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I NGHIEN CCru l/ Hien trang o nhiem mui tCrmpt so nganh cong nghiep dien hinh va de xuat cong nghe xurly I NGUYEN TH| THANH P H U O N G , NGUYfiN VAN PHUOiC Vten Moi TrUdng vd Tdi Nguyen, DHQG TP HCM[.]
l/ I NGHIEN CCru Hien trang o nhiem mui tCrmpt so nganh cong nghiep dien hinh va de xuat cong nghe xurly NGUYEN TH| THANH P H U O N G , NGUYfiN VAN PHUOiC Vten Moi TrUdng vd Tdi Nguyen, DHQG TP.HCM I nhiem mui Id dgng nhiem khong khirdtphUc tgp miii dUdc tgo tit si/ket hgp hdng trdm hgp chdt khdc dndng rdt thdp nhiem miii dugc ddc biet quan tdm vi ddc trUng miii hdi cua no, khd ndng tdc dgng den sUc khoe ngUdi, vd khd ndng phdt tdn tren dien rdt rgng.Viecxdc djnh nguon goc vd thdnh phdn chdt nhiem Id rdt quan trgng detUdd de xudt cdc cong nghe xit ly phit hgp DUa tren ket qud dgc miii phdt sinh tUcdc ngdnh cong nghiep bien d Viet Nam nhU thugc da, che bien mu cao su vd sdn xudt thUc dn chdn nuoi vd hogt dgng chdn nuoi heo Bdi bdo ndy trinh bdy ket qud dgc ndng cua cdc chdt gdy miii ddc trUng cm cdc ngdnh cdng nghiep ndi tren Tren ca sd tong quan cdc cdng nghe xvfly vd ddnh gid cdc Uu nhugc diem, bdi bdo dexudt cdng nghe Igc sinh hgc Id phii hgp nhdt cho xufly mui I dor pollution is a complex I t y p e of air pollution due to its " combination of hundreds of odorous compounds with very low concentrations Odor pollution is particularly concerned because of its impact on human health and the ability to spread over a wide area Determination of pollution sources and odor pollutant composition is very importants in order to find out appropriate odor treatment technology Based on monitoring results of typical industries such as tannery, rubber latex, animal feed and livestock, this report presents analytical results of odor compounds as well as assesses the advantages and disadvantages of different odor treatment methods Among these methods, biological technology is selected as an optimum solution to treat air pollution GlCfl T H l £ u nhiem mui ddpe die biet quan tim die tinh mfli hdi inh hddng din sUc khde ngfldi vi nang phat tin tren diln rdng cfla nd Cac inh hddng cip tinh den sdc khde d nhiem mui nhd cay mat, nhdc diu, di flng da, van dl ve ngfl di dflpc bao cao Mat khac, d nhilm mui cd the phit tin tren dien rdng b mflc dp dja phddng hoae khu vde nhiem mui cd the mdt hpp chat bay hdi riing le hay, chiem phan Idn, li mpt hdn 48 M d i trddng So 12/2015 hdp cua nhilu hpp ehit Mac du ehit d nhiem mui thdng thddng cd ndng dp rat thap, nhflng mui ngfldi rat nhay cam, vi dy nbd ngddng raui ddi vdi chat thii thdng thddng ma mui ngddi cd thi xac dinh ddpe la 0,00001 ppm, va cd kha nang phan bilt den hdn trieu mui khae Mat khae, eic tilu chuan va hfldng dan dl danh gii d nhiem mui hiln edn thilu vi rat khic Do vay vi|c xac dinh ngudn gdc phit sinh mui vi dac ndng dp mui rat khd khan Theo nghiin edu eua Joji Fukuyama ngudn phit thii mfli bat ngudn tfl boat ddng sin xuat cua cic logi hinh cdng nghiip khac nhau, phu thudc vio quy md phat triln, edng nghe sin xuit va die tinh ngudn thii Tuy nhiin, gia tri cua cic thdng sd nhd thinh phan mui, ndng dp raui, nhilt dp, Iflpng thai ed the thay ddi pham vi rdng Bang trinh bay nong dd mui cfla mdt sd ngudn thii tai Nhit Ban Trong san xuat edng nghiip, mui ed the phat sinh tfl nhilu ngudn khic bao gdm: hdi Mui tfl nguyin heu san xuit cua cic nganh chi bien thuy hai sin, cao su, hot tdm, hda chat cd ngudn gdc tU nhiin hoic nhan tao Cac nguyin lieu bin thin da co raui die trflng hoae phat sinh raui sfl phin hfly cac hdp chat hflu cd qui trinh van chuyin, Iflu trfl Mui tfl qua trinh sin xuat cdng nghiip Trong qui trinh san xuat, mui bda chat, phu pham hoic mui hflu ca phat sinh cdng doan say, chflng eit Mui sinh td he thong xfl ly nddc thii bay bdi va lln raen sinh hpe tai khu vdc cae bl: thu gom, dieu hda, tach diu md, lang xfl Iy ky xfl iy hieu va xd ly bim Thinh phan nhilm giy mui thddng chfla nhom eic chat gay mfli ed kha nang de dinh Idpng dddi dang vd cP nhd araraoniac, bydrosulfua hay nhdm cic chat hflu cd nhd thudc bio vl thdc vit, dung mdi hflu cd (metan, butan, benzen, xylen, xielohexanon, toluen ) hoae nhdm cac chat rat khd dinh Iflpng, bay hdi d dilu kiln nhiet dp thddng nhd VOC (gdm nhilu chat hdu cd bay NGHlfiN CUU Wn Bang I Phan Ioai ngudn nhilm mui theo phin hdi mi diln hinh la nhdm eae chat thupe nginh edng nghiip sin xuat thdc phim (mui gia vi), my pham Cho den hiln nay, cdng ngh| xfl Iy mui van cdn Ii van de ton tgi d nddc ta Viec Ida ehpn quy trinh edng nghl xfl ly mui phai dap dng dflpc yiu eau ve tinh ning ky thuit va chi phi xfl Iy Do viy, mdt quy trinh xfl ly vdi sfl kit hdp nhilu phfldng phap khic dflpc de xuat Bai bao niy trinh bay tdng quan ngudn gdc phit sinh mui tfl mdt sd nganh edng nghiip biln d phia Nam Viet Nam nhfl edng nghiip thudc da, chi biln thfle in chin nudi, sin xuat cao su, va ehan nudi Dfla tren die dilm phit sinh mui cua cae nguon thii, cic cdng nghl xfl If thich hdp dfldc gidi thieu Uu nhddc dilm eua cie cdng Tigbl niy cung ddpe phan tieh, danh gia va so sanh Vit lieu va phfldng phap nghien cflu 1.1 Doi tiidngnghiin ctiu Ddi tddng nghien eflu gdm cic nginh edng nghiip phit sinh mui hdi Idn nhfl cdng nghiep thuOe da; ehan nudi; cbl biln cao su vi sin xuat thfle an chan nudi 1.2 PhUdngphdp nghien citu Khio sit quy trinh cdng nghl san xuat tai mpt sd cd sd san xuat cfla cac nginh cdng nghiip dddc liia chpn, qua dd danh gia nguon gdc phit sinh mui hdi, tai Ifldng d nhiem Ung vdi moi loai binh edng nghiep, tien hinh lay mau va phan tieh phan kbi thii eua nha miy vdi sd lin lip lgi Ii Ian Ket qua phan tich li cd sd dl nhan dang tdng thi eie thinh phin gay mfli hdi vi dinh gia dflpe mflc dp d nhiira trin tdng Ioai hinh cdng nghiep dgc trflng Nghiin cdu dda dinh hddng edng nghl xfl Iy vi giara thieu d nhilm mui ebo eie loai binh cdng nghiip tddng flng 1.3 PhUdng piidp phdn tich Cic ehi tieu phin tieh phu thupe vio tflng loai hinh cdng nghiip Kit qua nghien cflu 2.1 NguSn phdt sinh miii Kit qua quan trie d nhilm mui phat smh td rat nhilu nhi miy sin xuat tgi phia Nam Viet Nara dflpe thfle hiln bdi Viln Mdi trddng va Tii nguyen vi dddc phin Ioai theo eie nginh edng nghiip nbd sau 2.1.] Ngdnh cong nghiep thugc da Hau hit cie nhi miy thupe da ddpe khao sat diu d nhiem mui vdi nong dp kha cao Khi thai phit sinh tfl cdng doan hdi tddi, tay Idng, Nginh ngli£ (Nguon phit tM*) I Nha may bot giSy, nha may xCr 1]^ bun t l / : hoai, nha may xisl'ji nUdcth^i, nha mSy cao su, bai rSc Hopch^diila liAihir/nh Co sd phan compost nha miy ch4 bi&i c^, nha may xil ly biin XU hoai, trang trai gia I Ammonia, , TrimelhylAmi ' 1bluen& Xylene, I EthylAcetate ' Nh3may5an,nh^maydieuldijc,giat0i, < nha miy san xuSt keo, nha m i y van §p, cOa hang sCi3 chCla oto, nha may sin xuat nfii i Nha mSyma kim loai, nhS may diic, m j OfFset.son xe m^y I Trang trai gia cam, cCsa hang thii nuoi, nha I maysSnxuattinh b6t ngam vdi, tay vol, Iam mem, hoin thiln qui trinh phin buy eae chat hflu ed, protein tao NH^, H^S, eie hpp chat chfla mtd, Iflu huynh va VOC Ben canh dd, he thdng xfl Iy ndde thai eung la mdt cac ngudn gay d nhilm phit tin vao mdi trddng eac kbi cd mui hdi, khd chiu die bilt Ii tai eie khu vflc: be dieu hda, be tich md vi giai doan xd Iy yem Bang trinh biy kit qui quan trie eac chat d nhiem mfli td mdt sd nhi miy thudc da Kit qua khao sat tai eac vi tri phit sinh thii giy mui tai cd sd cho thay, ndng dp dac mie du nim gidi ban cho phep theo Tilu chuan vl sinh lao dpng cua Bd Y te nhflng eao hdn rat nhieu so vdi ngddng nhin bilt mui Ndng NH^ vi H^S theo kit qui dge ed gia tri dao dpng khoang tfl 1862.120 pg/m^vi81-1.120pg/m^ VOC ghi nhan phat sinh nhilu khau hoin thiln vi trau chudt, ndng dp dddc lln din 1.980[ig/m' So sanh vdi ngddng mui ed the chap nhin ddpe thi ndng HjS vdpt lln din hing nghin Ian Bang Cac hdp chat nhiem mui va ndng tai mdt so nhi miy thupe da ' I I 'Chata; _ _ _ K h a ^ l g y , l ^ "_^ ^ ~ ^ ^ s ~ T V Hoin Betach Beky | m f i i c d t h i | 3733^002/ i I md chap nhin QQ-BYT ; trau Ira' ' long (XLNT) (XLNT) lM9/m^) < iMlm') chugt 1.776 25.000 H.S 11120 184 0,474 _LQ2_ 492 I mui I Tay "'^'^ i Lia ; '^^y' nioc I Nha 876 790 216 Nguon: Phong thi nghiem Phdn tieh vd ky thudt cong nghi Vien Moi trUdng vd Tdi nguyen (2014-2015) 2.1.2 Ngdnh che biin mu eao su O nhilm mui tfl nginh chi biln mu eao su dang rit driac quan tara hiln Hiu het eie nhi may cbl biln mu cao su diu bi khilu kiln vi phat sinh mui hdi Cie hpp So 12/2015 M d i t r d d n g 14 I NGHIEN CUU chit d nhiem mui die trdng cua nganh ehe bien mu cao su Ii NH3, H^S, CH^OH vi axit beo bay bdi (VFA) Ddi vdi cie nhi may ehe bien cao su com, mui hoi bat ngudn tii sfl phin huy sinh hpe eic hpp chat hflu cd thdi gian Idu trd nguyen lieu hoic phin buy nhilt qui trinh ehe bien Cie nghiin cflu gin day nhat dflpc cdng bd bdi Vipavee vi cdng sfl (2003) cho biet, mui ddpe phin biet gifla cic dang cao su rin va cac axit beo cd trpng lddng phan tfl thap (Cj-Cj) Bing trinh biy ket qua dac cic chat d nhiem mui tfl mdt sd nhi may cbl bien mu cao su tilu bieu tai Viet Nam Kit qua cho thay, mac du ndng cic d nhiera mui diu nim gidi han eho phep cua TCVS 3733:2002/QD-BYT Rieng thdng sd VFA hien van ehfla ed quy chuan quy dinh gia tri tdi da cho phep thai vao mdi trddng Ndng dp NHjVa H^S khoing tfl 70540 ng/m' vi21-100 ng/m\ Khu vflc dinh ddng va say mu li khu vde cd ndng dp eac hpp chat giy mui cao nhat Khi so sanh vdi ngddng mui cd the chap nhin ddpe thi H,S vdpt ngfldng lln din 210 Ian cdn NH3 nim gidi han cho phep 2.1.3 Ngdnh chdn nudi nhiem mfli chin nudi gia sue phat sinh ehu yeu tfl khu vde chudng trgi, b | thdng mdong thoit nfldc thii eye bp, nha chfla phin vi khu xd ly chat thii (bl biogas, hara lang, b | thdng xd ly nddc thii, hd Idu chda) vdi sd hi|n diln eua eac khii bao gdm: NH^, H^S, mercaptan, VOC tfl hai ngudn dac trdng li nfldc thii vi phin Aramoniac vi eie amin de bay hdi la eac hpp chat nitd chinh ddde sin sinh thdi gian Idu trfl chat thai Khi protein vi axit amin ddpe sfl dung nhfl mpt ngudn nang Iflpng cho qui trinh khfl amin se lim phit smh ammoniac (Aarnink, 1997) theo phin dng: CO(NH^), + Hfl -»• 2NH/ + OH" + CO,=: NH, + H p + COj Trong dilu kiln yem khi, cac amin de bay hdi thfldng ddpe sin xuat tfl eie sin pham chfla protein Bang trinh biy kit qui dgc cic chat d nhiem mui tfl mdt sd cd sd chin nudi Ndng NH,, H^S va mercaptan Ian Ifldt dao ddng Ii 12280 |Jg/m^ 8-54 ng/m' va 8-58 jig/m^ Mui phit sinh tai khu vflc eie chudng nudi Ii Idn nhat Mgt khic, so sinh vdi ngfldng mui cd the chap nhan ddpe thi H^S vi mercaptan cd ndng vdpt ngfldng lin Ifldt la 17-113 lan vi 100-700 Ian OIMOI t n i d n g s612/2015 Bang Cic h^p chat nhiim mid va nong tai mot s6 nha miy che bien mu cao su Khu VlTc lav mai _ ^ ChSto nhiem miiMl>g/ m') NH, H.S may VFA NH, H.S may VFA NH, Nha H^S may VFA NHj Nha may VFA Nhi may DAnh d6ng 90 62 — 490 50 55 380 55 Canmi> Saymu thong XLNT 380 90 130 60 70 50 11 38 25 170 70 320 30 60 90 40 10 37 243 100 150 21 43 30 34 49 127 300 90 , 42 51 85 41 38 30 TCVS NgiTdng mill c6 thi 3733:2002/ chap nhAn QO-BYT Itiq/m') 776 0,474 15 000 1.776 0.474 15.000 1.776 0,474 25.000 15.000 0,474 15.000 Ngudn: Phong thi nghiem Phdn tich vd ky thudt cdng ngh& Vien Moi trUdng vd Tdi nguyin (2014) Bang Cic hdp chat nhiem mui va nong dO tai mpt sfi cdsdehannudi ^ Chlte^" ""^ ," Khujtfclgymau mui Chu«ng Chu6ngj thu (M/ I nu6ll nu6i2 chat m') miy H^S CH^SH CH'SH N h i NH miy H,S CHjSH Nha • NH, CH'SH 280 38 17 56 11 21 210 34 25 131 41 24 48 41 24 12 15 154 19 31 172 26 15 thai 71 27 31 136 54 58 120 47 53 109 52 29 ^ J Ngifdng [ j^.^^ _ , ^ | H3m thechJp „_gy^ J'^p^^ | "'"^^ | , S , j mg/m') K32 33 28 56 24 37 25 24 22 28 33 10 llig/m') 23 1.776 35 0,474 ' 0,083 20 1,776 63 0,474 16 22 0,083 53 1.776 0,474 39 13 _0,083 776 16 0,474 21 0,083 25.000 15.000 2.000 25.000 15.000 2.000 25.000 15 000 2.000 25.000 15.000 2.000 Nguon: Phong thi nghiem Phdn tich vd ky thudt cdng nghi Viin Mdi trUdng vd Tdi nguyen (2014) 2.1.4 Ngdnh chebien thUc dn chdn nuoi nhilm mui td nginh cbl bien thdc an chin nudi la van dl mdi trddng ndi edm thdi gian gin diy Trong qua trinh sin xuat tai nhi miy, eae thinh phan nguyen Ueu cd the bi biln tinh vi tao eie chat gay mui khd ehiu O nhiem mui hdi tfl nganh la ban thin eic nguyen heu nhd khd dau ninh, khd dau hat eii, bi dau phdng vi bdt ddng vit thuy san (bdt ei, bdt vd tom ) di cd mui die trflng Trong qui trinh cbl biln thdc an chin nudi se phit sinh mfli hau bit cic cdng doan nhfl nap Ii|u, trpn sd bp, ep, say, ddng bao Tuy nhiin ngudn phit sinh Idn nhat li td cdng doan say Khi cd mui bao gdm hydrogen sulfide (H^S), methylamine (CHjNH^), trimethylamine [(CH3)3N] va mercaptan Bing trinh bay ket qui quan trie rapt sd hpp chit gay raui cic nhi miy cbl biln thfle in chan nudi Ndng dp NHj, H^S va mercaptan cd gia tri khoing 50-6.100 pg/m^ 541.324 pg/m' vi 53-670 pg/m^ So vdi ngfldng mfli cd thi chap nhin dflpe thi ndng dO H2S va mercaptan tai cac nhi miy cbl bien thfle i n vflpt kha cao Trong dd, H^S vflpt 1002.000 Ian, mercaptan vflpt 550-8.000 Ian NGHIEN ctru K m Bang Cae hdp chat nhiem mfli vi nong dp tai mpt s6 nha may ehi biln thufc an chan nuoi Khu vUc l^y mau mill [pg/m^l Nhi miy Nha may Lim trii'nguyen lieu * = Epviin H I t h £ n g XLNT Say th£ chip nhin (ng/m'i " TCVS 3733:2002/ QO^YT (|ig/m') NHj 80 170 230 50 776 25.000 H^S 850 1.050 1.200 45 0,474 15.000 350 47 0,083 2000 6.100 170 1.776 25.000 760 140 0,474 15.000 CH^SH 110 NH, 1-520 H,S 815 CH,5H 148 780 59 0,083 2.000 NH, 1.230 5.210 104 1.776 25.000 H,S 430 1 029 85 0,474 15.000 CH.SH 124 520 84 0,083 2.000 ! Nguon: Phong thi nghiem Phdn tich vd ky thudt cong nghe- Vien Moi tnidng vd Tdi nguyen (2014) 2.2 Cong nghe xH ly nhiem miii HI thdng xfl Iy phii dat dflpe hilu qui giim thilu d nhiera mui den bing hoic thap hon yiu cau vi hoic tilu chuan cho phep Do viy vile Ida chpn cdng nghl xd ly phii hddng den toi du hda vl yiu cau hi|u qua xd ly, gii thinh vi tinh kha thi cua edng trinh Thdng thfldng thi vile kit hpp cac phfldng phap xfl ly khae se mang din hilu qua cao hdn Dfla vao dac diem ngudn d nhiem, yiu eau hilu qui xfl ly vi kinh phi eho vile xiy dflng va vgn banh he thdng xd Iy, quy trinh xfl ly kit hpp eae phflong phap vdi dfldc dl xuat de dgt dfldc hilu qua toi flu Cdng nghl xfl Iy mul dfldc xae dinh dfla tren phan, ndng dp cac chat tao mfli vi Idu Idpng phit thii theo quy md Idn, trung binh va nhd Kit qui tdng hpp phddng phap xd Iy theo quy md phit thii ddpe trinh bay dfldi day: Phfldng phap lpc sinh bpc cd ning dng dung d mpi ngudn thii vdi ldu Idpng thai tfl thap lln din trin 12.000 mVphut, phddng phip rda va ddt cd the xfl ly mui d quy md tnmg binh vdi Iflu Iflpng thii nho hdn 10.000 m'l phut Phfldng phap ngflng ty vi hap phu cd kha nang xfl Iy mui hilu qui vdi ngudn thai cd Iflu Ifldng nhd hdn 3.500 mVphut Tuy nhien, xem xet cdng nghl, ndng dp thii phii dflpc dgc bi|t quan tim, vdi ndng dp d nhilm thap (nhd hdn 250 ppmv) thi phddng phip hip phu vi rfla dat hilu qui cao xfl Iy raui; ngudn thii ed ndng d nhiem cao (250 den 1.000 ppmv) thi phfldng phip dot va ngdng tu dddc sfl dyng phu hdp hdn Luu IVQ^g khi(^ffift^/mm.) 10 10 120 {30 Ndng d$ (ppmv) 140+ |o 111111111 HAP PHU ^ ^ |230 |50D ^ ^ ^ ^ ^ |730 11000 HAPPHU NGUNGTU Cudi cung, phfldng phap Ipc sinh hpe van li phdong phip tdi du vi cd ning xfl Iy mui d khoang nong dp dao dpng rdng (0-1.000 ppmv) Tren thdc te, kha nang va gicti ban xd Iy cung nhfl chi phi dau td va van hinh hi thdng cua tflng Ioai edng nghl eung dddc xem xet d bing va bang Bang Die diem cua cic cdng nghe xfl ly mui Hathgng KhA ning v i gifll han xi!f ty j Hieu q u i vdi cac H,S (95%), NH^ (80%) va ' cac h ^ chat mCii hCfu co nhi/mercaptan Hieu q u i v6i H,S va hap chat mui Sulfur : Hap phu b i n g than hoat tinh Hieu q u i vdi d6ng c6 nong nhiem thap Khong hieu qua voJ NH, I Hap thu vat lieu dem hoac phun suong rong Hieu q u i vdi hydrogen sulphide, mercaptan, I cac lUu huynh huU co, ammonia, cac I hap chat nito hCIu ca nhu cic amin, axit hcru | CO, d o vJ cic hop chat I Chat hCiu ca bay hoi Khong hieu q u i vdi nhiem cd chii^ N va S c6 k h i nang phat sinh SO, va NO So 12/2015 H d i t m d n g 51 ^NGHmNCCrU Bang Danh gia cic phfldng phap xfl Iy miii , HithJng Hi«u qua Nhin ehung, vile Ida ehpn quy trinh cdng nghl xfl ly mui cho tflng Ioai hinh sin xuat die trdng se phu thupe vao thinh phan thii, ldu lddng ddng khi, tinh chat ngudn thii (nhi|t dp, dp am va ndng dp d nhiem ) Do viy, mdt quy trinh xd Iy thich hpp can kit bpp nhilu phdPng phap xfl ly khic Kit luin nhiem mfli hdi phit sinh la van de dang dfldc cac nhi quan Iy mdi trfldng quan tim, die bilt Ii mui tfl eae qui trinh sin xuit edng nghiip Cie d nhilm ehinh nbd NH , H,S, amin, mercaptan, VOC, Von dau I Van hanh tn vabAol VFA suih td qua trinh phin buy ehit hflu eO, Ien men ki vi bay bdi nguyen vit heu, phu gia boat dpng sin xuat Mpt sd loai hinh cdng nghiep die trflng nhfl thupe da, ehe bien cao su sd chi, chin nudi gia sue, che biln thfle an ehan nudi di phit sinh raui vdi tii Idpng cao, giy inh hddng ding kl din mdi trddng vi eip thiet phii cd giii phip xfl Iy phfl hpp Vile Ida chpn edng nghl xfl Iy mfli can xet din die dilm vi phan cua tflng ngudn phit thii mui vi kinh phi dau tfl Hiln nay, nhilu ky thuit xd ly mui di dflpc flng dung phd bien nhd oxy hda, hap thy, hap phu va phfldng phap lpc sinh hpc Tuy nhiin, tinh kha thi cua giai phip eong nghl yeu cau chi phi dau tfl, van hanh thip, tinh on dinh vi hilu qua cfla he thdng xflly Do tinh phdc tap cua thinh phan cie chat giy mui nen ky thuat xfl ly mui kit hpp nhilu phdPng phap khic ddde khuyin cio ap dung Trong dd, phfldng phip sinh hpc eho phep xfl Iy d eic khoing Idu lddng vi ndng dp dao dpng Idn cdn phddng phip hip phu xfl Iy bilu qua VOC vi cac hpp chat sulfuaB TAI LIEU THAM KHAO V Morgan, B, et al, Industna! odor sources and air pollutant concentrations in GlobeviHe, a Denver, Colorado neighborhood Technical paper journal of the Air & Waste Management Association, 2015 65(9) p 11271140 V Mills, B., Review of methods of odour control Filtration & Separation, 1995 32(2): p 147-146 V loji Fukuyama, Odor Pollution Control for Various Odor Emission Sources in Japan Yoshiharu Iwasaki, Olfactory measurement of odor, japan Association on Odor Environment, 2004 p}45-lS2 • Vipavee P Hoven K.R., Tanaka Y 2003 Determination of Chemical Components that Cause MalOdorfrom Natural Rubber Rubber Chemistry and Technology, 76(5), 1128-1144 • AaminkA.JA, 1997 Ammonia emissions from house for growing pigs as affected by pen design, indoor climate and behavior PhD Thesis, Wageningen, Netherlands • lanni,K.A., etal Air Quality Education in Animal Agriculture: Biofilters for Odor and Air Pollution Mitigation in Animal Agriculture D.R.LS University, Editor 2011 • Bindra, N, B Dubey, and A Dutta, Technological and life cycle assessment oforgani cs processing odour control technobgies Science of The Total Environment, 2015 527-528 p 401-412 • Hadlocon, Lf.S., R B Manuzon, and L Zhao, Development and evaluation ofafull-scaie spray scrubberfor ammonia recovery and production of nitrogen fertilizer at poultry facilities EnvironmentalTedmology, 2014 36(4): p 405^16 Mamrosh, D et at Consider improved scrubbing designs for acid gases 2008 Hydrocarbon processing(January): p 69-74 521 M d i trddng s612/201 s