INTERFACIAL AND CONFINED WATER Part 7 pptx

... hydration water were studied in most details (see Section 6, 7. 1 and [ 473 , 508–510, 512–515, 544, 585, 590–592, 601, 632–634, 636–639]). At low hydrations and up to h ≈ 0. 07 g/g (gram of water per ... percolation thresholds in different lattices. In particular, it is ∼2.09 and ∼2. 37 for site percolation and ∼1.96 and ∼2.00 for bond percolation on the honeycomb and squar...

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... of water, and patience. We have greatly profited from collaboration with Roland Winter, Nikolay Smolin, Aljaksei Krukau, and Alexey Mazur. Our view on the properties of interfacial and confined water ... dynamic water properties. Subsequent analysis of the properties of interfacial and con- fined water allows understanding of related phenomena. Naturally, the phase behavior a...

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... kcal/mol and U 0 ≥−0 .77 kcal/mol, liquid density depletes near the surface, whereas vapor density enhances. At higher temperatures, liquid and vapor density 48 Interfacial and confined water −1.93 ... 15 Figure 28: Density profiles of water in a cylindrical pore with R p = 25 ˚ A and U 0 = −4.62 kcal/mol at T = 300, 325, 350, 375 , 400, 425, 450, 475 , and 500 K. Two water la...

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... 1.60 ˚ A and a ξ = 0. 97 is shown by solid lines in both panels (data from [262]). 58 Interfacial and confined water in cylindrical pores with R p = 25, 30, and 35 ˚ A. The pore size and the layer ... power 82 Interfacial and confined water 2␰ ∼ 12 .75 Å 2␰ ∼ 6 .75 Å 2␰ ∼ 3 .75 Å 0.5 0.5 0.5 0.5 0.1 0.1 0.1 0.1 surface layer ( i 5 1) i 5 2 i 5 3 H 5 30 Å H 5 30 Å H 5 24 Å H 5...

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... computer simulations [10, 3 57, 371 , 86 Interfacial and confined water We would expect that the amplitude B 1 of the leading singular term in equation (13) should not depend on the water surface interaction ... 50.150 ± 0.0 07 25 −1.93 522.5 ± 50. 37 ± 0.01 25 −3.08 502.5 ± 50.63 ± 0.02 25 −3.85 502 ± 50 .70 ± 0.01 25 −4.62 502.5 ± 50 .70 ± 0.01 20 −0.39 540.0 ± 50.156 ± 0.0 07 20 −...

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... Water layers at hydrophilic surfaces 125 10 3 10 2 10 1 10 0 10 21 10 22 10 23 10 24 10 25 10 26 10 27 10 27 10 28 110 S C 5 0.0 47 C 5 0. 074 C 5 0. 078 C 5 0.082 n S 100 1000 Figure ... surface, water molecules show orientational This page intentionally left blank 136 Interfacial and confined water P (H max ) P (H max ) N 5 450 N 5 400 N 5 350 0.25 0.50 0 .75 0.25 0.50 0 .75...

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... solvents, the critical water level is determined by the miscibility of water and solvent and by the difference in the water protein and solvent–protein interac- tions. Clearly, less water amount is necessary ... possible. 178 Interfacial and confined water surface, assuming that about 74 % of lysozyme surface, which consist of polar and charged residues, is hydrophilic [4...

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... mol- ecular complexes of pyridines with water and demixing phenom- ena in aqueous solutions, J. Chem. Phys. 106 (19 97) 77 56 77 65. 236 Interfacial and confined water and charge transfer along biosurfaces. ... normal (fragile) water, the pressure-induced denaturation transition of hydrated proteins (see [665–6 67] and Section 6) may be related to 226 Interfacial and confine...

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... 2893–2899. [2 37] K. Lum, D. Chandler, J. D. Weeks, Hydrophobicity at small and large length scales, J. Phys. Chem. B 103 (1999) 4 570 –4 577 . [238] D. M. Huang, D. Chandler, Cavity formation and the drying transition ... solid-liquid interface, Europhys. Lett. 50 (2000) 4 87 493. 256 References experimental and simulation study, J. Chem. Phys. 1 17 (2002) 77 19 77 31. [1 97] M. Drir...

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... hydration events: An IR and gravimetric study, Biopolymers 18 (1 979 ) 11 87 1203. [635] S. Bone, R. Pethig, Dielectric studies of the binding of water to lysozyme, J. Mol. Biol. 1 57 (1982) 571 – 575 . [636] S. ... in DNA: Ruled by water of hydration? J. Chem. Phys. 110 (1999) 70 53– 70 57. [5 27] H. Grimm, A. Sokolov, A. Dianoux, Relaxational dynamics in dry and humid DNA, Appl....

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