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Laboratory of Metal Complex Activation of Small Molecules Head of the laboratory: Prof Shur Vladimir Borisovich Selected Publications Molecular Nitrogen Fixation in Solutions 1) M.E Vol'pin, V.B Shur Nitrogen Fixation on Complex Catalysts Dokl Akad Nauk SSSR, 156 (1964) 1102-1104 2) M.E Vol'pin, V.B Shur, M.A Ilatovskaya Fixation of Nitrogen by Systems Based on Dicyclopentadienyltitanium Dichloride Izv Akad Nauk SSSR, Ser.Khim., (1964) 1728-1729 [Bull Acad Sci USSR., Div Chem Sci., 13 (1964) 1644 (Engl Transl.)] 3) M.E Vol'pin, V.B Shur, L.P Bichin Study of the Fixation of Nitrogen on Complex Catalysts Using 15N Izv Akad Nauk SSSR, Ser.Khim., (1965) 720-721 [Bull Acad Sci USSR, Div Chem Sci., 14 (1965) 698-699 (Engl Transl.)] 4) M.E Vol'pin, V.B Shur Problems of Chemical Fixation of Molecular Nitrogen Vestnik Akad Nauk SSSR, № (1965) 51-58 5) M.E Vol'pin, A.A Belyi, V.B Shur Fixation of Nitrogen by Systems Based on Compounds of the Transition Metals and Inorganic Reducing Agents Izv Akad Nauk SSSR, Ser.Khim., (1965) 2225-2226 [Bull Acad Sci USSR, Div Chem Sci., 14 (1965) 2196 (Engl Transl.)] 6) M.E Vol'pin, V.B Shur Nitrogen Fixation by Transition Metal Complexes Nature, 209 (1966) 1236 7) M.E Vol'pin, V.B Shur Preparation of Amines in the Reactions of Molecular Nitrogen Izv Akad Nauk SSSR, Ser.Khim., (1966) 1873-1874 [Bull Acad Sci USSR., Div Chem Sci., 15 (1966) 1819 (Engl Transl.)] 8) M.E Vol'pin, V.B Shur, V.N Latyaeva, L.I Vyshinskaya, L.A Shul’gaitser Reaction of Nitrogen with Bis-Cyclopentadienyl Derivatives of Titanium Izv Akad Nauk SSSR, Ser.Khim., (1966) 385 [Bull Acad Sci USSR., Div Chem Sci., 15 (1966) 364 (Engl Transl.)] 9) M.E Vol'pin, V.B Shur Complexation As a Way of the Activation of Molecular Nitrogen Zh Vses Khim Obshchestva im D.I Mendeleeva, 12 (1967) 31-41 10) M.E Vol'pin, V.B Shur, R.V Kudryavtsev, L.A Prodayko Amine Formation in Molecular Nitrogen Fixation: Nitrogen Insertion into Transition Metal–Carbon Bonds Chem Commun., № 17 (1968) 1038-1040 11) M.E Vol'pin, M.A Ilatovskaya, L.V Kosyakova, V.B Shur Catalytic Nitrogen Fixation in the Presence of Transition Metal Compounds Dokl Akad Nauk SSSR, 180 (1968) 103-105 2 12) M.E Vol'pin, M.A Ilatovskaya, L.V Kosyakova, V.B Shur Catalytic Fixation of Nitrogen Chem Commun., № 18 (1968) 1074-1075 13) M.E Vol'pin, V.B Shur Chemical Fixation of Molecular Nitrogen Priroda, № 11 (1969) 29-34 14) M.E Vol'pin, A.A Belyi, N.A Katkov, R.V Kudryavtsev, V.B Shur Formation of Amines from Aromatic Hydrocarbons and Molecular Nitrogen During the Reducing Fixation of N Izv Akad Nauk SSSR, Ser.Khim., (1969) 2858-2859 [Bull Acad Sci USSR, Div Chem Sci., 18 (1969) 2697 (Engl Transl.)] 15) M.E Vol'pin, M.A Ilatovskaya, V.B Shur Catalytic Nitrogen Fixation Kinetika i Kataliz, 11 (1970) 333-341 16) M.E Vol'pin, V.B Shur Chemical Fixation of Molecular Nitrogen In: "Organometallic Reactions" (Eds E Becker and M Tsutsui), Vol 1, J Wiley, N.Y., 1970, p 55-117 17) M.E Vol'pin, A.A Belyi, V.B Shur, Yu.I Lyakhovetskyi, R.V Kudryavtsev, N.N Bubnov Study of Nitrogen Fixing Systems Investigation of the Mechanism of the Reduction of Titanocene Dichloride by Metallic Magnesium Dokl Akad Nauk SSSR, 194 (1970) 577-579 18) M.E Vol'pin, A.A Belyi, V.B Shur, N.A Katkov, I.M Nekaeva, R.V Kudryavtsev Formation of Amines from Aromatic Hydrocarbons in Molecular Nitrogen Fixation Reactions Chem Commun., № (1971) 246 19) V.B Shur, E.G Berkovich, M.E Vol'pin Formation of Aniline During the Thermal Decomposition of Diphenyltitanocene in the Presence of Nitrogen Izv Akad Nauk SSSR, Ser.Khim., (1971) 2358 [Bull Acad Sci USSR., Div Chem Sci., 20 (1971) 2248 (Engl Transl.)] 20) V.B Shur, E.G Berkovitch, L.B Vasiljeva, R.V Kudryavtsev, M.E Vol'pin Amine Formation in the Thermodecomposition of Diaryltitanocenes in the Presence of Dinitrogen J Organomet Chem., 78 (1974) 127-132 21) V.B Shur, E.G Berkovich, S.M Yunusov, Sh.M Mamedov, I.L Nizker, M.E Vol'pin New Systems Capable of Binding Molecular Nitrogen with the Formation of Amines Izv Akad Nauk SSSR, Ser.Khim., (1977) 2841 [Bull Acad Sci USSR., Div Chem Sci., 26 (1977) 2630 (Engl Transl.)] 22) E.G Berkovich, V.B Shur, M.E Vol'pin, B Lorenz, S Rummel, M Wahren Die Reaktion von Stickstoff mit Dehydrobenzol in der Koordinationssphäre von Titan Chem Ber., 113 (1980) 7078 23) M.E Vol'pin, V.B Shur Fixation of Molecular Nitrogen in Aprotic Media In: "New Trends in the Chemistry of Nitrogen Fixation" (Eds J.Chatt, L.M da Câmara Pina and R.L Richards), Acad Press, London, 1980, p 67-100 24) M.E Vol'pin, V.B Shur Nitrogen Fixation by Transition Metal Compounds: Results and Prospects J Organomet Chem., 200 (1980) 319-334 3 25) M.N Bochkarev, A.A Trifonov, G.A Razuvaev, M.A Ilatovskaya, V.B Shur Fixation of Molecular Nitrogen by Rare-Earth Metal Compounds Izv Akad Nauk SSSR, Ser.Khim., (1986) 1898-1900 [Bull Acad Sci USSR, Div Chem Sci., 35 (1986) 1726-1728 (Engl Transl.)] 26) M.N Bochkarev, A.A Trifonov, G.A Razuvaev, M.A Ilatovskaya, V.B Shur, M.E Vol’pin Activation of Molecular Nitrogen by Compounds of the Lanthanides Dokl Akad Nauk SSSR, 295 (1987) 1381-1384 [Dokl Chem., 295 (1987) 378-380 (Engl Transl.)] 27) M.E Vol’pin, V.B Shur, E.G Berkovich Transformations of Molecular Nitrogen into Aromatic Amines under the Action of Titanium Compounds Inorg Chim Acta, 280 (1998) 264-274 Development of Catalysts for the Low-Temperature Ammonia Synthesis from Dinitrogen and Dihydrogen 1) M.E Vol'pin, M.A Ilatovskaya, E.I Larikov, M.L Khidekel’, Yu.A Shvetsov, V.B Shur Nitrogen Fixation by Transition Metal Complexes Activating Molecular Hydrogen Dokl Akad Nauk SSSR, 164 (1965) 331-333 2) M.E Vol'pin, M.A Ilatovskaya, V.B Shur Catalytic Nitrogen Fixation Kinetika i Kataliz, 11 (1970) 333-341 3) M.E Vol'pin, V.B Shur Chemical Fixation of Molecular Nitrogen In: "Organometallic Reactions" (Eds E Becker and M Tsutsui), Vol 1, J Wiley, N.Y., 1970, p 55-117 4) V.A Postnikov, L.M Dmitrienko, R.F Ivanova, N.L Dobrolyubova, M.A Golubeva, T.I Gapeeva, Yu.N Novikov, V.B Shur, M.E Vol’pin Investigation of the Catalytic Activity of Lamellar Graphite-Transition Metal Compounds in the Synthesis of Ammonia Izv Akad Nauk SSSR, Ser.Khim., (1975) 2642-2646 [Bull Acad Sci USSR., Div Chem Sci., 24 (1975) 25292532 (Engl Transl.)] 5) A.V Nefed’ev, R.A Stukan, V.A Postnikov, V.B Shur, Yu.N Novikov, M.E Vol’pin Study of Catalysts for the Synthesis of Ammonia Based on Lamellar Compounds of Graphite with Ferric Chloride and Potassium by Gamma-Resonance Spectroscopy Method Izv Akad Nauk SSSR, Ser Khim., (1976) 2376-2378 [Bull Acad Sci USSR., Div Chem Sci., 25 (1976) 2219-2221 (Engl Transl.)] 6) M.E Vol'pin, Yu.N Novikov, V.A Postnikov, V.B Shur, B Bayerl, L Kaden, M Wahren, L.M Dmitrienko, R.A Stukan, A.V Nefed'ev Untersuchungen zur Katalyse der Ammoniaksynthese und des Stickstoffisotopenaustausches dürch Schichtverbindungen von Graphit mit Eisen, Ruthenium und Osmium Z anorg allg Chem., 428 (1977) 231-236 7) V.B Shur, S.M Yunusov, M.E Vol'pin Ammonia Synthesis from Nitrogen and Hydrogen Using Catalysts Based on Potassium Salts of Iron Carbonyl Hydrides and Metallic Potassium Dokl Akad Nauk SSSR, 277 (1984) 884-888 [Dokl Chem., 277 (1984) 246-250 (Engl Transl.)] 4 8) V.B Shur, S.M Yunusov, S Rummel, M Wahren, M.E Vol'pin Stepwise Synthesis of Ammonia from Nitrogen and Hydrogen by the Action of Catalysts Based on Potassium Salts of Transition Metal Carbonyl Hydrides and Potassium Metal Dokl Akad Nauk SSSR, 292 (1987) 1409-1413 [Dokl Chem., 292 (1987) 100-103 (Engl Transl.)] 9) I.L Arkhipov, R.A Stukan, S.M Yunusov, B.V Lokshin, M.G Ezernitskaya, V.B Shur, M.E Vol'pin Mössbauer and Infrared Spectroscopic Study of the Reactions of K 2[Fe2(CO)8] under the Influence of Activated Charcoal Metalloorg Khim., (1988) 314-320 [Organomet Chem USSR, (1988) 174-177 (Engl Transl.)] 10) K.S Rama Rao, P Kanta Rao, S.K Masthan, E Kaluschnaya, V.B Shur New Type of Carbon Coated Alumina Supports for the Preparation of Highly Active Ruthenium Catalysts for Ammonia Synthesis Appl Cat., 62 (1990) L19-L22 11) V.B Shur, S.M Yunusov, E.S Kalyuzhnaya, M.E Vol'pin Ammonia Synthesis Catalysts Derived from Potassium Salts of Ruthenium and Osmium Carbonyl Hydrides Supported on Activated Charcoal and Metallic Potassium Dokl Akad Nauk SSSR, 320 (1991) 353-356 [Dokl Chem., 320 (1991) 254-257 (Engl Transl.)] 12) V.B Shur, S.M Yunusov, M.A Ilatovskaya, S Rummel, M.E Vol'pin Interaction of AmmoniaSynthesis Catalyst, K2[Fe2(CO)8] + K on SKT Carbon, with Dinitrogen in the Absence and Presence of Dihydrogen Dokl Akad Nauk SSSR, 336 (1994) 631-635 [Dokl Chem., 336 (1994) 116-119 (Engl Transl.)] 13) V.B Shur, S.M Yunusov, M.A Ilatovskaya, S Rummel, M.E Vol'pin Nitrogen Isotope Exchange under Effect of Ammonia Synthesis Catalyst, K 2[Fe2(CO)8] + K on SKT Carbon Dokl Akad Nauk SSSR, 336 (1994) 789-794 [Dokl Chem., 336 (1994) 126-130 (Engl Transl.)] 14) S.M Yunusov, V.A Likholobov, V.B Shur Supported Ammonia Synthesis Catalysts Based on Anionic Ruthenium Cluster K2[Ru4(CO)13] The Promoting Effect of Cesium Nitrate Appl Cat A: General, 158 (1997) L35-L39 15) S.M Yunusov, B.L Moroz, A.S Ivanova, V.A Likholobov, V.B Shur Anionic Ruthenium Cluster K2[Ru4(CO)13] as Precursor of Catalytically Active Ruthenium Particles and Potassium Promoter New Efficient Ammonia Synthesis Catalysts Based on Supported K 2[Ru4(CO)13] J Molec Cat A: Chem., 132 (1998) 263-265 16) V.B Shur, S.M Yunusov On the Path to Catalysts for the Low-Temperature Ammonia Synthesis Izv Akad Nauk, Ser Khim., (1998) 796-806 [Russ Chem Bull., 47 (1994) 765-775 (Engl Transl.)] 17) S.M Yunusov, E.S Kalyuzhnaya, H Mahapatra, V.K Puri, V.A Likholobov, V.B Shur Supported Ammonia Synthesis Catalysts Based on Potassium Derivatives of Anionic Ruthenium, Osmium and Iron Carbonyl Clusters The First Catalysts on Carbon Support Exhibiting Activity in Ammonia Synthesis in the Absence of a Specially Added Electron Promoter J Molec Cat A: Chem., 139 (1999) 219-225 18) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, S.N Agafonova, V.A Likholobov, V.B Shur The Effect of Co and Ir on the Activity of the K 2[Fe2(CO8)]- and K2[Ru4(CO)13]-based Systems in Ammonia Synthesis The Synergistic Acceleration of the Ammonia Synthesis over the K2[Fe2(CO8)] + K Catalysts by Iridium J Molec Cat A: Chem., 165 (2001) 143-149 19) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, S.N Agafonova, V.A Likholobov, V.B Shur The Synergistic Acceleration of the Ammonia Synthesis over the K2[Fe2(CO8)] + K Catalysts on Carbon “Sibunit” by Rhodium Appl Cat A: General, 218 (2001) 251-256 20) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, A.S Ivanova, T.V Reshetenko, L.B Avdeeva, V.A Likholobov, V.B Shur New Ammonia Synthesis Catalysts Based on Supported Carbonyl Ruthenates as Precursors of Catalytically Active Ruthenium Particles and Potassium Promoter J Molec Cat A: Chem., 219 (2004) 149-153 21) A.S Ivanova, E.S Kalyuzhnaya, G.S Litvak, E.M Moroz, S.M Yunusov, V.S Lenenko, B.L Moroz, V.B Shur, V.A Likholobov New Y(La)-M-O Binary Systems (M=Ca, Sr, Ba): Synthesis, Physicochemical Characterization, and Application as the Supports of Ruthenium Catalysts for Ammonia Synthesis Kinetika i Kataliz, 45 (2004) 574-579 [Kinetics and Catalysis, 45 (2004) 541-546 (Engl Transl.)] 22) Yu.V Larichev, B.L Moroz, E.M Moroz, V.I Zaikovskii, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur, V.I Bukhtiyarov Effect of the Support on the Nature of Metal-Promoter Interactions in Ru-Cs+/MgO and Ru-Cs+/Al2O3 Catalysts for Ammonia Synthesis Kinetika i Kataliz, 46 (2005) 940-948 [Kinetics and Catalysis, 46 (2005) 891-899 (Engl Transl.)] 23) Yu.V Larichev, B.L Moroz, V.I Zaikovskii, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur, V.I Bukhtiyarov XPS and TEM Studies on the Role of the Support and Alkali Promoter in Ru/MgO and Ru–Cs+/MgO Catalysts for Ammonia Synthesis J Phys Chem C, 111 (2007) 9427-9436 24) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, A.S Ivanova, V.B Shur Ammonia Synthesis from Dinitrogen and Dihydrogen over the Catalysts Based on the Supported Mononuclear Potassium Carbonylruthenate Promoting Effect of Lithium Alkyls Izv Akad Nauk, Ser Khim., 2011, in press [Russ Chem Bull., Int.Ed., 60 (2011) in press] Molecular Nitrogen Complexes 1) V.B Shur, I.A Tikhonova, E.F Isaeva, M.E Vol'pin Formation of Nitrogen Complexes by the Reaction of a Ru(III) Derivative with Monoarylhydrazines Izv Akad Nauk SSSR, Ser Khim., (1971) 2357-2358 [Bull Acad Sci USSR., Div Chem Sci., 20 (1971) 2247 (Engl Transl.)] 6 2) V.I Nefedov, V.S Lenenko, V.B Shur, M.E Vol'pin, J.E Salyn, M.A Porai-Koshits Molecular Nitrogen as a Ligand A Study of Dinitrogen Complexes of Transition Metals, Diazocompounds and Azides by X-Ray Photoelectron Spectroscopy Inorg Chim Acta, (1973) 499-502 3) I.A Tikhonova, K Jähnisch, V.G Andrianov, S.F Byalotskii, Yu.T Struchkov, V.B Shur, É Schmitz, M.E Vol'pin Reaction of 3,3-Pentamethylenediazirine with Nonacarbonyliron and Aquapentaammine Derivative of Divalent Ruthenium New Pathway to the [Ru(NH 3)5H2О]2+ Complex Koord Khim., (1976) 1653-1658 [Sov J Coord Chem., (1976) 1274-1278 (Engl Transl.)] 4) V.B Shur, I.A Tikhonova, M.E Vol'pin Formation of Dinitrogen Complexes in the Interaction of the [Ru(NH3)5H2О]2+ Ion with Diazoacetic Ester and Aromatic Diazonium Salts Koord Khim., (1978) 1248-1255 [Sov J Coord Chem., (1978) (Engl Transl.)] 5) A.L Blumenfel’d, V.S Lenenko, B Lorentz, I Mebius, M Wahren, V.B Shur, M.E Vol’pin Investigation of Diazo Compounds, Azides, and Nitrogen Complexes of Transition Metals by NMR 15N Spectroscopy Dokl Akad Nauk SSSR, 251 (1980) 611-615 [Dokl Chem., 251 (1980) 143-148 (Engl Transl.)] 6) V.B Shur, I.A Tikhonova, G.G Aleksandrov, Yu.T Struchkov, M.E Vol'pin, E Schmitz, K Jähnisch The Diazirine Complex [(NH3)5Ru(N2C6H10)]2+: Synthesis, Structure and Conversion into the Dinitrogen Complex [(NH3)5RuN2)]2+ Inorg Chim Acta, 44 (1980) L275-L277 7) V.S Lenenko, A.G Knizhnik, E.I Mysov, V.B Shur, M.E Vol’pin Reduction of Aromatic Diazo Compounds by Alcohols to Hydrocarbons Catalyzed by the Nitrogen Complex trans(Ph2PCH2CH2PPh2)2W(N2)2 Dokl Akad Nauk SSSR, 255 (1980) 1131-1135 [Dokl Chem., 255 (1980) 591-594 (Engl Transl.)] 8) V.S Lenenko, A.P Borisov, V.D Makhaev, E.I Mysov, V.B Shur, M.E Vol’pin New Catalysts for the Reduction of Aromatic Diazo Compounds by Alcohols to Hydrocarbons Izv Akad Nauk SSSR, Ser Khim., (1983) 947-950 [Bull Acad Sci USSR, Div Chem Sci., 32 (1983) 858-860 (Engl Transl.)] 9) V.B Shur, I.A Tikhonova, M.E Vol'pin Catalytic Oxidation-Reduction Disproportionation of Phenylhydrazine by the Action of [Ru(NH 3)5Cl]Cl2 Izv Akad Nauk SSSR, Ser Khim., (1988) 943-944 [Bull Acad Sci USSR, Div Chem Sci., 37 (1988) 824 (Engl Transl.)] 10) V.S Lenenko, P Kränke, M Wahren, V.B Shur, M.E Vol’pin Acid-Catalyzed Attack of the Dinitrogen Ligand in the cis-(Ме2PhP)4Mo(N2)2 and trans-(Ph2PCH2CH2PPh2)2W(N2)2 Complexes by Nitronium and Nitrosonium Cations with the Formation of Nitrogen Oxides Izv Akad Nauk, Ser Khim., (1995) 1340-1346 [Russ Chem Bull., 44 (1995) 1293-1299 (Engl Transl.)] 7 11) E.G Berkovich, V.S Lenenko, L.I Vyshinskaya, G.A Vasil'eva, V.B Shur, M.E Vol'pin Formation of Aromatic Amines from Dinitrogen Complexes [Cp 2TiAr]2N2 (Ar = C6H5, mCH3C6H4) J Organomet Chem., 535 (1997) 169-173 Hexaazabenzene Molecule N6 and Possible Ways of Its Stabilization 1) E.G Gal’pern, I.V Stankevich, A.L Chistyakov, V.B Shur, M.E Vol’pin Is It Possible to Stabilize the Hexaazabenzene Cyclic System? Izv Akad Nauk SSSR, Ser Khim., (1987) 1675 [Bull Acad Sci USSR, Div Chem Sci., 36 (1987) 1552 (Engl Transl.)] 2) E.G Gal’pern, I.V Stankevich, A.L Chistyakov, V.B Shur, M.E Vol’pin Possibility of Stabilizing the Cyclic Hexaazabenzene System Dokl Akad Nauk SSSR, 302 (1988) 1384-1388 [Dokl Chem., 302 (1988) 302-305 (Engl Transl.)] 3) I.V Stankevich, A.L Chistyakov, V.B Shur, M.E Vol’pin Possible Existence of a Cyclic Trimer of Nitrous Oxide Dokl Akad Nauk SSSR, 313 (1990) 118-120 [Dokl Chem., 313 (1990) 194195 (Engl Transl.)] Activation of С–Н Bonds 1) V.N Latyaeva, L.I Vyshinskaya, V.B Shur, L.A Fedorov, M.E Vol'pin Reaction of Dicyclopentadienyldiphenyltitanium with Phenyllithium J Organomet Chem., 16 (1969) 103-109 2) M.E Vol'pin, A.A Belyi, V.B Shur, Yu.I Lyakhovetsky, R.V Kudryavtsev, N.N Bubnov Study of Nitrogen Fixing Systems Investigation of the Mechanism of the Reduction of Titanocenedichloride by Magnesium Dokl Akad Nauk SSSR, 194 (1970) 577-579 3) M.E Vol'pin, A.A Belyi, V.B Shur, Yu.I Lyakhovetsky, R.V Kudryavtsev, N.N Bubnov Cyclopentadienyl Ligands as a Hydrogen Source in the Formation of Titanium Hydride Complexes J Organomet Chem., 27 (1971) C5-C8 4) V.B Shur, E.G Berkovich, E.I Mysov, M.E Vol’pin Catalytic Activity of Cyclopentadienyl Titanium Complexes in Isotopic Exchange Reactions of Aromatic Hydrocarbons with Molecular Deuterium Izv Akad Nauk SSSR, Ser Khim., (1987) 2435-2439 [Bull Acad Sci USSR, Div Chem Sci., 36 (1987) 2259-2263 (Engl Transl.)] 5) M.A Ilatovskaya, S Rummel, Yu.V Isaev, S.M Yunusov, N.D Lenenko, M Herrmann, M Wahren, Yu.N Novikov, V.B Shur Lamellar Graphite Compounds with Metallic Potassium As Catalysts for Deuterium-Hydrogen Exchange in Hydrocarbons Izv Akad Nauk SSSR, Ser Khim., (1991) 1935-1936 [Bull Acad Sci USSR., Div Chem Sci., 40 (1991) 1722] 6) S.M Yunusov, S Rummel, M.A Ilatovskaya, M Herrmann, V.A Likholobov, V.B Shur, M.E Vol’pin Activation of Hydrocarbon С–Н Bonds by Catalysts Based on Potassium Salts of Transition Metal Carbonyl Hydrides on a Carbon Support Metalloorg Khim., (1992) 13951396 [Organomet Chem USSR, (1992) 685 (Engl Transl.)] 8 7) S Rummel, M.A Ilatovskaya, E.I Mysov, V.S Lenenko, H Langguth, V.B Shur Catalytic Activation of C–H Bonds in Aromatic Hydrocarbons, Ethene, and Methane by the Naphthalene/Sodium System in Tetrahydrofuran Angew Chem Int Ed Engl., 35 (1996) 24892491 8) S Rummel, S.M Yunusov, M.A Ilatovskaya, H Langguth, E.I Mysov, M Wahren, V.A Likholobov, V.B Shur Catalytic Activation of C–H Bonds of Alkanes, Ethene and Aromatic Hydrocarbons by the Adducts of Active Carbons with Metallic Potassium J Molec Cat A: Chem., 132 (1998) 277-280 9) S Rummel, M.A Ilatovskaya, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur Activation of C–H Bonds of Hydrocarbons by the ArH–Alkali Metal Systems in THF (ArH – Naphthalene, Biphenyl, Anthracene, Phenanthrene, trans-Stilbene, Pyrene) Alkylation of Naphthalene and Toluene with Ethene J Organomet Chem., 694 (2009) 1459-1466 10) S Rummel, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur Synergistic Effects of Alkali Metals in the Alkylation of Naphthalene and Toluene with Ethene in the ArH–Alkali Metal Systems in THF (ArH – Naphthalene, Phenanthrene) J Organomet Chem., 694 (2009) 1467-1472 Acetylene Complexes of Group IVB Metallocenes 1) V.B Shur, E.G Berkovich, M.E Vol'pin, B Lorenz, M Wahren Interaction of Titanocene Generated in the System Cp2TiCl2 + Mg in THF with Benzyne and Tolane A Novel Route to Titanaindene and Titanacyclopentadiene Complexes J Organomet Chem., 228 (1982) C36-C38 2) V.B Shur, S.Z Bernadyuk, V.V Burlakov, V.G Andrianov, A.I Yanovsky, Yu.T Struchkov, M.E Vol'pin Synthesis and X-Ray Structure Determination of an Organometallic Titanoxane [Cp2TiC(Ph)=CH(Ph)]2O Evidence for the Formation of a Titanocene Complex with Tolane J Organomet Chem., 243 (1983) 157-163 3) V.B Shur, V.V Burlakov, M.E Vol'pin Synthesis of Unsymmetrical Titanacyclopentadienes by Reacting a Titanocene Tolan Complex with Acetylenes Izv Akad Nauk SSSR, Ser Khim., (1983) 1929-1930 [Bull Acad Sci USSR, Div Chem Sci., 32 (1983) 1753 (Engl Transl.)] 4) V.B Shur, V.V Burlakov, A.I Yanovsky, P.V Petrovsky, Yu.T Struchkov, M.E Vol'pin Reaction of a Tolane Complex of Titanocene with Carbonyl Compounds Synthesis of Titanadihydrofuran Metallacycles J Organomet Chem., 297 (1985) 51-59 5) V.B Shur, V.V Burlakov, M.E Vol'pin Complex of Titanocene with Tolane Isolation, Spectral Characteristics, Reactivity J Organomet Chem., 347 (1988) 77-83 6) V.V Burlakov, U Rosenthal, P.V Petrovskii, V.B Shur, M.E Vol'pin A Complex of Titanocene with Bis(trimethylsilyl)acetylene Metalloorg Khim., (1988) 953-954 [Organomet Chem USSR, (1988) 526-527] 9 7) U Rosenthal, G Oehme, V.V Burlakov, P.V Petrovskii, V.B Shur, M.E Vol'pin 13 C{1H}NMR Studies of Selected Transition Metal Alkyne Complexes J Organomet Chem., 391 (1990) 119122 8) V.B Shur, V.V Burlakov, M.E Vol’pin Catalytic Activity of the Titanocene Complex with Tolane in Homogeneous Hydrogenation of Unsaturated Hydrocarbons J Organomet Chem., 439 (1992) 303-308 9) U Rosenthal, H Görls, V.V Burlakov, V.B Shur, M.E Vol’pin Alkinkomplexe des Titanocens und Permethyltitanocens ohne zusätzliche Liganden – Erste Structurvergleiche J Organomet Chem., 426 (1992) C53-C57 10) U Rosenthal, A Ohff, M Michalik, H Görls, V.V Burlakov, V.B Shur Transformation of the First Zirconocene Alkyne Complex without an Additional Phosphane Ligand into a Dinuclear σAlkenyl Complex by Hydrogen Transfer from η5-C5H5 to the Alkyne Ligand Angew Chem Int Ed Engl., 32 (1993) 1193-1195 11) U Rosenthal, A Ohff, M Michalik, H Görls, V.V Burlakov, V.B Shur Interaction of the Zirconocene Alkyne Complex Cp2Zr(THF).(Me3SiC2SiMe3) and the Binuclear Zirconium Alkenyl Complex {Cp[-(1:5-C5H4)]ZrC(SiMe3)=CH(SiMe3)}2 with Carbon Dioxide and Water Organometallics, 12 (1993) 5016-5019 12) V.V Burlakov, A.V Polyakov, A.I Yanovsky, Yu.T Struchkov, V.B Shur, M.E Vol’pin, U Rosenthal, H Görls Novel Acetylene Complexes of Titanocene and Permethyltitanocene without Additional Ligands The Synthesis, Spectral Characteristics and X-Ray Diffraction Study J Organomet Chem., 476 (1994) 197-206 13) U Rosenthal, A Ohff, W Baumann, A Tillack, H Görls, V.V Burlakov, V.B Shur Zirkonadihydrofuran-Komplexe: Darstellung, Structur und Reactivitäts-Betrachtungen J Organomet Chem., 484 (1994) 203-207 14) U Rosenthal, A Ohff, W Baumann, A Tillack, H Görls, V.V Burlakov, V.B Shur Structur, Eigenschaften und NMR-spectroscopische Charakterisierung von Cp 2Zr(Pyridin)- (Me3SiCCSiMe3) Z anorg allg Chem., 621 (1995) 77-83 15) V.V Burlakov, F.M Dolgushin, A.I Yanovsky, Yu.T Struchkov, V.B Shur, U Rosenthal, U Thewalt Interaction of Carbon Dioxide with the Bis(trimethylsilyl)acetylene Complex of Permethyltitanocene: Synthesis and Structure of the Binuclear Carbonate Complex of Permethyltitanocene (Cp*2Ti)2CO3 J Organomet Chem., 522 (1996) 241-247 16) L.I Strunkina, M.Kh Minacheva, P.V Petrovskii, Z.S Klemenkova, B.V Lokshin, V.V Burlakov, V.B Shur Interactions of Hafnocene and Zirconocene Dihydrides with 10 Acetylenes Synthesis of the First Acetylene Complex of Hafnium Izv Akad Nauk, Ser Khim., (1997) 853-856 [Russ Chem Bull., 46 (1997) 820-823 (Engl Transl.)] 17) V.V Burlakov, A.I Yanovsky, Yu.T Struchkov, U Rosenthal, A Spannenberg, R Kempe, O.G Ellert, V.B Shur Interaction of Carbon Dioxide with Acetylene Complexes of Titanocene Cp2Ti(RC2R) (R=Ph, SiMe3) Synthesis and Structure of Binuclear -Alkenylcarboxylate Complexes of Titanium (III) Cp2TiC(R)=C(R)COOTiCp2 and Unexpected Transformation of These Complexes into Titanafuranone Metallacycles Under the Action of Air Oxygen J Organomet Chem., 542 (1997) 105-112 18) V.V Burlakov, A.V Usatov, K.A Lyssenko, M.Yu Antipin, Yu.N Novikov, V.B Shur Synthesis and Structure of the First Fullerene Complex of Titanium Cp 2Ti(2-C60) Eur J Inorg Chem., (1999) 1855-1857 19) L.I Strunkina, M.Kh Minacheva, K.A Lyssenko, Z.S Klemenkova, A.Yu Volkonsky, P.V Petrovskii, V.V Burlakov, V.B Shur Interaction of Bis(trimethylsilyl)acetylene Complex of Titanocene with Mercury Trifluoroacetate Izv Akad Nauk, Ser Khim., (2003) 1299-1301 [Russ Chem Bull., Int Ed., 52 (2003) 1372-1375] Zwitterionic Group IVB Metallocenes 1)V.V Burlakov, S.I Troyanov, A.V Letov, E.I Mysov, G.G Furin, V.B Shur Synthesis of a Zwitterionic Metallocene of a New Type by the Reaction of the Bis(trimethylsilyl)acetylene Complex of Titanocene with Tris(pentafluorophenyl)borane Izv Akad Nauk, Ser Khim., (1999) 1022-1024 [Russ Chem Bull., 48 (1999) 1012-1013 (Engl Transl.)] 2)V.V Burlakov, S.I Troyanov, A.V Letov, L.I Strunkina, M.Kh Minacheva, G.G Furin, U Rosenthal, V.B Shur Interaction of Bis(trimethylsilyl)acetylene Complex of Titanocene with Tris(pentafluorophenyl)borane Synthesis and Structure of a New Type of Zwitterionic Metallocene (5-C5H5){5-[C5H4B(C6F5)3]}Ti J Organomet Chem., 598 (2000) 243-247 3)V.V Burlakov, P.-M Pellny, P Arndt, W Baumann, A Spannenberg, V.B Shur, U Rosenthal Reactions of Permethylmetallocene Alkyne Complexes of Titanium and Zirconium with Tris(perfluorophenyl)borane J Chem Soc Chem Commun., (2000) 241-242 4)V.V Burlakov, P Arndt, W Baumann, A Spannenberg, U Rosenthal, A.V Letov, K.A Lyssenko, A.A Korlyukov, L.I Strunkina, M.Kh Minacheva, V.B Shur Synthesis and X-Ray Crystal Structure Determination of New Zwitterionic Complexes of Titanocene Organometallics, 20 (2001) 4072-4079 5)A Spannenberg, V.V Burlakov, P Arndt, W Baumann, V.B Shur, U Rosenthal Crystal Structure of [1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)][hydroxytris(pentafluorophenyl)borato]titanium (III), C38H24BF15OTi Z Kristallogr NCS, 217 (2002) 546-548 11 6)L.I Strunkina, M.Kh Minacheva, K.A Lyssenko, O.I Haustova, V.V Burlakov, U Rosenthal, V.B Shur Synthesis of Zwitterionic Titanocene Monochloride Cp[5-C5H4B(C6F5)3]TiCl Containing Tris(pentafluorophenyl)borane Moiety in the 5-Cyclopentadienyl Ring Izv Akad Nauk, Ser Khim., (2003) 737-738 [Russ Chem Bull., Int Ed., 52 (2003) 773-774] 7)P Arndt, W Baumann, A Spannenberg, U Rosenthal, V.V Burlakov, V.B Shur Reactions of Titanium and Zirconium Derivatives of Bis(trimethylsilyl)acetylene with Tris(pentafluorophenyl)borane: A Titanium(III) Complex of an Alkynylboranate Angew Chem Int Ed., 42 (2003) 1414-1418 8)V.V Burlakov, A.V Letov, P Arndt, W Baumann, A Spannenberg, Ch Fisher, L.I Strunkina, M.Kh Minacheva, Ya.S Vygodskii, U Rosenthal, V.B Shur Zwitterionic Titanoxanes {Cp[5-C5H4B(C6F5)3]Ti}2O and {(5-iPrC5H4)[5-{1,3-iPrC5H3B(C6F5)3}]Ti}2O as Catalysts for Cationic Ring-Opening Polymerization J Molec Cat A: Chem., 200 (2003) 63-67 9)U Rosenthal, V.V Burlakov, P Arndt, W Baumann, A Spannenberg, V.B Shur Titanocene and Zirconocene Bis(trimethylsilyl)acetylene Complexes: Recent Chemistry and Reactions with Lewis Acids Eur J Inorg Chem., (2004) 4739-4749 10) L.I Strunkina, M.Kh Minacheva, K.A Lyssenko, P.V Petrovskii, V.V Burlakov, U Rosenthal, V.B Shur Protolytic B–C6F5 Bond Cleavage in Zwitterioniс Titanocene Monochloride Cp[5C5H4B(C6F5)3]TiCl with Water to Form Titanocene Chloride Hydroxide Complex Cp[5C5H4B(C6F5)2]TiCl(-OH) Izv Akad Nauk, Ser Khim., (2006) 169-171 [Russ Chem Bull., Int Ed., 55 (2006) 174-176] 11) L.I Strunkina, M.Kh Minacheva, K.A Lyssenko, V.V Burlakov, W Baumann, P Arndt, B.N Strunin, V.B Shur Interaction of Titanium (III) Zwitterionic Complex Cp[5C5H4B(C6F5)3]Ti with Organic Halides: Synthesis and X-Ray Crystal Structure Determination of Zwitterionic Titanocene Monohalides Cp[5-C5H4B(C6F5)3]TiX (X = Cl, Br) and their Catalytic Activity in the Ring-Opening Polymerization of -Caprolactone J Organomet Chem., 691 (2006) 557-565 12) L.I Strunkina, M.Kh Minacheva, K.A Lyssenko, P.V Petrovskii, N.E Mysova, B.N Strunin, V.V Burlakov, U Rosenthal, V.B Shur Electrophilic Reactivity of the Zwitterionic Titanocene Monohalides Cp[5-C5H4B(C6F5)3]TiX (X = Cl, Br): Reactions with Water and Methanol J Organomet Chem., 692 (2007) 4321-4326 12 Metallacyclic Derivatives of Group IV B Metallocenes and Their Reactions with Lewis Acids 1)V.V Burlakov, V.S Bogdanov, K.A Lyssenko, P.V Petrovskii, T Beweries, P Arndt, U Rosenthal, V.B Shur First Structurally Characterized Five-Membered Hafnacyclocumulene Сp2Hf(4-tBuС4tBu) Izv Akad Nauk, Ser Khim., (2008) 1294-1295 [Russ Chem Bull., Int Ed., 57 (2008) 1319-1320] 2)V.V Burlakov, T Beweries, V.S Bogdanov, P Arndt, W Baumann, P.V Petrovskii, A Spannenberg, K.A Lyssenko, V.B Shur, U Rosenthal Synthesis and Isolation of Di-nbutylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of New Hafnacycles Organometallics, 28 (2009) 2864-2870 3)V.V Burlakov, V.S Bogdanov, K.A Lyssenko, L.I Strunkina, M.Kh Minacheva, B.N Strunin, U Rosenthal, V.B Shur Formation of the Five-Membered Zirconacyclocumulene Cp 2Zr(η4ButC4But) and the Binuclear Zirconocene Butatrienyl Complex Cp 2(Bun)Zr(ButC4But)Zr(Bun)Cp2 in the Reaction of the Negishi Reagent with 1,4-Di(tert-butyl)butadiyne Izv Akad Nauk, Ser Khim., (2010) 653-655 [Russ Chem Bull., Int Ed., 59 (2010) 668-670] 4)V.V Burlakov, T Beweries, K Kaleta, V.S Bogdanov, P Arndt, W Baumann, A Spannenberg, V.B Shur, U Rosenthal Reactions of the Five-Membered Hafnacyclocumulene Cp2Hf(4-t-BuC4-t-Bu) with the Lewis Acids Tris(pentafluorophenyl)borane and Diisobutylaluminum Hydride Organometallics, 29 (2010) 2367-2371 5)V.V Burlakov, V.S Bogdanov, K.A Lyssenko,A Spannenberg, P.V Petrovskii, W Baumann, L.I Strunkina, M.Kh Minacheva, B.N Strunin, P Arndt, U Rosenthal, V.B Shur., Interaction of the Negishi Reagent Cp2ZrBun2 with 1,4-bis(tert-butyl)butadiyne Izv Akad Nauk, Ser Khim., (2011) in press [Russ Chem Bull., Int Ed., 60 (2011) in press] 6)V.V Burlakov, T Beweries, K Kaleta, V.S Bogdanov, P Arndt, W Baumann, A Spannenberg, V.B Shur, U Rosenthal Reactions of the Five-Membered Metallacyclocumulenes Cp2M(4-tBu-C4-t-Bu) (M = Ti, Zr) with Diisobutylaluminum Hydride Organometallics, (2011) in press Anticrowns 1)V.B Shur, I.A Tikhonova, P.V Petrovskii, M.E Vol'pin Complex Formation Between Trimeric oPhenylenemercury and Halide Anions and the Phase Transfer Catalysis of the Azo-Coupling Reaction Metalloorg Khim., (1989) 1431-1432 [Organomet Chem USSR, (1989) 759-760 (Engl Transl.)] 2)V.B Shur, I.A Tikhonova, A.I Yanovsky, Yu.T Struchkov, P.V Petrovskii, S.Yu Panov, G.G Furin, M.E Vol'pin Crown Compounds for Anions Unusual Complex of Trimeric Perfluoro-o-phenylenemercury with the Bromide Anion Having a Polydecker Sandwich Structure J Organomet Chem., 418 (1991) C29-C32 13 3)V.B Shur, I.A Tikhonova, A.I Yanovskii, Yu.T Struchkov, P.V Petrovskii, S.Yu Panov, G.G Furin, M.E Vol'pin Multideck Sandwich Complex of Trimeric Perfluoro-o- phenylenemercury with Iodide Anion Dokl Akad Nauk SSSR, 321 (1991) 1002-1004 [Dokl Chem., 321 (1991) 391-393 (Engl Transl.)] 4)V.B Shur, I.A Tikhonova, F.M Dolgushin, A.I Yanovsky, Yu.T Struchkov, A.Yu Volkonsky, E.V Solodova, S.Yu Panov, P.V Petrovskii, M.E Vol'pin Crown Compounds for Anions A Spinning Top-Shaped Complex of Cyclic Pentameric Perfluoroisopropylidenemercury with Two Chloride Anions J Organomet Chem., 443 (1993) C19-C20 5)V.B Shur, I.A Tikhonova, F.M Dolgushin, A.I Yanovsky, Yu.T Struchkov, A.Yu Volkonsky, P.V Petrovskii, E.V Solodova, S.Yu Panov, M.E Vol'pin Crown Compounds for Anions A Spinning Top-Shaped Complex of Cyclic Pentameric Perfluoroisopropylidenemercury with Two Bromide Anions Dokl Akad Nauk, 328 (1993) 339-341 6)A.P Zaraiskii, O.I Kachurin, L.I Velichko, I.A Tikhonova, G.G Furin, V.B Shur, M.E Vol'pin Cyclic Trimeric Perfluoro-o-phenylenemercury as the Phase Transfer Catalyst for Nitration with Dilute Nitric Acid Izv Akad Nauk, Ser Khim., (1994) 547-548 [Russ Chem Bull., 43 (1994) 507-508 (Engl Transl.)] 7)A.P Zaraiskii, O.I Kachurin, L.I Velichko, I.A Tikhonova, A.Yu Volkonsky, V.B Shur New Highly Efficient Phase Transfer Catalyst for Nitration with Dilute Nitric Acid Izv Akad Nauk, Ser Khim., (1994) 2047-2048 [Russ Chem Bull., 43 (1994) 1936-1937 (Engl Transl.)] 8)A.L Chistyakov, I.V Stankevich, N.P Gambaryan, I.A Tikhonova, V.B Shur Crown Compounds for Anions The Nature of Chemical Bonds in the Complexes of Halide Anions with Cyclic Trimeric Perfluoro-o-phenylenemercury and Some of Its Analogs Izv Akad Nauk, Ser Khim., (1995) 1035-1042 [Russ Chem Bull., 44 (1995) 997-1004 (Engl Transl.)] 9)I.A Tikhonova, F.M Dolgushin, A.I Yanovsky, Yu.T Struchkov, A.N Gavrilova, L.N Saitkulova, E.S Shubina, L.M Epstein, G.G Furin, V.B Shur Crown Compounds for Anions A Polymeric Complex of Cyclic Trimeric Perfluoro-o-phenylenemercury with Thiocyanate Anion Containing an Infinite Helical Chain of Alternating Molecules of MercuryContaining Macrocycle and SCN– Ions J Organomet Chem., 508 (1996) 271-273 10) A.L Chistyakov, I.V Stankevich, N.P Gambaryan, I.A Tikhonova, V.B Shur Crown Compounds for Anions MNDO Calculations of Complexes of Halide Anions with Cyclic Pentameric Difluoromethylidenemercury Izv Akad Nauk, Ser Khim., (1996) 44-48 [Russ Chem Bull., 45 (1995) 37-41 (Engl Transl.)] 11) A.L Chistyakov, I.V Stankevich, N.P Gambaryan, Yu.T Struchkov, A.I Yanovsky, I.A Tikhonova, V.B Shur Crown Compounds for Anions A New Approach to the Description 14 of Chemical Bonds in the Complexes of Halide Anions with Polymercury-containing Macrocycles J Organomet Chem., 536-537 (1997) 413-424 12) A.P Zaraiskii, O.I Kachurin, L.I Velichko, V.B Shur, I.A Tikhonova, G.G Furin Phase-Transfer Catalysis in Electrophilic Substitution Reactions: VIII Nitration of Arenes with Sodium Nitrite in Acid Medium under Conditions of Phase-Transfer Catalysis Zh Org Khim., 35 (1999) 10631067 [Russ J Org Chem., 35 (1999) 1039-1043 (Engl Transl.)] 13) L.N Saitkulova, E.V Bakhmutova, E.S Shubina, I.A Tikhonova, G.G Furin, V.I Bakhmutov, N.P Gambaryan, A.L Chistyakov, I.V Stankevich, V.B Shur, L.M Epstein Crown Compounds for Anions Spectroscopic and Theoretical Studies of Complexation of Borohydride Anions with Cyclic Trimeric Perfluoro-o-phenylenemercury J Organomet Chem., 585 (1999) 201-210 14) I.A Tikhonova, F.M Dolgushin, A.I Yanovsky, Z.A Starikova, P.V Petrovskii, G.G Furin, V.B Shur Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury with Nitriles A Remarkable Sensitivity of the Composition and Structure of the Resulting Complexes to the Nature of a Nitrile J Organomet Chem., 613 (2000) 60-67 15) E.S Shubina, I.A Tikhonova, E.V Bakhmutova, F.M Dolgushin, M.Yu Antipin, V.I Bakhmutov, I.B Sivaev, L.N Teplitskaya, I.T Chizhevsky, I.V Pisareva, V.I Bregadze, L.M Epstein, V.B Shur Crown Compounds for Anions: Sandwich and Half-Sandwich Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with Polyhedral closo-[B10H10]2– and closo-[B12H12]2– Anions Chem Eur J., (2001) 3783-3790 16) I.A Tikhonova, F.M Dolgushin, K.I Tugashov, G.G Furin, P.V Petrovskii, V.B Shur Coordination Chemistry of Macrocyclic Multidentate Lewis Acids Synthesis and Structures of Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with N,N-Dimethylacetamide and n-Butyronitrile Izv Akad Nauk, Ser Khim., (2001) 1595-1600 [Russ Chem Bull., Int Ed., 50 (2001) 1673-1678] 17) I.A Tikhonova, F.M Dolgushin, K.I Tugashov, P.V Petrovskii, G.G Furin, V.B Shur Coordination Chemistry of Polymercuramacrocycles Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury with Neutral Oxygeneous Lewis Bases J Organomet Chem., 654 (2002) 123-131 18) I.A Tikhonova, E.S Shubina, F.M Dolgushin, K.I Tugashov, L.N Teplitskaya, A.M Filin, I.B Sivaev, P.V Petrovskii, G.G Furin, V.I Bregadze, L.M Epstein, V.B Shur Crown Compounds for Anions Sandwich Complex of Cyclic Trimeric Perfluoro-o-phenylenemercury with [B12H11SCN]2– Anion Izv Akad Nauk, Ser Khim., (2003) 570-576 [Russ Chem Bull., Int Ed., 52 (2003) 594-600] 15 19) V.B Shur, I.A Tikhonova Perfluorinated Polymercuramacrocycles as Anticrowns Applications in Catalysis Izv Akad Nauk, Ser Khim., (2003) 2401-2416 [Russ Chem Bull., Int Ed., 52 (2003) 2539-2554] 20) I.A Tikhonova, F.M Dolgushin, K.I Tugashov, O.G Ellert, V.M Novotortsev, G.G Furin, M.Yu Antipin, V.B Shur Crown Compounds for Anions Sandwich Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with Hexacyanoferrate(III) and Nitroprusside Anions J Organomet Chem., 689 (2004) 82-87 21) V.B Shur, I.A Tikhonova Anticrowns In: “Encyclopedia of Supramolecular Chemistry” (Eds J.L Atwood and J.W Steed), Marcel Dekker, Inc., New York, 2004, 68-75 22) I.A Tikhonova, F.M Dolgushin, K.I Tugashov, P.V Petrovskii, M.Yu Antipin, V.B Shur Binding of Ferrocene by Cyclic Trimeric Perfluoro-o-phenylenemercury Synthesis and Structure of the First Double-Decker Sandwich Complex of a Sandwich Izv Akad Nauk, Ser Khim., (2004) 2754-2756 [Russ Chem Bull., Int Ed., 53 (2004) 2871-2873] 23) A.P Zaraisky, O.I Kachurin, L.I Velichko, I.A Tikhonova, G.G Furin, V.B Shur Cyclic Trimeric Perfluoro-o-phenylenemercury: A Highly Efficient Phase Transfer Catalyst for Nitration of Aromatic Substrates with Dilute Nitric Acid J Molec Cat A: Chem., 231 (2005) 103-111 24) Z Yan, I.A Tikhonova, Z Zhou, V.B Shur, Y Wu Cyclic Trimeric Perfluoro-o-phenylenemercury as a New Ionophore for Quaternary Ammonium Cation Selective Membrane Electrodes Anal Lett., 38 (2005) 377-388 25) I.A Tikhonova, F.M Dolgushin, A.A Yakovenko, K.I Tugashov, P.V Petrovskii, G.G Furin, V.B Shur Binding of Dienophiles by Macrocyclic Multidentate Lewis Acids Synthesis and XRay Crystal Structure Determination of Unusual Complexes of Cyclic Trimeric Perfluoro-ophenylenemercury with p-Benzoquinone and Maleic Anhydride Organometallics, 24 (2005) 3395-3400 26) I.A Tikhonova, K.I Tugashov, F.M Dolgushin, A.A Yakovenko, B.N Strunin, P.V Petrovskii, G.G Furin, V.B Shur Coordination Chemistry of Anticrowns: Synthesis and X-Ray Crystal Structure Determination of the Polydecker Sandwich Complexes of Cyclic Trimeric Perfluoro-ophenylenemercury with Azulene and 6-(N,N-Dimethylamino)pentafulvene Inorg Chim Acta, 359 (2006) 2728-2735 27) I.A Tikhonova, A.A Yakovenko, K.I Tugashov, F.M Dolgushin, V.V Novikov, M.Yu Antipin, V.B Shur Selective Binding of the Keto Form of Acetylacetone by Cyclic Trimeric Perfluoro-ophenylenemercury Quantitative Shift of the Keto-Enol Equilibrium in Acetylacetone Toward its Keto Form Stabilized by the Complexation Organometallics, 25 (2006) 6155-6158 28) I.A Tikhonova, K.I Tugashov, F.M Dolgushin, A.A Yakovenko, P.V Petrovskii, G.G Furin, A.P Zaraisky, V.B Shur Coordination Chemistry of Anticrowns: Complexation of Cyclic 16 Trimeric Perfluoro-o-phenylenemercury with Nitro Compounds J Organomet Chem., 692 (2007) 953-962 29) I.A Tikhonova, K.I Tugashov, F.M Dolgushin, P.V Petrovskii, V.B Shur Complexation of [9]Thiacrown-3 and 1,3,5-Trithiane with Cyclic Trimeric Perfluoro-o-phenylenemercury Synthesis and Structures of the First Complexes of Crown Compounds with an Anticrown Organometallics, 26 (2007) 5193-5198 30) V.N Tsupreva, O.A Filippov, F.M Dolgushin, K.I Tugashov, A.I Krylova, V.I Bragin, I.A Tikhonova, V.B Shur, L.M Epstein, E.S Shubina Coordination Chemistry of Anticrowns Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury (o-C6F4Hg)3 with the Cyanoborohydride Anion [H3BCN]− and Triethylamineborane Et3NBH3 Izv Akad Nauk, Ser Khim., (2008) 2489-2496 [Russ Chem Bull., Int Ed , 57 (2008) 2540-2547] 31) I.A Tikhonova, K.I Tugashov, F.M Dolgushin, A.A Korlyukov, P.V Petrovskii, Z.S Klemenkova, V.B Shur Coordination Chemistry of Mercury-Containing Anticrowns Synthesis and Structures of the Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with Ethanol, THF and Bis-2,2-Tetrahydrofuryl Peroxide J Organomet Chem., 694 (2009) 2604-2610 32) I.A Tikhonova, D.A Gribanyov, K.I Tugashov, F.M Dolgushin, A.F Smol’yakov, A.S Peregudov, Z.S Klemenkova, V.B Shur Complexation of [12]Crown-4, [18]Crown-6 and 1,3,5-Trioxane with Cyclic Trimeric Perfluoro-o-phenylenemercury Synthesis and Structures of the First Complexes of Crown Ethers with an Anticrown Organometallics, 28 (2009) 65676573 33) I.A Tikhonova, D.A Gribanyov, K.I Tugashov, F.M Dolgushin, A.S Peregudov, D.Yu Antonov, V.I Rosenberg, V.B Shur Coordination Chemistry of Mercury-Containung Anticrowns Synthesis and Structure of an Unusual Discrete, Double-Decker Sandwich Complex of Cyclic Trimeric Perfluoro-o-phenylenemercury with an Aromatic Hydrocarbon J Organomet Chem., 695 (2010) 1949-1952 34) I.A Tikhonova, D.A Gribanyov, K.I Tugashov, F.M Dolgushin, A.F Smol’yakov, A.S Peregudov, Z.S Klemenkova, V.B Shur Coordination Chemistry of Mercury-Containing Anticrowns Self-Assembly of Unusual Supramolecular Aggregates in the Interaction of the Three-Mercury Anticrown (o-C6F4Hg)3 with Crown Ethers in the Presence of Neutral Monodentate Oxygenous Lewis Bases Arkivoc, (2011) in press Some Other Publications 1) M.Kh Grigoryan, I.S Kolomnikov, E.G Berkovich, T.V Lysyak, V.B Shur, M.E Vol’pin Reaction of Carbon Dioxide with Ditolyltitanocenes under Thermal Decomposition Conditions 17 Izv Akad Nauk, Ser Khim., (1978) 1177-1180 [Bull Acad Sci USSR, Div Chem Sci., 27 (1978) 1024-1026 (Engl Transl.)] 2) V.B Shur, S.M Yunusov, E.I Mysov, A.A Belyi, M.E Vol’pin Synthesis of Unsolvated Organopotassium and Organosodium Compounds by the Reaction of Solid Unsaturated Hydrocarbons with Fused Potassium and Sodium Izv Akad Nauk, Ser Khim., (1982) 2638 [Bull Acad Sci USSR, Div Chem Sci., 31 (1982) 2336 (Engl Transl.)] 3) V.S Lenenko, A.I Yanovsky, Yu.T Struchkov, V.B Shur, M.E Vol’pin Synthesis and Structure of Dihydridodichlorotetrakis(dimethylphenylphosphine)molybdenum Koord Khim., 12 (1986) 636-642 4) E.Yu Baukova, L.M Bronshtein, P.M Valetskii, M.G Ezernitskaya, B.V Lokshin, L.I Strunkina, O.A Mikhailova, M.H Minacheva, V.B Shur Interaction of Zirconocene Hydrides with Polybutadiene Synthesis of Zirconium-Containing Polymers Metalloorg Khim., (1992) 1386-1390 [Organomet Chem USSR, (1992) 680-683 (Engl Transl.)] 5) O.A Mikhailova, M.H Minacheva, V.V Burlakov, V.B Shur, A.P Pisarevsky, A.I Yanovsky, Yu.T Struchkov Trimeric Bis(cyclopentadienyl)oxozirconium(IV) Benzene Solvate Acta Cryst., Sect C, 49 (1993) 1345-1347 6) I.I Tverdokhlebova, V.V Ivanov, S.A Bashkirova, V.M Men’shov, T.A Larina, E.A Chernyshov, I.A Tikhonova, V.B Shur Synthesis of Monomodal Polysilane by the Würts Reaction in the Presence of Mercury Vysokomol Soedin., Ser B, 37 (1995) 1227 7) I.I Tverdokhlebova, V.V Ivanov, T.A Larina, V.M Men’shov, I.A Tikhonova, S.A Bashkirova, G.G Furin, V.B Shur Effect of Mercury and its Derivatives on the Synthesis of Polysilanes by the Würts Reaction Vysokomol Soedin., Ser B, 38 (1996) 1601-1604 [Polymer Science, Ser B, 38 (1996) 356-360] 8) O.A Mikhailova, M.Kh Minacheva, Z.S Klemenkova, V.B Shur Interaction of Carbon Dioxide with Zirconocene and Hafnocene Dihydrides Izv Akad Nauk, Ser Khim., (1996) 23662368 [Russ Chem Bull., Int Ed., 45 (1996) 2248-2250] In Memory of Mark Vol’pin 1) I Levitin, V Shur Mark Vol’pin (Obituary) Inorg Chim Acta, 254 (1997) 203-207 2) I Levitin, V Shur Mark Vol’pin: Glorious Path in Science Inorg Chim Acta, 280 (1998) xvxix Selected Publications in 2008-2010 1) V.V Burlakov, V.S Bogdanov, K.A Lyssenko, P.V Petrovskii, T Beweries, P Arndt, U Rosenthal, V.B Shur First structurally characterized five-membered hafnacyclocumulene 18 Сp2Hf(4-tBuС4tBu) Izv Akad Nauk, Ser Khim., (2008) 1294-1295 [Russ Chem Bull., Int Ed., 57 (2008) 1319-1320] 2) V.N Tsupreva, O.A Filippov, F.M Dolgushin, K.I Tugashov, A.I.Krylova, V.I.Bragin, I.A Tikhonova, V.B Shur, L.M Epstein, E.S Shubina Coordination Chemistry of Anticrowns Complexation of Cyclic Trimeric Perfluoro-o-phenylenemercury (o-C6F4Hg)3 with the Cyanoborohydride Anion [H3BCN]− and Triethylamineborane Et3NBH3 Izv Akad Nauk, Ser Khim., (2008) 2489-2496 [Russ Chem Bull., Int Ed , 57 (2008) 2540-2547] 3) S Rummel, M.A Ilatovskaya, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur Activation of C–H Bonds of Hydrocarbons by the ArH–Alkali Metal Systems in THF (ArH – Naphthalene, Biphenyl, Anthracene, Phenanthrene, trans-Stilbene, Pyrene) Alkylation of Naphthalene and Toluene with Ethene J Organomet Chem., 694 (2009) 1459-1466 4) S Rummel, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur Synergistic Effects of Alkali Metals in the Alkylation of Naphthalene and Toluene with Ethene in the ArH–Alkali Metal Systems in THF (ArH – Naphthalene, Phenanthrene) J Organomet Chem., 694 (2009) 14671472 5) V.V Burlakov, T Beweries, V.S Bogdanov, P Arndt, W Baumann, P.V Petrovskii, A Spannenberg, K.A Lyssenko, V.B Shur, U Rosenthal Synthesis and Isolation of Di-nbutylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of New Hafnacycles Organometallics, 28 (2009) 2864-2870 6) I.A Tikhonova, K.I Tugashov, F.M Dolgushin, A.A Korlyukov, P.V Petrovskii, Z.S Klemenkova, V.B Shur Coordination Chemistry of Mercury-Containing Anticrowns Synthesis and Structures of the Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with Ethanol, THF and Bis-2,2-Tetrahydrofuryl Peroxide J Organomet Chem., 694 (2009) 2604-2610 7) I.A Tikhonova, D.A Gribanyov, K.I Tugashov, F.M Dolgushin, A.F Smol’yakov, A.S Peregudov, Z.S Klemenkova, V.B Shur Complexation of [12]Crown-4, [18]Crown-6 and 1,3,5-Trioxane with Cyclic Trimeric Perfluoro-o-phenylenemercury Synthesis and Structures of the First Complexes of Crown Ethers with an Anticrown Organometallics, 28 (2009) 65676573 8) V.V Burlakov, V.S Bogdanov, K.A Lyssenko, L.I Strunkina, M.Kh Minacheva, B.N Strunin, U Rosenthal, V.B Shur Formation of the five-membered zirconacyclocumulene Cp2Zr(η4-ButC4But) and the binuclear zirconocene butatrienyl complex Cp2(Bun)Zr(ButC4But)Zr(Bun)Cp2 in the reaction of the Negishi reagent with 1,4-di(tertbutyl)butadiyne Izv Akad Nauk, Ser Khim., (2010) 653-655 [Russ Chem Bull., Int Ed., 59 (2010) 668-670] 19 9) V.V Burlakov, T Beweries, K Kaleta, V.S Bogdanov, P Arndt, W Baumann, A Spannenberg, V.B Shur, U Rosenthal Reactions of the Five-Membered Hafnacyclocumulene Cp2Hf(4-t-Bu-C4-t-Bu) with the Lewis Acids Tris(pentafluorophenyl)borane and Diisobutylaluminum Hydride Organometallics, 29 (2010) 2367-2371 10) I.A Tikhonova, D.A Gribanyov, K.I Tugashov, F.M Dolgushin, A.S Peregudov, D.Yu Antonov, V.I Rosenberg, V.B Shur Coordination Chemistry of Mercury-Containung Anticrowns Synthesis and Structure of an Unusual Discrete, Double-Decker Sandwich Complex of Cyclic Trimeric Perfluoro-o-phenylenemercury with an Aromatic Hydrocarbon J Organomet Chem., 695 (2010) 1949-1952