Safety Data Sheet CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: Lead Free Solder Bar (SAC) Other name: － Product identifier：PF506、PF529、PF530、PF531、PF565、PF566、PF567、PF601、PF603、PF604、 PF605、PF606A、PF606、PF607、PF608A、PF608、PF608D、PF609、PF610、PF611、PF614、PF615、 PF616、PF617、PF619、PF620、PF621、PF625、PF627、PF629、PF630、PF631、PF632、PF632D、 PF633、PF634、PF635、PF636、PF637、PF638、PF639、PF640、PF640、PF643、PF644、PF645、 PF646、PF647、PF648、PF649、PF650、PF651、PF652、PF654、PF656、PF657、PF659、PF660、 PF663、PF664、PF665、PF667、PF668、PF669、PF671、PF677、PF679、PF680、PF701、PF702、 PF703、PF704、PF710、PF711、PF712、PF715、PF716、PF717、PF720、PF721、PF722、PF723、 PF724、PF727、PF731、PF732、PF736、PF737、PF738、PF756、PF801、PF802、PF803、PF804、 PF805、PF904 (-B、-B-H3、-B-H4) Suggest purpose: － Manufacture: SHENMAO TECHNOLOGY INC Address: No.12-1 Gongye 2nd Rd., Guayin industrial area, Taoyuan City 328, Taiwan TEL: (886)3-416-0177 FAX: (886)3-416-0133 Website: http://www.shenmao.com HAZARDS IDENTIFCATION Hazard classification: Specific target organ toxicity－repeated exposure Category 2 Hazardous to the aquatic environment, (acute toxicity) Category Indication content: Symbols：Health mark Signal word：Warning Hazard Statement： May cause damage to organs through prolonged or repeated exposure Harmful to aquatic life Prevention： 1.The body thinks not comfortably，Inquires of the medical service 2.Not inspiration dust 3.Avoids with the skin contact Other hazard: － COMPOSITION, INFORMATION OR INGREDIENT Mixture： Components-Chemical Name： Tin Hazards composition (wt %): 90~100 Page of （CAS No.）： 7440-31-5 Safety Data Sheet Silver 0.0-5.0 7440-22-4 Copper 0.0~6.0 7440-50-8 FIRST AID MEASURES First aid method in the different exposed way: Moves the patient to the fresh air place immediately If patient stop breathes, gives the artificial respiration Inhalation Keep the patient to be warm and the rest Send him to the hospital immediately Use the soap or the neutral cleanser and the water clean the skin immediately If seeps clothes, takes off clothes immediately, and uses the soap or the neutral cleanser and Skin contact the water to cleans the skin If still had Irritation feeling, take medical treatment immediately Eye contact Ingestion Clean eye by the massive clear water immediately and often opens the eyelid If still had Irritation feeling, take medical treatment immediately If the patient soberly, drinks the massive water immediately Urges to vomit by the finger insertion throat If the patient is insensible, don’t urge to vomit If still had Irritation feeling, take medical treatment immediately The most important symptoms and hazardous effect: Irritation feeling The protection to first-aid personnel: Should wear the protection equipment of level C to give first aid in the safe area Notes to physicians: If the patient swallows, consideration gastric lavage and bowel movement FIRE-FIGHTING MEASURES Suitable fire extinguishing media: carbon dioxide or dry chemical Specific hazards may be encountered during fire-fighting: The tin is nonflammable, but in the powder status it is inflammable Specific fire-fighting methods: Move the container out to the safe area Cooling storing or container expose in a fire scene with water Special equipment for the protection of firefighters: － ACCIDENTAL RELEASE MEASURES Personal precautions: The man who without wear protect equipping or clothes forbidden enter in the let out area before clean Environmental precautions: Ventilate to the let out area Methods for cleaning up: Recycle the material or bury with the qualified method in most convenient and safe way Page of Safety Data Sheet The liquid can be absorbed with the vermiculite, sand, soil or similar material HANDLING AND STORAGE Handling: During work avoids producing the dust Storage: Storage to suitably container which has the label Storage it in a coolly, dryly and ventilate well place EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering control: Partial air exhaust device Whole air exhaust device Control parameters: TWA(mg/m3) Tin STEL － CEILING － BEIs － Silver 0.01 － － － Copper 1.0 － － － Personal protective equipment: Respiratory protection: 0~10 mg/m3: Dustproof breathing mask 20 mg/m3: Dustproof breathing mask Air supply type breathing mask 50 mg/m3: Dustproof and air filter breathing mask Continuous air supply type breathing mask 100 mg/m3: 1.Contain high performance filter and air filter breathing mask Continuous air supply type breathing mask Unknown consistency: Continuous air supply type breathing mask Escape: 1.Contain high performance filter and air filter breathing mask Continuous air supply type breathing mask Hand protection: Rubber or plastic glove Eye protection: The safe goggles which can defend splash Face guard in an all-round way Don’t wear the contact lenses Skin and body protection: Apron, long sleeves clothes Hygiene measures: Take off the clothes of pollution as soon as possible after the work, wear or abandon after cleaning, and tell the person about the pollutant who washing the clothes Forbid smoking or diet in the workplace After work, must wash hands completely Keep the workplace clean Physics and chemical property Page of Safety Data Sheet Appearance(physical state, color): Silver gray Odor：－ Odor threshold: － Melting point: 217~370 ℃ pH: － Boiling point/Boiling point range: Flammability (solid, gas): － Decompose temperature: － Flash Point: － Test Method(Open cup or Close cup)： － Auto-ignition temperature: － Explosion Limit: － Vapor Pressure: － Vapor Density: － Density: 7.3-7.4 g/cm3 Solubility: － Partition coefficient(n-octanol/water,log Kow): － Evaporation rate: － 10 STABILITY AND REACTIVITY Stability: Stable under the normal state, the powder state will be oxidized in the air Possible hazardous reactions under specific conditions: Metal tin and turpentine contact will produce fire and explode Plastics, rubber Acid, soda, oxide, sulphur, halogens When the tin powder mixed with sodium peroxide, contact with the moisture will produces the fire; contact the carbon dioxide or ammonium nitrate (higher than 200℃) will produces explode Carbon tetrachloride Tetrachloromethane (moisture existence), halide, cupric nitrate solution, potassium peroxide Conditions to avoid: The powder state will be oxidized in the air Materials to avoid: Metal tin and turpentine contact Plastics, rubber Acid, soda, oxide, sulphur, halogens Tin powder mixed with sodium peroxide, carbon dioxide or ammonium nitrate (higher than 200℃) Carbon tetrachloride Tetrachloromethane (in moisture existence), halide, cupric nitrate solution, potassium peroxide Hazardous decomposition products: － 11 TOXICOLOGICAL INFORMATION Routes of exposure: nose, skin Symptoms: － Acute toxicity: May cause the irritation of eyes, nose, throat, skin It is nonpoisonous to eat But it will let the stomach to be uncomfortable by irritation Chronic toxicity or long term toxicity: The person who has the following conditions is easy to be endangered: Dermatosis, breathe disease chronically Page of Safety Data Sheet In animal's experiment, it can increase the meat swollen probability 12 ECOLOGICAL INFORMATION Ecotoxicity: － Persistent and biodegradable: － Bio-accumulative potential: － Mobility in soil: － Other adverse effects: － 13 DISPOSAL CONSIDERATIONS Methods of waste disposal: Bury with qualified hygiene 14 TRANSORTS INFORMATION UN No.: Not applicable UN Proper shipping name: Not applicable Transportation hazard classifcation: － Packing group: Not applicable Marine pollutant (Yes/No): Not applicable Specific transport measures and precautionary conditions: Not applicable 15 REGULATORY INFORMATION Applicable regulations: Occupational Safety and Health Act Laborer operating environment permits the thickness standard Industrial waste storage cleaning dispose method and facility standard Hazardous chemicals labeled general rule 16 OTHER INFORMATION Reference Occupational Safety and Health Administration , Ministry Of Labor, GHS inquiry system Department: SHENMAO Prepared By Add: No.12-1 Gongye 2nd Rd., Guanin industrial area, Taoyuan City 328, Taiwan TEL: (886)3-416-0177 Author Alan Huang Issued date 2019/3/12 The information herein is given in good faith, but no warranty, express or implied, is made Page of