INTERFACIAL AND CONFINED WATER Part 6 pdf

... t = 1. 46 for Himantormia lugubris and h c = 0.09 26 g/g, t = 1.18 for Cladonia 160 Interfacial and confined water molecules when hydration level achieves 0.1 to 0.2 g/g [511]. Neu- tron and light ... percolation threshold of water was reported at h = 0.04 56 g/g [593] and at h = 0. 06 g/g [594]. 158 Interfacial and confined water direct correlation between the hydratio...

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... τ for real water [3] (thick solid line), TIP4P water model [28], and for LJ fluids [29]. Scaling equation (1) with β = 0.3 26 [12] is shown by straight dashed lines. 6 Interfacial and confined water change ... bulk water 11 immiscibility gap [63 , 65 ]. This gap diminishes in a continuous way by substitution of heavy water by normal water, and at about 83% weight fraction...

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... kcal/mol [ 162 ]) was reported for NaF surface, whereas it is notice- ably higher for NaCl surface (14.0 kcal/mol [ 166 ] to 15.5 kcal/mol [ 165 ]), for Ca 2 F surface (about 13.5 kcal/mol [ 163 , 167 ]), and ... 25 ˚ AatT = 200 K (left) and at T = 375 K (right). 46 Interfacial and confined water ␳ (g/cm 3 ) 400 350 300 0.0 0.2 0.4 0 .6 0.8 1.0 T w T (K) Figure 25: Coexistence cur...

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... pores 76 Interfacial and confined water 20 0.10 0.088 0.090 0.092 0.0 96 0.098 0.100 0.102 0.104 0.1 06 0.12 0.14 0. 16 0.18 T 5 1. 16 T 5 1.10 T 5 1.09 T 5 1.08 T 5 1.13 468 1012 20 468 10 12 14 16 18 Dz ... ξ 0 = 1 .60 ˚ A and a ξ = 0.97 is shown by solid lines in both panels (data from [ 262 ]). 58 Interfacial and confined water in cylindrical pores with R p = 25, 30,...

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... coexistence curve and temperature dependence of the order parameter could be studied also for fluid confined in cylindrical pore. 1 06 Interfacial and confined water 0.5 4 6 8 101214 161 8202224 26 1.0 T c pore /T c T c R(Å) Figure ... about 0.85T c ,0.71T c , and 0 .65 T c for water in the pores of the width H p = 16, 10, and 8 ˚ A, respectively. For cylindrical pores of the r...

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... = 15 ˚ A and U 0 = −4 .62 kcal/mol: α is the angle between the dipole moment and the pore radius; β is the angle between the OH vectors and the pore radius. 122 Interfacial and confined water systems ... 67 ). So, the left and middle pictures in Fig. 66 show arrangement of water molecules below the perco- lation threshold, whereas a spanning water network is present in the...

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... hydration water were studied in most details (see Section 6, 7.1 and [473, 508–510, 512–515, 544, 585, 590–592, 60 1, 63 2 63 4, 63 6 63 9]). At low hydrations and up to h ≈ 0.07 g/g (gram of water per ... surface water interaction, and it was seen in some experiments and simulations [64 0, 64 1, 64 3, 64 4]. The double-logarithmic plot of the time dependences of the total...

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... from the normal (fragile) water, the pressure-induced denaturation transition of hydrated proteins (see [66 5 66 7] and Section 6) may be related to 2 26 Interfacial and confined water 300 7.0 7.5 ELP 350 ... Hoeve and Flory that the elasticity of elastin is rub- ber like [66 2, 66 3]. Irregular (or even random) location of the ordered This page intentionally left blank 218 Inte...

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... heterogeneous character of water s amorphous polymorphism, J. Appl. Crystal- logr. 40 (2007) S517–S521. [ 96] H. Tanaka, General view of a liquid-liquid phase transition, Phys. Rev. E 62 (2000) 69 68 69 76. [97] V. ... crossover model and physical limit of stability in supercooled water, J. Chem. Phys. 1 16 (2002) 565 7– 566 5. [99] D. A. Fuentevilla, M. A. Anisimov, Scaled equation...

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... layering transition, 24–5, 28–9, 34–42, 61 , 66 , 122, 137, 165 of liquid–liquid transition, 230 of prewetting transition, 21, 45 6, 61 , 64 6 Crossover, 68 , 75, 102–3, 169 3D–2D critical behavior, 93, ... (1997) 962 6– 963 0. [63 0] A. Oleinikova, N. Smolin, I. Brovchenko, Influence of water clus- tering on the dynamics of hydration water at the surface of a lysozyme, Biophys....

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