INTERFACIAL AND CONFINED WATER Part 6 pdf
INTERFACIAL AND CONFINED WATER Part 6 pdf
... t = 1. 46
for Himantormia lugubris and h
c
= 0.09 26 g/g, t = 1.18 for Cladonia
160 Interfacial and confined water
molecules when hydration level achieves 0.1 to 0.2 g/g [511]. Neu-
tron and light ... percolation threshold of
water was reported at h = 0.04 56 g/g [593] and at h = 0. 06 g/g [594].
158 Interfacial and confined water
direct correlation between the hydratio...
INTERFACIAL AND CONFINED WATER Part 1 doc
... τ
for real water [3] (thick solid line), TIP4P water model [28], and for LJ fluids
[29]. Scaling equation (1) with β = 0.3 26 [12] is shown by straight dashed lines.
6 Interfacial and confined water
change ... bulk water 11
immiscibility gap [63 , 65 ]. This gap diminishes in a continuous way
by substitution of heavy water by normal water, and at about 83%
weight fraction...
INTERFACIAL AND CONFINED WATER Part 2 docx
... kcal/mol [ 162 ]) was reported for NaF surface, whereas it is notice-
ably higher for NaCl surface (14.0 kcal/mol [ 166 ] to 15.5 kcal/mol
[ 165 ]), for Ca
2
F surface (about 13.5 kcal/mol [ 163 , 167 ]), and ... 25
˚
AatT = 200 K (left) and at
T = 375 K (right).
46 Interfacial and confined water
(g/cm
3
)
400
350
300
0.0 0.2 0.4 0 .6 0.8 1.0
T
w
T (K)
Figure 25: Coexistence cur...
INTERFACIAL AND CONFINED WATER Part 3 docx
... pores
76 Interfacial and confined water
20
0.10
0.088
0.090
0.092
0.0 96
0.098
0.100
0.102
0.104
0.1 06
0.12
0.14
0. 16
0.18
T 5 1. 16
T 5 1.10
T 5 1.09
T 5 1.08
T 5 1.13
468 1012
20 468 10
12
14 16 18
Dz ... ξ
0
= 1 .60
˚
A and a
ξ
= 0.97 is shown by solid lines
in both panels (data from [ 262 ]).
58 Interfacial and confined water
in cylindrical pores with R
p
= 25, 30,...
INTERFACIAL AND CONFINED WATER Part 4 docx
... coexistence curve and
temperature dependence of the order parameter could be studied also for
fluid confined in cylindrical pore.
1 06 Interfacial and confined water
0.5
4 6 8 101214 161 8202224 26
1.0
T
c
pore
/T
c
T
c
R(Å)
Figure ... about 0.85T
c
,0.71T
c
,
and 0 .65 T
c
for water in the pores of the width H
p
= 16, 10, and 8
˚
A,
respectively. For cylindrical pores of the r...
INTERFACIAL AND CONFINED WATER Part 5 potx
... = 15
˚
A and U
0
= −4 .62 kcal/mol:
α is the angle between the dipole moment and the pore radius; β is the angle
between the OH vectors and the pore radius.
122 Interfacial and confined water
systems ... 67 ). So, the left and middle
pictures in Fig. 66 show arrangement of water molecules below the perco-
lation threshold, whereas a spanning water network is present in the...
INTERFACIAL AND CONFINED WATER Part 7 pptx
... hydration water were studied in most details (see
Section 6, 7.1 and [473, 508–510, 512–515, 544, 585, 590–592, 60 1,
63 2 63 4, 63 6 63 9]). At low hydrations and up to h ≈ 0.07 g/g (gram
of water per ... surface water interaction, and it was seen in some experiments and
simulations [64 0, 64 1, 64 3, 64 4].
The double-logarithmic plot of the time dependences of the total...
INTERFACIAL AND CONFINED WATER Part 8 ppsx
... from
the normal (fragile) water, the pressure-induced denaturation transition
of hydrated proteins (see [66 5 66 7] and Section 6) may be related to
2 26 Interfacial and confined water
300
7.0
7.5
ELP
350 ... Hoeve and Flory that the elasticity of elastin is rub-
ber like [66 2, 66 3]. Irregular (or even random) location of the ordered
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218 Inte...
INTERFACIAL AND CONFINED WATER Part 9 pps
... heterogeneous
character of water s amorphous polymorphism, J. Appl. Crystal-
logr. 40 (2007) S517–S521.
[ 96] H. Tanaka, General view of a liquid-liquid phase transition, Phys.
Rev. E 62 (2000) 69 68 69 76.
[97] V. ... crossover model and physical limit
of stability in supercooled water, J. Chem. Phys. 1 16 (2002)
565 7– 566 5.
[99] D. A. Fuentevilla, M. A. Anisimov, Scaled equation...
INTERFACIAL AND CONFINED WATER Part 10 doc
... layering transition, 24–5, 28–9,
34–42, 61 , 66 , 122, 137, 165
of liquid–liquid transition, 230
of prewetting transition, 21, 45 6,
61 , 64 6
Crossover, 68 , 75, 102–3, 169
3D–2D critical behavior, 93, ... (1997)
962 6– 963 0.
[63 0] A. Oleinikova, N. Smolin, I. Brovchenko, Influence of water clus-
tering on the dynamics of hydration water at the surface of a
lysozyme, Biophys....