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ISO TR 16218 2013(E) Character PDF document pdf © ISO 2013 Packaging and the environment — Processes for chemical recovery Emballage et environnement — Processus de valorisation chimique TECHNICAL REP[.]

ISO/TR 16218 TECHNICAL REPORT First edition 2013-03-15 Packaging and the environment — Processes for chemical recovery ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Emballage et environnement — Processus de valorisation chimique Reference number ISO/TR 16218:2013(E) Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST © ISO 2013 ISO/TR 16218:2013(E) ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - COPYRIGHT PROTECTED DOCUMENT © ISO 2013 ŽŽ”‹‰Š–•”‡•‡”˜‡†ǤŽ‡••‘–Š‡”™‹•‡•’‡…‹ϐ‹‡†ǡ‘’ƒ”–‘ˆ–Š‹•’—„Ž‹…ƒ–‹‘ƒ›„‡”‡’”‘†—…‡†‘”—–‹Ž‹œ‡†‘–Š‡”™‹•‡‹ƒ›ˆ‘” ‘” „› ƒ› ‡ƒ•ǡ ‡Ž‡…–”‘‹… ‘” ‡…Šƒ‹…ƒŽǡ ‹…Ž—†‹‰ ’Š‘–‘…‘’›‹‰ǡ ‘” ’‘•–‹‰ ‘ –Š‡ ‹–‡”‡– ‘” ƒ ‹–”ƒ‡–ǡ ™‹–Š‘—– ’”‹‘” ™”‹––‡’‡”‹••‹‘Ǥ‡”‹••‹‘…ƒ„‡”‡“—‡•–‡†ˆ”‘‡‹–Š‡” ƒ––Š‡ƒ††”‡••„‡Ž‘™‘” ǯ•‡„‡”„‘†›‹–Š‡…‘—–”›‘ˆ –Š‡”‡“—‡•–‡”Ǥ …‘’›”‹‰Š–‘ˆϐ‹…‡ ƒ•‡’‘•–ƒŽ‡ͷ͸Ȉ Ǧͳʹͳͳ ‡‡˜ƒʹͲ Tel + 41 22 749 01 11 ƒšΪͶͳʹʹ͹ͶͻͲͻͶ͹ Ǧƒ‹Ž…‘’›”‹‰Š–̷‹•‘Ǥ‘”‰ Web www.iso.org —„Ž‹•Š‡†‹™‹–œ‡”Žƒ† ii Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Contents ƒ‰‡ Foreword iv Introduction v Scope Normative references ͵ ‡”•ƒ††‡ϐ‹‹–‹‘• Inventory of relevant existing documents ͷ †‡–‹ϐ‹…ƒ–‹‘‘ˆˆ—”–Š‡”’ƒ…ƒ‰‹‰Ǧ•’‡…‹ϐ‹…‡‡†•”‡Žƒ–‡†–‘…Š‡‹…ƒŽ”‡…‘˜‡”› Suitability for chemical recovery process Annex A ȋ‹ˆ‘”ƒ–‹˜‡Ȍ Examples of monomer recovery of PET Annex B ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of oil recovery Annex C ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of gas recovery Annex D ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of reduction agent in blast furnaces Annex E ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of raw material for coke manufacturing Annex F ȋ‹ˆ‘”ƒ–‹˜‡Ȍ Assessment checklist — suitability for chemical recovery process 10 Bibliography 11 ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - iii © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Foreword ȋ–Š‡ –‡”ƒ–‹‘ƒŽ”‰ƒ‹œƒ–‹‘ˆ‘”–ƒ†ƒ”†‹œƒ–‹‘Ȍ‹•ƒ™‘”Ž†™‹†‡ˆ‡†‡”ƒ–‹‘‘ˆƒ–‹‘ƒŽ•–ƒ†ƒ”†• „‘†‹‡• ȋ  ‡„‡” „‘†‹‡•ȌǤ Š‡ ™‘” ‘ˆ ’”‡’ƒ”‹‰ –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”†• ‹• ‘”ƒŽŽ› …ƒ””‹‡† ‘—– –Š”‘—‰Š  –‡…Š‹…ƒŽ …‘‹––‡‡•Ǥ ƒ…Š ‡„‡” „‘†› ‹–‡”‡•–‡† ‹ ƒ •—„Œ‡…– ˆ‘” ™Š‹…Š ƒ –‡…Š‹…ƒŽ …‘‹––‡‡ Šƒ• „‡‡ ‡•–ƒ„Ž‹•Š‡† Šƒ• –Š‡ ”‹‰Š– –‘ „‡ ”‡’”‡•‡–‡† ‘ –Šƒ– …‘‹––‡‡Ǥ –‡”ƒ–‹‘ƒŽ ‘”‰ƒ‹œƒ–‹‘•ǡ ‰‘˜‡”‡–ƒŽ ƒ† ‘Ǧ‰‘˜‡”‡–ƒŽǡ ‹ Ž‹ƒ‹•‘ ™‹–Š ǡ ƒŽ•‘ –ƒ‡ ’ƒ”– ‹ –Š‡ ™‘”Ǥ  …‘ŽŽƒ„‘”ƒ–‡• …Ž‘•‡Ž› ™‹–Š –Š‡ –‡”ƒ–‹‘ƒŽ Ž‡…–”‘–‡…Š‹…ƒŽ ‘‹••‹‘ ȋ Ȍ ‘ ƒŽŽ ƒ––‡”• ‘ˆ ‡Ž‡…–”‘–‡…Š‹…ƒŽ•–ƒ†ƒ”†‹œƒ–‹‘Ǥ –‡”ƒ–‹‘ƒŽ–ƒ†ƒ”†•ƒ”‡†”ƒˆ–‡†‹ƒ……‘”†ƒ…‡™‹–Š–Š‡”—Ž‡•‰‹˜‡‹–Š‡ Ȁ ‹”‡…–‹˜‡•ǡƒ”–ʹǤ Š‡ ƒ‹ –ƒ• ‘ˆ –‡…Š‹…ƒŽ …‘‹––‡‡• ‹• –‘ ’”‡’ƒ”‡ –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”†•Ǥ ”ƒˆ– –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”†• ƒ†‘’–‡† „› –Š‡ –‡…Š‹…ƒŽ …‘‹––‡‡• ƒ”‡ …‹”…—Žƒ–‡† –‘ –Š‡ ‡„‡” „‘†‹‡• ˆ‘” ˜‘–‹‰Ǥ —„Ž‹…ƒ–‹‘ ƒ• ƒ –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”† ”‡“—‹”‡• ƒ’’”‘˜ƒŽ „› ƒ– Ž‡ƒ•– ͹ͷ Ψ ‘ˆ –Š‡ ‡„‡” „‘†‹‡• …ƒ•–‹‰ƒ˜‘–‡Ǥ ‡š…‡’–‹‘ƒŽ…‹”…—•–ƒ…‡•ǡ™Š‡ƒ–‡…Š‹…ƒŽ…‘‹––‡‡Šƒ•…‘ŽŽ‡…–‡††ƒ–ƒ‘ˆƒ†‹ˆˆ‡”‡–‹†ˆ”‘ –Šƒ–™Š‹…Š‹•‘”ƒŽŽ›’—„Ž‹•Š‡†ƒ•ƒ –‡”ƒ–‹‘ƒŽ–ƒ†ƒ”†ȋDz•–ƒ–‡‘ˆ–Š‡ƒ”–dzǡˆ‘”‡šƒ’Ž‡Ȍǡ‹–ƒ› †‡…‹†‡„›ƒ•‹’Ž‡ƒŒ‘”‹–›˜‘–‡‘ˆ‹–•’ƒ”–‹…‹’ƒ–‹‰‡„‡”•–‘’—„Ž‹•Šƒ‡…Š‹…ƒŽ‡’‘”–Ǥ‡…Š‹…ƒŽ ‡’‘”–‹•‡–‹”‡Ž›‹ˆ‘”ƒ–‹˜‡‹ƒ–—”‡ƒ††‘‡•‘–Šƒ˜‡–‘„‡”‡˜‹‡™‡†—–‹Ž–Š‡†ƒ–ƒ‹–’”‘˜‹†‡•ƒ”‡ …‘•‹†‡”‡†–‘„‡‘Ž‘‰‡”˜ƒŽ‹†‘”—•‡ˆ—ŽǤ ––‡–‹‘‹•†”ƒ™–‘–Š‡’‘••‹„‹Ž‹–›–Šƒ–•‘‡‘ˆ–Š‡‡Ž‡‡–•‘ˆ–Š‹•†‘…—‡–ƒ›„‡–Š‡•—„Œ‡…–‘ˆ ’ƒ–‡–”‹‰Š–•Ǥ •ŠƒŽŽ‘–„‡Š‡Ž†”‡•’‘•‹„Ž‡ˆ‘”‹†‡–‹ˆ›‹‰ƒ›‘”ƒŽŽ•—…Š’ƒ–‡–”‹‰Š–•Ǥ Ȁ ͳ͸ʹͳͺ ™ƒ• ’”‡’ƒ”‡† „› ‡…Š‹…ƒŽ ‘‹––‡‡ Ȁ ͳʹʹǡ Packagingǡ —„…‘‹––‡‡  Ͷǡ Packaging and Environment ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - iv Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Introduction ‡•‘—”…‡—•‡‘’–‹‹œƒ–‹‘ǡ”‡•‘—”…‡•ƒ˜‹‰•ǡ‡˜‹”‘‡–ƒŽ‹’ƒ…–•ǯ‹‹‹œƒ–‹‘ƒ”‡ƒ‘‰’”‹‘”‹–‹‡• ‹ƒ’‡”•’‡…–‹˜‡‘ˆ•—•–ƒ‹ƒ„Ž‡†‡˜‡Ž‘’‡–ǤŠ‡•‡’”‹‘”‹–‹‡•ƒ’’Ž›ƒŽ•‘–‘–Š‡’ƒ…ƒ‰‹‰•‡…–‘”Ǥ‹…‡ ƒ››‡ƒ”•ǡ–Š‹•Žƒ––‡”Šƒ•†‡˜‡Ž‘’‡†‹‹–‹ƒ–‹˜‡•‹–Š‡•‡†‹”‡…–‹‘•ǡ™‘”‹‰‘–Š‡’ƒ…ƒ‰‹‰†‡•‹‰ ƒ•’‡…–•ƒ•™‡ŽŽƒ•‘–Š‡‘”‰ƒ‹œƒ–‹‘‘ˆ–Š‡Ž‘‰‹•–‹……Šƒ‹ǡ‘•‡––‹‰—’”‡…‘˜‡”›ƒ†”‡…›…Ž‹‰•…Š‡‡• ‘”‘–Š‡†‡˜‡Ž‘’‡–‘ˆ—•‡†’ƒ…ƒ‰‹‰”‡…‘˜‡”›‘””‡…›…Ž‹‰–‡…Š‘Ž‘‰‹‡•Ǥ ‘”˜ƒ”‹‘—•”‡ƒ•‘•ǡ‹…Ž—†‹‰–Š‡†‹˜‡”•‹–›‘ˆƒ–‹‘ƒŽ‘””‡‰‹‘ƒŽ…‘–‡š–•ǡ•‘‡…‘ˆ—•‹‘ƒ”‘•‡ˆ”‘ –Š‡ˆƒ…––Šƒ–‡‹–Š‡”Ž‡‰‹•Žƒ–‹‘•‘”…‘—‹…ƒ–‹‘‡••ƒ‰‡•ˆ”‘–Š‡…‘…‡”‡†•–ƒ‡Š‘Ž†‡”•…‘—Ž† ”‡Ž›‘…Ž‡ƒ”ƒ†—ƒ‹‘—•Ž›ƒ‰”‡‡†—’‘†‡ϐ‹‹–‹‘•‘ˆ–Š‡–‡”•—•‡†ƒ†‘ˆ–Š‡”‡•’‡…–‹˜‡„‡‡ϐ‹–• ‘ˆ–Š‡˜ƒ”‹‘—•”‡…‘˜‡”›Ȁ”‡…›…Ž‹‰‘’–‹‘•Ǥ ȀͳʹʹȀͶ‹•†‡˜‡Ž‘’‹‰•–ƒ†ƒ”†•‘–Š‡‘’–‹‹œƒ–‹‘‘ˆ–Š‡’ƒ…ƒ‰‹‰•›•–‡ȋ ͳͺ͸ͲʹȌǡ‘ ”‡—•‡ȋ ͳͺ͸Ͳ͵Ȍǡ‘ƒ–‡”‹ƒŽ”‡…›…Ž‹‰ȋ ͳͺ͸ͲͶȌǡ‘‡‡”‰›”‡…‘˜‡”›ȋ ͳͺ͸ͲͷȌƒ†‘‘”‰ƒ‹… ”‡…›…Ž‹‰ȋ ͳͺ͸Ͳ͸ȌǤ ͳͺ͸Ͳͳ™‹ŽŽ†‡ϐ‹‡–Š‡‰‡‡”ƒŽ”‡“—‹”‡‡–•ˆ‘”–Š‡—•‡‘ˆ–Š‡•‡ •–ƒ†ƒ”†• ‹–Š‡ϐ‹‡Ž†‘ˆ’ƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–Ǥ Š‹•‡…Š‹…ƒŽ‡’‘”–‹•ƒƒ––‡’––‘…Žƒ”‹ˆ›•‘‡‹†‡ƒ•”‡Žƒ–‹‰–‘–Š‡…‘…‡’–‘ˆDzŠ‡‹…ƒŽ‡…‘˜‡”›dzǡ –‘’—–‹–‹–Š‡’‡”•’‡…–‹˜‡‘ˆ–Š‡‘–Š‡””‡…‘˜‡”›‘’–‹‘•ƒ†–‘Š‡Ž’Ž‘…ƒŽ•–ƒ‡Š‘Ž†‡”•–‘‹†‡–‹ˆ›–Š‡ Ž‘…ƒŽŽ›‘•–ƒ’’”‘’”‹ƒ–‡–”‡ƒ–‡–‘’–‹‘ǡ‘–Š‡„ƒ•‹•‘ˆƒ…‘‘—†‡”•–ƒ†‹‰‘ˆ–Š‡–‡”•ƒ†‘ˆ –Š‡„ƒ•‹…”‡“—‹”‡‡–••’‡…‹ϐ‹…–‘‡ƒ…Š”‡…‘˜‡”›–‡…Š‘Ž‘‰›Ǥ –Š‹•‡…Š‹…ƒŽ‡’‘”–ǡ–Š‡‡–Š‘†‘Ž‘‰‹‡• ‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›‘ˆ—•‡†’ƒ…ƒ‰‹‰ƒ”‡†‡•…”‹„‡†Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - v © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST TECHNICAL REPORT ISO/TR 16218:2013(E) Packaging and the environment — Processes for chemical recovery Scope ‡˜‡”ƒŽ’”‘…‡••‡•ˆ‘”…Š‡‹…ƒŽ”‡…‘˜‡”›‘ˆ—•‡†’ƒ…ƒ‰‹‰ƒ”‡…‘•‹†‡”‡†–‘„‡ƒ–‡”‹ƒŽ”‡…›…Ž‹‰ǤŠ‡ ˆ‘…—•‘ˆ–Š‹•‡…Š‹…ƒŽ‡’‘”–‹•ˆ‘”—•‡†’ƒ…ƒ‰‹‰ǡƒŽ–Š‘—‰Š–Š‡’”‘…‡••‡•†‡•…”‹„‡†ƒ”‡‘–•’‡…‹ϐ‹… ˆ‘”—•‡†’ƒ…ƒ‰‹‰ƒ†…ƒ„‡—•‡†ˆ‘””‡…‘˜‡”›‘ˆ‘–Š‡”ƒ–‡”‹ƒŽ•‘ˆ•ƒ‡–›’‡Ǥ”‘…‡••‡•ˆ‘”…Š‡‹…ƒŽ ”‡…‘˜‡”› ‘ˆ —•‡† ’ƒ…ƒ‰‹‰ ƒ”‡ ƒ’’Ž‹…ƒ„Ž‡ ˆ‘” ’Žƒ•–‹… ’ƒ…ƒ‰‹‰ ‘” „‹‘ƒ••Ǧ„ƒ•‡† ’ƒ…ƒ‰‹‰ǡ ™Š‹…Š ‹‰Š–„‡‹–‡”’”‡–‡†‹–™‘†‹ˆˆ‡”‡–™ƒ›•ǣ Ȅ ’”‘…‡••‡•–‘”‡…‘˜‡”˜ƒŽ—ƒ„Ž‡…Š‡‹…ƒŽ•—„•–ƒ…‡•„›…Š‡‹…ƒŽ–”‡ƒ–‡–‘ˆ—•‡†’ƒ…ƒ‰‹‰ǡˆ‘” ‡šƒ’Ž‡ǡ –‘ ”‡…‘˜‡” ‘‘‡”• ‘ˆ ’‘Ž›‡–Š›Ž‡‡ –‡”‡’Š–ŠƒŽƒ–‡ ȋȌ „› Š›†”‘Ž›•‹•ǡ ‰Ž›…‘Ž›•‹• ‘” ‡–Šƒ‘Ž›•‹•ǡ –‘ ”‡…‘˜‡” ‘‹Ž „› …ƒ–ƒŽ›–‹… ”‡ƒ…–‹‘ ‘” ’›”‘Ž›•‹•ǡ –‘ ”‡…‘˜‡” ˜ƒŽ—ƒ„Ž‡ ‰ƒ•‡• •—…Š ƒ• Š›†”‘‰‡„›‰ƒ•‹ϐ‹…ƒ–‹‘ǡ–‘”‡…‘˜‡”…‘‡ǡ‘‹Žƒ†‰ƒ••‡•„›…‘‡ˆƒ…–‹‘Ǣ Ȅ ’”‘…‡••‡•–‘†‹”‡…–Ž›•—„•–‹–—–‡—•‡†’ƒ…ƒ‰‹‰ˆ‘”ƒ–—”ƒŽ”‡•‘—”…‡•™ ‹–Š‘—–…Š‡‹…ƒŽ’”‡–”‡ƒ–‡–ǡ ˆ‘” ‡šƒ’Ž‡ǡ ϐŽƒ‡• ‘ˆ —•‡† ’Žƒ•–‹… ’ƒ…ƒ‰‹‰ ƒ› —•‡ ‹ „Žƒ•– ˆ—”ƒ…‡ ‹ –Š‡ ’Žƒ…‡ ‘ˆ …‘‡ ƒ• ƒ ”‡†—…‹‰ƒ‰‡–Ǥ šƒ’Ž‡•ƒ†‡›…Šƒ”ƒ…–‡”‹•–‹…•‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›’”‘…‡••‡•ƒ”‡‰‹˜‡‹‡š‡• to E  ‘” –Š‡ ’—”’‘•‡ ‘ˆ –Š‹• ‡…Š‹…ƒŽ ‡’‘”–Ǣ DzŠ‡‹…ƒŽ ”‡…‘˜‡”›dz ‡ƒ• –Š‡ ’”‘†—…–‹‘ ‘ˆ …Š‡‹…ƒŽ•ǡ ‹†‡–‹…ƒŽ –‘ ‘” †‹ˆˆ‡”‹‰ ˆ”‘ǡ –Š‡ •–ƒ”–‹‰ ”ƒ™ ƒ–‡”‹ƒŽ• –Šƒ– ™‡”‡ —•‡† ˆ‘” –Š‡ ’”‘†—…–‹‘ ‘ˆ –Š‡ ’ƒ…ƒ‰‹‰ ƒ–‡”‹ƒŽ•ǡ‘”–Š‡†‹”‡…–•—„•–‹–—–‹‘‘ˆƒ–—”ƒŽ”‡•‘—”…‡•„›—•‹‰—•‡†’ƒ…ƒ‰‹‰ǤŠ‡•‡”‡…‘˜‡”‡†…Š‡‹…ƒŽ•…ƒ „‡—•‡†ƒ••—…Šǡ‘”ƒ•”‡ƒ…–ƒ–•‹ˆ—”–Š‡”…Š‡‹…ƒŽ•›–Š‡•‡•Ǣ†‹”‡…–Ž›Ǯin situǯ‘”‹ƒ‘–Š‡”’”‘†—…–‹‘’”‘…‡••Ǥ Normative references ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Š‡ ˆ‘ŽŽ‘™‹‰ †‘…—‡–•ǡ ‹ ™Š‘Ž‡ ‘” ‹ ’ƒ”–ǡ ƒ”‡ ‘”ƒ–‹˜‡Ž› ”‡ˆ‡”‡…‡† ‹ –Š‹• †‘…—‡– ƒ† ƒ”‡ ‹†‹•’‡•ƒ„Ž‡ ˆ‘” ‹–• ƒ’’Ž‹…ƒ–‹‘Ǥ ‘” †ƒ–‡† ”‡ˆ‡”‡…‡•ǡ ‘Ž› –Š‡ ‡†‹–‹‘ …‹–‡† ƒ’’Ž‹‡•Ǥ ‘” —†ƒ–‡† ”‡ˆ‡”‡…‡•ǡ–Š‡Žƒ–‡•–‡†‹–‹‘‘ˆ–Š‡”‡ˆ‡”‡…‡††‘…—‡–ȋ‹…Ž—†‹‰ƒ›ƒ‡†‡–•Ȍƒ’’Ž‹‡•Ǥ ʹͳͲ͸͹ǡPackaging — Vocabulary ͳͺ͸Ͳͳǡƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–Ȅ ‡‡”ƒŽ”‡“—‹”‡‡–•ˆ‘”–Š‡—•‡‘ˆ •–ƒ†ƒ”†•‹–Š‡ϔ‹‡Ž† of packaging and the environment ͵ ‡”•ƒ††‡ϐ‹‹–‹‘• ‘”–Š‡’—”’‘•‡•‘ˆ–Š‹•†‘…—‡–ǡ–Š‡–‡”•ƒ††‡ϐ‹‹–‹‘•‰‹˜‡‹ ʹͳͲ͸͹ǡ ͳͺ͸Ͳͳǡƒ†–Š‡ ˆ‘ŽŽ‘™‹‰ƒ’’Ž›Ǥ 3.1 monomer recovery ’”‘…‡••‡•–‘”‡…‘˜‡”‘‘‡”••—…Šƒ•„›†‡…‘’‘•‹–‹‘‘ˆ—•‡†’ƒ…ƒ‰‹‰ ‘–‡ ͳ –‘ ‡–”›ǣ Š‡ ‹†—•–”‹ƒŽ ’”‘…‡••‡• ƒ”‡ ‡•–ƒ„Ž‹•Š‡† –‘ ”‡…‘˜‡” ‘‘‡”• –‘ ’”‘†—…‡ ’‘Ž›‡–Š›Ž‡‡ –‡”‡’Š–ŠƒŽƒ–‡ȋȌ•—…Šƒ•†‹‡–Š›ŽǦ–‡”‡’Š–ŠƒŽƒ–‡ȋȌǡ„‹•ǦŠ›†”‘š›‡–Š›ŽǦ–‡”‡’Š–ŠƒŽƒ–‡ȋ Ȍƒ†‡–Š›Ž‡‡ ‰Ž›…‘Žȋ Ȍ„›…Š‡‹…ƒŽ†‡…‘’‘•‹–‹‘‘ˆǤŠ‡’”‘…‡••‡•–‘”‡…‘˜‡”‘‘‡”•ˆ”‘–Š‡ˆ‘ŽŽ‘™‹‰’‘Ž›‡”• ƒ”‡ƒ––Š‡†‡˜‡Ž‘’‡–•–ƒ‰‡ˆ‘”’‘Ž›‡”••—…Šƒ•Ǣ’‘Ž›…ƒ”„‘ƒ–‡ȋȌǡ’‘Ž›ƒ‹†‡ȋȌǡ’‘Ž›•–›”‡‡ȋȌƒ†’‘Ž› Žƒ…–‹…ƒ…‹†ȋȌ’‘Ž›‡”Ǥ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) 3.2 oil recovery ’”‘…‡••‡•–‘”‡…‘˜‡”‘‹Žˆ”‘—•‡†’ƒ…ƒ‰‹‰•—…Šƒ•„›†‡…‘’‘•‹–‹‘™‹–Š‘”™‹–Š‘—–…ƒ–ƒŽ›•– 3.3 gas recovery ’”‘…‡••‡•–‘”‡…‘˜‡”‰ƒ•‡•—•‡ˆ—Žˆ‘”…Š‡‹…ƒŽ‹†—•–”‹‡•ƒ•–Š‡‹””ƒ™ƒ–‡”‹ƒŽ•ȋŠ›†”‘‰‡ƒ†…ƒ”„‘ ‘‘Ǧ‘š‹†‡Ȍ•—…Šƒ•„›…ƒ”„‘‹œƒ–‹‘ƒ†’ƒ”–‹ƒŽ„—”‹‰‘ˆ—•‡†’ƒ…ƒ‰‹‰ 3.4 reduction agent in blast furnaces ’”‘†—…– ’”‘˜‹†‹‰ …ƒ”„‘ ƒ† Š›†”‘‰‡ –‘ ”‡’Žƒ…‡ …‘‡ ™‹–Š —•‡† ’ƒ…ƒ‰‹‰ ‹ „Žƒ•– ˆ—”ƒ…‡• ˆ‘” steel production ‘–‡ͳ–‘‡–”›ǣ –Š‡…‘˜‡–‹‘ƒŽ•–‡‡Ž’”‘†—…–‹‘’”‘…‡••‡•ǡ…‘‡‹•—•‡†ƒ•ƒ”‡†—…–‹‘ƒ‰‡–Ǥ 3.5 raw material for coke manufacturing ’”‘†—…––‘’ƒ”–‹ƒŽŽ›”‡’Žƒ…‡…‘ƒŽ™‹–Š—•‡†’ƒ…ƒ‰‹‰ˆ‘””ƒ™ƒ–‡”‹ƒŽ‘ˆ…‘‡ˆ—”ƒ…‡•–‘’”‘†—…‡…‘‡ Inventory of relevant existing documents ƒ”‹‘—•‘’–‹‘•‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›ƒ”‡ƒŽ•‘ƒ††”‡••‡†‹•‘‡•–ƒ†ƒ”†‹œƒ–‹‘†‘…—‡–•ǡˆ‘”‡šƒ’Ž‡ Ȅ ͳͷʹ͹ͲǣʹͲͲͺǡŽƒ•–‹…•Ȅ —‹†‡Ž‹‡•ˆ‘”–Š‡”‡…‘˜‡”›ƒ†”‡…›…Ž‹‰‘ˆ’Žƒ•–‹…•™ƒ•–‡ Ȅ ͳͺ͸Ͳͳǡƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–Ȅ ‡‡”ƒŽ”‡“—‹”‡‡–•ˆ‘”–Š‡—•‡‘ˆ •–ƒ†ƒ”†•‹ –Š‡ϐ‹‡Ž†‘ˆ’ƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡– Ȅ ͳͺ͸ͲͶǡƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–Ȅƒ–‡”‹ƒŽ”‡…›…Ž‹‰ Ȅ ʹͳͲ͸͹ǡƒ…ƒ‰‹‰Ȅ‘…ƒ„—Žƒ”› ͷ †‡–‹ϐ‹…ƒ–‹‘‘ˆˆ—”–Š‡”’ƒ…ƒ‰‹‰Ǧ•’‡…‹ϐ‹…‡‡†•”‡Žƒ–‡†–‘…Š‡‹…ƒŽ”‡…‘˜‡”› Š‡’”‹‡‘„Œ‡…–‹˜‡‘ˆ–Š‹•‡…Š‹…ƒŽ‡’‘”–‹••’‡…‹ϐ‹…ˆ‘”—•‡†’ƒ…ƒ‰‹‰Ǥ ‘”†‡”–‘‡‡––Š‡‡‡†•‘ˆ –Š‡ƒ”‡–ǡ–Š‡—•‡†’ƒ…ƒ‰‹‰ˆ”ƒ…–‹‘‡†‹‰—’‹ƒ…Š‡‹…ƒŽ”‡…‘˜‡”›’”‘…‡••‹•‹ƒ›…ƒ•‡•—•‡† ‹…‘„‹ƒ–‹‘™‹–Š‘–Š‡”ƒ–‡”‹ƒŽˆ”ƒ…–‹‘•‘ˆ–Š‡•ƒ‡–›’‡ǤŠ‡”‡ˆ‘”‡–Š‡’”‘…‡••‡•†‡•…”‹„‡†‹–Š‹• ‡…Š‹…ƒŽ‡’‘”–ƒ”‡‹’”ƒ…–‹•‡‘–”‡•–”‹…–‡†–‘—•‡†’ƒ…ƒ‰‹‰Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - ƒ…Š ”‡…‘˜‡”› ‘’–‹‘ Šƒ• ‹–• ‘™ •’‡…‹ϐ‹…ƒ–‹‘•ǡ ‡Ǥ‰Ǥ —„‡” ‘ˆ ƒ–‡”‹ƒŽ•ǡ ƒš‹— Ž‡˜‡Ž• ‘ˆ …‘–ƒ‹ƒ–‹‘ǡ‡–…Ǥ‡”–ƒ‹ƒ–‡”‹ƒŽ•ƒ›„‡‹…‘’ƒ–‹„Ž‡™‹–Š•‘‡…Š‡‹…ƒŽ”‡…‘˜‡”›’”‘…‡••‡•Ǥ  …ƒ•‡•‘ˆ•‹‰‹ϐ‹…ƒ–ƒ‘—–‘ˆ•—…Šƒ–‡”‹ƒŽ•„‡‹‰‹…Ž—†‡†ǡ’”‡Ǧ–”‡ƒ–‡––‘”‡‘˜‡–Š‡•‡•Š‘—Ž†„‡ ‹–”‘†—…‡†–‘ƒ˜‘‹†–Š‘•‡’”‘„Ž‡•Ǥ Suitability for chemical recovery process Š‡‹…ƒŽ”‡…‘˜‡”›‹•‹…Ž—†‡†ƒ•ƒ–‡”‹ƒŽ”‡…›…Ž‹‰ƒ•ƒ‘’–‹‘Ǥ ˆ—•‡†’ƒ…ƒ‰‹‰ǡ‹Ǥ‡Ǥ•‘—”…‡ƒ–‡”‹ƒŽǡ ‹•…‘ŽŽ‡…–‡†‹‘‘Ǧƒ–‡”‹ƒŽ”‘—–‡ǡ–Š‡—•‡†’ƒ…ƒ‰‹‰‹•ˆ‡ƒ•‹„Ž‡ˆ‘”‡…Šƒ‹…ƒŽ”‡…›…Ž‹‰Ǥ –Š‡…ƒ•‡ ‘ˆ„‘––Ž‡•ǡŠ‘™‡˜‡”ǡ…Š‡‹…ƒŽ”‡…‘˜‡”›„›‘‘‡””‡…‘˜‡”›‹•ƒŽ•‘ˆ‡ƒ•‹„Ž‡–‘‘„–ƒ‹Š‹‰Š‰”ƒ†‡ ”‡•‹Ǥ –Š‡…ƒ•‡‘ˆ‡š’ƒ†‡†’‘Ž›•–›”‡‡ȋȌǡ•‘‡’ƒ”–•‘ˆ•‘—”…‡ƒ–‡”‹ƒŽ…ƒ„‡”‡…›…Ž‡†„› ‡…Šƒ‹…ƒŽ”‡…›…Ž‹‰ǡƒ†–Š‡‘–Š‡”’ƒ”–•ǡ‹Ǥ‡Ǥ…‘–ƒ‹ƒ–‡†ƒ–‡”‹ƒŽǡƒ”‡‰‡‡”ƒŽŽ›—•‡†ƒ••‘—”…‡‘ˆ …Š‡‹…ƒŽ”‡…‘˜‡”›Ǥ ˆ—•‡†’ƒ…ƒ‰‹‰ǡ‹Ǥ‡Ǥ•‘—”…‡ƒ–‡”‹ƒŽǡ‹•…‘ŽŽ‡…–‡†‹…‘‹‰Ž‡†ƒ–‡”‹ƒŽ”‘—–‡ǡ •—…Šƒ–‡”‹ƒŽ…ƒ„‡—•‡†ƒ••‘—”…‡•‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›‘–Š‡”–Šƒ‘‘‡””‡…‘˜‡”›ǤŠ‡•‡”‡…‘˜‡”› ‘’–‹‘•’‘••‡••™‹†‡ƒ……‡’–ƒ„‹Ž‹–›‘ˆ•‘—”…‡ƒ–‡”‹ƒŽǡ…‘‹‰Ž‡†‘”…‘–ƒ‹ƒ–‡†ǡ‹ˆ‘Ž›‹–†‘‡•‘– ‹’‡†‡–Š‡‘’‡”ƒ–‹‘‘ˆˆƒ…‹Ž‹–‹‡•Ǥ Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) ‡šƒ’Ž‡‘ˆƒ••‡••‡–…Š‡…Ž‹•–‹•‰‹˜‡‹‡š ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -  Žƒ•–‹…ƒ–‡”‹ƒŽ•ƒ”‡‘•–•—‹–ƒ„Ž‡ˆ‘”–Š‡•‡’”‘…‡••‡•Ǥ ‘™‡˜‡”ǡ‹ˆ–Š‡”‡‹•‘‘„•–ƒ…Ž‡‘–Š‡‘’‡”ƒ–‹‘ ‘ˆˆƒ…‹Ž‹–‹‡•ǡ„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ••—…Šƒ•™‘‘†ǡ’ƒ’‡”ƒ†ϐ‹„”‡…ƒ„‡‹…‘”’‘”ƒ–‡†‹–‘–Š‡’”‘…‡••Ǥ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex A ȋ‹ˆ‘”ƒ–‹˜‡Ȍ Examples of monomer recovery of PET A.1 Material ›’”‘†—…–ǡ‹…Ž—†‹‰„‘––Ž‡•ǡϐ‹Žǡϐ‹„”‡ƒ†ˆƒ„”‹…•ǡ…ƒ„‡—•‡†ˆ‘”–Š‡‘‘‡””‡…‘˜‡”›‘ˆ Ǥ•‡†„‘––Ž‡•ƒ”‡ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••Ǥ•‡†„‘––Ž‡•ƒ”‡•‘”–‡† before processing A.2 Decomposition processes ‹†—•–”‹ƒŽ’”‘…‡••‡•ǡ„‘––Ž‡•ƒ”‡•Š”‡††‡†ǡ™ƒ•Š‡†ǡƒ††”‹‡†–‘’”‘†—…‡ϐŽƒ‡•ƒ••Š‘™‹ Figure A.1ƒ†’”‹‘”–‘„‡‹‰†‡…‘’‘•‡†‹ƒ•‡…‘†•–‡’ǤŠ‡…‘–ƒ‹ƒ–•ƒ”‡—•—ƒŽŽ›”‡‘˜‡†ƒ– –Š‡ϐŽƒ‹‰‘’‡”ƒ–‹‘Ǥ shredding washing drying PET bottle chemical decomposition PET lakes ‹‰—”‡ǤͳȄ”‡Ǧ–”‡ƒ–‡–ȋϐŽƒ‡’”‘†—…–‹‘Ȍ ™‘†‡…‘’‘•‹–‹‘’”‘…‡••‡•Šƒ˜‡„‡‡‡•–ƒ„Ž‹•Š‡†ǡƒ‡Ž›‰Ž›…‘Ž›•‹•ƒ†‡–Šƒ‘Ž›•‹•ǡƒ••Š‘™‹ Figure A.2ƒ†Figure A.3ǡ”‡•’‡…–‹˜‡Ž›Ǥ PET lakes Depolymerization Decolouration Crystallization Filtration Molecular distillation BHET Ethylene glycol Puriied BHEAT PET resin Polymerization Ethylene glycol Figure A.2 — Glycolysis process  ‰Ž›…‘Ž›•‹•ǡ –Š‡ ‹š–—”‡ ‘ˆ  ϐŽƒ‡• ƒ† ‡–Š›Ž‡‡ ‰Ž›…‘Ž ‹• Š‡ƒ–‡† —’ –‘ †‡…‘’‘•‡ Ǥ ‹•Ǧ Š›†”‘š›‡–Š›ŽǦ–‡”‡’Š–ŠƒŽƒ–‡ȋ Ȍ‹•”‡…‘˜‡”‡†„›–Š‹•’”‘…‡••ǤŠ‡”‡…‘˜‡”‡† ‹•†‡Ǧ…‘Ž‘—”‡†ǡ …”›•–ƒŽŽ‹œ‡†ǡ ϐ‹Ž–‡”‡†ǡ ƒ† –Š‡ ‘Ž‡…—Žƒ” †‹•–‹ŽŽ‡† –‘ ‘„–ƒ‹ ’—”‡  Ǥ Š‡ ’—”‡   ‹• †‹”‡…–Ž› ‡’Ž‘›‡†–‘’‘Ž›‡”‹œ‡”‡•‹Ǥ–Š›Ž‡‡‰Ž›…‘Ž‹•”‡…‘˜‡”‡†ˆ”‘–Š‡’‘Ž›‡”‹œƒ–‹‘’”‘…‡••Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) PET lakes DMT Decolouration Crystallization Filtration Puriied DMT Depolymerization Ethylene glycol Methanol TPA Methanol PET resin Polymerization BHET Ethylene Glycol Figure A.3 — Methanolysis process ‡–Šƒ‘Ž›•‹•ǡ–Š‡‹š–—”‡‘ˆϐŽƒ‡•ƒ†‡–Šƒ‘Ž‹•Š‡ƒ–‡†—’–‘†‡…‘’‘•‡Ǥ‹Ǧ‡–Š›ŽǦ –‡”‡’Š–ŠƒŽƒ–‡ ȋȌ ‹• ”‡…‘˜‡”‡† „› –Š‹• ’”‘…‡••Ǥ Š‡ ”‡…‘˜‡”‡†  ‹• †‡Ǧ…‘Ž‘—”‡†ǡ …”›•–ƒŽŽ‹œ‡†ǡ ϐ‹Ž–‡”‡†–‘‘„–ƒ‹’—”‡ǤŠ‡’—”‡‹•…‘˜‡”–‡†‹–‘’—”‡–‡”‡’Š–ŠƒŽ‹…ƒ…‹†ȋȌƒ†‡–Šƒ‘ŽǤ Š‹•‹•…‘˜‡”–‡†‹–‘ „›ƒ††‹–‹‘‘ˆ‡–Š›Ž‡‡‰Ž›…‘Žǡ™Š‹…Š‹•‡’Ž‘›‡†–‘’‘Ž›‡”‹œ‡ ”‡•‹Ǥ–Š›Ž‡‡‰Ž›…‘Ž‹•”‡…‘˜‡”‡†ˆ”‘–Š‡’‘Ž›‡”‹œƒ–‹‘’”‘…‡••Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex B ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of oil recovery B.1 Material ›‘”‰ƒ‹…ƒ–‡”‹ƒŽ•‹…Ž—†‹‰’Žƒ•–‹…•ƒ†„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ•…ƒ„‡—•‡†ˆ‘”‘‹Ž”‡…‘˜‡”›Ǥ•‡† ’ƒ…ƒ‰‹‰‹•ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••ǡ‹ˆ‘Ž›‹–‹•…‘ŽŽ‡…–‡†Ȁ•‘”–‡†Ǥ‘‹‰Ž‡† ƒ†•Ž‹‰Š–Ž›…‘–ƒ‹ƒ–‡†—•‡†’ƒ…ƒ‰‹‰…ƒƒ’’Ž›ˆ‘”–Š‹•’”‘…‡••Ǥ  Žƒ•–‹…ƒ–‡”‹ƒŽ•ƒ”‡‘•–•—‹–ƒ„Ž‡ˆ‘”–Š‹•’”‘…‡••Ǥ ‘™‡˜‡”ǡ‹ˆ–Š‡”‡‹•‘‘„•–ƒ…Ž‡‘–Š‡‘’‡”ƒ–‹‘‘ˆ –Š‡†‡Ǧ Ž‡š–”—†‡”ǡ„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ••—…Šƒ•™‘‘†ǡ’ƒ’‡”ƒ†ϐ‹„”‡ƒ”‡‹…‘”’‘”ƒ–‡†‹–‘–Š‡’”‘…‡••Ǥ B.2 Process ‹Ž”‡…‘˜‡”›‹•ƒ’”‘…‡••–‘”‡…‘˜‡”Š‹‰Š“—ƒŽ‹–›‘‹ŽȋŠ›†”‘Ǧ…ƒ”„‘‘‹ŽȌˆ”‘—•‡†’ƒ…ƒ‰‹‰„›–”‡ƒ–‡– ƒ–Š‹‰Š–‡’‡”ƒ–—”‡•ȋ—†‡”‹‡”–…‘†‹–‹‘•Ȍ™‹–Š‘”™‹–Š‘—–…ƒ–ƒŽ›•–•ǤŠ‡”‡ƒ”‡•‡˜‡”ƒŽ’”‘…‡••‡• ”—‹‰‹ ƒ’ƒǤ–›’‹…ƒŽ’”‘…‡••‹••Š‘™‹ ‹‰—”‡Ǥͳ Gas Used packaging (Source material) Recovered HCl Gas incineration HCl recover Heat Pretreatment by de-HCl extruder Agglomerate Heating in pyrolysis drum Product cooling High quality oil Energy recovery Residue Figure B.1 — A typical process of oil recovery system Š‡—•‡†’ƒ…ƒ‰‹‰‹•ǡƒ–ϐ‹”•–ǡ‹–”‘†—…‡†‹–‘ƒ‡š–”—†‡”–‘”‡‘˜‡…ŠŽ‘”‹‡Ǥ›‹…‹‡”ƒ–‹‘‘ˆ–Š‡ ‰‡‡”ƒ–‡†‰ƒ•ǡ Ž‹•”‡…‘˜‡”‡†ˆ‘””‡…›…Ž‹‰ǤŠ‡Š‡ƒ–‰‡‡”ƒ–‡†„›‹…‹‡”ƒ–‹‘‹•—–‹Ž‹œ‡†‹–Š‡’”‘…‡••Ǥ Š‡’Žƒ•–‹…‡Ž–‡š–”—†‡†ˆ”‘–Š‡‡š–”—†‡”‹•‹–”‘†—…‡†‹–‘ƒ’›”‘Ž›•‹•†”—–‘†‡…‘’‘•‡’‘Ž›‡”•Ǥ Š‡’”‘†—…–•ƒ”‡…‘‘Ž‡†–‘‘„–ƒ‹Š‹‰Š“—ƒŽ‹–›‘‹Žǡ™Š‡”‡ƒ•‰ƒ•…‘’‘‡–•ƒ”‡‡”‰‡†™‹–Š–Š‡‰ƒ• ‰‡‡”ƒ–‡†ˆ”‘–Š‡‡š–”—†‡”ǤŠ‡”‡•‹†—‡‹–Š‡’›”‘Ž›•‹•†”—…ƒŽŽ‡†…Šƒ”‹•—–‹Ž‹œ‡†ˆ‘”‡‡”‰›”‡…‘˜‡”›Ǥ B.3 Use Š‡”‡…‘˜‡”‡†Š‹‰Š“—ƒŽ‹–›‘‹Ž…ƒ„‡—•‡†‹–Š‡’Žƒ…‡‘ˆŠ‡ƒ˜›‘‹Žǡƒ•‡‹–Š‡”…Š‡‹…ƒŽˆ‡‡†•–‘…‘”ˆ—‡ŽǤ ͳ ‘–‡–Šƒ––Š‡‘‹Ž”‡…‘˜‡”›’”‘…‡••…ƒ„‡Ž‡••‡ˆϐ‹…‹‡––Šƒ‘–Š‡””‡…‘˜‡”›’”‘…‡••‡•Ǥ –Š‡’”‘…‡••ǡ ƒ’‘”–‹‘‘ˆ–Š‡—•‡†’ƒ…ƒ‰‹‰‹•…‘•—‡†–‘•—’’Ž›‡‡”‰›ˆ‘”–Š‡’”‘…‡••ǤŠ—•ǡƒŽŽ‘ˆ–Š‡—•‡†’ƒ…ƒ‰‹‰‹• ‡˜‡””‡…‘˜‡”‡†ƒ•‘‹ŽǤŠ‡’”‹‘”‹–›‘ˆ‘‹Ž”‡…‘˜‡”›‹••‡–Ž‘™‡”–Šƒ–Š‡’”‹‘”‹–›ˆ‘”‘”‡‡ˆϐ‹…‹‡–’”‘…‡••‡•Ǥ ʹ Š‡†‡…‘’‘•‡†‰ƒ•ƒ†‘‹Žƒ”‡—–‹Ž‹œ‡†ƒ•ˆ—‡Ž‘”…Š‡‹…ƒŽ”ƒ™ƒ–‡”‹ƒŽǤ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex C ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of gas recovery C.1 Material ›‘”‰ƒ‹…ƒ–‡”‹ƒŽ•‹…Ž—†‹‰’Žƒ•–‹…•ƒ†„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ•…ƒ„‡—•‡†ˆ‘”‰ƒ•”‡…‘˜‡”›Ǥ•‡† ’ƒ…ƒ‰‹‰‹•ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••ǡ‹ˆ‘Ž›‹–‹•…‘ŽŽ‡…–‡†Ȁ•‘”–‡†Ǥ‘‹‰Ž‡† ƒ†•Ž‹‰Š–Ž›…‘–ƒ‹ƒ–‡†—•‡†’ƒ…ƒ‰‹‰…ƒƒ’’Ž›ˆ‘”–Š‹•’”‘…‡••Ǥ C.2 Process ‹†—•–”‹ƒŽ’”‘…‡••‡•ǡŠ›†”‘‰‡Šƒ•„‡‡‘„–ƒ‹‡†„›…”ƒ…‹‰ƒ–—”ƒŽ‰ƒ•‘”’‡–”‘Ž‡—Ǥ›–Š‡‰ƒ• ”‡…‘˜‡”›ˆ”‘—•‡†’ƒ…ƒ‰‹‰ǡ–Š‡•‡”‡•‘—”…‡•ƒ”‡”‡’Žƒ…‡†„›–Š‡—•‡†’ƒ…ƒ‰‹‰Ǥ–›’‹…ƒŽ’”‘…‡••‹• shown in Figure C.1 Steam Gas Used packaging (Source material) Gasiication in low temp.furnace Conditioning in high temp.furnace Gas (H2, CO) Heat Utilization Residue Incineration Slag O2 Figure C.1 — A typical process of gas recovery system •‡† ’ƒ…ƒ‰‹‰ ‹• ‰ƒ•‹ϐ‹‡† ‹ ƒ Ž‘™ –‡’‡”ƒ–—”‡ ˆ—”ƒ…‡ —†‡” ‹‡”– …‘†‹–‹‘Ǥ Š‡ …Šƒ” ‹• „—”‡† —•‹‰‘š›‰‡–‘•—’’Ž›‡‡”‰›ˆ‘”–Š‡’”‘…‡••ǤŠ‡‡ˆϐŽ—‡–‰ƒ•‡•ƒ”‡–Š‡–”‡ƒ–‡†™‹–Š•–‡ƒ‹ƒŠ‹‰Š –‡’‡”ƒ–—”‡ˆ—”ƒ…‡–‘’”‘†—…‡˜ƒŽ—ƒ„Ž‡‰ƒ•‡•ȋŠ›†”‘‰‡ǡ…ƒ”„‘‘‘Ǧ‘š‹†‡ǡ‡–…ǤȌˆ‘”–Š‡”ƒ™ƒ–‡”‹ƒŽ• ‹…Š‡‹…ƒŽ‹†—•–”‹‡•ǤŠ‡•Žƒ‰‘ˆ–Š‡”‡•‹†—‡‹…‹‡”ƒ–‹‘‹•—–‹Ž‹œ‡†–‘”‡…‘˜‡””ƒ”‡‡–ƒŽ•ǡ‡–…Ǥ C.3 Use Š‡‰ƒ•‡•”‡…‘˜‡”‡†ƒ”‡—•‡ˆ—Žƒ•ƒˆ‡‡†•–‘…–‘ƒ—ˆƒ…–—”‡ƒ‘‹ƒƒ†‘”‰ƒ‹……Š‡‹…ƒŽ•Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,`- © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Annex D ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of reduction agent in blast furnaces › ‘”‰ƒ‹… ƒ–‡”‹ƒŽ• ‹…Ž—†‹‰ ’Žƒ•–‹…• ƒ† „‹‘ƒ••Ǧ„ƒ•‡† ƒ–‡”‹ƒŽ• …ƒ „‡ —•‡† ˆ‘” ”‡†—…–‹‘ ƒ‰‡–‹„Žƒ•–ˆ—”ƒ…‡•Ǥ•‡†’ƒ…ƒ‰‹‰‹•ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••ǡ‹ˆ‘Ž›‹–‹• …‘ŽŽ‡…–‡†Ȁ•‘”–‡†Ǥ‘‹‰Ž‡†ƒ†•Ž‹‰Š–Ž›…‘–ƒ‹ƒ–‡†—•‡†’ƒ…ƒ‰‹‰…ƒƒ’’Ž›ˆ‘”–Š‹•’”‘…‡••Ǥ D.2 Process  –Š‡ …‘˜‡–‹‘ƒŽ •–‡‡Ž ’”‘†—…–‹‘ ’”‘…‡••‡•ǡ …‘‡ ‹• —•‡† ƒ• ƒ ”‡†—…–‹‘ ƒ‰‡–Ǥ Š‡ ‹†—•–”‹ƒŽ ’”‘…‡••‡•ƒ”‡‡•–ƒ„Ž‹•Š‡†–‘”‡’Žƒ…‡…‘‡–‘—•‡†’ƒ…ƒ‰‹‰Ǥ–›’‹…ƒŽ’”‘…‡••‹••Š‘™‹ ‹‰—”‡Ǥͳ Incineration Absorption Washing Gas Used packaging (Source material) PVC sorting PVC De-chlorination Solid Other materials Shredding Classifying Recovered HCl Blast furnace gas Blast furnace Power generation Steel Figure D.1 — A typical process to use used packaging as reduction agent in blast furnace Š‡—•‡†’ƒ…ƒ‰‹‰‹••‘”–‡†–‘”‡‘˜‡ƒ†‘–Š‡”…‘–ƒ‹ƒ–•Ǥ•‘”–‡†‹•–”‡ƒ–‡†‹ƒ”‘–ƒ”› ‹Ž™‹–Š…‘‡–‘”‡‘˜‡…ŠŽ‘”‹‡ǤŠ‡‰ƒ•‡•‰‡‡”ƒ–‡†‹–Š‡”‘–ƒ”›‹Žƒ”‡‹…‹‡”ƒ–‡†–‘”‡…‘˜‡” ŽǤ Š‡•‘Ž‹†ȋ…‘‡ƒ†…Šƒ”Ȍ‹•—–‹Ž‹œ‡†ƒ•ƒ”‡†—…‹‰ƒ‰‡–‹„Žƒ•–ˆ—”ƒ…‡•Ǥˆ–‡”•‘”–‹‰‘—–ȋ‘–Š‡” ’Žƒ•–‹…•Ȍǡ–Š‡—•‡†’ƒ…ƒ‰‹‰‹••Š”‡††‡†ƒ†…Žƒ••‹ϐ‹‡†–‘—•‡ˆ‘””‡†—…‹‰ƒ‰‡–‹„Žƒ•–ˆ—”ƒ…‡•ˆ‘” •–‡‡Ž’”‘†—…–‹‘Ǥ’ƒ”–‘ˆ–Š‡•‘—”…‡ƒ–‡”‹ƒŽ•‹–”‘†—…‡†‹–‘„Žƒ•–ˆ—”ƒ…‡•‹•…‘˜‡”–‡†‹–‘„Žƒ•– ˆ—”ƒ…‡‰ƒ•ǡ™Š‹…Š‹•—–‹Ž‹œ‡†ˆ‘”’‘™‡”‰‡‡”ƒ–‹‘Ǥ Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - D.1 Material ISO/TR 16218:2013(E) Annex E ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of raw material for coke manufacturing E.1 Material › ‘”‰ƒ‹… ƒ–‡”‹ƒŽ• ‹…Ž—†‹‰ ’Žƒ•–‹…• ƒ† „‹‘ƒ••Ǧ„ƒ•‡† ƒ–‡”‹ƒŽ• …ƒ „‡ —•‡† ˆ‘” ”ƒ™ ƒ–‡”‹ƒŽ ˆ‘”…‘‡ƒ—ˆƒ…–—”‹‰Ǥ•‡†’ƒ…ƒ‰‹‰‹•ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••ǡ‹ˆ‘Ž›‹–‹• …‘ŽŽ‡…–‡†Ȁ•‘”–‡†Ǥ‘‹‰Ž‡†ƒ†•Ž‹‰Š–Ž›…‘–ƒ‹ƒ–‡†—•‡†’ƒ…ƒ‰‹‰…ƒƒ’’Ž›ˆ‘”–Š‹•’”‘…‡••Ǥ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - E.2 Process Š‡‹†—•–”‹ƒŽ’”‘…‡••‡•ƒ”‡‡•–ƒ„Ž‹•Š‡†–‘’ƒ”–‹ƒŽŽ›”‡’Žƒ…‡…‘ƒŽ–‘—•‡†’ƒ…ƒ‰‹‰ˆ‘””ƒ™ƒ–‡”‹ƒŽ‘ˆ …‘‡ˆ—”ƒ…‡•–‘’”‘†—…‡…‘‡Ǥ–›’‹…ƒŽ’”‘…‡••‹••Š‘™‹Figure E.1 Used packaging (Source material) PVC & metal removal Agglomeration Carbonation in coke oven Hydrocarbon oil, 40% of plastics Chemical feedstock for plastics, etc Coke 20% of plastics Blast furnace (Reducing agent) Coke oven gas, 40% of plastics Power generation, etc Coal Figure E.1 — A typical process for utilization as a raw material for coke oven Š‡ —•‡† ’ƒ…ƒ‰‹‰ ‹•ǡ ƒ– ϐ‹”•–ǡ •‘”–‡† –‘ ”‡‘˜‡  ƒ† ‡–ƒŽ•Ǥ ‘” •‘‘–Š ‘’‡”ƒ–‹‘ ‘ˆ ‡ƒ†‡”ǡ ‡–ƒŽ••Š‘—Ž†„‡”‡‘˜‡†„‡ˆ‘”‡‡ƒ†‹‰ǤŠ‡—•‡†’ƒ…ƒ‰‹‰‹•–Š‡‹–”‘†—…‡†‹–‘ƒ‡ƒ†‡”–‘ ˆ‘” ƒ‰‰Ž‘‡”ƒ–‡•Ǥ Š‡ ƒ‰‰Ž‘‡”ƒ–‡• ƒ”‡ ’—– ‹–‘ ƒ …‘‡ ‘˜‡ ™‹–Š …‘ƒŽǤ Š‡ ƒ‰‰Ž‘‡”ƒ–‡• ‘ˆ —•‡† ’ƒ…ƒ‰‹‰ƒ”‡…ƒ”„‘‹œ‡†‹‹‡”–…‘†‹–‹‘–‘ˆ‘”…‘‡ǤŠ‡†‡…‘’‘•‡†‰ƒ•ƒ†‘‹Žƒ”‡—–‹Ž‹œ‡†ƒ• ˆ—‡Žˆ‘”’‘™‡”‰‡‡”ƒ–‹‘‘”…Š‡‹…ƒŽˆ‡‡†•–‘…ˆ‘”’Žƒ•–‹…•ǡ‡–…Ǥ © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ISO/TR 16218:2013(E) Assessment checklist — suitability for chemical recovery process Documentation No: ƒ…ƒ‰‹‰‹†‡–‹ϐ‹…ƒ–‹‘ǣ Part(s) of packaging intended for chemical recovery: Intended chemical recovery process: Intended process output/use: F.1 Assessment Description of intended chemical recovery process Describe process, e.g schematic over˜‹‡™ǡϔŽ‘™…Šƒ”–ǡ‹’—–ȋ•Ȍƒ†‘—–’—–ȋ•Ȍ Requirements for collecǦ tion and sorting List requirements, e.g needs to be collected in certain material fraction, ‹†‡–‹ϔ‹…ƒ–‹‘‹•‘”–‹‰ǡ‡–…Ǥ ‡•…”‹„‡Š‘™”‡“—‹”‡‡–•ƒ”‡ˆ—Žϔ‹ŽŽ‡† Chemical recovery process Accepted materials, need for pre-treat- ‡•…”‹„‡Š‘™”‡“—‹”‡‡–•ƒ”‡ˆ—Žϔ‹ŽŽ‡† requirements ment/processing, detrimental materials, contaminations, etc 4.Conclusion of suitability assessment Suitable / not suitable Documentation No: ƒ…ƒ‰‹‰‹†‡–‹ϐ‹…ƒ–‹‘ǣ Part(s) of packaging intended for chemical recovery: Intended chemical recovery process: Intended process output/use:  –Š‡ Ž‹‰Š– ‘ˆ –Š‡ ƒ••‡••‡– ”‡•—Ž–• ”‡…‘”†‡† ƒ„‘˜‡ǡ –Š‹• ’ƒ…ƒ‰‹‰ ‹• ‹ …‘ˆ‘”‹–› ™‹–Š –Š‡ ”‡“—‹”‡‡–•‘ˆ Ȁͳ͸ʹͳͺǤ ‡–ƒ‹Ž•‘ˆ–Š‡•—’’Ž‹‡” ƒ‡ǣ Title: ”‰ƒ‹œƒ–‹‘ǣ ƒ‹Ž‹‰ƒ††”‡••ǣ ‹–›ǣ         ‘—–”›ǣ ƒ–‡ǣ         ‹‰ƒ–—”‡ǣ 10 Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS © ISO 2013 – All rights reserved Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - Annex F ȋ‹ˆ‘”ƒ–‹˜‡Ȍ ISO/TR 16218:2013(E) Bibliography ȏͳȐ ͳ͹ͶʹʹǡPlastics — Environmental aspects — General guidelines for their inclusion in standards ȏʹȐ –ƒŽ›Ǧ ͳ͵ʹͷ͸Ͳʹ ǡPlastic raw-secondary materials — Blends of heterogeneous plastics based ‘’‘Ž›‘Ž‡ϔ‹•ˆ”‘‹†—•–”‹ƒŽ”‡•‹†—‡ƒ†Ȁ‘”ˆ”‘’‘•–…‘•—‡”ƒ–‡”‹ƒŽ•–‘„‡—•‡†ˆ‘””‡†—…‹‰ ’”‘…‡••‡•‹„Žƒ•–ˆ—”ƒ…‡Ȅƒ”–ͷͽǣ‡“—‹”‡‡–•ƒ†–‡•–‡–Š‘†•ȋ—†‡”†‡˜‡Ž‘’‡–Ȍ ȏ͵Ȑ –ƒŽ›Ǧ ͳ͵ʹͷ͸Ͳʹ ǡPlastic raw-secondary materials — Blends of heterogeneous plastics based ‘’‘Ž›‘Ž‡ϔ‹•ˆ”‘‹†—•–”‹ƒŽ”‡•‹†—‡ƒ†Ȁ‘”ˆ”‘’‘•–…‘•—‡”ƒ–‡”‹ƒŽ•–‘„‡—•‡†ˆ‘”…‘˜‡”•‹‘ ‹–‘Ž‹“—‹†ƒ†Ȁ‘”‰ƒ•ˆ—‡ŽȄƒ”–ͷ;ǣ‡“—‹”‡‡–•ƒ†–‡•–‡–Š‘†•ȋ—†‡”†‡˜‡Ž‘’‡–Ȍ ȏͶȐ ǡ‘˜‡”–‹‰™ƒ•–‡’Žƒ•–‹…•‹–‘ƒ”‡•‘—”…‡Ǥ‘’‡†‹—‘ˆ–‡…Š‘Ž‘‰‹‡•ʹͲͲͻ ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - 11 © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST ``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` - ISO/TR 16218:2013(E) ౧ͷͷǤͲʹͲ ”‹…‡„ƒ•‡†‘ͳͳ’ƒ‰‡• © ISO 2013 – All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO No reproduction or networking permitted without license from IHS Licensee=University of Alberta/5966844001, User=sharabiani, shahramfs Not for Resale, 11/30/2013 22:33:40 MST

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