INTERFACIAL AND CONFINED WATER Part 10 doc

... 29, 36, 145 amorphous, 10 11, 148 cubic, 110 hexagonal, 1, 10, 110, 148 Interfacial equation, 55 Ising film, 103 Ising model, 10, 12, 18–19, 24, 67–8, 72, 82, 89, 94 3D, 18, 102 2D, 24, 37, 46, 93 Ising ... cluster, 128, 130, 172–5, 191, 224 of random walk, 169 Fractal structure, 189 Freezing temperature, 1 10, 21–4, 40, 62–6, 111, 234 of 2D water, 39 of confined water, 110 Heat ca...

Ngày tải lên: 05/08/2014, 21:22

... of water, and patience. We have greatly profited from collaboration with Roland Winter, Nikolay Smolin, Aljaksei Krukau, and Alexey Mazur. Our view on the properties of interfacial and confined water ... dynamic water properties. Subsequent analysis of the properties of interfacial and con- fined water allows understanding of related phenomena. Naturally, the phase behavior a...

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... whereas a denser film coexists with a liquid. 30 Interfacial and confined water 10 21 10 22 10 23 10 24 pressure (bar) 250 260 270 280 290 300 310 320 330 T (K) bulk liquid–vapor transition ZnO FeOOH Cr 2 O 3 SnO 2 Figure ... and bulk liquid coexist with a water film. The temperature of this triple point is a 50 Interfacial and confined water ␳ (g/cm 3 ) r (Å) r (Å) T 5 3...

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... all pores 76 Interfacial and confined water 20 0 .10 0.088 0.090 0.092 0.096 0.098 0 .100 0 .102 0 .104 0 .106 0.12 0.14 0.16 0.18 T 5 1.16 T 5 1 .10 T 5 1.09 T 5 1.08 T 5 1.13 46 8101 2 2046 810 12 14 16 ... 1.60 ˚ A and a ξ = 0.97 is shown by solid lines in both panels (data from [262]). 58 Interfacial and confined water in cylindrical pores with R p = 25, 30, and 35 ˚...

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... latter 88 Interfacial and confined water T ϭ 475 K T ϭ 545 K T ϭ 300 K T ϭ 400 K 1.4 ϫ 10 Ϫ4 1.2 ϫ 10 Ϫ4 1.0 ϫ 10 Ϫ4 8.0 ϫ 10 Ϫ5 6.0 ϫ 10 Ϫ5 4.0 ϫ 10 Ϫ5 2.0 ϫ 10 Ϫ5 4.5 ϫ 10 Ϫ3 4.0 ϫ 10 Ϫ3 3.5 ϫ 10 Ϫ3 3.0 ... conditions, and accordingly, there is no critical distance for cap- illary evaporation. In equilibrium with a saturated bulk, a liquid water is 104 Interfa...

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... hydration water from conventional percolation in strict 2D 121 124 Interfacial and confined water 10 0 10 22 10 21 10 23 10 24 10 25 10 26 10 27 10 28 10 29 10 210 110 S L 5 80 Å L 5 100 Å L 5 ... Water layers at hydrophilic surfaces 125 10 3 10 2 10 1 10 0 10 21 10 22 10 23 10 24 10 25 10 26 10 27 10 27 10 28 110 S C 5 0.047 C 5 0...

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... solvents, the critical water level is determined by the miscibility of water and solvent and by the difference in the water protein and solvent–protein interac- tions. Clearly, less water amount is necessary ... is restored at h ≈ 0.38 g/g [ 510] . Mossbauer spectroscopy studies evidence restoration of the internal dynamics of lysozyme 172 Interfacial and confined water 10...

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... simulation studies of water near the surface of differently hydrated plastocyanin [640, 641]. 200 Interfacial and confined water t (ps) 10 2 10 2 10 4 10 3 10 0 10 0 10 1 10 1 G520 G530 G512 <r 2 > ... hydration of biomolecules. Water in low-hydrated biosystems 183 10 100 S n S 1 10 213 10 211 10 29 10 27 10 25 10 23 10 21 n S ~ S 22.05 Figure 10...

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... n S follows a power law for 2D percolation in the 10 21 10 23 10 25 10 27 10 29 10 211 10 213 1 10 100 S n S n S ∼ S 22.05 Figure 130: Size distribution n S of water clusters in the hydra- tion shell of ... mol- ecular complexes of pyridines with water and demixing phenom- ena in aqueous solutions, J. Chem. Phys. 106 (1997) 7756–7765. 236 Interfacial and confined wa...

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... 2893–2899. [237] K. Lum, D. Chandler, J. D. Weeks, Hydrophobicity at small and large length scales, J. Phys. Chem. B 103 (1999) 4570–4577. [238] D. M. Huang, D. Chandler, Cavity formation and the drying transition ... materials by 1H NMR using water as a probe molecule, J. Phys. Chem. B 101 (1997) 107 09 107 14. [352] T. S. T. Iiyama, K. Nishikawa, K. Kaneko, Study of the structure...

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