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  • Cover Page

  • Introduction to Volume 3

  • COMPREHENSIVE COORDINATION CHEMISTRY II

  • Volumes

  • Info on Volume 3

  • Volume 3

    • 3.1 Group 1s and 2s Metals

      • Introduction and Review of Coordination Properties

      • Trends since the Mid-1980s

        • Increased Use of Sterically Bulky Ligands

        • Recognition of the Importance of Non-ionic Interactions

        • Reappraisal of the "Spectator" Role of s-Block Ions

        • Application of Computational Methods to Complexes

      • Macrocyclic Compounds

        • Porphyrins and Phthalocyanines

        • Group 16 Ligands

          • Crown ethers

          • Cryptands and related species

          • Calixarenes

          • Alkalides and electrides

      • Nonmacrocyclic Complexes

        • Hydroborates

        • Group 14 Ligands

        • Group 15 Ligands

          • Nitrogen donor ligands

            • Amides, especially bis(trimethylsilyl)amides

            • Imidoalkalis

            • Thiocyanates

            • N-donor stabilized metal-centered radicals

            • Other nitrogen donor ligands

          • Phosphorus donor ligands

            • Neutral phosphines

            • Monosubstituted phosphido complexes

            • Disubstituted phosphido complexes

          • Arsenic donor ligands

        • Group 16 Ligands

          • Oxygen donor ligands

            • Carboxylates

            • Diketonates

            • Enolates

            • Alkoxides and aryloxides

            • Other oxygen donor ligands

            • Chemical vapor deposition

          • Sulfur donor ligands

          • Selenium and tellurium donor ligands

        • Group 17 Ligands

      • References

    • 3.2 Scandium, Yttrium, and the Lanthanides

      • Scandium

        • Introduction

        • Group 14 Ligands

        • Group 15 Ligands

          • Ammonia and amines

          • Thiocyanates

          • Amides

          • Compounds of porphyrins and other macrocyclic ligands

          • Compounds with P- and N, P-donor ligands

        • Group 16 Ligands

          • Salts and the aqua ion

            • Anhydrous and hydrated salts

            • The scandium aqua ion

            • Hydroxide complexes

          • Complexes of other group 16-donor ligands

          • Alkoxides

          • Diketonates and other chelating ligands

          • Crown ether complexes and related systems

        • Mixed Group 15 and 16 Donors

        • Complexes of Group 17 Ligands

          • Binary halides and simple complexes

          • Other halide complexes

      • Yttrium And The Lanthanides

        • Introduction

        • Group 14 Ligands

          • Alkyls

        • Group 15 Ligands

          • Ammonia and other monodentate neutral ligands

          • Nitrile complexes

          • 2,2`-Bipyridyl, 1,10-phenanthroline and other bidentate neutral ligands

          • Complexes of terpyridyl and other tridentate ligands

          • Amides and pyrazolides

          • Polypyrazolylborates

          • Thiocyanate

        • Group 15 Ligands Involving Phosphorus

        • Group 16 Ligands Involving Oxygen

          • The aqua ion and hydrated salts

          • Phosphine and arsine oxides, and other neutral monodentate donors

          • Diketonates

          • Alkoxides and aryloxides

        • Mixed Group 15 and 16 Donors

          • MRI agents

          • EDTA complexes

          • Complexes of DTPA and its derivatives

          • Complexes of DOTA and other complexing agents

          • Complexes of mixed Group 15 and 16 donors as spectroscopic probes

        • Complexes of Macrocycles Involving Group 15 and 16 Donors

          • Porphyrins and phthalocyanines

          • Texaphyrins

          • Crown ethers and other macrocycles

          • Calixarenes

        • Group 16 Ligands Involving Sulfur, Selenium, and Tellurium

          • Group 17 ligands

        • Complexes of the Ln2beta ion

          • Group 14 ligands

          • Group 15 ligands involving nitrogen

          • Group 15 ligands involving phosphorus

          • Group 16 ligands involving oxygen

          • Group 16 ligands involving sulfur, selenium, and tellurium

          • Group 17 ligands

        • Complexes of the Ln4+ ion

          • Group 15 ligands

          • Group 16 ligands

          • Group 17 ligands

      • References

    • 3.3 The Actinides

      • Introduction

        • Historical Development of Actinide Coordination Chemistry

          • Characteristics of the actinides

          • Coordination numbers and geometries

      • Early Actinide Metals-Thorium to Plutonium

        • Trivalent Oxidation State

          • General characteristics

          • Simple donor ligands

            • Ligands containing anionic group 15 donor atoms

              • Amide ligands

              • Polypyrazolylborate ligands

            • Ligands containing neutral group 15 donor atoms

              • Ammonia

              • Ammonia

              • Nitriles

              • Phosphines

            • Ligands containing anionic group 16 donor atoms

              • Oxides

              • Hydroxides

              • Carbonates

              • Nitrates and Phosphates

              • Sulfates

              • Alkoxide Compounds

              • Triflate complexes

              • Sulfur donor ligands

            • Ligands containing neutral group 16 donor atoms

              • Aqua species

              • Ethers, cyclic ethers

              • Carbamides

              • Phosphine oxides

            • Ligands containing group 17 donor atoms

              • Binary halides

              • Complex halides

          • Chelating ligands

            • Multidentate donor ligands

              • Hydroxamate

              • Catecholate

              • 8-Hydroxyquinoline and derivatives

              • Oxalate

              • Polyoxometallates

            • Macrocyclic ligands

              • Crown ethers

          • Borohydride and aluminohydride ligands

        • Tetravalent Oxidation State

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 14 donor atoms

              • Amide complexes

              • Amidinate complexes

              • Phosphide complexes

              • Polypyrazolylborate ligands

              • Thiocyanate and selenocyanate

              • Sulfenamide

            • Ligands containing neutral group 15 donor atoms

              • Ammonia

              • Amines, hydrazines, and hydroxylamines

              • Heterocyclic ligands

              • Nitriles

              • Aliphatic phosphines

              • Arsines

            • Ligands containing anionic group 16 donor atoms

              • Oxides

              • Hydroxides

              • Peroxides and other dichalcogenides

              • Carbonates

              • Carboxylates

              • Nitrates

              • Phosphates

              • Sulfates and sulfites

              • Perchlorates and iodates

              • Oxides

              • Oxides

            • Ligands containing neutral group 16 donor atoms

              • Aqua species

              • Ethers, cyclic ethers

              • Alcohols

              • Ketones, aldehydes, esters

              • Carbamides

              • Ureas

              • N-oxides, phosphine oxides, arsine oxides, and related ligands

              • Sulfoxides

              • Thioethers

              • Aqua species

            • Ligands containing group 17 donor atoms

              • Binary halides

              • Complex halides

              • Oxohalides

          • Chelating ligand

            • Multidentate donor ligands

              • Hydroxamates, cupferron, and related ligands

              • Catecholate

              • Pyoverdin

              • Pyridonate

              • 8-Hydroxyquinoline and derivatives

              • Carbamate

              • Oxalate

              • beta-Diketonates

              • CMPO

              • Hydroxamates, cupferron, and related ligands

              • Hydroxamates, cupferron, and related ligands

              • Hydroxamates, cupferron, and related ligands

            • Schiff base-derived ligands

            • Macrocyclic ligands

              • N-Heterocyclic ligands

              • Crown ethers

          • Borohydride ligands

        • Tetravalent Oxidation State (Am, Cm, Bk, Cf)

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 16 donor atoms

              • Oxides

              • Hydroxides

            • Ligands containing group 17 donor atoms

              • Ammonia and amines

              • Heterocyclic ligands

              • Nitriles

              • Phosphines, arsines

              • Thiocyanate and selenocyanate

            • Diamides

              • Oxides

              • Hydroxides

              • Carbonates and Carboxylates

              • Nitrates

              • Phosphates and arsenates

              • Sulfates and selenates

              • Perchlorates and iodates

              • Alkoxide complexes

              • Thiolate complexes

            • Ligands containing neutral group 16 donor atoms

              • Aqua species

              • Ethers

              • Ketones, aldehydes, esters

              • Carbamides

              • Urea

              • Phosphine oxide

              • Sulfoxide

              • Phosphine sulfide, phosphine selenide

            • Ligands containing Group 17 ligands

              • Binary halides

              • Complex halides

              • Oxohalides

          • Chelating ligand

            • beta-Diketonates

              • Hydroxamate

              • 8-Hydroxyquinoline and derivatives

              • Oxalate

              • Diamides

              • Polyoxometallates

            • Other

              • N-Heterocyclic ligands

              • Crown ethers

        • Hexavalent Oxidation State

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 14 donor atoms

            • Ligands containing anionic group 15 donor atoms

              • Amidinate ligands

              • Pyrazolylborate

              • Phosphoraniminato complexes

              • Cyanate and thiocyanate

              • Azide

            • Macrocyclic ligands

              • N-Heterocyclic ligands

              • Calixarenes

              • Crown ethers

            • Ligands containing anionic group 16 donor atoms

              • Oxides

              • Hydroxides

              • Peroxides

              • Carbonates

              • Nitrates

              • Phosphates

              • Arsenates

              • Molybdates

              • Sulfates and sulfites

              • Oxides

              • Oxides

              • Oxides

              • Oxides

            • Ligands containing neutral group 16 donor atoms

              • Aqua species

              • Ethers

              • Alcohols

              • Ketones, aldehydes, esters

              • Carbamide and related ligands

              • Ureas

              • Nitroalkanes

              • Amine N-oxides, phosphine oxides, arsine oxides, and related ligands

              • Sulfoxides

              • Aqua species

            • Ligands containing group 17 ligands

              • Binary halides

              • Complex halides

              • Oxohalides

          • Chelating ligands

            • Multidentate donor ligands

              • Hydroxamates, cupferron and related ligands

              • Catecholate

              • Pyridonate

              • 8-Hydroxyquinoline and derivatives

              • Carbamate

              • Oxalate

              • beta-Diketonates

              • Amino acids

              • CMPO

              • Hydroxamates, cupferron and related ligands

              • Hydroxamates, cupferron and related ligands

              • Hydroxamates, cupferron and related ligands

            • Schiff base ligands

            • Macrocyclic ligands

              • N-Heterocyclic ligands

              • Calixarenes

              • Crown ethers

        • Heptavalent Oxidation State

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 16 donor atoms

          • Chelating ligands

      • The Later Actinide Metals-Transplutonium Elements

        • Divalent Oxidation State (Am, Cm, Cf, Es, Fm, Md, No)

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 16 donor atoms

              • Oxides and aqueous

            • Ligands containing group 17 donor atoms

        • Trivalent Oxidation State (Am-Lr)

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 15 donor atoms

            • Ligands containing group 16 donor atoms

              • Oxides

              • Hydroxide, aqua, and hydrates

              • Oxoanions

              • Carbonates and carboxylates

              • Phosphoric, phosphinic, and phosphonic acid

              • Phosphine oxides

            • Ligands containing group 17 donor atoms

          • Chelating ligands

              • beta-Diketonates

              • Other

              • Diamides

              • Diphosphinic acids

              • Other

          • Macrocyclic ligands

        • Tetravalent Oxidation State (Am, Cm, Bk, Cf)

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 16 donor atoms

              • Oxides

              • Hydroxides

              • Carbonates and carboxylates

              • Other

            • Ligands containing group 17 donor atoms

          • Chelating ligands

              • beta-Diketonates

              • Other

        • Pentavalent Oxidation State (Am)

          • General characteristics

          • Simple donor ligands

            • Ligands containing group 16 donor atoms

              • Oxide

              • Aquo and hydroxides

              • Carbonates and carboxylates

              • Oxoanion complexes

            • Ligands containing group 17 donor atoms

        • Hexavalent Oxidation State(Am)

          • General characteristics

            • Ligands containing group 16 donor atoms

              • Oxides

              • Aqua, hydroxides

              • Oxoanion complexes

              • Carbonates and carboxylates

              • Other

              • Ligands containing group 17 donor atoms

        • Heptavalent Oxidation State

      • Other Sources

      • Acknowledgement

      • References

    • 3.4 Aluminum and Gallium

      • Aluminum

        • Introduction

        • Group 14 Ligands

        • Group 15 Ligands

          • Nitrogen ligands

          • Phosphorus and arsenic ligands

        • Group 16 Ligands

          • Oxygen ligands

          • Crown ethers

          • Sulfur, selenium, and tellurium ligands

          • Sulfur-based crown ethers

        • Group 17 Ligands

          • Hydride ligands

          • Halide ligands

        • Compounds Containing Al-Al Bonds

          • Neutral compounds containing the Al-Al bond

          • Radical anions: A degree of multiple bonding in the Al-Al bond

      • Gallium

        • Introduction

        • Group 14 Ligands

        • Group 15 Ligands

          • Nitrogen ligands

          • Phosphorus, arsenic, and antimony ligands

        • Group 16 Ligands

          • Crown ethers

        • Group 17 Ligands

          • Two-coordinate gallium centers

        • Compounds Containing Ga-Ga Bonds

          • Neutral compounds containing the Ga-Ga bond

          • Radical anions and multiple bond character

          • Cyclogallenes and metalloaromaticity

          • Ga-Ga triple bonds

      • References

    • 3.5 Indium and Thallium

      • Indium

        • Introduction

        • Indium (III)

          • Group 14 ligands

            • Carbon ligands

            • Silicon, germanium, tin, and lead ligands

          • Group 15 ligands

            • Nitrogen ligands

            • Phosphorus, arsenic, antimony, and bismuth ligands

          • Group 16 ligands

            • Oxygen ligands

            • Sulfur, selenium, tellurium ligands

          • Group 17 ligands

            • Halides and carbon ligands

            • Halides and group 15 and group 16 ligands

            • Halides and multidentate ligands

            • Anionic complexes with halide ligands

          • Hydride ligands

          • Mixed-donor-atom ligands

        • Indium (II)

          • Group 14 ligands

          • Group 15 ligands

          • Group 16 ligands

          • Group 17 ligands

          • Hydride ligands

        • Indium(I)

          • Group 14 ligands

          • Group 15 ligands

          • Group 16 ligands

          • Group 17 ligands

      • Thallium

        • Introduction

        • Thallium (III)

          • Group 14 ligands

            • Carbon ligands

            • Silicon, germanium, tin, and lead ligands

          • Group 15 ligands

            • Nitrogen ligands

            • Phosphorus, arsenic, antimony, and bismuth ligands

          • Group 16 ligands

            • Oxygen ligands

            • Sulfur, selenium, tellurium ligands

          • Group 17 ligands

          • Hydride ligands

        • Thallium (II)

        • Thallium (I)

          • Group 14 ligands

          • Group 15 ligands

            • Nitrogen ligands

          • Group 16 ligands

            • Oxygen ligands

            • Sulfur, selenium, tellurium ligands

          • Group 17 ligands

          • Hydride ligands

      • References

    • 3.6 Arsenic, Antimony, and Bismuth

      • Introduction

      • Arsenic

        • Group 14 Compounds

        • Group 15 Compounds

        • Group 16 Compounds

        • Group 17 Compounds

        • Arsenic in the Environment, Biology, and Medicine

      • Antimony

        • Group 14 Compounds

        • Group 15 Compounds

          • N-donor ligands

          • P-, As-, and Sb-donor ligands

        • Group 16 Compounds

          • O-donor ligands

          • S-, Se-, and Te-donor ligands

        • Group 17 Ligands

        • Antimony in the Environment, Biology, and Medicine

      • Bismuth

        • Group 14 Compounds

        • Group 15 Compounds

          • N-donor ligands

          • P- and As-donor ligands

        • Group 16 Compounds

          • O-donor ligands

          • N/O-donor ligands

          • S-, Se-, and Te-donor ligands

          • S/O- and S/N-donor ligands

        • Group 17 Compounds

        • Bismuth in the Environment, Biology, and Medicine

      • References

    • 3.7 Germanium, Tin, and Lead

      • Introduction

      • Complexes with Carbon Donor Ligands

      • Complexes with M(14)-M(14) Bonds

        • Complexes with M(14)-M(14) Homoelement Bonds

        • Complexes with M(14)-M(14) Heteroelement Bonds

      • Complexes with Group 15 Ligands

        • Complexes with Neutral Monodentate Nitrogen Ligands

        • Complexes with Anionic Monodentate Nitrogen Ligands

        • Complexes with Neutral Bidentate Nitrogen Ligands

        • Complexes with Anionic Bidentate Nitrogen Ligands

        • Complexes with Polypyrazolyl Ligands

        • Complexes with Tridentate Nitrogen Ligands

        • Complexes with Tetradentate Nitrogen Ligands

        • Complexes with Polydentate Nitrogen Ligands

        • Complexes with Phosphorus or Arsenic Ligands

          • Complexes of MIV with phosphines or arsines

          • Complexes of MII with phosphines or arsines

          • Complexes of MIV with phosphides or arsinides

          • Complexes of MII with phosphides or arsinides

      • Complexes with Group 16 Ligands

        • Complexes with Neutral Oxygen Ligands

        • Complexes with Anionic Monodentate Oxygen Ligands

        • Complexes with Monoanionic Bidentate Oxygen Ligands

        • Complexes with Carboxylates or Phosphinates

        • Complexes with Dianionic Bidentate Oxygen Ligands

        • Complexes with Neutral Sulfur Ligands

        • Complexes of Anionic Monodentate Sulfur, Selenium, or Tellurium Ligands

        • Complexes of Anionic Bidentate Sulfur, Selenium, or Tellurium Ligands

        • Complexes of Dianionic Bidentate Sulfur, Selenium, or Tellurium Ligands

      • Complexes with Group 17 Ligands

      • Complexes of Hydride Ligands

      • Complexes of Ligands with Mixed Donor Sets

        • Complexes of Heterobidentate Ligands

        • Complexes of Heterotridentate Ligands

        • Complexes of Heterotetradentate Ligands

        • Complexes of Heterodonor Ligands of Higher Denticity

      • References

    • 3.8 Appendix to Volume 3

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