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THÔNG TIN TÀI LIỆU
Cấu trúc
Cover Page
Introduction to Volume 3
COMPREHENSIVE COORDINATION CHEMISTRY II
Volumes
Info on Volume 3
Volume 3
3.1 Group 1s and 2s Metals
Introduction and Review of Coordination Properties
Trends since the Mid-1980s
Increased Use of Sterically Bulky Ligands
Recognition of the Importance of Non-ionic Interactions
Reappraisal of the "Spectator" Role of s-Block Ions
Application of Computational Methods to Complexes
Macrocyclic Compounds
Porphyrins and Phthalocyanines
Group 16 Ligands
Crown ethers
Cryptands and related species
Calixarenes
Alkalides and electrides
Nonmacrocyclic Complexes
Hydroborates
Group 14 Ligands
Group 15 Ligands
Nitrogen donor ligands
Amides, especially bis(trimethylsilyl)amides
Imidoalkalis
Thiocyanates
N-donor stabilized metal-centered radicals
Other nitrogen donor ligands
Phosphorus donor ligands
Neutral phosphines
Monosubstituted phosphido complexes
Disubstituted phosphido complexes
Arsenic donor ligands
Oxygen donor ligands
Carboxylates
Diketonates
Enolates
Alkoxides and aryloxides
Other oxygen donor ligands
Chemical vapor deposition
Sulfur donor ligands
Selenium and tellurium donor ligands
Group 17 Ligands
References
3.2 Scandium, Yttrium, and the Lanthanides
Scandium
Introduction
Ammonia and amines
Amides
Compounds of porphyrins and other macrocyclic ligands
Compounds with P- and N, P-donor ligands
Salts and the aqua ion
Anhydrous and hydrated salts
The scandium aqua ion
Hydroxide complexes
Complexes of other group 16-donor ligands
Alkoxides
Diketonates and other chelating ligands
Crown ether complexes and related systems
Mixed Group 15 and 16 Donors
Complexes of Group 17 Ligands
Binary halides and simple complexes
Other halide complexes
Yttrium And The Lanthanides
Alkyls
Ammonia and other monodentate neutral ligands
Nitrile complexes
2,2`-Bipyridyl, 1,10-phenanthroline and other bidentate neutral ligands
Complexes of terpyridyl and other tridentate ligands
Amides and pyrazolides
Polypyrazolylborates
Thiocyanate
Group 15 Ligands Involving Phosphorus
Group 16 Ligands Involving Oxygen
The aqua ion and hydrated salts
Phosphine and arsine oxides, and other neutral monodentate donors
MRI agents
EDTA complexes
Complexes of DTPA and its derivatives
Complexes of DOTA and other complexing agents
Complexes of mixed Group 15 and 16 donors as spectroscopic probes
Complexes of Macrocycles Involving Group 15 and 16 Donors
Porphyrins and phthalocyanines
Texaphyrins
Crown ethers and other macrocycles
Group 16 Ligands Involving Sulfur, Selenium, and Tellurium
Group 17 ligands
Complexes of the Ln2beta ion
Group 14 ligands
Group 15 ligands involving nitrogen
Group 15 ligands involving phosphorus
Group 16 ligands involving oxygen
Group 16 ligands involving sulfur, selenium, and tellurium
Complexes of the Ln4+ ion
Group 15 ligands
Group 16 ligands
3.3 The Actinides
Historical Development of Actinide Coordination Chemistry
Characteristics of the actinides
Coordination numbers and geometries
Early Actinide Metals-Thorium to Plutonium
Trivalent Oxidation State
General characteristics
Simple donor ligands
Ligands containing anionic group 15 donor atoms
Amide ligands
Polypyrazolylborate ligands
Ligands containing neutral group 15 donor atoms
Ammonia
Nitriles
Phosphines
Ligands containing anionic group 16 donor atoms
Oxides
Hydroxides
Carbonates
Nitrates and Phosphates
Sulfates
Alkoxide Compounds
Triflate complexes
Ligands containing neutral group 16 donor atoms
Aqua species
Ethers, cyclic ethers
Carbamides
Phosphine oxides
Ligands containing group 17 donor atoms
Binary halides
Complex halides
Chelating ligands
Multidentate donor ligands
Hydroxamate
Catecholate
8-Hydroxyquinoline and derivatives
Oxalate
Polyoxometallates
Macrocyclic ligands
Borohydride and aluminohydride ligands
Tetravalent Oxidation State
Ligands containing group 14 donor atoms
Amide complexes
Amidinate complexes
Phosphide complexes
Thiocyanate and selenocyanate
Sulfenamide
Amines, hydrazines, and hydroxylamines
Heterocyclic ligands
Aliphatic phosphines
Arsines
Peroxides and other dichalcogenides
Nitrates
Phosphates
Sulfates and sulfites
Perchlorates and iodates
Alcohols
Ketones, aldehydes, esters
Ureas
N-oxides, phosphine oxides, arsine oxides, and related ligands
Sulfoxides
Thioethers
Oxohalides
Chelating ligand
Hydroxamates, cupferron, and related ligands
Pyoverdin
Pyridonate
Carbamate
beta-Diketonates
CMPO
Schiff base-derived ligands
N-Heterocyclic ligands
Borohydride ligands
Tetravalent Oxidation State (Am, Cm, Bk, Cf)
Ligands containing group 16 donor atoms
Phosphines, arsines
Diamides
Carbonates and Carboxylates
Phosphates and arsenates
Sulfates and selenates
Alkoxide complexes
Thiolate complexes
Ethers
Urea
Phosphine oxide
Sulfoxide
Phosphine sulfide, phosphine selenide
Ligands containing Group 17 ligands
Other
Hexavalent Oxidation State
Amidinate ligands
Pyrazolylborate
Phosphoraniminato complexes
Cyanate and thiocyanate
Azide
Peroxides
Arsenates
Molybdates
Carbamide and related ligands
Nitroalkanes
Amine N-oxides, phosphine oxides, arsine oxides, and related ligands
Ligands containing group 17 ligands
Hydroxamates, cupferron and related ligands
Amino acids
Schiff base ligands
Heptavalent Oxidation State
The Later Actinide Metals-Transplutonium Elements
Divalent Oxidation State (Am, Cm, Cf, Es, Fm, Md, No)
Oxides and aqueous
Trivalent Oxidation State (Am-Lr)
Ligands containing group 15 donor atoms
Hydroxide, aqua, and hydrates
Oxoanions
Carbonates and carboxylates
Phosphoric, phosphinic, and phosphonic acid
Diphosphinic acids
Pentavalent Oxidation State (Am)
Oxide
Aquo and hydroxides
Oxoanion complexes
Hexavalent Oxidation State(Am)
Aqua, hydroxides
Other Sources
Acknowledgement
3.4 Aluminum and Gallium
Aluminum
Nitrogen ligands
Phosphorus and arsenic ligands
Oxygen ligands
Sulfur, selenium, and tellurium ligands
Sulfur-based crown ethers
Hydride ligands
Halide ligands
Compounds Containing Al-Al Bonds
Neutral compounds containing the Al-Al bond
Radical anions: A degree of multiple bonding in the Al-Al bond
Gallium
Phosphorus, arsenic, and antimony ligands
Two-coordinate gallium centers
Compounds Containing Ga-Ga Bonds
Neutral compounds containing the Ga-Ga bond
Radical anions and multiple bond character
Cyclogallenes and metalloaromaticity
Ga-Ga triple bonds
3.5 Indium and Thallium
Indium
Indium (III)
Carbon ligands
Silicon, germanium, tin, and lead ligands
Phosphorus, arsenic, antimony, and bismuth ligands
Sulfur, selenium, tellurium ligands
Halides and carbon ligands
Halides and group 15 and group 16 ligands
Halides and multidentate ligands
Anionic complexes with halide ligands
Mixed-donor-atom ligands
Indium (II)
Indium(I)
Thallium
Thallium (III)
Thallium (II)
Thallium (I)
3.6 Arsenic, Antimony, and Bismuth
Arsenic
Group 14 Compounds
Group 15 Compounds
Group 16 Compounds
Group 17 Compounds
Arsenic in the Environment, Biology, and Medicine
Antimony
N-donor ligands
P-, As-, and Sb-donor ligands
O-donor ligands
S-, Se-, and Te-donor ligands
Antimony in the Environment, Biology, and Medicine
Bismuth
P- and As-donor ligands
N/O-donor ligands
S/O- and S/N-donor ligands
Bismuth in the Environment, Biology, and Medicine
3.7 Germanium, Tin, and Lead
Complexes with Carbon Donor Ligands
Complexes with M(14)-M(14) Bonds
Complexes with M(14)-M(14) Homoelement Bonds
Complexes with M(14)-M(14) Heteroelement Bonds
Complexes with Group 15 Ligands
Complexes with Neutral Monodentate Nitrogen Ligands
Complexes with Anionic Monodentate Nitrogen Ligands
Complexes with Neutral Bidentate Nitrogen Ligands
Complexes with Anionic Bidentate Nitrogen Ligands
Complexes with Polypyrazolyl Ligands
Complexes with Tridentate Nitrogen Ligands
Complexes with Tetradentate Nitrogen Ligands
Complexes with Polydentate Nitrogen Ligands
Complexes with Phosphorus or Arsenic Ligands
Complexes of MIV with phosphines or arsines
Complexes of MII with phosphines or arsines
Complexes of MIV with phosphides or arsinides
Complexes of MII with phosphides or arsinides
Complexes with Group 16 Ligands
Complexes with Neutral Oxygen Ligands
Complexes with Anionic Monodentate Oxygen Ligands
Complexes with Monoanionic Bidentate Oxygen Ligands
Complexes with Carboxylates or Phosphinates
Complexes with Dianionic Bidentate Oxygen Ligands
Complexes with Neutral Sulfur Ligands
Complexes of Anionic Monodentate Sulfur, Selenium, or Tellurium Ligands
Complexes of Anionic Bidentate Sulfur, Selenium, or Tellurium Ligands
Complexes of Dianionic Bidentate Sulfur, Selenium, or Tellurium Ligands
Complexes with Group 17 Ligands
Complexes of Hydride Ligands
Complexes of Ligands with Mixed Donor Sets
Complexes of Heterobidentate Ligands
Complexes of Heterotridentate Ligands
Complexes of Heterotetradentate Ligands
Complexes of Heterodonor Ligands of Higher Denticity
3.8 Appendix to Volume 3
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