ISO TR 16218 2013(E) Character PDF document pdf © ISO 2013 Packaging and the environment — Processes for chemical recovery Emballage et environnement — Processus de valorisation chimique TECHNICAL REP[.]
ISO/TR 16218 TECHNICAL REPORT First edition 2013-03-15 Packaging and the environment — Processes for chemical recovery ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Emballage et environnement — Processus de valorisation chimique Reference number ISO/TR 16218:2013(E) Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST © ISO 2013 ISO/TR 16218:2013(E) ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - COPYRIGHT PROTECTED DOCUMENT © ISO 2013 Ǥ ϐǡ ǡ ǡ ǡ ǡ Ǥ ǯ Ǥ ϐ ͷȈǦͳʹͳͳ ʹͲ Tel + 41 22 749 01 11 ΪͶͳʹʹͶͻͲͻͶ Ǧ ̷Ǥ Web www.iso.org ii Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Contents Foreword iv Introduction v Scope Normative references ͵ ϐ Inventory of relevant existing documents ͷ ϐ Ǧ ϐ Suitability for chemical recovery process Annex A ȋȌ Examples of monomer recovery of PET Annex B ȋȌ An example of oil recovery Annex C ȋȌ An example of gas recovery Annex D ȋȌ An example of reduction agent in blast furnaces Annex E ȋȌ An example of raw material for coke manufacturing Annex F ȋȌ Assessment checklist — suitability for chemical recovery process 10 Bibliography 11 ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - iii © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Foreword ȋȌ ȋ ȌǤ Ǥ Ǥ ǡ Ǧǡ ǡ Ǥ ȋȌ Ǥ Ȁ ǡʹǤ Ǥ Ǥ ͷ Ψ Ǥ ǡ ȋDzdzǡȌǡ Ǥ Ǥ Ǥ Ǥ Ȁ ͳʹͳͺ Ȁ ͳʹʹǡ Packagingǡ Ͷǡ Packaging and Environment ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - iv Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Introduction ǡ ǡ ǯ Ǥ Ǥ ǡ ǡ ǡ Ǥ ǡ ǡ ϐ ϐ Ȁ Ǥ ȀͳʹʹȀͶ ȋͳͺͲʹȌǡ ȋͳͺͲ͵Ȍǡ ȋͳͺͲͶȌǡ ȋͳͺͲͷȌ ȋͳͺͲȌǤͳͺͲͳϐ ϐ Ǥ Dz dzǡ ǡ ϐ Ǥ ǡ Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - v © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST TECHNICAL REPORT ISO/TR 16218:2013(E) Packaging and the environment — Processes for chemical recovery Scope Ǥ ǡ ϐ Ǥ Ǧ ǡ ǣ Ȅ ǡ ǡ ȋȌ ǡ ǡ ǡ ϐ ǡ ǡ Ǣ Ȅ ǡ ǡ ϐ Ǥ to E Ǣ Dz dz ǡ ǡ ǡ Ǥ ǡ Ǣ Ǯin situǯ Ǥ Normative references ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - ǡ ǡ Ǥ ǡ Ǥ ǡ ȋ ȌǤ ʹͳͲǡPackaging — Vocabulary ͳͺͲͳǡ Ȅ ϔ of packaging and the environment ͵ ϐ ǡϐʹͳͲǡͳͺͲͳǡ Ǥ 3.1 monomer recovery ͳ ǣ ȋȌ ǦȋȌǡǦǦȋȌ ȋ Ȍ Ǥ Ǣ ȋȌǡȋȌǡȋȌ ȋȌǤ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) 3.2 oil recovery 3.3 gas recovery ȋ ǦȌ 3.4 reduction agent in blast furnaces steel production ͳǣ ǡ Ǥ 3.5 raw material for coke manufacturing Inventory of relevant existing documents ǡ Ȅ ͳͷʹͲǣʹͲͲͺǡ Ȅ Ȅ ͳͺͲͳǡ Ȅ ϐ Ȅ ͳͺͲͶǡ Ȅ Ȅ ʹͳͲǡ Ȅ ͷ ϐ Ǧ ϐ ϐ Ǥ ǡ Ǥ Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - ϐ ǡ ǤǤ ǡ ǡ Ǥ Ǥ ϐ ǡǦ Ǥ Suitability for chemical recovery process Ǥ ǡǤǤ ǡ Ǧǡ Ǥ ǡǡ Ǥ ȋȌǡ ǡǡǤǤ ǡ Ǥ ǡǤǤ ǡ ǡ Ǥ ǡ ǡ Ǥ Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Ǥǡ ǡǦ ǡϐ Ǥ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex A ȋȌ Examples of monomer recovery of PET A.1 Material ǡ ǡϐǡϐ ǡ Ǥ Ǥ before processing A.2 Decomposition processes ǡǡǡ ϐ Figure A.1 Ǥ ϐǤ shredding washing drying PET bottle chemical decomposition PET lakes ǤͳȄǦȋϐ Ȍ ǡ ǡ Figure A.2Figure A.3ǡ Ǥ PET lakes Depolymerization Decolouration Crystallization Filtration Molecular distillation BHET Ethylene glycol Puriied BHEAT PET resin Polymerization Ethylene glycol Figure A.2 — Glycolysis process ǡ ϐ Ǥ Ǧ ǦȋȌ Ǥ Ǧ ǡ ǡ ϐǡ Ǥ Ǥ Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) PET lakes DMT Decolouration Crystallization Filtration Puriied DMT Depolymerization Ethylene glycol Methanol TPA Methanol PET resin Polymerization BHET Ethylene Glycol Figure A.3 — Methanolysis process ǡϐ ǤǦǦ ȋȌ Ǥ Ǧ ǡ ǡ ϐǤ ȋȌǤ ǡ Ǥ Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex B ȋȌ An example of oil recovery B.1 Material Ǧ Ǥ ǡ ȀǤ Ǥ Ǥǡ ǦǡǦ ǡϐ Ǥ B.2 Process ȋǦ Ȍ ȋ Ȍ Ǥ Ǥ Ǥͳ Gas Used packaging (Source material) Recovered HCl Gas incineration HCl recover Heat Pretreatment by de-HCl extruder Agglomerate Heating in pyrolysis drum Product cooling High quality oil Energy recovery Residue Figure B.1 — A typical process of oil recovery system ǡϐǡ Ǥ ǡ Ǥ Ǥ Ǥ ǡ Ǥ Ǥ B.3 Use ǡ Ǥ ͳ ϐ Ǥ ǡ Ǥǡ Ǥ ϐ Ǥ ʹ Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex C ȋȌ An example of gas recovery C.1 Material Ǧ Ǥ ǡ ȀǤ Ǥ C.2 Process ǡ Ǥ ǡ Ǥ shown in Figure C.1 Steam Gas Used packaging (Source material) Gasiication in low temp.furnace Conditioning in high temp.furnace Gas (H2, CO) Heat Utilization Residue Incineration Slag O2 Figure C.1 — A typical process of gas recovery system ϐ Ǥ Ǥϐ ȋǡ Ǧǡ ǤȌ Ǥ ǡ Ǥ C.3 Use Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,`- © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex D ȋȌ An example of reduction agent in blast furnaces Ǧ Ǥ ǡ ȀǤ Ǥ D.2 Process ǡ Ǥ Ǥ Ǥͳ Incineration Absorption Washing Gas Used packaging (Source material) PVC sorting PVC De-chlorination Solid Other materials Shredding Classifying Recovered HCl Blast furnace gas Blast furnace Power generation Steel Figure D.1 — A typical process to use used packaging as reduction agent in blast furnace Ǥ Ǥ Ǥ ȋ Ȍ Ǥȋ Ȍǡ ϐ Ǥ ǡ Ǥ Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - D.1 Material ISO/TR 16218:2013(E) Annex E ȋȌ An example of raw material for coke manufacturing E.1 Material Ǧ Ǥ ǡ ȀǤ Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - E.2 Process Ǥ Figure E.1 Used packaging (Source material) PVC & metal removal Agglomeration Carbonation in coke oven Hydrocarbon oil, 40% of plastics Chemical feedstock for plastics, etc Coke 20% of plastics Blast furnace (Reducing agent) Coke oven gas, 40% of plastics Power generation, etc Coal Figure E.1 — A typical process for utilization as a raw material for coke oven ǡ ϐǡ Ǥ ǡ Ǥ Ǥ Ǥ Ǥ ǡ Ǥ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Assessment checklist — suitability for chemical recovery process Documentation No: ϐ ǣ Part(s) of packaging intended for chemical recovery: Intended chemical recovery process: Intended process output/use: F.1 Assessment Description of intended chemical recovery process Describe process, e.g schematic overǡϔ ǡȋȌȋȌ Requirements for collecǦ tion and sorting List requirements, e.g needs to be collected in certain material fraction, ϔ ǡ Ǥ ϔ Chemical recovery process Accepted materials, need for pre-treat- ϔ requirements ment/processing, detrimental materials, contaminations, etc 4.Conclusion of suitability assessment Suitable / not suitable Documentation No: ϐ ǣ Part(s) of packaging intended for chemical recovery: Intended chemical recovery process: Intended process output/use: ǡ ȀͳʹͳͺǤ ǣ Title: ǣ ǣ ǣ ǣ ǣ ǣ 10 Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Annex F ȋȌ ISO/TR 16218:2013(E) Bibliography ȏͳȐ ͳͶʹʹǡPlastics — Environmental aspects — General guidelines for their inclusion in standards ȏʹȐ Ǧͳ͵ʹͷͲʹǡPlastic raw-secondary materials — Blends of heterogeneous plastics based ϔȀ ȄͷͽǣȋȌ ȏ͵Ȑ Ǧͳ͵ʹͷͲʹǡPlastic raw-secondary materials — Blends of heterogeneous plastics based ϔȀ ȀȄͷ;ǣȋȌ ȏͶȐ ǡ Ǥ ʹͲͲͻ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - 11 © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - ISO/TR 16218:2013(E) ౧ͷͷǤͲʹͲ ͳͳ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST