... acrylates are often incompatible [107] A typical recipe for the preparation of a suspension copolymerization of ethyl acrylate and MMA and of an acrylic solution terpolymerization of 2-ethylhexyl ... shown that the rate of polymerization increased with an increase of ionic radius of the metals (Sm > Y > Yb > Lu) and decreased with an increase of steric bulk of the auxiliary ligands (C5H5 > C5Me5) ... Indeed, synthesis of random copolymers of styrene and low amounts of n-butyl acrylate provided high yields and narrow molecular mass distributions, but increasing the level of acrylate resulted...
Ngày tải lên: 13/08/2014, 16:21
Tài liệu Báo cáo khoa học: Exposure of IgG to an acidic environment results in molecular modifications and in enhanced protective activity in sepsis doc
... Reactivity of native (lines and 4), pH buffer-exposed (lines and 5) and pH 2.8 buffer-exposed (lines and 6) IVIg with Bacillus anthracis antigens The membranes were incubated with two concentrations of ... reactivity of IgG, we used real-time kinetic measurements of the interaction of IVIg with C-reactive protein (CRP) The binding profiles obtained after single injections of native and of low-pH ... prevents brisk changes in the levels of components of inflammation, coagulation, and other pathways [21] The administration of a single dose of 500 mgÆkg)1 of the modified IVIg had significant (P...
Ngày tải lên: 16/02/2014, 15:20
Báo cáo khoa học: The 2-oxoacid dehydrogenase multi-enzyme complex of the archaeon Thermoplasma acidophilum ) recombinant expression, assembly and characterization docx
... However, detection of E3 and lipoic acid in various archaea [10–12] led to the discovery of a putative OADHC operon in Haloferax volcanii [13] and our subsequent detection of similar putative ... 2-oxoacids and 2-Oxoacid dehydrogenase complex from the Archaea pyruvate [14] In the current paper, we report the cloning and expression of the E2 and E3 genes of the same operon from T acidophilum, and ... target lysine of which is flanked by D and V residues, as it is in the E2 protein of the E coli OGDHC and of the Bacillus subtilis BCOADHC (Fig 1) However, in addition to the identity of the neighbouring...
Ngày tải lên: 16/03/2014, 05:20
Báo cáo khoa học: Transport of taurocholate by mutants of negatively charged amino acids, cysteines, and threonines of the rat liver sodium-dependent taurocholate cotransporting polypeptide Ntcp docx
... properties of these cysteines tested by deletion mutants and lipophilic binding properties other than by SH-groups tested by tryptophane The deletion mutants of the cysteines from loops III and ... company Alignments An alignment of nine members of the SBAT-family, five basolateral (Ntcp rat [1], Ntcp mouse1 and [9], Ntcp rabbit [24], and NTCP human [2]) and four apical (Isbt rat [6], Isbt ... wild-type and mutant Ntcp-protein, both elongated by the FLAGÒ sequence After days of expression, the vitelline membrane was removed by hand and the oocytes were fixed in a solution of 80% methanol/20%...
Ngày tải lên: 17/03/2014, 09:20
Báo cáo Y học: Amino acids 3–13 and amino acids in and flanking the 23FxxLF27 motif modulate the interaction between the N-terminal and ligand-binding domain of the androgen receptor pdf
... function of AR NTD and thus does not allow discrimination between loss of AR.NTD-AR.LBD binding and loss of AR.NTD transactivating function In the yeast assay, loss of transactivation function of AR ... the ratio of activities determined in the presence and absence of R1881 (C) Western analysis of indicated GalAD-AR.NTD proteins in the yeast protein interaction system (left panel) and of indicated ... results are presented in Fig In the absence of ligand, none of the AR NTD proteins showed LBD interaction However, in the presence of ligand, both AR.NTDwt and AR.NTDD3– 13 bound to AR LBD with similar...
Ngày tải lên: 17/03/2014, 10:20
Báo cáo khoa học: Characterization of surface n -alkanes and fatty acids of the epiphytic lichen Xanthoria parietina, its photobiont a green alga Trebouxia sp., and its mycobiont, from the Jerusalem hills pot
... 2003 Alkanes and fatty acids of Xanthoria and symbionts (Eur J Biochem 270) 2123 Fig Gas chromatographic separation on serially capillary coupled columns of n-alkanes and methyl esters of fatty acids ... medicines, and is used in many Asian countries [40] It has also been found as a major effluent component in the paper and pulp industry [41] and is one of the toxic compounds accumulated in fish and other ... analysis of the hydrocarbons and fatty acids of X parietina, its photobiont and mycobiont collected from four different locations indicated the presence of 27 n-alkanes and six major fatty acids...
Ngày tải lên: 23/03/2014, 17:21
Báo cáo lâm nghiệp: "ree nutrition of Norway spruce as modified by liming and experimental acidification at the Höglwald site, Germany, from 1982 to 2004" pdf
... irrigation The area of each experimental treatment is 2500 m2 , separated into centre (9001000 m2 ) and periphery A plan of the Hửglwald experiments is given in Kreutzer and Weiss [26] The stands were ... deionised and adjusted to rain water conductivity (1020 àS cm1 ) through the addition of Ca(NO3 )2 and MgSO4 For acid irrigation, a pH of approx 2.6 was obtained through the addition of H2 SO4 ... Eect of acidication and liming on tree nutrition 865 Figure Mean K concentrations of current (C), and current + two year needles (C+2) at the dierent treatments Error bars representing the standard...
Ngày tải lên: 07/08/2014, 16:20
báo cáo khoa học: " Proteome analysis of Norway maple (Acer platanoides L.) seeds dormancy breaking and germination: influence of abscisic and gibberellic acids" ppsx
... Proteomic analysis of the seeds of another woody plant, Prunus campanulata, provide evidence of the involvement of prunin and dehydrin in the response to warm and cold conditions of stratification, ... maintenance methylation and affecting expression of thousands of genes The hog1 mutant plants grow slowly and have low fertility and reduced seed germination Complementation of the hog1 mutation ... seeds Taken together, the expression of alpha- and beta-tubulins is the important determinant of completion of dormancy breaking and initiation of germination and growth Conclusion Temperate Norway...
Ngày tải lên: 12/08/2014, 03:20
THE EFFECT OF OMEGA-3 FATTY ACIDS ON AIRWAY INFLAMMATION, HYPERPNEA-INDUCED BRONCHOCONSTRICTION, AND AIRWAY SMOOTH MUSCLE CONTRACTILITY IN ASTHMA
... Americans reported having asthma with 60% of those 5-17 years of age missing at least one day of school and 34% of those over 18 years of age missing at least one day of work due to asthma symptoms; this ... the product of the cooperation of multiple Indiana University departments and campuses The author would like to thank the Medical Scientist Training Program and Department of Cellular and Integrative ... other types of drugs are often prescribed as well (43) Corticosteroids reduce inflammation over time by inhibiting the production of proinflammatory prostaglandins, leukotrienes, and cytokines...
Ngày tải lên: 24/08/2014, 12:48
báo cáo khoa học: " Ascorbate metabolism and the developmental demand for tartaric and oxalic acids in ripening grape berries" pot
... contribution of the reduced form of Asc to the tAsc pool of berries at the latter stages of ripening could be the result of an increased rate of Asc recycling via the activity of MDAR and DHAR and/ or ... fruit and vegetative tissue can use D-mannose and Lgalactose for the synthesis of Asc and for further metabolism to TA and OA A quantitative analysis of the developmental fluctuations of Asc and ... transgenic maize and tobacco [75] Surprisingly, there have been no studies on the influence of genetic manipulation of MDAR despite molecular cloning of plant isoforms [76-79] and purification of a chloroplastic...
Ngày tải lên: 12/08/2014, 03:21
Prediction of service life due to the exposure of chlorides of reinforced concrete bridges near coastal areas in Vietnam = Dự báo tuổi thọ sử dụng của cầu bê tông cốt thép ven biển Việt Nam do xâm nhập clo (tóm tắt + toàn văn)
... Protection of cation 4.2 Examples for a bridge 4.2.1 Parameters needed for predicting of the service life of the bridge 4.2.1.1 Parameters of structure and material Table 4.2 Parameters of structure and ... Magazine of Transport and Communications, issue 41- 3/2013; 7/ Dinh, D.V and Trung, D.V., “Determination and prediction of diffusion coefficients of chloride into concrete”, Vietnam Road and Bridge ... technology and alkalinity recovery area around concrete" of the transport institute of science and technology in 2007 [20] Their purpose is to reduce the concentration of chloride ion in concrete and...
Ngày tải lên: 26/09/2014, 09:43
Potential Climate Change Impacts on Corals and Coral Reefs in Melanesia from Bleaching Events and Ocean Acidification
... second and third decade and by 2040-49 marginal (Ω=3.0–3.5) conditions are shown for most of New Guinea and adequate saturation for the rest of Melanesia By 2060-69 and a projected pCO2 of 517 ... that erosion of reefs from the combined impacts of coral beaching and acidification would decrease availability of habitat and shelter, leading to decreases in populations of fishes and cryptic ... Melanesia and the Indo-Pacific, and the inclusion of the Raja Ampat Islands of west New Guinea in the “coral triangle” of maximum species diversity for the world (Fenner 2007), the addition of a New...
Ngày tải lên: 08/06/2016, 11:26
Biodegradable Polymers Composed of Naturally Occurring α-Amino Acids
... of diketopiperazines and other cyclic and linear unidentified products This leads to imbalance of stoichiometry and contributes to the limitation of chain growth In spite of this, Huang’s study ... study initiated a rational synthesis of a large variety of key monomers – TAADs – and showed the suitability of the incorporation of enzyme-specific α-AAs and ester bonds into macro-chains for ... synthesis of PEAs and PEURs above where the synthesis of highmolecular-weight polymers on the basis of short-chain DDCs or BCFs is problematic This is because in the synthesis of PEAs and PEURs,...
Ngày tải lên: 25/10/2013, 08:20
Tài liệu Báo cáo khoa học: Suppressed catalytic efficiency of plasmin in the presence of long-chain fatty acids Identification of kinetic parameters from continuous enzymatic assay with Monte Carlo simulation ppt
... parameters of plasmin in the presence of fatty acids The values of kp and Km were determined from the amidolytic assay of plasmin activity, according to Model I, in the presence of oleate (OA) and arachidonate ... Evaluation of kinetic parameters Fig Comparison of three models for the catalytic action of plasmin in the presence of stearate The p-nitroaniline (P) released in the course of hydrolysis of 40 lM ... mean (symbols) and standard deviation (cross-lines) of four measurements Lines represent best global fit of the data set to the equation of Model I described in the Materials and methods The...
Ngày tải lên: 18/02/2014, 17:20
Báo cáo khoa học: Covalent activation of heart AMP-activated protein kinase in response to physiological concentrations of long-chain fatty acids docx
... ratio of 2.7 : and observed rates of fatty acid utilization of between 63 and 59 lmolÆh)1 per g dry weight through an initial ÔpulseÕ and subsequent ÔchaseÕ period The extent of activation of the ... activation of AMPK making an involvement of sphingolipid signalling unlikely Phosphorylation of Thr172 within AMPK a-subunits was a significant feature of the activation of AMPK by fatty acids and one ... blocked the activation of AMPK by palmitate is of note and requires further investigation of the adrenergic signalling mechanism that is involved Although effects of epinephrine and palmitate to decrease...
Ngày tải lên: 07/03/2014, 15:20
Báo cáo khoa học: Hidden stereospecificity in the biosynthesis of divinyl ether fatty acids ppt
... and trimethylsilylated), and m ⁄ z 308 and 309 (methyl esters of divinyl ether fatty acids) Acknowledgements Mrs Gunvor Hamberg is thanked for expert technical assistance and for collection and ... removal of the pro-S hydrogen and retention of the pro-R hydrogen (Table 1, Fig 2) Discussion Since the pioneering work by Schroepfer and Bloch on the stereochemistry of the desaturation of stearate ... the stereochemistry and mechanism of the cyclooxygenase reaction leading to prostaglandins [16], and the use of this knowledge for establishing the productive conformation of the arachidonic acid...
Ngày tải lên: 16/03/2014, 18:20
báo cáo hóa học:" Minireview: Transaminases for the synthesis of enantiopure beta-amino acids" doc
... the same folding type Representatives of class I and II are aspartate TAs and aromatic TAs, of class III ω-TAs and of class V phosphoserine TAs D-alanine TAs and branched chain amino acid TAs are ... resolutions and asymmetric syntheses, e.g the usage of different (co-)solvents and variation of pH and PLP concentration as well as different strategies of product removal (Koszelewski et al 2008) Of ... though several chemical and enzymatic routes (and chemoenzymatic tandems) are applied and under intense investigation, there still is no gold standard for the preparation of enantiopure β-amino...
Ngày tải lên: 21/06/2014, 17:20
Báo cáo y học: " Potential therapeutic effects of branched-chain amino acids supplementation on resistance exercise-based muscle damage in humans" pps
... sarcolemma and Z disks resulting in increased serum levels of CK Of note, the time-release and clearance of CK depends mainly on the type of exercise and its variables (volume, intensity, and duration) ... Laboratory of Applied Nutrition and Metabolism, School of Physical Education and Sports, University of São Paulo, São Paulo, SP, Brazil; Institute of Biomedical Science, University of São Paulo, ... BCAA (1.8 g of leucine, 0.75 g of isoleucine, and 0.75 g of valine) during weeks before and week during a high-intensity total-body RE (3 sets of repetitions maximum, exercises) and observed...
Ngày tải lên: 11/08/2014, 23:21
Báo cáo y học: "Should dialysis be offered in all cases of metformin-associated lactic acidosis" pot
... Vol 13 No Finkle accounted for 0.84% of all admissions and demonstrated a 30% mortality rate Eighty percent of these patients developed acute renal failure and 62.5% required hemodialysis Only ... is not thought to be the primary cause of the acidosis Restoration of hemodynamic stability rather than dialysis is the goal of therapy in these cases Most of the patients who died in this study ... use of oral antidiabetic drugs in the United States, 1990-2001 Diabetes Care 2003, 26:1852-1855 Garber MD: Metformin: mechanisms of antihyperglycemic action, other pharmacodynamic properties, and...
Ngày tải lên: 13/08/2014, 11:23