Phsicochemical Treatment of Hazardous Wastes - Chapter 1 potx
Phsicochemical Treatment of Hazardous Wastes - Chapter 1 potx
...
FIGURE 1. 1
Cumulative growth in federal environmental laws and amendments in the United States.
Number of Laws
0
20
40
60
80
10 0
12 0
18 70 18 80 18 90 19 00 19 10 19 20 19 30 19 40 19 50 19 60 19 70 19 80 19 90 ... Compounds
10 .5.2 Aromatic Compounds
10 .6 Summary
References
Chapter 11
Sonolysis 423
11 .1 Introduction
11 .2 Fundamental Processes in Son...
Phsicochemical Treatment of Hazardous Wastes - Chapter 2 potx
... Project, DOE/EIS- 019 8, U.S. Department of
Energy, UMTRA Project Of ce, Washington, D.C., April, 19 95.)
30%
20%
16 %
10 %
11 %
14 %
13 %
6%
5%
5%
18 %
15 %
14 %
10 %
22%
5%
10 %
8%
0%
5%
10 %
15 %
20%
25%
30%
Uranium
Tritium
Thorium
Radium
Plutonium
Lead
Beryllium
Mercury
Arsenic
Chromium
PCBs
TCE
Petroleum/Fuel ...
Acrylonitrile 83 1. 1 ¥ 10
–4
Chlorobenzene 90 3.7 ¥ 1...
Phsicochemical Treatment of Hazardous Wastes - Chapter 3 pptx
... catalytic de-
composition of CO
2
on Fe (11 1) surfaces studied with high resolution EELSS,
J. Surface Sci., 3 31 333(A), 13 8 14 2, 19 95.
TX69272_C03.fm Page 80 Tuesday, November 11 , 2003 11 :39 AM
© ... York, 2, 11 71, 19 95.
Charles, A.W., Ed., Hazardous Waste Management, McGraw-Hill, New York, 19 89.
Cheremisinoff, P.C., Ed., Encyclopedia of Environmental Control Technolo...
Phsicochemical Treatment of Hazardous Wastes - Chapter 4 docx
... 10
5
s
1
(7)
—
Promotion Reactions
(8)
k
8
= 1. 1 × 10
8
M
1
s
1
(9)
k
9
= 2.7 × 10
7
M
1
s
1
(10 )
k
10
= 7.5 × 10
9
M
1
s
1
(11 )
k
11
= 1. 0 × 10
10
M
1
s
1
Recombination ... 645–649, 19 78. With permission.)
1. 0
0 .1
10
10
2
10
3
10
6
k obs
3 567 812 4
pH
10
4
10
5
10 11 12 13
9
10
8
10
7
O
O
H
H
+
O
O
–
H
O
O
H...
Phsicochemical Treatment of Hazardous Wastes - Chapter 6 pps
... LLC
214 Physicochemical Treatment of Hazardous Wastes
About 10 to 16 % of total 2,4-D was adsorbed, whereas 89% of total Meto-
lachlor was adsorbed. The complexes of Fe-GAL, -HEIDA, and -NTA have
comparatively ...
Oxidation of Dichlorophenols
Dichlorophenol
Rate Constants
( 10
7
1/ s)
2,4-Dichlorophenol 2.28
2,3-Dichlorophenol 8. 61
2,5-Dichlorophenol 11 .90
2,...
Phsicochemical Treatment of Hazardous Wastes - Chapter 8 pps
... 3.8 514 –8.794 UV = 11 7 W/m
2
0.84 61
k = 11 .32 E
HOMO
– 4.9 611 11 .32 UV = 12 8 W/m
2
0.8 717
k = 13 . 21 E
HOMO
– 5.7 911 13 . 21 UV = 14 1 W/m
2
0.8742
k = 0 .16 3 E
LUMO
– 0.0208 0 .16 3 [O
3
] = 37 ... + 0 .10 4 0.222 68 0.9467
k = 0. 311 E
HOMO
+ 0 .14 5 0. 311 87 0. 911 9
k = 0. 413 E
HOMO
+ 0 .19 38 0. 413 10 5 0.89 21
k = 0. 519 E
HOMO
+ 0.2438 0. 519 11 7 0.8784
k...
Phsicochemical Treatment of Hazardous Wastes - Chapter 9 pps
... permission.
O
CHO
CHO
CHO
CHO
CHO
CHO
O
COOH
COOH
COOH
COOH
COOH
COOH
O
O
O
12
40
12
21. 5
60
60 14 3.5
21. 5
19
20
33.5
33
10 .5
50
30
63
47
30
75
7
TX69272_C09.fm Page 357 Tuesday, November 11 , 2003 12 :14 PM
© 2004 by CRC Press LLC
358 Physicochemical Treatment of Hazardous ... Values of Log k/k
0
of Chlorophenols
Chlorophenol Log K
ow
s
res
Log k/k
0
(calc.) Log k...
Phsicochemical Treatment of Hazardous Wastes - Chapter 11 pot
... Physicochemical Treatment of Hazardous Wastes
11 .3 .10 Chlorinated Hydrocarbons
Cheung et al. (19 91) investigated sonication of 1, 1 , 1- trichloroethane and
trichloroethylene by using a W-385 Ultrasonicator ... permission.
TX69272_C 11. fm Page 446 Tuesday, November 11 , 2003 12 :24 PM
© 2004 by CRC Press LLC
Sonolysis
4 31
(11 .10 )
(11 .11 )
It must also be taken into...
Phsicochemical Treatment of Hazardous Wastes - Chapter 12 doc
... × 10
9
2.42
SO
3
4.0 × 10
9
2.46 ± 0.05 1. 65 × 10
9
2 .14 1. 06 × 10
9
2.42
NO
2
3.0 × 10
10
3.33 ± 0.05 1. 9 × 10
10
3.22 2.5 × 10
10
3.80
CF
3
1. 8 × 10
9
2 .11 ± 0.05 1. 9 × 10
10
3.22 2.5 × 10
10
3.80
CH
2
OH ... × 10
8
1. 57 2.7 × 10
9
2.83
I 1. 2 × 10
10
2.93 ± 0.06 1. 3 × 10
10
3.03 2.7 × 10
9
2.83
CN 1. 6 × 10
10
3.06 ± 0.06 1. 4 × 1...
Phsicochemical Treatment of Hazardous Wastes - Chapter 13 doc
... 1, 2,4-Trichlorobenzene 19 .755 –9.2 41 1. 31 1. 26 ±0.05 –0.05
6 2-Chlorophenal 18 .15 8 –9. 210 1. 67 1. 78 ±0.04 0 .11
7 3-Chlorophenal 19 .340 –9.236 1. 78 1. 80 ±0.04 0. 01
8 4-Chlorophenal 19 .12 9 –9.009 1. 95 1. 84 ... –0.04
2 1, 2-Dichlorobenzene 46.269 –9.295 1. 43 1. 43 ±0.03 0.00
3 1, 3-Dichlorobenzene 42.337 –9.4 21 1. 36 1. 42 ±0.03 0.06
4 1, 4-Dichlorobenzene 41. 990...