carbon carbon σ bond length in 1 3 butadiene
Guanidine and guanidinium salt catalyzed enantioselective phosphorus carbon bond formation reactions 1
... Catal 2007, 34 9, 10 52 10 56 31 Terada, M.; Ikehara, T.; Ube, H., J Am Chem Soc 2007, 12 9, 14 112 14 1 13 32 (a) Merino, P.; Marqués-López, E.; Herrera, R P., Adv Synth Catal 2008, 35 0, 11 95 12 08 (b) ... 90 R /S 3 :1 86 :1 5 :1 55 :1 12 :1 54 :1 Scheme 1. 11 Ebetino’s asymmetric Michael addition of phosphinic and aminophosphinic acid An asymmetric Michael addition of phosphinic and aminophosphinic acid ... Adv Synth Catal 2004, 34 6, 10 35 10 50 Hiratake, J.; Oda, J., Biosci Biotech Biochem 19 97, 61, 211 – 218 Pietrusiewicz, K M.; Zablocka, M., Chem Rev 19 94, 94, 13 75 14 11 (a) Semenzin, D.; Etemad-Moghadam,...
Ngày tải lên: 14/09/2015, 08:38
3 carbon isotope discrimination in roots and shoots of major weed species of southern u s rice fields and its potential use for analysis of rice–weed root interactions
... 2 13 .8 a 2 13 .8 0.05 2 13 .1 a 20. 23 ab 2 13 .0 a 212 .9 a 212 .4 20. 51 215 .8 c 216 .8 b 216 .7 0.94 215 .8 c 0.58 a 214 .7 b 215 .0 ab 214 .9 0. 23 2 13 .8 ab 215 .1 ab 215 .0 1. 23* 215 .0 bc 1. 56* a 2 13 .0 a 215 .0 ... - 214 .7 c 217 .2 d 217 .1 d 2.45* a 2 13 .9 bc 215 .2 cd 215 .1 cd 1. 19* a 212 .4 a 2 13 .5 bc 2 13 .5 bc 1. 08* ab 212 .9 ab 214 .2 bc 214 .2 bc 1. 30 * ab 212 .5 a 2 13 .9 bc 2 13 .8 bc 1. 29* ab 212 .5 a 211 .9 ab 211 .9 ... ab 214 .9 1. 90* 2 13 .4 a 2 13 .7 a 2 13 .6 0. 21 2 13 .8 ab 0.55 a 2 13 .2 a 214 .3 ab 214 .0 0.89 230 .9 e 228.6 c 228.8 22 .12 * 228 .1 d 21. 76* b 228.8 d 226.9 c 227.4 21. 40* 23. 02* 229.0 d 21. 71* b 232 .1 f...
Ngày tải lên: 04/09/2015, 07:24
Guanidine and guanidinium salt catalyzed enantioselective phosphorus carbon bond formation reactions 3
... [3, 5-MeOC6H4CH2] 18 1c 58 32 ; 20 13 6d [3- NO2C6H4CH2] 18 1d 58 36 ; 14 13 6e [Et] 18 1e 45 38 ; 18 a 13 6a [Bn] 13 6f [i-Bu] 18 1f 48 56; 32 donor : acceptor 1: 1.2 b Isolated c Determined by HPLC The phosphinates 13 6 ... + 10 mol% 16 8.HBAr F4 NHTs syn -18 1 13 6 [R] OR O P Ph o C, DCM Ph Ph 13 6a entrya Ph O P OBn 18 1 Ph NHTs anti -18 1 yield/%b ee/%c 74 Chapter 18 1a 56 30 ; 25 13 6b [2-NpCH2] 18 1b 37 35 ; 15 13 6c [3, 5-MeOC6H4CH2] ... i -18 0a entry solvent donor : acceptor time/ha THF 1: 1.2 24 40 65 1: 1 DCM 1: 1.2 60 65 50 1: 1 Toluene 1: 2 20 44 73 1: 1 Toluene 2 :1 20 70 37 3 :1 5d CHCl3 2 :1 96 n.d n.d n.d 2 :1 20 82 25 3 :1 3: 1...
Ngày tải lên: 14/09/2015, 08:38
A New Technique Using Headspace Gas Monitoring to Determine Carbon Source Addition in a BNR Process
... Comparison in VFAs Comparison in HAc J0 4 13 -2 -1 185 mg/L 16 9 mg/L 16 6 mg/L +9.5 % +11 .4 % J0 4 13 -2-2 19 9 mg/L 16 9 mg/L 16 6 mg/L +17 .8 % +19 .9 % J0 418 -3 533 mg/L 507 mg/L 4 21 mg/L +5 .1 % +26.6 % J0 515 -1 36 7 ... monitored using this approach and experimental design was able to estimate the initial acetate concentration in the reactor - 63 - 210 200 19 0 18 0 17 0 16 0 15 0 14 0 13 0 12 0 11 0 10 0 J1206-0-pH 7.70 ... Times (minutes) Estimated conc (mg/L as HAc) Analytical conc (mg/L as HAc) Error in % * 8 .3 10 9.9 1. 0 16 .5 20 19 .8 1. 0 14 .1 17 16 .8 1. 2 4.6 4.8 4.2 30 .2 36 35 .8 0.6 *Error estimation in percentage:...
Ngày tải lên: 05/09/2013, 08:40
Occurrence of Polyhydroxyalkanoate as Temporal Carbon Storage Material in Activated Sludge during The Removal of Organic Pollutants
... STEP-AO A2N 55 .3 mgC/L 7 .3 mgC/L 61. 7 mgC/L 11 .4 mgC/L -1. 1 mgC/L 30 .3 mgC/L 21% -15 % 49% CD MUCT 36 .6 mgC/L 13 0.5 mgO/L 7.6 mgC/L 200.2 mgO/L 21% 15 3% SBR -1 SBR-2 32 .9 mgO/L 32 .7 mgO/L 21. 4 mgO/L ... acetate 17 14 15 0.04 0.04 Continuous Carrousel Ditch Continuous University of Cape Town CD MUCT Sewage Sewage 20 28 15 18 0.02 0.04a) Sequencing Anaerobic-oxic SBR -1 Sewage 7.5 12 0 .30 a) Sequencing ... Water Res., 32 (11 ), 31 9 3- 3207 Seviour, R.J., Mino, T and Onuki, M (20 03) The Microbiology of Biological Phosphorus Removal in Activated Sludge Systems, FEMS Microbiol Rev., 27, 99 -12 7 Takabatake,...
Ngày tải lên: 05/09/2013, 09:38
Carbon emission patterns in different income countries
... -0.0500 31 9 0. 016 6047 -3. 01 0.005 -0.084045 -0. 016 018 7 GDP per capita 0. 015 36 43 0.00688 73 2. 23 0. 034 0.0 012 5 63 0.0294724 0 .38 22 0.055 73% Intercepts 0.0 217 982 0.00475 83 4.58 0.000 0. 012 0 514 0.0 31 5 4 51 ... 0. 41 00205 43 2 .35 010 635 3 0. 81 P>|t| 0.028 0.599 0.7 61 0. 237 0.687 0. 032 0. 432 95% confidential intervals R-squared -.00288 03 -.00 018 95 -. 015 32 53 0256966 -. 032 6 9 13 0 438 894 0.8250 -.0046 917 017 635 7 ... 0.54 31 0.4589 0.6294 GDP per capita 0. 215 4 0 .33 67 0.9204 0.60 41 0. 31 0 9 0.8 433 0.9 812 0.6698 0. 31 6 3 0.9069 2004 0.9577 0. 914 9 0.4244 0. 435 0.5 017 0 .30 06 0. 31 0 8 0.974 0.5 415 0.28 93 0.9422 0.9 833 ...
Ngày tải lên: 05/09/2013, 16:10
Common erros in English part 1 3
... are less usual spellings) shelf (singular) shelves (plural) See PLURALS (v) sheriff (not -rr-) shining or shinning? shine + ing = shining shin + ing = shinning See ADDING ENDINGS (i) and (ii) shoe ... drive However, in speech, the tone of voice will indicate which is intended shaming or shamming? shame + ing = shaming sham + ing = shamming See ADDING ENDINGS (i) and (ii) 18 3 SHAN'T shan't ... employer for a RAISE An increase in salary is called 'a rise' in the UK and 'a raise' in America raping or rapping? rape + ing = raping rap + ing = rapping See ADDING ENDINGS (i), (ii) rapt or...
Ngày tải lên: 28/10/2013, 07:15
Tài liệu Chapter 6: Carbon-carbon bond formation pptx
... PCT Int Appl WO 97 05 ,15 1, 19 97, to Hoechst A.-G.; C.A 19 97, 12 6, 19 934 8t 31 S Haber, H.-J Kleiner, PCT Int Appl WO 97 05 ,10 4, 19 97, to Hoechst A.-G.; C.A 19 97, 12 6, 19 934 9u 32 N A Bumagin, V ... Chem in the USSR 19 89, 2, 636 ; Metalloorg Khim 19 89, 2, 12 00 33 N A Bumagin, V V Bykov, Tetrahedron 19 97, 42, 14 437 34 N A Bumagin, D A Tsarev, Tetrahedron Lett 19 98, 39 , 815 5 35 N A Bumagin, ... Wiley-VCH, Weinheim, 19 98, p 38 3 10 D Sinou, Top Curr Chem 19 99, 206, 41 11 D Sinou, in Aqueous-Phase Organometallic Catalysis (B Cornils, W A Herrmann, eds.), Wiley-VCH, Weinheim, 19 98, p 4 01 12 N A...
Ngày tải lên: 23/12/2013, 07:19
Tài liệu Báo cáo khoa học: The crystal structure of human a-amino-b-carboxymuconatee-semialdehyde decarboxylase in complex with 1,3-dihydroxyacetonephosphate suggests a regulatory link between NAD synthesis and glycolysis ppt
... Apoptosis induced by niacin-related FEBS Journal 276 (2009) 6 615 –66 23 ª 2009 The Authors Journal compilation ª 2009 FEBS 66 21 Crystal structure of human ACMSD 10 11 12 13 14 15 16 17 18 19 20 S ... B-factor protein (A2) ˚ Mean B-factor solvent (A2) ˚ Mean B-factor DHAP ⁄ Zn (A2) ˚ Mean B-factor glycerol atoms (A2) 2 635 216 10 ⁄ 19 .3 25.6 0. 018 1. 6 15 .3 25.2 39 .3 ⁄ 10 .1 25.6 corresponding solvent ... His 17 4 Asp 2 91 w1 DHAP B Met 19 5 w1 w 268 DHAP Leu 296 w 51 C1 Trp 19 1 Phe 294 centre into a small pocket delimited by residues Asp2 91, Trp1 91, Met195, Arg47 and the Phe294Pro295-Leu296 amino...
Ngày tải lên: 18/02/2014, 06:20
Báo cáo khoa học: Carbohydrate binding sites in Candida albicans exo-b-1,3-glucanase and the role of the Phe-Phe ‘clamp’ at the active site entrance ppt
... 3 211 38 . 23 2.00 (2 .11 –2.00) P 212 1 21 a = 58.57 b = 64. 63 c = 94.48 a = b = c = 90° 0.069 (0. 43) 17 .4 (3. 7) 10 0.0 (10 0.0) 5.4 (5 .3) 25 035 0 .15 4 0.200 0.020 1. 46 0 .11 32 33 334 21 24 30 8 21 22 19 .85 1. 80 ... 19 .85 1. 80 (1. 85 1. 80) P 212 1 21 a = 59.95 b = 65 .32 c = 96.54 a = b = c = 90° 0. 039 (0 .16 ) 14 .2 (4.7) 99 .3 (94 .1) 3. 2 (2.4) 35 5 63 0 . 13 6 0 .16 3 0. 012 1. 25 0.08 3 214 24 289 17 19 24 75 38 .19 1. 70 (1. 79 1. 70) ... F144Y ⁄ F258Y E292Q:L5 F229A ⁄ E292S:L3 32 .65 1. 90 (1. 95 1. 90) P 212 1 21 a = 60 .33 b = 65 .39 c = 96.49 a = b = c = 90° 0.052 (0. 21) 13 .8 (3. 3) 98.9 (95 .3) 3. 3 (2.6) 30 432 0 . 13 5 0 .16 8 0. 014 1. 35 ...
Ngày tải lên: 15/03/2014, 23:20
Báo cáo khoa học: NovelN,N¢-diacyl-1,3-diaminopropyl-2-carbamoyl bivalent cationic lipids for gene delivery – synthesis,in vitro transfection activity, and physicochemical characterization docx
... [NC(O)O], 13 1.4 0 13 0.52 (C=C), 73. 44 (CH), 65 .34 , 59.28, 58.46, 46.96, 46.77, 40.58, 37 .86, 33 .86, 33 .77, 33 .70, 30 .94, 30 .90, 30 .84, 30 .79, 30 . 71, 30 .66, 30 .62, 30 . 53, 30 .50, 30 .40, 30 .38 , 30 .32 , 30 .27, ... 1, 3lb2 D (nm) 200 1, 3lb4 800 1, 3lb5 600 400 200 40 1, 3lb1 20 1, 3lb2 1, 3lb3 20 1, 3lb4 1, 3lb5 40 60 80 +/ 1: 1 +/ 2 :1 +/ 4 :1 liposomes +/ 1: 1 1, 3lb1 200 1, 3lb2 liposomes 60 1, 3lb3 +/ 4 :1 D 80 40 D (nm) ... 55. 61 56.06 3. 22 2.29 3. 41 3. 81 57.92 6. 41 37 .75 41. 62 40.29 48.68 23. 73 39.04 37 C 2. 01 0.94 0.72 6. 71 1.09a 3. 81 Phase stateb dp dAc 36 .59 36 . 31 38 .62 39 .89 23 C 1. 34 1. 37 0.75...
Ngày tải lên: 23/03/2014, 07:20
Báo cáo khoa học: Novel b-1,3-, 1,6-oligoglucan elicitor from Alternaria alternata 102 for defense responses in tobacco docx
... Composition 9.85 10 .49 10 .69 11 . 31 205 ,16 1 ,11 7 233 ,16 1 ,11 7 233 ,16 1 ,18 9 ,11 7 18 9 ,11 7 2 ,3, 4,6 2,4,6 2 ,3, 4 2,4 Terminal-Glc 3- linked-Glc 6-linked-Glc 3, 6-linked-Glc 0.97 1. 94 1. 16 1. 00 FEBS Journal 2 73 (2006) ... (min) 25 10 15 20 Time (min) 25 W a te TBC -1 1000 Co ntr o l 2799 [GDP =17 +Na]+ 2474 [GDP =15 +Na]+ B 2 636 [GDP =16 +Na]+ 19 87 [GDP =12 +Na]+ 18 25 [GDP =11 +Na]+ 15 00 [GDP=9+Na]+ 20 214 9 [GDP = 13 +Na]+ 2 31 2 ... [11 13 ] A b -1, 6 b -1, 3 glucan (b -1, 3 backbone with a b -1, 6 side chain) isolate from Pyricularia oryzae induces phytoalexin production in rice but not in soybean [12 ] Linear glucans are active in tobacco...
Ngày tải lên: 23/03/2014, 11:20
A Comparative Analysis of Carbon Dioxide Emissions in Coated Paper Production Key Differences between China and the U.S. pot
... 4, 937 6, 034 6,258 6,406 9% 80.4% Sulfite Pulp 54 50 67 41 51 -1% 0.6% Chemi-Mechanical Pulp 35 7 644 7 51 868 967 28% 12 .1% Recovered Material Pulp 32 45 10 2 72 77 24% 1. 0% Total 5,265 6, 034 7, 31 9 ... types) in China 12 Table 1. 2 China’s Pulp Imports, 2002-2006 (kilotons per year) 13 Table 1. 3 Brazil's Pulp and Paper Investment Program, 2002-2 012 16 Table 2 .1 Partial ... Production Pulp Exports Paper Exports 2 012 % Increase 1. 4 million 2.6 million +86% 8.0 Mt 14 .5 Mt + 81% 7.7 Mt 3. 5 Mt 1. 4 Mt 13 .4 Mt 7.4 Mt 2.0 Mt +74% +11 1% + 43% Source: Brazilian Pulp and Paper...
Ngày tải lên: 24/03/2014, 05:20
Phòng tắm "3 in 1" giá 1,8 tỷ đồng cho giới thượng lưu pot
... khay tắm bồn hoàn toàn đá khối tự nhiên có giá lên tới 10 0 triệu đồng Phòng xông Logical Twin "3 in 1" Effegibi (Italy) có giá bán khoảng 1, 8 tỷ đồng, với chức xông khô, xông ướt tắm tráng Sản ... thống thoát sàn nhập từ hãng Unidrain (Đan Mạch) có chiều dài từ 30 cm đến 2m, thiết kế độc đáo, đảm bảo tính thẩm mỹ cao Mẫu thoát nước cho sản nhà tắm Unidrain HighLine dùng đá, gạch ốp trực tiếp ... thủ công 10 0% Sen vòi rồng mạ vàng có giá trăm triệu đồng Theo EuroStyle, vật liệu mẫu mã định giá thành Trong sản phẩm phổ thông công ty có giá từ vài triệu đồng thiết kế cầu kỳ, tinh xảo vòi...
Ngày tải lên: 25/03/2014, 13:20
Báo cáo khoa học: Tertiary structure in 7.9 M guanidinium chloride ) the role of Glu53 and Asp287 in Pyrococcus furiosus endo-b-1,3-glucanase pot
... nm for E53A and to 35 6 nm for the double 617 2 K1 (M )1) v2 9.8 2.5 9.6 3. 0 ã ã ã ã 10 )5 10 )4 10 )4 10 )3 3 .3 3.4 1. 1 4.4 ã ã ã ã 10 7 10 5 10 6 10 5 v 2.9 3 .1 1.7 3 .1 ã ã ã ã 10 )4 10 )4 10 )3 10 )4 mutant ... Protein [GdmCl]0.5 DGH2O (M) (kJặmol )1) mg DDGH2O )1 )1 (kJặmol ặM ) (kJặmol )1) Wild-type D287A E53A E53A D287A 6.7 6.2 6.0 6.2 9.2 5.9 5.6 5 .3 0 . 13 0 .15 0 .12 0 .15 61. 5 36 .5 33 .9 33 .1 1. 23 ... mutations in staphylococcal nuclease Biochemistry 32 , 10 1 31 1 0 13 9 Kumar S & Nussinov R (2002) Relationship between ion pair geometries and electrostatic strengths in proteins Biophys J 83, 15 9 516 12 Makhatadze...
Ngày tải lên: 30/03/2014, 04:20
Báo cáo khoa học: The C-terminal region of the proprotein convertase 1⁄ 3 (PC1⁄ 3) exerts a bimodal regulation of the enzyme activity in vitro pdf
... tight-binding inhibitors of murine PC1 ⁄ and Hfurin J Biol Chem 2 73, 31 5 74– 31 5 80 Rabah N, Gauthier D, Wilkes BC, Gauthier DJ & Lazure C (2006) Single amino acid substitution in the PC1 ⁄ propeptide ... insuring cell-surface anchoring [37 ] In other cases, the CT-peptide contains integral transmembrane motifs affecting the sorting and recycling of furin and PC5 ⁄ 6B [38 –40] In the case of PC1 ... purification of recombinant mPC1 ⁄ and hfurin Recombinant murine PC1 ⁄ was produced using the baculovirus expression system in Sf9 insect cells [7] or through intracoelemic injection in insect larvae...
Ngày tải lên: 30/03/2014, 08:20
carbons and carbon supported catalysts in hydroprocessing
... meq/g Init voltage MV 0.44 0.22 0.22 0 .30 0.26 0 .16 0 .16 0 . 13 0 .14 0 .36 0.08 0 .11 0 .10 0 .12 0. 21 0 .14 0 .14 0 . 13 0.50 0.75 0.75 1. 20 1. 20 1. 60 1. 50 1. 60 1. 80 15 15 35 97 53 40 42 –6 16 Ni(NO3)2 ... Reactions 10 5 10 6 10 9 11 1 11 3 11 4 11 5 11 8 12 2 12 3 Catalyst Deactivation 8 .1 8.2 Deactivation Involving Model Feeds Deactivation Involving Real Feeds 12 7 13 1 xi Contents Chapter Chapter 10 Patent ... Total base, mol/g CNT a 18 0 0. 73 11 8.4 Â 10 À6 1. 9 Â 10 À6 1. 2 Â 10 À7 6.4 Â 10 À6 1. 7 Â 10 À5 246 0.76 12 6.4 Â 10 À4 2.4 Â 10 À5 4 .3 Â 10 À6 3. 6 Â 10 À5 a CNT treated with HNO3 Carbon nanotubes are made...
Ngày tải lên: 01/04/2014, 10:26
Báo cáo hóa học: " Glycerol conversion to 1, 3-Propanediol is enhanced by the expression of a heterologous alcohol dehydrogenase gene in Lactobacillus reuteri" ppt
... Express 2 011 , 1: 37 http://www.amb-express.com/content /1/ 1 /37 during glucose/glycerol cofermentation in batch and continuous cultures Biotechnol Lett 20: 9 13 – 916 doi :10 .10 23/ A :10 05 434 31 6 757 Gonzalez-Pajuelo ... glycerol into 1, 3- propanediol Appl Microbiol Biotechnol 87: 217 7– 218 4 doi :10 .10 07/s002 53- 010 -2678-0 doi :10 .11 86/ 219 1-0855 -1- 37 Cite this article as: Vaidyanathan et al.: Glycerol conversion to 1, 3Propanediol ... chemicals using pathway engineering Biochim Biophys Acta 15 43: 434 –55 doi :10 .10 16/S 016 7-4 838 (00)00 234 -X Colin T, Bories A, Moulin G (2000) Inhibition of Clostridium butyricum by 1, 3propanediol...
Ngày tải lên: 20/06/2014, 23:20
Báo cáo khoa học: " Cap-independent protein translation is initially responsible for 4-(N-methylnitrosamino)-1-(3-pyridyl)-butanone (NNK)-induced apoptosis in normal human bronchial pithelial cells" pot
... Chem 19 99, 274, 17 9 41- 17945 31 Stoneley M, Paulin FE, Le Quesne JP, Chappell SA, Willis AE C-myc 5' untranslated region contains an internal ribosome entry segment Oncogene 19 98, 16 , 4 23- 428 32 ... protein translation can be induced under various cellular conditions Several apoptosis-related genes including XIAP [16 ], DAP5 [14 ], cmyc [ 31 ] and Apaf -1, contain IRES [12 ], thus, whose protein ... Sonenberg N, Kasinath BS Insulin regulation of protein translation repressor 4E-BP1, an eIF4E-binding protein, in renal epithelial cells Kidney Int 20 01, 59, 866-875 Brown EJ, Albers MW, Shin TB, Ichikawa...
Ngày tải lên: 07/08/2014, 18:20