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Development of reduced models for proton exchange membrane fuel cells

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THÔNG TIN TÀI LIỆU

Cấu trúc

  • Preface

  • Acknowledgements

  • Summary

  • List of Tables

  • List of Figures

  • List of Symbols

  • Introduction

    • Advantages and Disadvantages of Fuel Cells

    • Types of Fuel Cells

    • Fuel cell commercialization

    • Objectives

    • Structure of the thesis

  • Proton Exchange Membrane Fuel Cell

    • Flow field

    • Gas diffusion layer

    • Catalyst layer

    • Membrane

    • Cell performance

  • Literature review

    • One-dimensional models

    • Two-dimensional models

      • `Across-the-channel' models

      • `Along-the-channel' models

    • Three-dimensional models

    • Fuel cell stack models

    • Summary

  • Mathematical formulations

    • Governing Equations

      • Single-Phase Model

      • Multi-phase Model

    • Constitutive Relations

    • Agglomerate Model

    • Base-case parameters

  • Geometrical Reduction of Three-Dimensional Flow Channels into Two-Dimensional Porous Counterparts in Fuel Cells

    • Introduction

    • Mathematical formulation

      • 3D model

      • Geometrically reduced 2D Model

    • Numerics

    • Correlation

      • Correlation for transport properties of the flow fields

      • Correlation for parameters of the gas diffusion layers and current collectors

    • Verification

    • Conclusions

  • Scaling Analysis and a Simple Correlation for the Cathode of a PEMFC

    • Introduction

    • Mathematical formulation

      • Governing equations

      • Boundary conditions

    • Scaling analysis

      • Nondimensional form

      • Determination of scales

    • Correlation for cathode performance

    • Results and discussion

      • Cathode performance and validation

      • A correlation for the overall cell performance

    • Conclusions

  • Development of Fast and Efficient Mathematical Models for the Cathode of a PEMFC

    • Introduction

    • Mathematical formulation

      • Governing equations

      • Governing equations for the reduced model

      • Potentiostatic vs. galvanostatic boundary condition

    • Results and discussion

      • Validation

      • Verification

      • Computational cost

    • Conclusions

  • Validated Reduction and Accelerated Numerical Computation of a Model for the PEMFC

    • Introduction

    • Mathematical formulation

    • Analysis

      • Scaling

      • Summary of reduced model equations

    • Numerics

    • Calibration, verification, and validation

    • Computational cost and efficiency

    • Conclusions

  • Asymptotically Reduced Model for a PEMFC Stack: Automated Model Generation and Verification

    • Introduction

    • Mathematical Formulation

      • Full set of governing equations

      • Reduced governing equations

      • Reduced boundary conditions

    • Numerics

    • Automated Model Generation

    • Calibration and Validation

    • Verification without perturbations between cells

    • Verification with perturbations between cells

    • Computational Cost and Efficiency

    • Conclusions

  • Computationally Efficient Multi-Phase Models for a PEMFC: Asymptotic Reduction and Thermal Decoupling

    • Introduction

    • Mathematical formulation

      • Boundary conditions

      • Reduced model

    • Numerics

    • Calibration, verification, and validation

    • Thermal Decoupling

    • Computational cost and efficiency

    • Conclusions

  • Conclusions and Future Work

    • Summary of results

    • Recommendations for future work

  • Bibliography

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