INTERFACIAL AND CONFINED WATER Part 9 pps

... Phys. Chem. 99 ( 199 5) 2 893 –2 899 . [237] K. Lum, D. Chandler, J. D. Weeks, Hydrophobicity at small and large length scales, J. Phys. Chem. B 103 ( 199 9) 4570–4577. [238] D. M. Huang, D. Chandler, Cavity ... interacting waterlike particles, Phys. Rev. Lett. 49 ( 198 2) 1 895 –1 898 . [ 396 ] D. Stauffer, Introduction to Percolation Theory, London and Philadelphia; Taylor and Franci...

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... diagram for amorphous solid water, Phys. Rev. E 48 ( 199 3) 4605–4610. [ 79] P. Poole, F. Sciortino, U. Essmann, H. E. Stanley, Spinodal of liquid water, Phys. Rev. E 48 ( 199 3) 3 799 –3817. [80] F. Sciortino, ... 18 (2006) R9 19 R977. [62] M. A. Anisimov, E. E. Gorodetskii, V. D. Kulikov, J. V. Sengers, Crossover between vapor-liquid and consolute critical phenomena, Phys. Rev. E 51 ( 1...

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... about 0 .99 , 0 .96 , and 0 .90 , for methanol on nonane, decane, and undecane sur- faces, respectively [130]. The character of a wetting transition depends on a fluid and on the surface properties, and ... properties of biosystems . . . 194 8 States of interfacial water in fully hydrated biosystems 215 9 Summary and outlook 233 References 237 Index 303 12 Interfacial and...

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... observed for ethylene [155, 193 , 194 ], ethane [ 195 ], propane [ 196 ], molecular oxygen [ 197 ], and alcohols [ 198 ]. The freezing temperature of 2D water is about 0. 49 T c (Fig. 16), whereas the bulk ... of water 29 BeO [1 79] , FeOOH [160]), and on the crystal surface of MgO [180, 181]. At ambient temperature, the condensed 2D water was found to be liquid- like for the lay...

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... close to 0.82 in all pores 76 Interfacial and confined water 20 0.10 0.088 0. 090 0. 092 0. 096 0. 098 0.100 0.102 0.104 0.106 0.12 0.14 0.16 0.18 T 5 1.16 T 5 1.10 T 5 1. 09 T 5 1.08 T 5 1.13 4681012 2046810 12 14 ... 1.60 ˚ A and a ξ = 0 .97 is shown by solid lines in both panels (data from [262]). 58 Interfacial and confined water in cylindrical pores with R p = 25, 30, a...

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... fluid decreases to 0.889T c ,0 .91 9T c , and 0 .95 7T c , respectively [325, 326]. For comparable fluid–wall interaction, the liquid–vapor critical temperature is about 0 .96 4T c and 0 .98 1T c in the pores ... diagram of confined water 95 the shifts ΔT c = 0.0015T c ,0.0029T c , and 0.047T c , respectively, were obtained [2 89, 292 ]. In the ordered cylindrical mesopores with radius...

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... size distribution obeys the universal power law: n S ∼ S −τ , ( 19) with exponents τ = 187 /91 ≈ 2.05 [ 396 ] and τ ≈ 2.2 [ 397 ] in the case of random 2D and 3D percolation, respectively. In an infinite system, ... between the water dipole moment and the pore radius and of the angle β between the water OH vector and the pore radius (Fig. 82). In the first surface layer, most of...

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... solvents, the critical water level is determined by the miscibility of water and solvent and by the difference in the water protein and solvent–protein interac- tions. Clearly, less water amount is necessary ... hydration water at biosurfaces and b) effect of temperature and pressure on the state and properties of this hydration layer. These two aspects are considered in th...

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... percolation thresholds in different lattices. In particular, it is ∼2. 09 and ∼2.37 for site percolation and ∼1 .96 and ∼2.00 for bond percolation on the honeycomb and square lattices, respec- tively, which ... hydration water were studied in most details (see Section 6, 7.1 and [473, 508–510, 512–515, 544, 585, 590 – 592 , 601, 632–634, 636–6 39] ). At low hydrations and up to...

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... 234 of 2D water, 39 of confined water, 110 Heat capacity, 3–7 maximum, 6, 92 , 235 Hysteresis, 27, 92 , 95 , 99 , 115 coexistence curve, 92 , 96 , 99 critical temperature, 92 , 99 , 195 Ice: 2D, 29, 36, ... 218 Disorder, 12 spatial, 196 –7, 201, 2 09 10 temporal, 196 , 199 Disordered pores, 92 –4 Disordered water, 227, 2 29 31 Disordering effect of the surface, 28, 82, 97 DNA...

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