Lesley-University-Chemical-Hygiene-Plan-April-2019_0

Lesley University Chemical Hygiene Plan Lesley University 1815 Massachusetts Avenue Cambridge, MA 02138 Preliminary 2.0 Issued: September 2004 Update: April 2019 July 2017 October 2008 March 2009 Lesley University EMERGENCY RESPONSE SUMMARY CAMPUS EMERGENCIES: x 8888 (MEDICAL, CRIME, FIRE/SMOKE, CHEMICAL VAPORS OR OTHER EMERGENCY) Emergency Coordinator: Andy Faulkner, 617-349-8881 Campus Public Safety: Emergency or Non-emergency, extension 8888 City of Cambridge: ambulance, police, fire, 9-911 If you discover a fire, smoke, toxic vapors, or a chemical/oil spill: R - Remove: Remove people in immediate danger without endangering yourself, then: A - Activate: Fire: Activate nearest fire alarm box (near exit), exit, & call 8888 Chemical Spill/Leak: Leave and notify Physical Plant, 8881 Provide the location C - Confine: IF YOUR SAFETY WILL NOT BE ENDANGERED: Fire: Close fire doors, windows and switch off exhaust fans Spills/leaks: Leave windows open & exhaust fans on Turn off air supply (recirculates) Plan your escape: Never permit fire to get between you and an escape route E - Evacuate: Evacuate the building (in case of fire) or the area (in case of a spill/leak) Leave via a safe fire exit NEVER use elevators in a Fire Only use the stairs R.A.C.E.: If smoke, flames, toxic vapors, or any other emergency is discovered: Leave the area, call Public Safety, 8888, and provide information about the incident • Alarm Locations: Fire alarm pull stations devices are located throughout each building, near exits Alarm signals are located on each floor & are audible bell/siren and/or visual (strobe) & audible alarms Do not attempt to extinguish a fire, unless you have been trained to use an extinguisher • Emergency Exits: Use the primary or the closest emergency egress route unless it is unsafe Exits are equipped with illuminated exits signs Follow these exit signs to the nearest ground level exit • Assembly Areas: Use the closest egress route, if it is safe, and go to the designated assembly area or the closest, clear area that is at least 150 feet from the building Do not obstruct emergency personnel or vehicle access Account for all evacuated students, visitors, faculty, and staff Notify the person-incharge of unaccounted individuals or observations requiring further action • Special Needs: Identify those persons who may need to be alerted or assisted Provide assistance as required • Check: Quickly inspect each room in your area as you exit to ensure that everyone has been evacuated However, Do not endanger yourself! • Chemical Emergencies: It is unlikely that a chemical emergency will require a building evacuation However, if you discover chemical emergency, leave the area, secure the room, and notify Public Safety (8888) Lesley University provides trained and authorized response personnel who will evaluate the situations and take appropriate action to control the incident Evacuate all affected areas as necessary If trained and authorized to use them, chemical spill kits are available through the Chemistry and Environmental Lab, Physical Plant, and Public Safety Department Notify Physical Plant if you discover a chemical spill / leak Lesley University University Hall Cambridge, Massachusetts Emergency Response Guidelines Chemical Spill / Accident / Explosion • Notify Security at 617.349.8888 Provide location and chemical information, if known, and have someone stay on line to give additional information while emergency units are in route • Obtain Safety Data Sheet (SDS) from the Safety Coordinator for the spilled chemical, if known All SDS Sheets are kept in room 2-143 in the filing cabinet drawer marked “” • Any chemical cloud that can affect community members in their offices would very likely affect them outside in the assembly area If time is of prime importance, it may be necessary to evacuate several blocks from the building by foot If this occurs, move crosswind or upwind to avoid fumes or vapors, never downwind When appropriate, proceed to assembly areas listed below • NOTE: Do not attempt to clean up a hazardous chemical spill Physical Plant Personnel will arrange for clean up through an environmental service provider Fire Emergency • Never endanger your personal safety or the safety of others If the fire can't be readily extinguished activate the closest fire alarm pull station if available • Evacuate the building • After Evacuation, call 911 and security (617) 349-8888 Report street address, etc • Report to your designated assembly area: parking lot next to 49 Roseland St Important fire emergency issues: • Never silence the fire alarm panel • Do not use elevators during a fire alarm • Use caution when entering a fire scene (feel doors for heat prior to opening) • Always evacuate the building Regulatory Notifications Contact the Physical Plant (x 8881) to determine if regulatory notifications are required See the Emergency Contact list Evacuation Guidelines (Post in Appropriate Locations) When notified to evacuate, proceed as follows: • Alert nearby personnel of the emergency • Quickly shutdown operating equipment (e.g gas or vacuum lines) • Calmly and expeditiously proceed to the nearest exit • • • Close fire doors when exiting Leave room (e.g., office, bathroom, etc.) doors open (To permit an occupant survey.) Designated personnel should check offices, bathrooms, and other spaces while proceeding to the exit • Use the nearest exit or stairs to exit the location • Walk, not run • Inform all persons seen en-route to the exit of the evacuation notification • Upon exiting the building, proceed to the parking lot adjacent to 49 Roseland Street or move at least 150 feet from the affected location • Upon arrival at the assembly area, report to the person in charge immediately and provide critical information such as, event causes, injured employees, observations noted during exit, unaccounted people, etc • Await further instructions from the person in charge • Never leave the assembly area without authorization from the person in charge Never re-enter a building or affected area until permitted by the Shift Supervisor (Emergency Coordinator / Incident Commander) Lesley University Chemical Hygiene Plan EMERGENCY INFORMATION (Post conspicuously in the Lab and at the entrance to each Lab) Laboratory Safety Support: • D Morimoto, Chair, Natural Sciences and Math: • G Ferris, Chemical Hygiene Officer, (CHO): 9-1-617.349.8226 9-1-617.349.8296 Laboratory Technician (CHO Alaternate): • N Ryzhenko: 9-1-617.349.2396 Lesley University Emergency Contact Numbers: Cambridge Police / Fire / Ambulance Emergency Public Safety Office (Emergency & Non-emergency) Physical Plant Hospital, Emergency Medical Services: Mount Auburn Hospital (725 Concord Ave., Cambridge, MA 02138) Massachusetts General Hospital (Center for Disaster Medicine) Cambridge Hospital (Emergency Department) Ambulance Services (Professional Ambulance) 9-911 9-1-617-349-8888 9-1-617-349-8881 9-911 9-1-617-354-0546 9-1-617-726-2000 (Phone) 9-1-617-665-1429 (Facsimile) 9-1-617-665-2460 9-1-617-492-2700 Emergency / Spill Response Contractors: Clean Harbors Environmental Services Triumvirate Environmental Services Veolia Environmental Services 9-1-800.645.8265 9-1-800.966.9282 9-1-800-354-2382 Emergency Coordinators: Primary: Andy Faulkner, Director of Physical Plant: Grace Ferris, Chemical Hygiene Officer: Alternate: Chuck Goss, Assistance Director of Physical Plant: (Office) 617-349-8882 (Cell) 617-438-9312 (Office) 617.349.8296 (Cell) 617-515-2610 (Office) 617.349.8794 (Cell) 617-799-3750 Nataliya Ryzhenko, Chemical Hygiene Officer (Alternate): (Office) 617.349.2396 (Cell) 217.377.2391 Danielle Sullivan, Manager, Facilities Coordinator: (Office) 617-349-8881 (Cell) Environmental, Health and Safety Support Contact: Bob Spielvogel (Office) 617.232.5369 (Cell) 617.755.2798 Emergency Services – Business Information: • • • Cambridge Fire Department Cambridge Police Department Cambridge Emergency Management Massachusetts Department of Environmental Protection • MassDEP, Northeast Region • 24-Hour Emergency Hotline US Environmental Protection Agency (USEPA) • National Response Center (Coast Guard) • Cambridge Local Emergency Planning Committee (LEPC) • Chair: Deputy Chief Brian Gover • State Emergency Response Commission (SERC) • Massachusetts Water Resources Authority 617-349-4900 617-349-3378 617-349-4918 617-654-6500 888-304-1133 617-223-2265 800-424-8802 617-349-4918 617.894.4826 (Cell) 508-820-2000 617-305-5940 Chemical Hygiene Plan Table of Contents Topic Quick Reference Guide Emergency Information Page 1.0 Introduction 1.1 Laboratory Safety Objective 1.2 Laboratory Safety Program Purpose 1.3 Program Scope 1.4 Plan Review 2.0 Responsibilities 2.1 Responsibilities Summary 2.2 Chemical Hygiene Officer 2.3 Laboratory Instructor 2.4 Laboratory CHO 2.5 Faculty, Staff, and Students (Laboratory Personnel) 2.6 Laboratory Safety Committee 2.7 Administration 2.8 Other Lesley University Departments 3.0 Hazard Identification and Communication 3.1 Introduction 3.2 Hazard Communication 3.3 Chemicals Developed In the Laboratory 3.4 Prior Review / Approval 3.5 “Particularly Hazardous Substances” 4.0 Safety Guidelines 4.1 Introduction 4.2 General Safety Practices 4.3 Hazardous Waste Management 4.4 Safety Equipment Evaluation 5.0 Exposure Prevention and Protection 5.1 Introduction and Implementation 5.2 Fume Hoods 5.3 Safety Shields 5.4 Safety Shower and Eye Wash 5.5 Personal Hygiene 5.6 Personal Protective Equipment (PPE) 5.7 Portable Fire Extinguishers 5.8 First Aid Kits 6.0 Information and Training 6.1 Faculty and Staff 6.2 Training Responsibilities 6.3 Training Records -7- Preliminary 2.0 Lesley University Chemical Hygiene Plan April 2019 7.0 Medical Consultation and Exposure Evaluation 7.1 Medical Consultation 7.2 Exposure / Injury Response 7.3 Information Provided to the Physician 7.4 Physician’s Report 7.5 Incident Investigation and Report 7.6 Employee Exposure Determination 8.0 Hazardous Materials Security Appendices A Selection and Use of Personal Protective Equipment (PPE) B Information for Employees Using Respirators When Not Required Under [the OSHA Respiratory Protection] Standard, Appendix D to OSHA's Respiratory Protection, 29 CFR 1910.134 (Mandatory) C Hazard Communications: • Safety Data Sheets • Departmental Chemical Inventory D Safety Guide (SG) Development Outline E Prior Approval / Prior Review - Highly Hazardous Compounds Tables Peroxide-Forming Chemicals Shock Sensitive Chemicals Poisonous Gases Pyrophoric Chemicals Biologically Active Compounds OSHA “Carcinogens” OSHA Toxic and Hazardous Substances Materials Affecting Hazardous Waste Classification, (“P” listed waste) F Laboratory Safety - Student Contract G Student Training Certification H Employee Training Certification I Occupational Exposure to Hazardous Chemicals in Laboratories, OSHA, 29 CFR 1910.1450 J Health and Safety Technical Resources - Electronic -8- Preliminary 2.0 Lesley University Chemical Hygiene Plan April 2019 1.0 Introduction 1.1 Laboratory Safety Objective Lesley University (LU) is committed to providing a safe and healthy laboratory environment for students, staff and faculty and will comply with governmental safety and environmental regulations Laboratory personnel, faculty, staff, Lesley University administration, students, and resource partners share responsibility for minimizing risk of exposure to safety and health hazards associated with the laboratory environment Lesley University expects each individual working in a laboratory to take appropriate precautions, utilize available control measures, and obtain necessary information to identify and control laboratory hazards These actions must be applied during routine, non-routine and other laboratory activities not specifically addressed in this document 1.2 Laboratory Safety Program Purpose To facilitate employees and students safety while working in their laboratories, LU has developed and implemented a comprehensive Laboratory Safety Program The purpose of this program is to provide laboratory faculty and staff with technical guidance and systems to evaluate hazards and apply appropriate control measures to limit exposure to hazardous chemicals thereby mitigating the risks associated with work in an academic laboratory The Laboratory Safety Program is designed to enable laboratory users to identify, communicate and effectively manage hazards associated with laboratory operations The Chemical Hygiene Plan (CHP) forms the foundation of the Laboratory Safety Program LU has designated a Chemical Hygiene Officer (CHO) to support the development, implementation, and communication of Lesley’s Laboratory Safety Program and the CHP To facilitate access to the information contained in this program by all appropriate individuals, Lesley University will communicate the contents of these programs in writing, through training programs and via LU’s web site Prior to beginning the laboratory experience, each student, faculty, and staff member will receive a safety orientation This program will be provided initially and repeated periodically to enhance the understanding of laboratory safety This safety orientation was developed to communicate information about both laboratory hazards and precautions that must be taken to ensure that risks are managed and hazards are controlled, as outlined in the CHP 1.3 Program Scope The Chemical Hygiene Plan applies when chemicals substances are used under the following conditions: (i) chemical manipulations are performed in containers designed to be easily and safely manipulated by one person; (ii) multiple chemical procedures or chemicals are used; and (iii) demonstrably effective laboratory practices and equipment are available and in common use to minimize the potential for employee exposure to hazardous chemicals 1.4 Plan Review Lesley University’s Laboratory Safety Committee will review the CHP effectiveness at least annually and update the plan as necessary -9- Preliminary 2.0 Lesley University Chemical Hygiene Plan April 2019 2.0 Responsibilities Laboratory safety and CHP compliance are responsibilities shared by faculty, staff, students, and administration Each plays a crucial role for ensuring safety during laboratory use and for maintaining CHP and regulatory compliance The following summarizes the general responsibilities of each functionary 2.1 Summary The Chemical Hygiene Officer is responsible for administering the CHP With the Faculty’s assistance and the Department Head’s support, the CHO facilitates CHP implementation, laboratory safety, and regulatory compliance The CHO relies on the laboratory instructors to facilitate safety, compliance, and CHP implementation while working in a chemistry laboratory Students are responsible for reading, understanding, and following the Faculty’s safety instructions and for participating in safety training The faculty provides oversight and guidance to the CHO, with both parties responsible for the identification, evaluation, and control of recognized or anticipated laboratory hazards Lesley University’s Facilities and Operation’s Department identifies and provides access to safety, industrial hygiene, and environmental compliance technical resources Physical Plant facilitates hazard control evaluation and maintenance 2.2 Responsibilities 2.2.1 Department Head: Facilitates CHP implementation by: • Designating a Laboratory “Chemical Hygiene Officer”, CHO • Providing financial and resource support, as appropriate • Mediating the prior approval process and other safety or compliance related issues • Reviewing and approving the annual CHP evaluation and revision 2.2.2 Laboratory CHO: Reports to the Department Head and facilitates CHP implementation by: • Working with Faculty to implement CHP guidelines and safety practices • Acting as the Laboratory’s safety and compliance resource and liaison with Support Departments • Monitoring procurement, use, and disposal of chemicals and hazardous wastes • Maintaining required documents and documentation • Conducting or coordinating employee CHP training • Coordinating exposure monitoring (sampling), when necessary • Preparing the Laboratory and Faculty to respond effectively to emergencies • Communicating with the Department Head on Laboratory compliance and safety issues, e.g., chemical exposures, emergencies, contaminations, medical consultations, etc., and other employee safety or environmental compliance issues 2.2.3 Laboratory Faculty: Works together with the Department Head, CHO, and students to implement the CHP by: • Reviewing, following, and enforcing CHP guidelines and safety practices • Educating students, CHOs, and others, as appropriate, on laboratory operations, procedures, and experiments - 10 - Table Peroxide-Forming Chemicals (Partial List / List not complete) The chemicals listed below can form explosive peroxide crystals on exposure to air, and therefore require special handling procedures after the container is opened Some of the chemicals form peroxides that are violently explosive in concentrated solution or as solids, and therefore should never be evaporated to dryness Others are polymerizable unsaturated compounds and can initiate a runaway, explosive polymerization reaction All peroxidizable compounds should be stored away from heat and light They should be protected from physical damage and ignition sources A warning label will be affixed to all peroxidizable materials indicating the date of receipt and the date the container was first opened Due to the special handling requirements, users must have the appropriate laboratory equipment, information, knowledge and training to use these compounds safely Use of these materials requires prior approval by the Laboratory Safety Committee or CHO A Severe Peroxide Hazard with Exposure to Air (Discard within months of opening) • • • diisopropyl ether (isopropyl ether) divinylacetylene (DVA) vinylidene chloride (1,1dichloroethylene) • • • potassium metal sodium amide (sodamide) potassium amide B Peroxide Hazard on Concentration Do not distill or evaporate without first testing for the presence of peroxides (Discard or test for peroxides after months of opening) • • • • • • • • • • acetaldehyde diethyl acetal (acetal) cumene (isopropylbenzene) cyclohexene cyclopentene decalin (decahydronaphthalene) diacetylene (butadiene) dicyclopentadiene diethyl ether (ether) diethylene glycol dimethyl ether (diglyme) dioxane • • • • • • • • • • ethylene glycol dimethyl ether (glyme) ethylene glycol ether acetates ethylene glycol monoethers (cellosolves) furan methylacetylene methylcyclopentane methyl isobutyl ketone tetrahydrofuran (THF) tetralin (tetrahydronaphthalene) vinyl ethers C Hazard of Rapid Polymerization Initiated by Internally-Formed Peroxides • vinyl pyridine Liquids Gases (Discard or test for peroxides after (Discard after 12 months of opening) months of opening) • • • chloroprene (2-chloro-1,3-butadiene) vinyl acetate styrene • • • • butadiene vinylacetylene (MVA) tetrafluoroethylene (TFE) vinyl chloride Table Shock Sensitive Chemicals (Partial List / List not complete) The chemicals listed below may detonate when subjected to shock or friction Due to the special handling requirements, users must have the appropriate laboratory equipment, information, knowledge and training to use these compounds safely Use of these materials requires prior approval by the Laboratory Safety Committee or CHO • • • • • • • • • • • • • • • • • • • • • • Acetylenic compounds, especially polyacetylenes, haloacetylenes, and heavy metal salts of acetylenes (copper, silver, and mercury salts are particularly sensitive) Acyl nitrates Alkyl nitrates, particularly polyol nitrates such as nitrocellulose and nitroglycerine Alkyl and acyl nitrites Alkyl perchlorates Amminemetal oxosalts: metal compounds with coordinated ammonia, hydrazine, or similar nitrogenous donors and ionic perchlorate, nitrate, permanganate, or other oxidizing group Azides, including metal, nonmetal, and organic azides Chlorite salts of metals, such as AgClO2 and Hg(ClO2)2 Diazo compounds such as CH2N2 Diazonium salts, when dry Fulminates such as mercury fulminate (Hg(CNO)2) Hydrogen peroxide (which becomes increasingly treacherous as the concentration rises above 0%) forms explosive mixtures with organic materials and decomposes violently in the presence of traces of transition metals N-Halogen compounds such as difluoroamino compounds and halogen azides N-Nitro compounds such as N-nitromethylamine, nitrourea, nitroguanidine, and nitric amide Oxo salts of nitrogenous bases: perchlorates, dichromates, nitrates, iodates, chlorites, chlorates, and permanganates of ammonia, amines, hydroxylamine, guanidine, etc Perchlorate salts (which can form when perchloric acid mists dry in fume hoods or associated duct work Most metal, nonmetal, and amine perchlorates can be detonated and may undergo violent reaction in contact with combustible materials) Peroxides and hydroperoxides, organic Peroxides (solid) that crystallize from or are left from evaporation of peroxidizable solvents (see Table 1) Peroxides, transition-metal salts Picrates, especially salts of transition and heavy metals, such as Ni, Pb, Hg, Cu, and Zn Polynitroalkyl compounds such as tetranitromethane and dinitroacetonitrile Polynitroaromatic compounds especially polynitrohydrocarbons, phenols, and amines (e.g., dinitrotoluene, trinitrotoluene, and picric acid) Note: Perchloric acid must be used only in specially-designed perchloric acid fume hoods that have built-in wash down systems to remove shock-sensitive deposits Before purchasing this acid, CHO must arrange for use of an approved perchloric acid hood Preliminary Lesley University Chemical Hygiene Plan August 2006 Table Poisonous Gases (Partial List / List not complete) These gases are either US Department of Transportation's Category listed material, or a Linde Specialty Gases company's Group - Very Poisonous substance These chemicals are highly toxic gases at ambient temperature and pressure They have an extremely high potential for causing significant harm if not adequately controlled Arsine Chlorine trifluoride Diborane Germane Nitrogen dioxide Oxygen difluoride Phosphorus pentafluoride Sulfur tetrafluoride Boron trichloride Cyanogen Dinitrogen tetroxide Hydrogen selenide Nitrogen trioxide Phosgene Selenium hexafluoride Tellurium Hexafluoride Chlorine pentafluoride Cyanogen chloride Fluorine Nitric oxide Nitrosyl chloride Phosphine Stibine Tetraethyldithiopyrophosphate Tetraethylpyrophosphate Guidance: Laboratories may chose to add other chemicals to the above list, for example, sulfur-containing compounds such as mercaptans can cause significant odor when used in the laboratory Due to the special handling requirements, users must have the appropriate laboratory equipment, information, knowledge and training to use these compounds safely Use of these materials requires prior approval by the Laboratory Safety Committee or CHO Preliminary Lesley University Chemical Hygiene Plan August 2006 Table Pyrophoric Chemicals (Partial List / List not complete) The chemicals listed below will readily oxidize and ignite spontaneously in air Due to the special handling requirements, users must have the appropriate laboratory equipment, information, knowledge and training to use these compounds safely Use of these materials requires prior approval by the Laboratory Safety Committee or CHO • Grignard reagents, RMgX • Metal alkyls and aryls, such as RLi, RNa, R3Al, R2Zn • Metal carbonyls such as Ni(CO)4, Fe(CO)5, Co2(CO)8 • Alkali metals such as Na, K • Metal powders, such as Al, Co, Fe, Mg, Mn, Pd, Pt, Ti, Sn, Zn, Zr • Metal hydrides such as NaH, LiAlH4 • Nonmetal hydrides, such as B2H6 and other boranes, PH3, AsH3 • Nonmetal alkyls, such as R3B, R3P, R3As • Phosphorus (white) • Others Preliminary Lesley University Chemical Hygiene Plan August 2006 Table Biologically Active Compounds (Partial List / List not complete) The chemicals listed below are extremely hazardous Due to the special handling requirements, users must have the appropriate laboratory equipment, information, knowledge and training to use these compounds safely Use of these materials requires prior approval by the Laboratory Safety Committee or CHO Biologically active compounds • protease inhibitors (e.g PMSF, Aprotin, Pepstatin A, Leopeptin); • protein synthesis inhibitors (e.g cycloheximide, Puromycin); • transcriptional inhibitors (e.g a-amanitin and actinomycin D); • DNA synthesis inhibitors (e.g hydroxyurea, nucleotide analogs (i.e dideoxy nucleotides), actinomycin D, acidicolin); • phosphatase inhibitors (e.g okadaic acid); • respiratory chain inhibitors (e.g sodium azide); • kinase inhibitors (e.g NaF); • mitogenic inhibitors (e.g colcemid); and • mitogenic compounds (e.g concanavalin A) • Castor bean (Ricinus communis) lectin: Ricin A, Ricin B, RCA toxins • Diisopropyl fluorophosphate: highly toxic LSLlinesterase inhibitor; the antidote, atropine sulfate and 2-PAM (2-pyridinealdoxime methiodide) must be readily available • Jaquirity bean lectin (Abrus precatorius) • N-methyl-N'-nitro-N-nitrosoguanidine: carcinogen (this chemical forms explosive compounds upon degradation) • Phalloidin from Amanita Phalloides: used for staining actin filaments • Retinoids: potential human teratogens • Streptozotocin: potential human carcinogen • Urethane (ethyl carbamate): an anesthetic agent, potent carcinogen and strong teratogen, volatile at room temperature • Hydrofluoric Acid, Hydrogen Cyanide, Phenol, etc Preliminary • Lesley University Chemical Hygiene Plan July 2003 Others -3- Preliminary Lesley University Chemical Hygiene Plan July 2003 Table OSHA “Carcinogens” Reference: 29 CFR 1910.1003 This section applies to any area in which the following 13 carcinogens are manufactured, processed, repackaged, released, handled, or stored, but shall not apply to transshipment in sealed containers, except for the labeling requirements under paragraphs (e)(2), (3) and (4) of this section The 13 carcinogens are the following: Substance 4-Nitrobiphenyl, alpha-Naphthylamine, methyl chloromethyl ether, 3,3'-Dichlorobenzidine (and its salts) bis-Chloromethyl ether, beta-Naphthylamine, Benzidine, 4-Aminodiphenyl, Ethyleneimine, beta-Propiolactone, 2-Acetylaminofluorene, 4-Dimethylaminoazobenezene, N-Nitrosodimethylamine, -3- Chemical Abstracts Service Register Number (CAS No.) CAS No 92933; CAS No 134327; CAS No 107302; CAS No 91941; CAS No 542881; CAS No 91598; CAS No 92875; CAS No 92671; CAS No 151564; CAS No 57578; CAS No 53963; CAS No 60117; CAS No 62759 Preliminary Lesley University Chemical Hygiene Plan July 2003 Table OSHA Toxic and Hazardous Substances The following OSHA standards provide detailed compliance requirements that must be satisfied if employee exposure routinely exceeds the OSHA permissible exposure limit (or action level, where specified) These substances / standards are not superseded by OSHA’s Hazardous Chemicals in Laboratories standard Copies of these standards may be obtained from the Chemical Hygiene Officer or by visiting the OSHA Web Site Substance OSHA Standard 29 CFR 1910 Asbestos, tremolite, anthophyllite and actinolite Coal tar pitch volatiles “Carcinogens” alpha-Naphthylamine 4,4'-Methylene bis(2-chloroaniline) Methyl chloromethyl ether 3,3'-Dichlorobenzidine (and salts) bis-Chloromethyl ether beta-Naphthylamine Benzidine 4-Aminodiphenyl Ethyleneimine beta-Propiolactone 2-Acetylaminofluorene 4-Dimethylaminoazobenzene N-Nitrosodimethylamine Vinyl Chloride Arsenic (inorganic) Lead Chromium (VI) Cadmium Benzene Coke Oven Emissions Bloodborne Pathogens Cotton dust 1,2-Dibromo-3-chloropropane Acrylonitrile Ethylene oxide Formaldehyde 4,4'-Methylenedianiline 1,3-Butadiene Methylene Chloride Ionizing Radiation Non-Asbestiform tremolite, anthophyllite and actinolite 1001 1002 1003 1004 1005 1006 1007 1008 1009 1010 1011 1012 1013 1014 1015 1016 1017 1018 1025 1026 1027 1028 1029 1030 1043 1044 1045 1047 1048 1050 1051 1052 1096 1101 -3- Preliminary Lesley University Chemical Hygiene Plan August 2006 Table Materials Affecting Hazardous Waste Classification (“P” listed waste) Preliminary Lesley University Chemical Hygiene Plan August 2006 Appendix F Laboratory Safety Student Contract Lesley University is committed to providing a safe and healthy laboratory environment for students, staff and faculty and complying with governmental safety and environmental regulations Laboratory personnel, faculty, staff, Lesley University administration, students and resource partners share responsibility for minimizing risk of exposure to safety and health hazards associated with work in the laboratory environment Lesley University expects each individual working in a laboratory to take appropriate precautions, utilize available control measures, and obtain necessary information to identify and manage laboratory hazards These actions will be applied during routine, non-routine or other laboratory activities not specifically addressed in this document Lesley University provides the following resources to ensure Laboratory Personnel safety: • • • • Laboratory Instructors and CHO Chemical Hygiene Plan Safety Orientation Instruction Internal and External Resources (Accessed through the Laboratory Instructors and CHO) Student Contract I will utilize the resources provided by Lesley University to facilitate safety while I am working in the laboratory I will follow the instructions provided during the Laboratory Safety Orientation and by the Instructor and will advise the Laboratory Instructor or CHO of any concerns, uncontrolled hazards, adverse health effects, spills, etc., resulting from the laboratory experience If I have any concerns, I understand I can speak freely with the Laboratory Instructor or CHO who is my primary resource and is available to manage laboratory risks Student: Print Signature Date: Instructor: Print Signature - 49 - Preliminary Lesley University Chemical Hygiene Plan August 2006 Date: - 50 - Preliminary Lesley University Chemical Hygiene Plan August 2006 Appendix G Student Training Certification Training Date(s): Training Location: Student Statement: I have received training and instruction as outlined in Lesley University’s Chemical Hygiene Plan (CHP) The training included the following: • Laboratory Safety responsibilities, authority, and resources; • Safety Guidelines (See Section 4.0, “Standard Safety Practices”; • Chemical Hygiene Plan review; • Hazard Identification and Communication (See Section 3.0) ; and • Emergency Response, First Aid and Exposure Prevention and Control Resources Name (Print) Signature SS# (Last Digits) Instructor Certification: I have provided the training as specified by Lesley University’s CHP and have determined that the student has demonstrated knowledge and an adequate understanding of laboratory safety Training Instructor: Instructor’s Signature: Date: - 51 - Preliminary Lesley University Chemical Hygiene Plan August 2006 Appendix H Employee Training Certification Training Date(s): Training Location: Employee Statement: I have received training and instruction as outlined in Lesley University’s Chemical Hygiene Plan (CHP) The training included the following: • • • • Applicable details of the Lesley University’s Chemical Hygiene Plan Methods and observations that may be used to detect the presence or release of a hazardous chemical (such as monitoring conducted by the employer, visual appearance or odor of hazardous chemicals during a spill or release, etc.) An overview of the physical and health hazards of chemicals in the work area The measures employees can take to protect themselves from laboratory hazards, including specific procedures the Lesley University has implemented to protect employees from exposure to hazardous chemicals, such as appropriate engineering and work practices controls, emergency procedures, and use of personal protective equipment Name (Print) Signature SS# (Last Digits) Instructor Certification: I have provided the training as specified by Lesley University’s CHP and have determined that the employee has demonstrated knowledge and an adequate understanding of laboratory safety Training Instructor: Instructor’s Signature: - 52 - Preliminary Lesley University Chemical Hygiene Plan August 2006 Date: Appendix I Occupational Exposure to Hazardous Chemicals in Laboratories, OSHA, 29 CFR 1910.1450 - 53 - Preliminary Lesley University Chemical Hygiene Plan August 2006 Appendix J Health and Safety Technical Resources Recommendations for Chemical Protective Clothing, NIOSH: (http://www.cdc.gov/niosh/ncpc/ncpc2.html) Provides a resource for identifying appropriate types of barrier material for protection against skin contact with the chemicals Based on the NIOSH Pocket Guide to Chemical Hazards Prudent Practices in the Laboratory: Handling and Disposal of Chemicals (commonly known as “Prudent Practices”), National Research Council, 1995 OSHA: 29 CFR 1910, Subpart Z, Toxic and Hazardous Substances, 29 CFR 1910.1000 – 1096 The following list does not contain mandatory and nonmandatory appendices Refer 29 CFR 1910 to access the standard’s appendices 1910.1009 - beta-Naphthylamine 1910.1028 - Benzene 1910.1000 - Air contaminants 1910.1010 - Benzidine 1910.1029 - Coke oven emissions Air Contaminants 1910.1000 TABLE Z-1 - TABLE Z-1 Limitsmits for 1910.1011 4-Aminodiphenyl  1910.1030 - Bloodborne pathogens 1910.1000 TABLE Z-2 - TABLE Z-2 1910.1012 - Ethyleneimine 1910.1043 - Cotton dust 1910.1000 TABLE Z-3 - TABLE Z-3 Mineral Dusts 1910.1013 beta-Propiolactone  1910.1044 - 1,2-dibromo-3-chloropropane 1910.1001 - Asbestos 1910.1014 - 2-Acetylaminofluorene 1910.1045 - Acrylonitrile of term - 4-Dimethylaminoazobenzene 1910.1002 - Coal tar pitch volatiles; interpretation 1910.1015  1910.1047 - Ethylene oxide 1910.1003 - 13 Carcinogens (4-Nitrobiphenyl, etc.) 1910.1016 - N-Nitrosodimethylamine 1910.1048 - Formaldehyde 1910.1004 - alpha-Naphthylamine 1910.1017 - Vinyl chloride 1910.1050 - Methylenedianiline 1910.1005 - [Reserved] 1910.1018 Inorganic arsenic  1910.1051 - 1,3-Butadiene 1910.1006 Methyl chloromethyl ether  medical records - Methylene Chloride 1910.1020 - Access to employee exposure and1910.1052 1910.1007 - 3,3'-Dichlorobenzidine (and its salts) 1910.1025 Lead 1910.1096 - Ionizing radiation   1910.1008 - bis-Chloromethyl ether 1910.1027 - Cadmium - 54 -