rauk - orbital interaction theory of organic chemistry 2e (wiley, 2001)
... termi- 1 Orbital Interaction Theory of Organic Chemistry, Second Edition. Arvi Rauk Copyright ( 2001 John Wiley & Sons, Inc. ISBNs: 0-4 7 1-3 583 3-9 (Hardback); 0-4 7 1-2 204 1-8 (Electronic) Orbital ... of Organic Chemistry, Second Edition. Arvi Rauk Copyright ( 2001 John Wiley & Sons, Inc. ISBNs: 0-4 7 1-3 583 3-9 (Hardback); 0-4 7 1-2 20...
Ngày tải lên: 04/06/2014, 15:33
... atomic orbitals of other atoms, they help to determine the shape of the molecule formed. Example. In much of organic (carbon) chemistry, the 2s orbital of carbon is mixed with: (a) one p orbital ... with values of l ϭ 0,1,2, ,(n Ϫ 1) that determines the shape of the orbital. The value of l implies particular angular momenta of the electron resulting from the shape of...
Ngày tải lên: 13/12/2013, 16:15
Fundamentals of organic chemistry
... electron 9 0-9 5% of the time). Figure 1.5 The shapes of some s and p orbitals. Pure, unhybridized p orbitals are almost-touching spheres. The p orbitals in hybridized atoms are lobe-shaped ... Solomons/SoloCh01 2) Plots of Ψ 2 in three dimensions generate the shapes of the familiar s, p, and d atomic orbitals. 3) An orbital is a region of space where the probabi...
Ngày tải lên: 15/01/2014, 12:45
... TABLE OF CONTENTS PAGE B. Synthesis of Salvarsan (Arsphena- mme), 3,3'-diammo-4,4'-dihydroxyar- senobenzene dihydrochlonde 92 1. 3-Nitro-4-hydroxyphenylarsomc acid 92 2 Reduction of ... unsubstituted para- position, the main product of the reaction is ^-nitroso-o-cresol« OF ORGANIC CHEMISTRY 17 54 g. of o-cresol are dissolved in 4 liters of ice-water in a batter...
Ngày tải lên: 09/05/2014, 17:00
gattermann - laboratory methods of organic chemistry
... p. 244 ; (b) /3-Naphthyl methyl ether, p. 244. 3. Ortho- and para-Nitrophenols 246 4. Kolbe's salicylic acid synthesis 249 5. Synthesis of the ester of a /3-keto-acid. Acetoacetic ... Sodium jj-nitrophenyl-amM-diazotate, p. 290. 4. 23-Tolunitrile from p-toluidine (Sandmeyer's reaction) . . . 291 Benzonitrile, p. 292, ^i-Toluio acid, p. 292. 5. Arsanilic acid from...
Ngày tải lên: 04/06/2014, 15:25
olah - superacid chemistry 2e (wiley, 2009)
... 246 3.5.2.7. 9-Barbaralyl (Tricyclo[3.3.1.0 2,8 ]nona-3, 6-dien-9-yl) Cations and Bicyclo[3.2.2] nona-3,6,8-trien-2-yl Cations 253 3.5.2.8. The 1,3,5,7-Tetramethyl- and 1,2,3,5, 7-Pentamethyl-2-ad amantyl ... vistas of chemistry and a fascinating, broad field of chemistry is developing at superacidities. Because acidity is a term related to a reference base, superacidity a llows exten...
Ngày tải lên: 03/04/2014, 12:14
davies - organotin chemistry 2e (wiley, 2004)
... relative abun- dances of the ions, in Figure 2-1 . Me 4 Sn Me 3 Sn + -Me Me 2 Sn -Me -Me -Me Sn 100% 22% 12%25% MeSn + -Me -MeMe , -MeMe Bu 4 Sn Bu 3 Sn + BuSn + SnH Sn + -Bu -2 Bu -C 4 H 8 SnH 3 + Bu 2 SnH + -C 4 H 8 BuSnH 2 + - C 4 H 8 -C 4 H 8 71% 100% ... 1,3-dichloro-1,1,3,3,-tetramethyl Me 3 SnCH=CHCH=CHSnMe 3 stannane, 1,3-butadiene-1,4-diylbis[trimethyl cyclo-BrPhSn(CH 2 )...
Ngày tải lên: 03/04/2014, 12:15
mundy - name reactions and reagents in organic synthesis 2e (wiley, 2005)
... Me -S-Me 1: A Ph-P p-ph Ph pi I n Ph-P P-Ph II Ph Ph Acronyms and Abbreviations xii I IcLI~BH r LTMp LiTMP I MCPBA F Ms 2-( 6-Chloro- 1H-benzotriazole- 1 -yl )- 1,1,3,3-tetramethyIuronium ... Trimethylsilyltrifluoro- methanesulfonate Triphenylsilyl Trityl Tosyl p-toluenesulfonyl xv Et i-Pr i-Pr -Si ‘2 - i-Pr’ n Me-” N-Me Me Me I Pr4N’RuO...
Ngày tải lên: 03/04/2014, 12:16