INTERFACIAL AND CONFINED WATER Part 8 ppsx

... water, J. Chem. Phys. 112 (2000) 799 80 9. [59] A. K. Soper, M. A. Ricci, Structures of high-density and low- density water, Phys. Rev. Lett. 84 (2000) 288 1– 288 4. [60] H. Kanno, H. Yokoyama, Y. ... water, Phys. Rev. Lett. 88 (2002) 195701. States of interfacial water in fully hydrated biosystems 227 R (Å) P (R ) R (Å) 0. 08 320 K 340 K 360 K 380 K 400 K 420 K 440 K 280 K 285...

Ngày tải lên: 05/08/2014, 21:22

... of water, and patience. We have greatly profited from collaboration with Roland Winter, Nikolay Smolin, Aljaksei Krukau, and Alexey Mazur. Our view on the properties of interfacial and confined water ... properties of biosystems . . . 194 8 States of interfacial water in fully hydrated biosystems 215 9 Summary and outlook 233 References 237 Index 303 12 Interfacial and co...

Ngày tải lên: 05/08/2014, 21:22

... isotherms of water on the hydroxylated surface of Cr 2 O 3 at 2 68. 9 K (a), 2 78. 4 K (b), 283 .2 K (c), 288 .2 K (d), 293.3 K (f), 302.7 K (g), 3 08. 0 K (h), 313.3 K (i), 3 18. 2 K (j), 323.3 K (k), 3 28. 3 K ... [162], NaCl [ 182 ], SrF 2 , and ZnO [ 183 ], whereas it is solid-like for Cr 2 O 3 [159, 1 78, 183 ]. At low temperatures, condensed water phase is a 2D ice with some parti...

Ngày tải lên: 05/08/2014, 21:22

... 0 .82 in all pores 76 Interfacial and confined water 20 0.10 0. 088 0.090 0.092 0.096 0.0 98 0.100 0.102 0.104 0.106 0.12 0.14 0.16 0. 18 T 5 1.16 T 5 1.10 T 5 1.09 T 5 1. 08 T 5 1.13 4 681 012 204 681 0 12 14 ... systems within rather narrow interval of U 0 and for high temperatures only. 80 Interfacial and confined water 0.0 024 81 012 1 2 3 445 1.0 0 .8 0.6 0.4 0.2 0.0...

Ngày tải lên: 05/08/2014, 21:22

... simulations) is about 0 .85 T c ,0.71T c , and 0.65T c for water in the pores of the width H p = 16, 10, and 8 ˚ A, respectively. For cylindrical pores of the radii R p = 18. 5, 8. 4, and 6 .8 ˚ A, the hysteresis ... equilibrated directly with a bulk vapor [379, 380 ] or bulk liquid [205, 206, 2 08] by simulations in the Gibbs ensemble [ 187 ]. The latter 88 Interfacial and c...

Ngày tải lên: 05/08/2014, 21:22

... to top): −0.39; −1.93; −3. 08; −3 .85 , and −4.62 kcal/mol. 1 38 Interfacial and confined water out of this transition. However, we can expect percolation transition of water on real hydrophilic surfaces, ... by small energetic barrier [ 385 ]. Metastability of liquid water between hydrophobic surfaces [ 381 , 387 ] and/ or liquid density depletion near these surfaces [ 388 , 389...

Ngày tải lên: 05/08/2014, 21:22

... solvents, the critical water level is determined by the miscibility of water and solvent and by the difference in the water protein and solvent–protein interac- tions. Clearly, less water amount is necessary ... photoiso- merization of bacteriorhodopsin reduces [ 480 – 484 ] and proton pumping stops below 60% relative humidity [ 483 – 486 ]. The above examples show Role of inte...

Ngày tải lên: 05/08/2014, 21:22

... [621]. 188 Interfacial and confined water 10 100 200 300 400 B-DNA, major groove B-DNA, minor groove A-DNA, major groove A-DNA, minor groove 12 14 16 18 20 10 0.0 0.2 0.4 0 .8 1.0 0.0 0.2 0.4 0.6 0 .8 1.0 0.6 12 major ... toward Water in low-hydrated biosystems 193 34 g o Ϫ o 56 789 3456 789 10 r (Å) C/Å Ϫ2 r (Å) 0.027 0.055 0. 082 Plane 80 ϫ 80 Å 2 C/Å Ϫ2 0.071 0.104 0.1 18 Sp...

Ngày tải lên: 05/08/2014, 21:22

... of interacting waterlike particles, Phys. Rev. Lett. 49 (1 982 ) 189 5– 189 8. [396] D. Stauffer, Introduction to Percolation Theory, London and Philadelphia; Taylor and Francis, 1 985 . [397] N. Jan, ... MPa and 188 K, Ber. Bunsenges. Phys. Chem. 84 (1 980 ) 462–470. [103] F. X. Prielmeier, E. W. Lang, R. J. Speedy, H D. Luedemann, Diffusion in supercooled water to 300 MPa, Phys. Rev....

Ngày tải lên: 05/08/2014, 21:22

... 51, 55, 58, 67, 72–6, 80 –3, 86 , 93–4, 1 08 9, 234 Critical exponent: of order parameter, 3, 25, 37 2D, 93, 47 bulk (3D), 81 , 97 effective, 96 in percolation problems, 127, 1 68, 188 surface, 84 , 97 Critical ... 36, 145 amorphous, 10–11, 1 48 cubic, 110 hexagonal, 1, 10, 110, 1 48 Interfacial equation, 55 Ising film, 103 Ising model, 10, 12, 18 19, 24, 67 8, 72, 82 , 89 , 94 3...

Ngày tải lên: 05/08/2014, 21:22