Phsicochemical Treatment of Hazardous Wastes - Chapter 3 pptx
Phsicochemical Treatment of Hazardous Wastes - Chapter 3 pptx
...
Cu
3
aq
Fe
3+
aq
Pb
3+
aq
Cu
3
(OH)
3
2–
Pb
(CO
2
)
3
CuCO
3
AgSH
CdOH
–
CoOH
–
Zn(OH)
–
Ag
3
S
3
H
3
2-
Me-SR
Me-OOCR
Me-lipids
Me-humic-acid ... Surface Sci., 33 1 33 3(A), 138 –142, 1995.
TX69272_C 03. fm Page 80 Tuesday, November 11, 20 03 11 :39 AM
© 2004 by CRC Press LLC
72
Physicochemical Treatment of Hazar...
Phsicochemical Treatment of Hazardous Wastes - Chapter 1 potx
... Arsenic
13. 3.2 .3 Uranium
13. 3.2.4 Mercury
13. 3 .3 Reduction of Inorganic Pollutants
13. 3 .3. 1 Chlorine
13. 4 QSAR Models
13. 5 Engineering Applications
13. 5.1 Continuous and Funnel-and-Gate PRBs
13. 5.1.1 ... Compounds
13. 3.1.2 Saturated Halogenated Compounds
13. 3.1 .3 Polychlorobiphenyls
13. 3.1.4 Nitroaromatic Compounds
13. 3.1.5 Nitrates and Nitrites
13. 3.2 Red...
Phsicochemical Treatment of Hazardous Wastes - Chapter 2 potx
... 2.21–2.79
Ethylbenzene 3. 11 3. 05 3. 15
o
-Xylene 3. 11 2.77 3. 13
m
-Xylene 3. 20 —
p
-Xylene 3. 17 3. 15 3. 18
Polycyclic aromatic hydrocarbons
Anthracene 4 .34 —
Benzo[a]anthracene ... 0.4 0.5 0 .36 0.19 C
3
H
7
2. 13 –0.07 –0. 13 –0.06 –0.08
CONH
2
–0.01 0.28 0 .36 0.24 0.14 C(CH
3
)
3
3. 56 –0.10 –0.20 –0.07 –0. 13
CO
2
CH
3
1.47 0 .3...
Phsicochemical Treatment of Hazardous Wastes - Chapter 4 docx
...
2.955
2.909
2.854
2.816
28.2
28.5
36 .2
35 .1
2.58 03
25.517
5.692
5.882
4.711
4. 832
1.982
1.912
OH — 569
0 83
559
756
569 0 83
559 756
— 1.908
1. 832
H
2
O
2
— 30 3
037
30 3
38 2
26 736
26 471
25
586
25
35 5
1.812
1. 732
Note: ... –226.889 93 –75.59 737 –151.2 833 2 5.80 4.06
CCSD(T)//
MP2
–226. 930 82 –75.61491 –151 .30 656 5.87 4. 13
B3LYP//B3LYP –227 .37 381 –75.762...
Phsicochemical Treatment of Hazardous Wastes - Chapter 6 pps
... 5 × 10
3
M; Fe
2+
= 2 × 10
3
M; pH = 3. 5; ionic strength = 0.05 M as N
2
SO
4
.
4
4.1
4.2
4 .3
4.4
4.5
4.6
4.7
4.8
4.9
5
2 2.5 3 3.5 4
-log (CP)
-log(r
0
(M/S))
2-MCP 2,4-DCP 2,4,6-TCP average ... 29, 20 83, 1995. With permission.)
N
N
N
N
H
Cl
HN CH
CH
3
CH
3
H
3
CH
2
C
N
N
N
N
H
Cl
HN CH
CH
3
CH
3
H
3
CC
N
N
N
NH
2
OH
H
2
N
N
N
N
N
H
Cl
HN CH
CH
3
CH
3
N
N
N
N
H
Cl...
Phsicochemical Treatment of Hazardous Wastes - Chapter 8 pps
... 0.1 63 E
HOMO
+ 0.0552 0.1 63 [O
3
] = 37 ppmv 0.9574
k = 0 .31 4 E
HOMO
+ 0.10 73 0 .31 4 [O
3
] = 37 ppmv 0.9 039
k = 0.6198 E
HOMO
+ 0.2097 0.6198 [O
3
] = 37 ppmv 0.2785
k = 1.008 E
HOMO
+ 0 .34 4 ...
Chemosphere
, 30 ,
231 7– 233 1, 1995.
Vollmuth, S. and Niessner R., Degradation of polychlorinated dibenzo-
p
-dioxins and
polychlorinated dibenzofurans during t...
Phsicochemical Treatment of Hazardous Wastes - Chapter 9 pps
... 2.7
3, 4-Dichlorophenol 3. 47 0.600 4.5 4.2
3, 5-Dichlorophenol 3. 72 0.746 4.4 4.1
2,4,5-Trichlorophenol 3. 72 0.827 3. 6 3. 7
3, 4,5-Trichlorophenol 4.29 0.9 73 5.1 5.2
2,4,6-Trichlorophenol 3. 37 0.681 ... major by-product was found to be 2 ,3, 5-trichloro-1,4-hydro-
quinone. After 60 min of reaction, the toxicity of the intermediates was
less than that of 2 ,3, 5-TCP. The...
Phsicochemical Treatment of Hazardous Wastes - Chapter 11 pot
... (min
–1
) R
2
2-Hydroxybenzoic acid 3. 0 0.9981 2.7 0.9875
3- Hydroxybenzoic acid 4.9 0.9997 3. 4 0.9972
4-Hydroxybenzoic acid 5.1 0.9999 3. 1 0.9988
3, 4-Dihydroxybenzoic
acid
1.9 0.9760 1.9 0.9 835
GA 2.6 ... Ultrasonic-induced dehalo-
genation and oxidation of 2-, 3- , and 4-chlorophenols in air-equilibrated aque-
ous media: similarities with irradiated semiconductor particles...
Phsicochemical Treatment of Hazardous Wastes - Chapter 12 doc
... 10
9
2.42
NO
2
3. 0 × 10
10
3. 33 ± 0.05 1.9 × 10
10
3. 22 2.5 × 10
10
3. 80
CF
3
1.8 × 10
9
2.11 ± 0.05 1.9 × 10
10
3. 22 2.5 × 10
10
3. 80
CH
2
OH 1 .3 × 10
8
0.97 ± 0.05 1.9 × 10
10
3. 22 2.5 × 10
10
3. 80
SH ... 10
10
2. 93 ± 0.06 1 .3 × 10
10
3. 03 2.7 × 10
9
2. 83
CN 1.6 × 10
10
3. 06 ± 0.06 1.4 × 10
10
3. 07 4.8 × 10
9
3. 08
COO- 3. 1 × 10
9
2 .35 ± 0.05 3. 6 × 10...
Phsicochemical Treatment of Hazardous Wastes - Chapter 13 doc
... –1.57 ±0. 03 –0.04
2 1,2-Dichlorobenzene 46.269 –9.295 –1. 43 –1. 43 ±0. 03 0.00
3 1 , 3- Dichlorobenzene 42 .33 7 –9.421 –1 .36 –1.42 ±0. 03 0.06
4 1,4-Dichlorobenzene 41.990 –9. 235 –1 .36 –1 .38 ±0.04 0.02
5 ... 0. 132 6.99 5. 23
0.1-M MES 6 0 .34 1 0.482 2. 03 1.44
0.1-M HEPES 7 0 .39 3 0.5 13 1.76 1 .35
0.1-M Tricine 8 0.259 — 2.67 —
0.1-M CHES 9 ————
Source: Siantar, D.P. et...
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