Đánh giá mứ độ ô nhiễm bụi tsp và pm10 tại khu vự mông dương, quảng ninh và nhận dạng á nguồn nướ thải liên quan

Hopke, Pentti Paatero, William C.. Watson et al., Protocol for Applying and Validating the CMB Model for PM2.5 and VOC, Vols.. Lindgren, "Particulate air pollution in six Asian cities: S

B O I HI -   M B 10 TI KHU V NHN DN TH  thung LUC  NG DN KHOA HC : i) i  2010 1708177927711062afca8-8e63-4ced-a1c8-73651be2c161 1708177927711bf744853-8da3-4412-8c14-a4c56c5cf58c 1708177927711865871ec-805a-489b-8846-3d43cead6ecf LI C c h          t  a Ti   bng d lu c ti hc bi Vin Khoa h            c tp                                             P                        i li c  n Th   v        n h  p K thu     c tp Cui li cng u kit lu   H  Kim Oanh ii MC LC L iii DANH M VIT TT iv DANH MNG v DANH MC  TH vi DANH M LC vii M U CHNG I 1.1 TNG QUAN Bi 1.1.1.m 1.1.2.i 1.1.3.nh hng ca bn sc khe ngi 1.1.4.Phy mu bi 1.1.5.Phi 1.2 i tip nhn 11 1.2.1.i tip nhn 11 1.2.2.i tip nhn 11 1.2.3. 14 CHNG II THC NGHIM 21 2.1 Thit b t t s du 21 2.2 c nghim 22 2.2.1.Phn cc nghim 22 2.2.2.Ly mu 23 2.2.3.u 28 2.2.4.t qu  30 2.2.5.Ch 34 CHNG III KT QU O LUN 38 3.1 N bi 38 3.2 n c ca bi PM10 42 i 3.2.1.N BC 43 3.2.2.h ca bi PM10 45 3.2.3.n ion ca bi PM10 46 3.3 Nhn dn thi ca bi  b 48 3.3.1.i lng ca bi (reconstructed mass) 48 3.3.2.Kt qu ca vi 49 KT LUN 52 U THAM KHO 53 PH LC a ii L  Kim Oanh, hc   20082010 , c hi  m bi ti khu vn dn thi   i s ng dn ca TS    Vin       ng, T i h    i     nhng kt qu o lun lu th  bt k  iii DANH M VIT T T ADB: Asian Development Bank   AIT: Asian Institute of Technology  Hc vi      Lan BC: Black carbon    CH: m ly mu tm Hi  Qung Ninh CMB : Chemical Mass Balance  Cng khc DL: Detection limit  Gii hn EC: Element carbon   HVS: High volume sampler  Thit b ly mu th n IC: Ion Chromatography   ICP-AES: Inductively Coupled Plasma Atomic Emission Spectroscopy  Cm ng cao tn plasma ph   ICP-OES: Inductively Coupled Plasma Optical Emmission Spectrometer  Cm ng cao tn Plasma ph  quang hc ICS1000: Ion Chromatography System  h thng s MD: m ly mu ti Trm x         Qung Ninh MQ: Milli Q water  n tr  PE: Polivinyl etylen PM: Particulate matter  Bi PMF: Positive Matrix Factorization    PVDF: Polyvinyl Diflorit QA/QC: Quality Assurance/Quality Control  Qu   ng/ Ki  chng SPM: Suspended particulate matter  Bng TSP: Total suspended particles  Tng bng VOC : Volatile organic compounds  Cp cht h  iv DANH MNG Bng I-i t  18 Bng II-1: T  y m u 25 Bng II-2: Kt qu hiu chun lu lng cn xuy mu PM 10 .32 Bng II- bnh (%) ci PM2,5 10-2,5 35 Bng II-4: B bnh ca ph-OES 36 Bng II-5: Gii hn (DLi ca thit b ICP-OES s dng 36 Bng III-1: Bng tng hp s lng mu tt ly mu 38 Bng III-2: Tng hp n bi tm ly m 38 Bng III-3: T l n PM10 /TSP 42 Bng III-a bi PM10 t 42 B-ng bi PM10 (g/Nm3) 48 v DANH M TH -1: Cu ty mu th n HVS .6 -2: Cu tu ly mu cy mu th n HVS -3: Cu tu ly mu bi PM10 -4: S  h thng ICP  OES -i tip nhn 13 -1: S  u 22 -2: B khu vu .23 -3: S   y mu 25 -ng IC 29 - bng ICP-OES 30 - th  BC 32 -7: Mi quan h gia khi l bnh c thu  -5 -6g 34 -1: Bi b10 ta 39 -2: Bi b10 ta 40 -3: Bin b10 t 41 -4: Bi b10 t 41 -5: N BC ta 44 -6: N BC t .44 -7: N   46 -8: N a 47 -9: N  47 -10: Mi bi PM 10 t  .50 -11: M i bi PM 10 t  .50 vi DANH M LC Ph lc A: Mt s c trng ca than ly ti m ng a Ph li v t ly mu b Ph lu t ng tt c Ph lu t ng ti Cm Ht g Ph lu t ng tt i Ph lc F: Source profile s du m Ph lc G: Bc ca source profile s du n Ph lc H: Du .p Ph lc I: Kt qu chy i PM10 t s Ph lc J: Kt qu chi PM10 t u vii M U   Nam                                        10 10 