Thermal Analysis of Polymeric Materials Part 5 docx

... 382 7 65 1 ,52 1 10.0 0.8 3.8 7.6 11 .5 38 76 153 25. 0 0.3 1 .5 3.0 4 .5 15 31 61 50 .0 0.2 0.8 1 .5 2.3 8 15 31 100.0 0.1 0.4 0.8 1.2 4 8 15 150 .0 0.1 0.2 0 .5 0.8 3 5 10 ___________________________________________________________________ Fig. ... ( Jcm 2 ) ____________________________________________________ T(K) 0.1 0 .5 1.0 1 .5 5.0 10.0 20.0 _________________________...

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... 2 .55 kJ mol 1 , as indicated in the 5 Structure and Properties of Materials ___________________________________________________________________ 53 0 Fig. 5. 107 Fig. 5. 106 5. 3 .5 Deformation of ... structure of cyclotetraeicosane (C 24 H 48 )ismore 5. 4 Transitions and Prediction of Melting ___________________________________________________________________ 54 5 Fig. 5...

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... 146–161, 146– 150 , 151 –161 flux and production 147, 148, 148 internal variables 155 – 158 , 156 , 157 melting of lamellar crystals 148– 155 , 149, 150 , 152 – 155 relaxation times 159 –161, 159 –161 Subject ... 58 4 viscometer 57 6 Ubbelohde 64 viscosity 4 15 melt 57 5 57 8, 57 5, 57 7, 57 8 molar-mass dependence 193, 57 6 shear thinning 57 7 Newtonian 4 15, 416, 57 7 rang...

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... 54 7 5. 5.2 Classes of Mesophases 55 1 5. 5.3 Jump-motion in Crystals 55 5 5. 5.4 Conformational Disorder 55 8 5. 5 .5 Examples 56 1 Summary of the section on morphology 57 1 5. 6 Melts and Glasses 5. 6.1 ... 53 8 5. 4.3 Crystals of Non-spherical Motifs 54 1 5. 4.4 Crystals of Linear Hydrocarbons 54 2 5. 4 .5 Crystals of Macromolecules 54 4 5. 5 Mesophases and...

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... of 5 k should be compared to the CC bond length of 0. 154 nm. 1.3.10 Stiff Chain Macromolecules Four types of macromolecules of largely different Kuhn length are listed at the top of Fig. 1 .50 . ... materials of optimum properties and leads to the understanding of the behavior of already known polymeric materials, the elusive goal of every modern material scientist....

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... Capacity __________________________________________________________________ 1 45 Fig. 2.77 Fig. 2.78 Chap. 5, it is possible to interpret the behavior of polymeric materials as is described in more detail on-hand of a larger series of examples in Chaps. ... in the lower part of Fig. 2.80 illustrates this statement. Equation (1) in Fig. 2.81 expresses the time dependence of t...

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... another. The basic transitions of interest to thermal analysis are described in the classification scheme of Fig. 2.103. In the bottom half of Fig. 2.1 15 the properties of the condensed phases arereviewedandtheir ... of the “Future Thermal Analysis is largely based on the article Kreitmeier SN, Liang, GL, Noid DW, Sumpter BG (1996) Thermal Analysis via Molecular Dynamic...

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... 718.4 413 348 6 15 812 292 6 15 891 351 728 N 472.6 391 292 6 15 891 161 418 946  O 247 .5 463 351 728 139 4 85 F 76.6 56 3 441  270 1 85  Si 368.4 2 95 290  369  P 314 .5 320   S ... 1911–1899. Professor of Chemistry at the University of Heidelberg, Germany. He observed in 1 859 that each element emits light of a characteristic wavelength. These studie...

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... (1). Figure 4. 95 illustrates the evaluation of the constant - as the slope of a plot of the square of the reciprocal of the uncorrected specific heat capacity as a function of the square of the frequency ... different value of Online elimination of the effects of asymmetry and different pan mass, as described in Appendix 11, should improve the ease of measurement. This...

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... 34: 419–426; Paulik F, Paulik J (1973) J Thermal Anal 5: 253 –270; (19 75) 8: 55 7 57 6. 50 . Sørensen OT, Rouquerol J, eds (2003) Sample-controlled Thermal Analysis (SCTA): Orign, Goals, Multiple ... Region of Polymers, J Macromolecular Sci, Phys 38: 10 45 1 054 . 38. Toda A, Tomita C, Hikosaka M (1998) Temperature Modulated DSC of Irreversible Melting of Nylon 6 Crystals. J...

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