Chemical Degradation Methods for Wastes and Pollutants - Chapter 7 pdf

... 5.0Â1081.4Â1095.5Â109Chloroform 3.0Â10101.1Â10 7 5Â106o-Cresol NF NF 1.1Â1010p-Cresol 4.2Â10 7 NF 1.2Â10101,2-Dichlorobenzene 4 .7 Â109NF NF1,3-Dichlorobenzene 5.2Â109NF NF1,4-Dichlorobenzene ... hydrated electron, hydrogen atom, and hydroxyl radical reactions with benzene, 1,3-cyclohexadiene, 1,4-cyclo-hexadiene, and cyclohexene. J Phys Chem 1 970 ; 74 :2 878 –2884.30. Schested K, Corﬁtzen ... reaction products. For ex-ample, the production of oxalic acid, formic acid, and formaldehyde arepredicted by Eqs. (33), (34), and (40), respectively, as chloroform is min-eralized by free...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 1 pps

... 0. 177 1 07 Parathion 0.0 076 (240–320)e89Parathion 0.0016f89aCEAT=2-chloro-4-ethylamine-1,3,5-s-triazine;bCIAT=2-chloro-4-isopropylamine-1,3,5-s-triazine;cCAAT=2-chloro-4,6-diamine-1,3,5-s-triazine.dIn ... and Modiﬁed Fenton M ethods for Pollutant Degradation Matthew A. Tarr5. Sonochemical Degradation of Pollutants Hugo Destaillats, Michael R. Hoﬀmann, and Henry C.Wallace6. Electrochemical Methods ... Electrochemical Methods for Degradation of Organic Pollutants in Aqueous MediaEnric Brillas, Pere-Lluı´s Cabot, and Juan Casado 7. The Electron Beam Process for the Radiolytic Degradation of Pollutants Bruce...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 2 pps

... degradation of phenyltriﬂuoromethylke-tone, a triﬂuoroacetic acid-forming pollutant, and octan-1-ol, a very hydro-phobic pollutant. Water Sci Technol 2001; 44:263– 270 .126. Puriﬁcs Environment Technologies ... place in thephotocatalytic degradation of quinoline. This mechanism has been proposedin the case of other aromatics, such as 4-chlorophenol (76 ) and 4-chloro-catechol (77 ).The primary event may ... Chem 1996; 97: 181–186.103. Obee TN. Photooxidation of sub-parts-per-million toluene and formaldehydelevels on titania using a glass-plate reactor. Environ Sci Technol 1996;30:3 578 –3584.104....

Chemical Degradation Methods for Wastes and Pollutants - Chapter 3 potx

... 38(11):4169–4 174 . 70 . Savage PE, Gopalan S, Mizan TI, Martini CJ, Brook EE. Reactions at su-percritical conditions: applications and fundamentals. AIChE J 1995; 41 (7) : 172 3– 177 8. 71 . Model M. Processing methods ... phenol and biphenyls), and the related productsdibenzofuran and dibenzo-p-dioxin [82,83, 87] . Li et al. [84] studied theintermediates from the oxidation of 2-chlorophenol and noted the produc-tion ... 15Airﬂow rate (lb/hr) 1690 1660 1 670 1650 1690 171 0 1650Feed water ﬂow rate (lb/hr) 72 1 70 3 74 4 70 322 622 70 Quench water ﬂow rate (lb/hr) 2240 2290 2020 171 0 278 0 3020 2430Kerosene—startup (lb)...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 4 docx

... conjunctionFenton and Modified Fenton Methods for Pollutant Degradation 179 TMCopyright © 2003 by Marcel Dekker, Inc. All Rights Reserved.4Fenton and Modified Fenton Methods for Pollutant Degradation Matthew ... 58: 177 1– 177 7. 97. Breslow R, Dong SD. Biomimetic reactions catalyzed by cyclodextrins and theirderivatives. Chem Rev 1998; 98:19 97 2011.98. Monﬂier E, Tilloy S, Castanet Y, Martreux A. Chemically ... acid by hydrogen peroxide. Chemosphere 1999; 38: 271 9– 273 1.55. Huang H-H, Lu M-C, Chen J-N. Catalytic decomposition of hydrogen per-oxide and 2-chlorophenol with iron oxides. Water Res 2001;...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 5 ppsx

... products performed with high-performance liquid chromatography (HPLC) and ion chromatographyrevealed the presence of small organic acids such as oxalic and formic acids,together with SO42À and NO3Àions ... NO3Àions as ﬁnal by-products. A similar trendwas observed by Joseph et al. [58] for the degradation of azobenzene and therelated monoazo dyes, methyl orange, o-methyl red, and p-methyl red.Working ... sonochemical degradation of many other chloromethanes and chloroethanes was reported by Bhatnagar and Cheung [49]. Aqueous so-lutions of CCl2H2, CCl3H, CCl4, 1,2-dichloroethane, 1,1,1-trichloroethane,trichloroethylene,...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 6 potx

... outlet for gases. (From Ref. 57. )Electrochemical Methods for Degradation 261TMCopyright © 2003 by Marcel Dekker, Inc. All Rights Reserved.The electrochemical methods described in this chapter for ... chapter. Figure 2 Classiﬁcation of electrochemical methods for the destruction of organicsin aqueous wastes. Electrochemical Methods for Degradation 2 37 TMCopyright © 2003 by Marcel Dekker, Inc. ... placeFigure 17 Electrolysis cell, closed in a reaction chamber, for the Co(III)-mediateddestruction of organics in sulfuric acid. (From Ref. 75 .)Electrochemical Methods for Degradation 2 67 TMCopyright...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 8 pot

... NAb 79 .1 77 .6 77 .6 69.5 NA 88 .7 64.3 59 .7 Total percent extraction 93.1 84.3 91 81 84 87. 5 96.6 87. 8 85aExtractions performed after initial soil slurry in NH3(40jC) was cooled to 17jC and ... RW. Methods for the destruction of ozone depleting sub-stances. US Patent 5,559, 278 , 1996. 37. Mouk RW, Abel AE. Non-metallized and substoichiometric metallized re-actions with ammonia and ... (ppm)PosttreatmentPCB level (ppm)Harrisburg, PAaSand, clay 77 7 <1.0Los Alamos, NMbSand, silt, clay 77 <2.0New YorkcSand, silt 1250 <2.0Monroe, LAdSand, silt, clay 8.8 <1.0The range...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 9 pot

... cast iron: sorption and masstransfer. J Environ Eng 1998; 124:1012–1019. 173 . Allen-King RM, Halket RM, Burris DR. Reductive transformation and sorption of cis- and trans-1,2-dichloroethene in ... in zero-he adspace systems. 213th National Meeting, SanFrancisco, CA, American Chemical Society 19 97; 37( 1):81–83. 177 . Li T, Farrell J. Rate-limiting mechanisms for carbon tetrachloride and trichloroethylene ... Palumbo AV,Jacobs GK. Biogeochemical dynamics in zero-valent iron columns: implica-tions for permeable reactive barriers. Environ Sci Technol 1999; 33:2 170 –2 177 .1 97. Klausen J, Tro¨ber SP,...

Chemical Degradation Methods for Wastes and Pollutants - Chapter 10 (end) doc

... investigate the eﬀect ofcellulolytic enzymes on MSW degradation [73 ]. Econase consists mainly ofendo-1,4-h-D-glucanase, cell obiohydrolase, and exo-1,4-h-D-glucosidase inaddition to a number of other ... Organopollutant degradation by ligninolyic fungi. EnzymeMicrob Technol 1989; 11 :77 6 77 7.31. Cornwell RL, Tinland-Butez M-F, Tardone PJ, Cabasso I, Hammel KE.Lignin degradation and lignin peroxidase ... For example, as shown in Fig. 8, solutions of 3- chlorophenol, 4-chlorophenol, 2,6-dichlorophenol, 3-methylphenol, and 4- methylphenol were substantially detoxiﬁed during treatment with HRP and SBP....

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