Stereochemical assignment and total synthesis of an antimalarial lipopeptide

... STEREOCHEMICAL ASSIGNMENT AND TOTAL SYNTHESIS OF AN ANTIMALARIAL LIPOPEPTIDE SHIBAJI KUMAR GHOSH (M.Sc, UNIVERSITY OF CALCUTTA) A THESIS SUBMITTED FOR THE DEGREE OF DOCTOR OF PHILOSOPHY ... Ghosh, Martin J Lear; Stereochemical Assignment and Total Synthesis of an Anti-malarial Lipopeptide , The 6th Mathematics and Physical Science Graduate Congress, Uni...

Ngày tải lên: 10/09/2015, 15:52

... δ 15 9 .42 , 15 8 .10 , 15 5.06, 15 5.03, 15 4 .19 , 15 3.80, 15 3.25, 15 1.98, 12 9.50, 12 9.03, 12 8.39, 12 8 .12 , 12 4. 42, 12 3.22, 12 2.83, 12 1. 34, 12 1.29, 12 0.66, 11 1 .49 , 11 1.23, 11 1. 01, 11 0.55, 10 6 .10 , 10 4. 92, ... 16 1.5, 16 1 .4, 16 1.3, 15 9.8, 15 9.7, 15 9.7, 15 9.6, 15 8.7, 15 8.2, 15 7.3, 15 3.7, 14 4. 7, 12 3.9, 12 3.9,...

Ngày tải lên: 10/09/2015, 15:48

... O OTs 5- 10 C43H36O9S2 760.9 OBn OTs O FT-IR Data 3 25 O OH OBn 5- 11 C29H24O5 452 .5 OH O 326 Appendix O O O OBn 5- 12 C29H24O5 452 .5 O FT-IR Data 327 O O O 5- 13 C44H32O8 688.7 O O O O O 328 Appendix ... Data 337 HO O 5- 28 C14H16O3 232.3 O 338 Appendix HO O 5- 33 C14H16O3 232.3 OH FT-IR Data 339 AcO O O 5- 32 C16H18O4 274.3 340 Appendix AcO O OAc 5- 35 C18H20O5 316.3 FT-IR Dat...

Ngày tải lên: 10/09/2015, 15:49

... Low-Resolution-Mass Data HO O 5-33 C14H16O3 232.3 OH 373 AcO O O 5-32 C16H18O4 274.3 374 Appendix Low-Resolution-Mass Data AcO O OAc 5-35 C18H20O5 3 16. 3 375 AcO O 5-38 C18H20O6 332.3 OAc O 3 76 Appendix ... Low-Resolution-Mass Data 353 OH O 5-2 C18H14O3 278.3 O 354 Appendix Low-Resolution-Mass Data 355 O 5-4 C36H24O4 520 .6 O O O O O 5 -6 C36H24O4 520 .6 O O 3 56 Appendix Low-Resolutio...

Ngày tải lên: 10/09/2015, 15:50

... 232.1099 412 Appendix O AcO O 5-32 C16H18O4 274 .1205 High-Resolution-Mass Data 413 O AcO OAc 5-35 C18H20O5 316.1311 414 Appendix O O AcO OAc 5-38 C18H20O6 332.1260 High-Resolution-Mass Data 415 O ... High-Resolution-Mass Data 391 O O O O 5-4 C36H24O4 520.1 675 392 Appendix O O O O 5-6 C36H24O4 520.1 675 High-Resolution-Mass Data 393 O I OH 5-8 C8H7IO2 261.9491 394 Appendix O I OTs 5-9 C15H13...

Ngày tải lên: 10/09/2015, 15:50

... Programme (PhD student under the supervision of Dr Martin Lear) • Affinity- Guided Isolation, Structure Elucidation and Total Synthesis of Laetirobin A and Its Analogue Synthesis for Therapeutic Development ... theta = 27. 48 99 .8 % Absorption correction Sadabs, (Sheldrick 2001) Max and transmission 0. 988 8 and 0.9456 Refinement method Full-matrix l...

Ngày tải lên: 10/09/2015, 15:50

... article as: Atkinson et al., Granuloma debridement and the use of an injectable calcium phosphate bone cement in the treatment of osteolysis in an uncemented total knee replacement Journal of Orthopaedic ... to find any data in the literature pertaining to the use of bone cements in the context of osteolytic cysts in knee art...

Ngày tải lên: 20/06/2014, 04:20

... PART I TOTAL SYNTHESIS AND BIOLOGICAL EVALUATION OF ANTILLATOXIN AND FRAGMENTS PART II SYNTHETIC STUDIES TOWARDS THE TOTAL SYNTHESIS OF CYTOCHALASANS AND TUBEROSTEMONINE APPENDIX ... Biological Evaluation of Antillatoxin and Fragments 1. 1 Historical Background 1. 2 Previous Synthetic Studies 1. 3 Our Retrosynthetic Analysis of...

Ngày tải lên: 16/09/2015, 08:31

... Derivation and preliminary validation of an administrative claims-based algorithm for the effectiveness of medications for rheumatoid arthritis Jeffrey R Curtis1,#, John W Baddley1,2, Shuo Yang1, ... VARA visits; all other data used for the analysis were from the administrative claims data To test the performance of the effectiveness algorithm...

Ngày tải lên: 25/10/2012, 10:45

... (58), (67) and (68), for given S1 and S , one can drive the maximum cooling load and corresponding COP of the irreversible quantum Carnot refrigerator with heat resistance and heat leakage analytically ... performance of harmonic and spin-1/2 quantum refrigeration cycles, many authors studied the performance of quantum refrigerator using ideal quantum Bose a...

Ngày tải lên: 05/09/2013, 15:28

... reduction in NOX emission and increase in smoke, CO and HC emissions [3-5] Pradeep & Sharma [3] investigated the effects of hot EGR along with JB100 (100% Jatropha biodiesel) on engine performance and ... CO and unburned HC emissions The aim of the current study is to investigate the effect of EGR on performance parameters and exhaust emissions...

Ngày tải lên: 05/09/2013, 16:11

... females Fig Ability to perform ADL Analysis by gender Tlie Ceylon Journal of Medical Science Physical health and functional ability of an elderly population in Sri Lanka 13 Table Number and % (in parenthesis) ... Identification of health problems and functional ability of an elderly population is of importance to health planners and policy make...

Ngày tải lên: 14/02/2014, 06:20

... way out of the danger unleashed by the death of God: “We are indeed the last man in the Nietzschean sense of the term, and the overman will be whoever can overcome the absence of God and the absence ... origins of which can be found in Christianity and its hermeneutics of the subject, and on the other hand the constitution of the subject as obedie...

Ngày tải lên: 07/03/2014, 17:20

... blue) and standard (magenta) substrates after ns of MD (C) Overlay of positions of N-propionyl modified (light blue) and standard (magenta) substrates after ns of MD (D) Molecular surface of the ... carbohydrates (left panel), protein (middle panel) and for enzymatic activity (right panel) Lane 1, PoHex; lane 2, PoHex plus Endo H; lane 3, PoHex plus a-mannosidase; lane 4, E...

Ngày tải lên: 14/03/2014, 23:20

... translating two proteins of 199 amino acids and 182 amino Fig Alternative splicing of the IL-18 gene in rainbow trout (A) An alternative mRNA splicing site is present in exon of the trout IL-18 ... exons and five introns The Fig Comparison of the genomic organization of IL-18 and IL-1b genes in human, rainbow trout and the predicted Fugu/tetraodon orga...

Ngày tải lên: 16/03/2014, 16:20