... of physicalchemistry Organic andPhysicalChemistry of Polymers by Yves Gnanou and Michel Fontanille provides a unique approach to combine fundamentals of organic andphysicalchemistryand ... ORGANIC ANDPHYSICALCHEMISTRY OF POLYMERS ORGANIC ANDPHYSICALCHEMISTRY OF POLYMERS Yves Gnanou Michel Fontanille A JOHN WILEY & SONS, INC., PUBLICATION ORGANIC ANDPHYSICALCHEMISTRY OF ... Yves Organic andphysicalchemistry of polymers / by Yves Gnanou and Michel Fontanille p cm Includes index ISBN 978-0-471-72543-5 (cloth) Polymers Polymers—Synthesis Chemistry, Physicaland theoretical...
... copolymers is peculiar and deserves a specific development In such a structure, the A and B blocks are connected to one another by a covalent bond, and their respective molar mass andcomposition can ... each one of these units and the surrounding medium (solvent, another repetitive unit, stretched or chains at rest) Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille ... solvent if χ12 values lie between 0.4 and 0.5 and a non-solvent for higher values From the expressions (4.22) and (4.32), the critical temperature of demixing (Tc ) and θ temperature can be correlated...
... and m denote the mass of the amorphous and crystalline phases and the total mass phases, respectively If V c , V , ρc , and ρ are the bulk volumes and the densities of the crystalline phase and ... Bovey and L W Jelinski, Chain Structure and Conformation of Macromolecules, Academic Press, New York, 1982 6 DETERMINATION OF MOLAR MASSES AND STUDY OF CONFORMATIONS AND MORPHOLOGIES BY PHYSICAL ... each of the two Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille Copyright 2008 John Wiley & Sons, Inc 147 148 DETERMINATION OF MOLAR MASSES AND STUDY OF CONFORMATIONS...
... and ln(ηr /c2 ) against concentration with B1 = 2.5 when particles are nonsolvated rigid spheres and B2 = 14.1; in this equation, B1 and B2 can take different values, depending on the shape and ... [η]1 M1 = [η]2 M2 Using the Mark–Houwink–Sakurada expression and since K1 and α1 are known for the standard polymer and K2 and α2 for the polymer analyzed, one can easily deduce M2 with the following ... structure—that is, chemical, optical, thermal, and mechanical properties, and so on If P a , P c , and P are the specific properties of the amorphous, crystalline, and semicrystalline states—the latter...
... Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille Copyright 2008 John Wiley & Sons, Inc 249 250 CHAIN POLYMERIZATIONS This first step called initiation and often ... appearance and disappearance of these radicals are equal and one can write kAB [∼∼A• ][B] = kBA [∼∼B• ][A] Because monomer A is consumed by reactions (8.1) and (8.4) and monomer B by reactions (8.2) and ... significant than those characterizing the enthalpy term, and hence the latter is more prominent The values of H and S found in handbooks (Polymer Handbook , Comprehensive Polymer Science, etc.), were...
... except for a few cases Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille Copyright 2008 John Wiley & Sons, Inc 357 358 REACTIVITY AND CHEMICAL MODIFICATION OF POLYMERS ... Eastmond, A Ledwith, S Russo, and P Sigwalt (Eds.), Comprehensive Polymer Science, Vols and 4: Chain Polymerisation, Pergamon Press, Oxford, 1989 G Moad and D H Solomon, The Chemistry of Free Radical ... and M Van Beylen, Ionic polymerization and Living Polymers, Chapman and Hall, New York, 1993 H L Hsieh and R P Quirk, Anionic Polymerization—Principles and Practical Applications, Marcel Dekker,...
... α- and (α,ω-di) functionalized polymers], including macromonomers • Block and graft copolymers • Polymers with complex topology • Organic andPhysicalChemistry of Polymers, by Yves Gnanou and ... thermomechanical properties and responses, with the semicrystalline state combining the properties of both the amorphous and of crystalline states at the macroscopic level Organic andPhysicalChemistry of ... Design: Concepts and Practice, PFI, New York, 1994 M Lazzari, G Liu, and S Lecommandoux (Ed.), Block Copolymers in Nanoscience, Wiley VCH, Weinheim, 2006 K Matyjaszewski, Y Gnanou, and L Leibler...
... moduli (E, G) and the tensile and shear compliance (D, J ) can be transformed from E = f (t) into E = f (T ) and vice versa, in the limit of small deformations and homogeneous, isotropic, and amorphous ... situations: (a) soft and strong polymer; (b) soft and ductile polymer; (c) rigid and fragile polymer; (d) rigid and ductile polymer A brittle fracture occurs in the elastic range and is associated ... analytical technique Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille Copyright 2008 John Wiley & Sons, Inc 467 468 RHEOLOGY, FORMULATION, AND POLYMER PROCESSING TECHNIQUES...
... Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille Copyright 2008 John Wiley & Sons, Inc 513 514 LINEAR (MONODIMENSIONAL) SYNTHETIC POLYMERS 15.1.1 Polyethylene and ... groups and amide functional groups The alpha-helix corresponds to the structure shown in Figure 14.1, with two possible directions of notation corresponding to right-handed and left-handed helixes ... or acetate) and another acid or an anhydride, generally organic Cellulose acetonitrates, acetopropionates, and acetobutyrates are utilized as films and varnishes POLYSACCHARIDES AND THEIR DERIVATIVES...
... Bhowick and H L., Stephens (Ed.), Handbook of Elastomers, Marcel Dekker, New York, 1988 M Lewin and E Pearce (Ed.), Handbook of Fiber Chemistry, Marcel Dekker, New York, 1998 S Fakirov (Ed.), Handbook ... Gardziella, L A Pilato, and A Knop, Phenolic Resins: Chemistry, Applications, Standardization, Safety and Ecology, Springer, New York, Berlin, 1999 E Occhiello, Polyurethanes: Chemistryand Technology, ... polycondensation of o-phthalic anhydride with glycerol, and the resulting network is represented hereafter Organic andPhysicalChemistry of Polymers, by Yves Gnanou and Michel Fontanille Copyright 2008 John...
... cells and the HBx and HBV core mRNA levels and then the FXRa mRNA levels were determined via RT-PCR The RT-PCR bands were quantified and normalized relative to the b-actin mRNA control band using ... to regulation by bile acids in human hepatoma cells Cholic acid and chenodeoxycholic acid (CDCA) are two major primary bile acids detected in human bile [19– 21] The effects of bile acids on HBV ... Bile acid metabolism and HBV gene expression H Y Kim et al the liver, intestine, kidney and adipose tissue via the regulation of the expression and function of genes involved in bile acid...
... advanced mathematical and statistical methods are steadily becoming more and more pervasive in the chemistry literature Methods of physical chemistry, such as quantum chemistryand spectroscopy, ... courses and as a resource for individual study by students and professionals in all subfields of chemistryand in related fields such as environmental science, geochemistry, chemical engineering, and ... Mathematical Methods for Physicaland Analytical Chemistry David Z Goodson Department of Chemistry & Biochemistry University of Massachusetts Dartmouth WILEY A...
... (PEA) What is polyester amide Applications Advantage of Lipid- based components Previous Examples of Lipid- based PEA Objectives and Results Conclusions Boc H N O O O O H N Boc TFA O H2N O ... Science-Polymer Edition, 2007 18(6): p 673-685 Guo, K and C.C Chu, Journal of Polymer Science Part a-Polymer Chemistry, 2005 43(17): p 3932-3944 Advantage of Lipid- based components Functional groups: ... Hojabri, L., X.H Kong, and S.S Narine, Biomacromolecules, 2009 10(4): p 884-891 Williams, C.K and M.A Hillmyer, Polymer Reviews, 2008 48(1): p 1-10 Previous Examples of Lipid- based PEA PEA derived...
... microdomains in cellular membranes that are enriched in sphingolipids, cholesterol and raft-targeted proteins This particular lipidand protein composition is thought to facilitate protein-protein interactions ... producing cells, the reported modulation of lipid Figure lymphocytes Nef alters the lipidcomposition of DRMs in HIV-1 infected T Nef alters the lipidcomposition of DRMs in HIV-1 infected T lymphocytes ... affects their lipid microenvironment The overlap in changes induced by Nef on the lipidcomposition of bulk host cell microdomains and purified virions implies that the altered particle composition...
... probability of alleles g ih and g ih’ ’ being IBD and being of breed origin A, and Pr( g ih ≡ g ih’ ’ ∈ B) is the probability of alleles g ih and g ih’ ’ being IBD and being of breed origin B ... higher lipid accretion rate at this growth period Suggestive QTL for protein content of the fat-free substance and protein andlipid content of the empty body were identified between SW259 and SW1943 ... chromosome X for traits of carcass characteristics, chemical andphysical body compositionand accretion rates as well as daily gain, feed intake and food conversion ratio considering the specific features...
... Xerox Corp Standardized in 1980 as IEEE 802.3 CSMA/CD algorithm is same for both Ethernet and 802.3 Frame format differs between Ethernet and 802.3 Frame format differs between Ethernet and 802.11 ... the Virtual Carrier-Sensing indicates the medium is idle and the station can transmit q For the station to transmit both the physicaland virtual carrier sense must report an idle condition otherwise ... and (2) the NAV is zero February 2005 Coypright 2005 All Rights Reserved 22 Slot Times The slot time multiplied by the random number to obtain the wait time is dependent upon the particular physical...
... consists of a spool valve and a solenoid coil The spool valve, which acts directly in accordance with electric signals, opens and closes the passage that links the pressure chamber and the pump chamber ... passage between the pressure chamber and pump chamber The pressurized fuel spills into the pump chamber, thus decreasing the pressure in the pressure chamber and ending the pumping of fuel Solenoid ... levels of precision, quick response, and pressure resistance, as well as a large spill volume There are two types of solenoid spill valves: the pilot valve type, and the direct-acting solenoid valve...
... (γ) form of light energy (not particle like α and β) Chemistry, Julia Burdge, 2nd e., McGraw Hill Rutherford’s Experiment ++++++++++++ γ β α Chemistry, Julia Burdge, 2nd e., McGraw Hill ... predict the daughter nuclide if you know parent and emitted particle Tro, Chemistry: A Molecular Approach 12 Alpha Emission • an α particle contains protons and neutrons helium nucleus α He • most ... change in the composition of the nucleus Same atomic number and mass number • least ionizing, but most penetrating • generally occurs after the nucleus undergoes some other type of decay and the...
... (inputs and outputs), including oral, parenteral, urine, and stool volumes Physical exam, including chest and abdomen, with particular attention to active problems Emphasize changes from previous physical ... test results and circle abnormal values Current medications: List all medications and dos ages Assessment and Plan: This section should be organized by problem A separate assessment and plan should ... History, Pertinent Physical Examination, and Laboratory Data: Describe the course of the patient's disease up until the time that the patient came to the hospital, including physical exam and laboratory...