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Automotive and Air pollution Spring Semester 2015-2016 CHAPTER MEASURES FOR EMISSION CONTROL Huynh Thanh Cong Ho Chi Minh City University of Technology Exhaust gas emissions and some control technologies Exhaust Gas Emissions Internal Engine Measuring Exhaust Gas Aftertreatment Introduction Oxidation Catalytic Converter DeNOX Systems Particulate Filter Exhaust Gas Aftertreatment Systems Current Discussion Internal engine measuring External engine measuring Internal Engine Measuring Engine Modifications – CO Formation incomplete combustion (e.g because of local or global shortage on oxygen) Remedy avoidance of rich mixture zones Engine Modifications – HC Formation - unburned or partly burned fuel - thermal cracking products, also from lube oil - quenching-effect Remedy - good mixture formation - no extreme lean combustion operation - no extreme rich combustion operation - short piston land - small surface-to-volume ratio of combustion chamber - reduced sac hole volume of nozzle Engine Modifications – NOx Formation - secondary product of combustion: - high temperatures - oxygen available - long dwell time - NOmax at λ 1,1 (local) - NOX IDI < NOX DI Remedy - low temperature (local) - short dwell time - late injection - water injection - EGR Scheme of External Exhaust Gas Recirculation (EGR) EGR Control Valve EGR cooler Exhaust gas Air Main cooler EGR-valve EGR rate &R &R m m x EGR = I = A & & +m &R m m m& m& m& A R I Temperature sensor Trottle flap Main cooler flap [ kg / h ] fresh-air-flow [ kg / h ] EGR flow [ kg / h ] gas flow through the intake-valves (inlet flow) Micro-catalyst Pre-cooler flap Pre-cooler Source: 17 Aachener Kolloquium 2008, Dr M Gruber, Audi AG Influence of EGR Rate on Emissions NOX, ppm PM, µg/s 500 PM NOx 0.4 NOX, ppm HC, ppm C 500 500 HC NOx 400 400 400 0.3 300 300 0.2 200 0.1 100 300 200 100 200 0 10 20 30 40 50 EGR, % 10 20 30 40 50 EGR, % Effect of EGR Ratio on NOX/PM (A) and NOX/HC (B) Emission Trade-Off 1.9 liter, 1200 rpm, 30% load, HPL EGR Source: dieselnet.com 2005 ... temperatures - oxygen available - long dwell time - NOmax at λ 1,1 (local) - NOX IDI < NOX DI Remedy - low temperature (local) - short dwell time - late injection - water injection - EGR Scheme... Influence of Nozzle Hole Number on NOX and PM-Emissions comparison 8- to 7-hole nozzle trade-off 1500/min, part load Audi 4.2l-V8-TDI-engine 7-hole nozzle 8-hole nozzle specific NOX emission [g/kWh]... Formation - unburned or partly burned fuel - thermal cracking products, also from lube oil - quenching-effect Remedy - good mixture formation - no extreme lean combustion operation - no extreme