15.3 Mesoporous Alumina in Heterogeneous Catalysis
15.3.1 Base-Catalyzed Reactions
15.3.2 Epoxidation
15.3.3 Hydrodechlorination
15.3.4 Hydrodesulfurization
15.3.5 Olefin Metathesis
15.3.6 Oxidative Dehydrogenation
15.3.7 Oxidative Methanol Steam Reforming
15.4 Conclusions and Outlook
16: Nanoceramics for Medical Applications
16.1 Introduction
16.2 Tissue Engineering and Regeneration
16.2.1 Scaffolds
16.2.2 Liposomes
16.3 Nanohydroxyapatite Powders for Medical Applications
16.4 Nanocoatings and Surface Modifications
16.4.1 Calcium Phosphate Coatings
16.4.2 Sol–Gel Nanohydroxyapatite and Nanocoated Coralline Apatite
16.4.3 Surface Modifications
16.5 Simulated Body Fluids
16.6 Nano- and Macrobioceramics for Drug Delivery and Radiotherapy
16.6.1 Nanobioceramics for Drug Delivery
16.6.2 Microbioceramics for Drug Delivery
16.6.3 Microbioceramics for Radiotherapy
16.7 Nanotoxicology and Nanodiagnostics
17: Self-healing of Surface Cracks in Structural Ceramics
17.1 Introduction
17.2 Fracture Manner of Ceramics
17.3 History
17.4 Mechanism
17.5 Composition and Structure
17.5.1 Composition
17.5.2 SiC Figuration
17.5.3 Matrix
17.6 Valid Conditions
17.6.1 Atmosphere
17.6.2 Temperature
17.6.3 Stress
17.7 Crack-healing Effect
17.7.1 Crack-healing Effects on Fracture Probability
17.7.2 Fatigue Strength
17.7.3 Crack-healing Effects on Machining Efficiency
17.8 New Structural Integrity Method
17.8.1 Outline
17.8.2 Theory
17.8.3 Temperature Dependence of the Minimum Fracture Stress Guaranteed
17.9 Advanced Self-crack Healing Ceramics
17.9.1 Multicomposite
17.9.2 SiC Nanoparticle Composites
17.10 Availability to Structural Components of the High Temperature Gas Turbine
18: Ecological Toxicology of Engineered Carbon Nanoparticles
18.1 Introduction
18.2 Fate and Exposure
18.2.1 General
18.2.2 Stability in Aquatic Systems
18.2.3 Bioavailability and Uptake
18.2.4 Tissue Distribution
18.2.5 Food Web
18.2.6 Effects on the Uptake of Other Contaminants
18.3 Effects
18.3.1 General
18.3.2 Oxidative Stress and Nanoparticles
18.3.3 Effects on Specific Tissues
18.3.3.1 Brain
18.3.3.2 Gills
18.3.3.3 Liver
18.3.3.4 Gut
18.3.4 Developmental Effects
18.4 Summary
19: Carbon Nanotubes as Adsorbents for the Removal of Surface Water Contaminants
19.1 Introduction
19.2 Structure and Synthesis of Carbon Nanotubes
19.3 Properties of Carbon Nanotubes
19.3.1 Mechanical, Thermal, Electrical, and Optical Properties of Carbon Nanotubes
19.3.2 Adsorption-Related Properties of Carbon Nanotubes
19.4 Carbon Nanotubes as Adsorbents
19.4.1 Adsorption of Heavy Metal Ions
19.4.1.1 Adsorption of Lead (II)
19.4.1.2 Adsorption of Chromium (VI)
19.4.1.3 Adsorption of Cadmium (II)
19.4.1.4 Adsorption of Copper (II)
19.4.1.5 Adsorption of Zinc (II)
19.4.1.6 Adsorption of Nickel (II)
19.4.1.7 Competitive Adsorption of Heavy Metals Ions
19.4.2 Adsorption of Other Inorganic Elements
19.4.2.1 Adsorption of Fluoride
19.4.2.2 Adsorption of Arsenic
19.4.2.3 Adsorption of Americium-243 (III)
19.4.3 Adsorption of Organic Compounds
19.4.3.1 Adsorption of Dioxins
19.4.3.2 Adsorption of 1,2-Dichlorobenzene
19.4.3.3 Adsorption of Trihalomethanes
19.4.3.4 Adsorption of Polyaromatic Compounds
19.5 Summary of the Results, and Conclusions
20: Molecular Imprinting with Nanomaterials
20.1 Introduction
20.1.1 Molecular Imprinting: The Concept
20.1.1.1 History of Molecular Imprinting
20.1.1.2 Covalent Imprinting
20.1.1.3 Noncovalent Imprinting
20.1.1.4 Alternative Molecular Imprinting Approaches
20.1.2 Towards Imprinting with Nanomaterials
20.2 Molecular Imprinting in Nanoparticles
20.2.1 Emulsion Polymerization
20.2.1.1 Core–Shell Emulsion Polymerization
20.2.1.2 Mini-Emulsion Polymerization
20.2.2 Precipitation Polymerization
20.2.2.1 Applications and Variations
20.2.2.2 Microgel/Nanogel Polymerization
20.2.3 Silica Nanoparticles
20.2.4 Molecularly Imprinted Nanoparticles: Miscellaneous
20.3 Molecular Imprinting with Diverse Nanomaterials
20.3.1 Nanowires, Nanotubes, and Nanofibers
20.3.2 Quantum Dots
20.3.3 Fullerene
20.3.4 Dendrimers
20.4 Conclusions and Future Prospects
21: Near-Field R aman Imaging of Nanostructures and Devices
21.1 Introduction
21.2 Near-Field Raman Imaging Techniques
21.3 Visualization of Si–C Covalent Bonding of Single Carbon Nanotubes Grown on Silicon Substrate
21.4 Near-Field Scanning Raman Microscopy Using TERS
21.5 Near-Field Raman Imaging Using Optically Trapped Dielectric Microsphere
21.6 Conclusions
22: Fullerene-Rich Nanostructures
22.1 Introduction
22.2 Fullerene-Rich Dendritic Branches
22.3 Photoelectrochemical Properties of Fullerodendrons and Their Nanoclusters
22.4 Fullerene-Rich Dendrimers
22.5 Conclusions
23: Interactions of Carbon Nanotubes with Biomolecules: Advances and Challenges
23.1 Introduction
23.2 Structure and Properties
23.3 Debundalization
23.4 Noncovalent Functionalization
23.5 Dispersion of Carbon Nanotubes in Biopolymers
23.6 Interaction of DNA with Carbon Nanotubes
23.7 Interaction of Proteins with Carbon Nanotubes
23.8 Technology Development Based on Biopolymer-Carbon Nanotube Products
23.8.1 Diameter- or Chirality-Based Separation of Carbon Nanotubes
23.8.2 Fibers
23.8.3 Sensors
23.8.4 Therapeutic Agents
23.9 Conclusions
24: Nanoparticle-Cored Dendrimers and Hyperbranched Polymers: Synthesis, Properties, and Applications
24.1 Introduction
24.2 Synthesis of Nanoparticle-Cored Dendrimers via the Direct Method, and their Properties and Application
24.3 Synthesis of Nanoparticle-Cored Dendrimers by Ligand Exchange Reaction, and their Properties and Applications
24.4 Synthesis of Nanoparticle-Cored Dendrimers by Dendritic Functionalization, and their Properties and Applications
24.4.1 Nanoparticle-Cored Dendrimers by the Convergent Approach
24.4.2 Nanoparticle-Cored Dendrimers by the Divergent Approach
24.5 Synthesis of Nanoparticle-Cored Hyperbranched Polymers by Grafting on Nanoparticles
24.6 Conclusions and Outlook
Acknowledgment
25: Concepts in Self-Assembly
25.1 Introduction
25.2 Theoretical Approaches to Self-Organization
25.2.1 Thermodynamics of Self-Organization
25.2.2 The “Goodness” of the Organization
25.2.3 Programmable Self-Assembly
25.3 Examples of Self-Assembly
25.3.1 The Addition of Particles to the Solid/Liquid Interface
25.3.1.1 Numerically Simulating RSA
25.3.2 Self-Assembled Monolayers (SAMs)
25.3.3 Quantum Dots (QDs)
25.3.4 Crystallization and Supramolecular Chemistry
25.3.5 Biological Examples
25.3.6 DNA
25.3.7 RNA and Proteins
25.4 Self-Assembly as a Manufacturing Process
25.5 Useful Ideas
25.5.1 Weak Competing Interactions
25.5.2 Percolation
25.5.3 Cooperativity
25.5.4 Water Structure
25.6 Conclusions and Challenges
26: Nanostructured Organogels via Molecular Self-Assembly
26.1 Introduction
26.2 Block Copolymer Gels
26.2.1 Concentration Effects
26.2.2 Temperature Effects
26.2.3 Microdomain Alignment
26.2.4 Tensile Deformation
26.2.5 Network Modifiers
26.2.5.1 Inorganic Nanofillers
26.2.5.2 Polymeric Modifiers
26.2.6 Nonequilibrium Mesogels
26.2.7 Special Cases
26.2.7.1 Liquid Crystals
26.2.7.2 Ionic Liquids
26.2.7.3 Multiblock Copolymers
26.2.7.4 Cosolvent Systems
26.3 Organic Gelator Networks
26.3.1 Hydrogen Bonding
26.3.1.1 Amides
26.3.1.2 Ureas
26.3.1.3 Sorbitols
26.3.1.4 Miscellaneous LMOG Classes
26.3.2 π−π Stacking
26.3.3 London Dispersion Forces
26.3.4 Special Considerations
26.3.4.1 Biologically Inspired Gelators
26.3.4.2 Isothermal Gelation
26.3.4.3 Solvent Effects
26.4 Conclusions
27: Self-assembly of Linear Polypeptide-based Block Copolymers
27.1 Introduction
27.2 Solution Self-assembly of Polypeptide-based Block Copolymers
27.2.1 Aggregation of Polypeptide-based Block Copolymers
27.2.1.1 Polypeptide Hybrid Block Copolymers
27.2.1.2 Block Copolypeptides
27.2.2 Polypeptide-based Hydrogels
27.2.3 Organic/Inorganic Hybrid Structures
27.3 Solid-state Structures of Polypeptide-based Block Copolymers
27.3.1 Diblock Copolymers
27.3.1.1 Polydiene-based Diblock Copolymers
27.3.1.2 Polystyrene-based Diblock Copolymers
27.3.1.3 Polyether-based Diblock Copolymers
27.3.1.4 Polyester-based Diblock Copolymers
27.3.1.5 Diblock Copolypeptides
27.3.2 Triblock Copolymers
27.3.2.1 Polydiene-based Triblock Copolymers
27.3.2.2 Polystyrene-based Triblock Copolymers
27.3.2.3 Polysiloxane-based Triblock Copolymers
27.3.2.4 Polyether-based Triblock Copolymers
27.3.2.5 Miscellaneous
27.4 Summary and Outlook
28: Structural DNA Nanotechnology: Information-Guided Self-Assembly
28.1 Introduction
28.2 Periodic DNA Nanoarrays
28.3 Finite-Sized and Addressable DNA Nanoarrays
28.4 DNA Polyhedron Cages
28.5 DNA Nanostructure-Directed Nanomaterial Assembly
28.6 Concluding Remarks
Index
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