Phsicochemical Treatment of Hazardous Wastes - Chapter 3 pptx

... Cu 3 aq Fe 3+ aq Pb 3+ aq Cu 3 (OH) 3 2– Pb (CO 2 ) 3 CuCO 3 AgSH CdOH – CoOH – Zn(OH) – Ag 3 S 3 H 3 2- Me-SR Me-OOCR Me-lipids Me-humic-acid ... Surface Sci., 33 1 33 3(A), 138 –142, 1995. TX69272_C 03. fm Page 80 Tuesday, November 11, 20 03 11 :39 AM © 2004 by CRC Press LLC 72 Physicochemical Treatment of Hazar...

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... Arsenic 13. 3.2 .3 Uranium 13. 3.2.4 Mercury 13. 3 .3 Reduction of Inorganic Pollutants 13. 3 .3. 1 Chlorine 13. 4 QSAR Models 13. 5 Engineering Applications 13. 5.1 Continuous and Funnel-and-Gate PRBs 13. 5.1.1 ... Compounds 13. 3.1.2 Saturated Halogenated Compounds 13. 3.1 .3 Polychlorobiphenyls 13. 3.1.4 Nitroaromatic Compounds 13. 3.1.5 Nitrates and Nitrites 13. 3.2 Red...

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... 2.21–2.79 Ethylbenzene 3. 11 3. 05 3. 15 o -Xylene 3. 11 2.77 3. 13 m -Xylene 3. 20 — p -Xylene 3. 17 3. 15 3. 18 Polycyclic aromatic hydrocarbons Anthracene 4 .34 — Benzo[a]anthracene ... 0.4 0.5 0 .36 0.19 C 3 H 7 2. 13 –0.07 –0. 13 –0.06 –0.08 CONH 2 –0.01 0.28 0 .36 0.24 0.14 C(CH 3 ) 3 3. 56 –0.10 –0.20 –0.07 –0. 13 CO 2 CH 3 1.47 0 .3...

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... 2.955 2.909 2.854 2.816 28.2 28.5 36 .2 35 .1 2.58 03 25.517 5.692 5.882 4.711 4. 832 1.982 1.912 OH — 569 0 83 559 756 569 0 83 559 756 — 1.908 1. 832 H 2 O 2 — 30 3 037 30 3 38 2 26 736 26 471 25 586 25 35 5 1.812 1. 732 Note: ... –226.889 93 –75.59 737 –151.2 833 2 5.80 4.06 CCSD(T)// MP2 –226. 930 82 –75.61491 –151 .30 656 5.87 4. 13 B3LYP//B3LYP –227 .37 381 –75.762...

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... 5 × 10 3 M; Fe 2+ = 2 × 10 3 M; pH = 3. 5; ionic strength = 0.05 M as N 2 SO 4 . 4 4.1 4.2 4 .3 4.4 4.5 4.6 4.7 4.8 4.9 5 2 2.5 3 3.5 4 -log (CP) -log(r 0 (M/S)) 2-MCP 2,4-DCP 2,4,6-TCP average ... 29, 20 83, 1995. With permission.) N N N N H Cl HN CH CH 3 CH 3 H 3 CH 2 C N N N N H Cl HN CH CH 3 CH 3 H 3 CC N N N NH 2 OH H 2 N N N N N H Cl HN CH CH 3 CH 3 N N N N H Cl...

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... 0.1 63 E HOMO + 0.0552 0.1 63 [O 3 ] = 37 ppmv 0.9574 k = 0 .31 4 E HOMO + 0.10 73 0 .31 4 [O 3 ] = 37 ppmv 0.9 039 k = 0.6198 E HOMO + 0.2097 0.6198 [O 3 ] = 37 ppmv 0.2785 k = 1.008 E HOMO + 0 .34 4 ... Chemosphere , 30 , 231 7– 233 1, 1995. Vollmuth, S. and Niessner R., Degradation of polychlorinated dibenzo- p -dioxins and polychlorinated dibenzofurans during t...

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... 2.7 3, 4-Dichlorophenol 3. 47 0.600 4.5 4.2 3, 5-Dichlorophenol 3. 72 0.746 4.4 4.1 2,4,5-Trichlorophenol 3. 72 0.827 3. 6 3. 7 3, 4,5-Trichlorophenol 4.29 0.9 73 5.1 5.2 2,4,6-Trichlorophenol 3. 37 0.681 ... major by-product was found to be 2 ,3, 5-trichloro-1,4-hydro- quinone. After 60 min of reaction, the toxicity of the intermediates was less than that of 2 ,3, 5-TCP. The...

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... (min –1 ) R 2 2-Hydroxybenzoic acid 3. 0 0.9981 2.7 0.9875 3- Hydroxybenzoic acid 4.9 0.9997 3. 4 0.9972 4-Hydroxybenzoic acid 5.1 0.9999 3. 1 0.9988 3, 4-Dihydroxybenzoic acid 1.9 0.9760 1.9 0.9 835 GA 2.6 ... Ultrasonic-induced dehalo- genation and oxidation of 2-, 3- , and 4-chlorophenols in air-equilibrated aque- ous media: similarities with irradiated semiconductor particles...

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... 10 9 2.42 NO 2 3. 0 × 10 10 3. 33 ± 0.05 1.9 × 10 10 3. 22 2.5 × 10 10 3. 80 CF 3 1.8 × 10 9 2.11 ± 0.05 1.9 × 10 10 3. 22 2.5 × 10 10 3. 80 CH 2 OH 1 .3 × 10 8 0.97 ± 0.05 1.9 × 10 10 3. 22 2.5 × 10 10 3. 80 SH ... 10 10 2. 93 ± 0.06 1 .3 × 10 10 3. 03 2.7 × 10 9 2. 83 CN 1.6 × 10 10 3. 06 ± 0.06 1.4 × 10 10 3. 07 4.8 × 10 9 3. 08 COO- 3. 1 × 10 9 2 .35 ± 0.05 3. 6 × 10...

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... –1.57 ±0. 03 –0.04 2 1,2-Dichlorobenzene 46.269 –9.295 –1. 43 –1. 43 ±0. 03 0.00 3 1 , 3- Dichlorobenzene 42 .33 7 –9.421 –1 .36 –1.42 ±0. 03 0.06 4 1,4-Dichlorobenzene 41.990 –9. 235 –1 .36 –1 .38 ±0.04 0.02 5 ... 0. 132 6.99 5. 23 0.1-M MES 6 0 .34 1 0.482 2. 03 1.44 0.1-M HEPES 7 0 .39 3 0.5 13 1.76 1 .35 0.1-M Tricine 8 0.259 — 2.67 — 0.1-M CHES 9 ———— Source: Siantar, D.P. et...

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