Nucleophilic substitution

Organic chemitry   t8 nucleophilic substitution on the carbonyl group

Organic chemitry t8 nucleophilic substitution on the carbonyl group

... equivalent of a nucleophilic substitution reaction on the sulfur oxygen double bond. RCO O S Cl O S Cl Cl O RCO O H RCO O H SO Cl Cl RCO O SO Cl Cl Cl The reaction then follows a typical nucleophilic ... conjugate base of a much weaker acid (pK a ~ 5). Thus, the position of equilibrium for nucleophilic substitution is more favorable for an acyl halide than for an anhydri...

Ngày tải lên: 05/03/2014, 22:28

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Báo cáo y học: "Parvovirus B19 Genotype Specific Amino Acid Substitution in NS1 Reduces the Protein’s Cytotoxicity in Culture"

Báo cáo y học: "Parvovirus B19 Genotype Specific Amino Acid Substitution in NS1 Reduces the Protein’s Cytotoxicity in Culture"

... explore the effect of the NS1 I181M amino acid substitution on B19 NS1-induced cytotoxicity in liver cells. Our work has shown that the I181M substitution significantly re- duces B19 NS1-induced ... disease groups, identified two amino acid substitutions in B19 NS1 that differed between the biliary atresia and fulminant liver failure patient groups. Substitution E201D, believed to...

Ngày tải lên: 26/10/2012, 09:32

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What is the question to which ‘substitution’ is the answer

What is the question to which ‘substitution’ is the answer

... and that this in part accounts for the com- plexity of the essay, Substitution . There is more than one question to which substitution is the an- swer. One of them is, indeed, the question ... meaning of concrete experience. Levinas is not asking about the conditions of substitution to find what lies behind it. Substitution happens. In some sense it has already happened. But in so far ......

Ngày tải lên: 01/11/2013, 10:20

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Contrastive analysis of nominal substitution english and vietnamese discourse

Contrastive analysis of nominal substitution english and vietnamese discourse

... Of Nominal Substitution In English And Vietnamese Discourse Part II Content Chapter One: In general 1.1. What is substitution and types of substitution. Much has been said about substitution. ... Nominal Substitution In English And Vietnamese Discourse devices: reference, substitution, ellipsis and conjunction. Most of them have been carefully studied. However, one minor type of s...

Ngày tải lên: 12/12/2013, 00:03

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A study on ambiguity caused by ellipsis and substitution in english = nghiên cứu về sự mập mờ về nghĩa gây ra do phép tỉnh lược và phép thay thế trong tiếng anh luận văn tốt nghiệp đại học

A study on ambiguity caused by ellipsis and substitution in english = nghiên cứu về sự mập mờ về nghĩa gây ra do phép tỉnh lược và phép thay thế trong tiếng anh luận văn tốt nghiệp đại học

... of substitution and types of substitution. • Investigate the circumstances in which ellipsis and substitution usually cause ambiguity. • Indicate the main ambiguities caused by ellipsis and substitution. • ... 2006: 8) Quirk et. al. (1972: 677) defines substitution as follows: substitution is a device for abbreviating and for avoiding repetition. Across sentences, substitution...

Ngày tải lên: 14/12/2013, 00:41

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Tài liệu Báo cáo " The effect of cobalt substitution on structure and magnetic properties of nickel ferrite " pptx

Tài liệu Báo cáo " The effect of cobalt substitution on structure and magnetic properties of nickel ferrite " pptx

... VNU Journal of Science, Mathematics - Physics 25 (2009) 153-159 153 The effect of cobalt substitution on structure and magnetic properties of nickel ferrite Nguyen Khanh Dung 1, *, ... yields monotonic increase in the saturation magnetization of Ni- ferrite which may be due to the substitution of Ni 2+ ions by Co 2+ on the octahedral sties. Therefore, the increasing Co 2+

Ngày tải lên: 13/02/2014, 04:20

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Tài liệu Báo cáo khoa học: Domain deletions and substitutions in the modular protein evolution doc

Tài liệu Báo cáo khoa học: Domain deletions and substitutions in the modular protein evolution doc

... an event (substitution or camouflage) was recorded. Therefore, the calcula- ted numbers of substitution and camouflage events cannot be used to infer any conclusions on the act- ual substitution ... position a similar amino acid sequence Domain−wise evolutionary events Annotation artifacts Substitution A Substitution A A D B C C A A B C C Shadow domain seq B Shadow domain Deletion A A...

Ngày tải lên: 19/02/2014, 07:20

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Tài liệu Báo cáo khoa học: "Bayesian Symbol-Refined Tree Substitution Grammars for Syntactic Parsing" pptx

Tài liệu Báo cáo khoa học: "Bayesian Symbol-Refined Tree Substitution Grammars for Syntactic Parsing" pptx

... and symbol refinement without heuristics. 3 Symbol-Refined Tree Substitution Grammars In this section, we propose Symbol-Refined Tree Substitution Grammars (SR-TSGs) for syntactic parsing. Our SR-TSG ... unsupervised fashion. That is, we wish to infer the symbol sub- categories of every node and substitution site (i.e., nodes where substitution occurs) from parse trees. Extracted rules a...

Ngày tải lên: 19/02/2014, 19:20

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Tài liệu Báo cáo khoa học: "Corpus Expansion for Statistical Machine Translation with Semantic Role Label Substitution Rules" doc

Tài liệu Báo cáo khoa học: "Corpus Expansion for Statistical Machine Translation with Semantic Role Label Substitution Rules" doc

... other sentences. The problem is how to identify where a substitution should happen and which phrase pairs are valid can- didates for the substitution. While syntactical con- straints have been ... for application of only one substitution. Although the idea is straightforward, we face two problems in practice. First, for frequent semantic frames, the number of substitution candidates ca...

Ngày tải lên: 20/02/2014, 04:20

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Tài liệu Báo cáo khoa học: "Direct Word Sense Matching for Lexical Substitution" ppt

Tài liệu Báo cáo khoa học: "Direct Word Sense Matching for Lexical Substitution" ppt

... 2005). To perform lexical substitution NLP applica- tions typically utilize a knowledge source of syn- onymous word pairs. The most commonly used resource for lexical substitution is the manually constructed ... constructed by Dekang Lin (Lin, 1998). We generically refer to such resources as substitution lexicons. When using a substitution lexicon it is assumed that there are some con...

Ngày tải lên: 20/02/2014, 12:20

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