rieger - electrochemistry

... Potentials 42 [F-h -[ F-]o =(2.00 x 1 0-3 mol L- 1 X10 mUllO mL) [F-h - [F-]o=0.181 x 1 0-3 molL-l Substituting [F-h =(2.86 ±0.08)[F-]0,we obtain [F-]o (2.86±0.08 -1 ) =0.181x 1 0-3 . or! [F-]o =(9.7 ... 1.77 -1 .87 1.41 1.28 NOs -+ N~. -+ HN02 -+ NO -+ Nf -+ N2 -+ NHr OH + -+ N2 H r;+ -+ NH4+ L tI t ~.05 t t0.94 1.29 L35 ~.86 0...

Ngày tải lên: 01/04/2014, 11:38

... including DNA biosensors, imped- ance spectroscopy, detection for capillary electrophoresis, diamond electrodes, carbon-nanotube- and nanoparticle-based assays and devices, large-amplitude AC voltammetry, ... interferences can lead to their pre- vention, through adequate attention to key operations. Improved signal-to-background characteristics can be achieved using dual- working electrode te...

Ngày tải lên: 04/10/2012, 13:23

... offers also an up-to-date, easy-to-read presen- tation of more recent advances, including new methodologies, sensors, detec- tors, and microsystems. The book is suitable for a graduate-level course ... including DNA biosensors, imped- ance spectroscopy, detection for capillary electrophoresis, diamond electrodes, carbon-nanotube- and nanoparticle-based assays and devices, large-amplitude AC v...

Ngày tải lên: 25/10/2013, 08:20

... Reduced O 2 O -2 H 2 O 2 H 2 O F 2 , Cl 2 , Br 2 , I 2 F -1 , Cl -1 , Br -1 , I -1 ClO 3 -1 (BrO 3 -1 , IO 3 -1 ) Cl -1 , (Br -1 , I -1 ) H 2 SO 4 (conc) SO 2 or S or H 2 S SO 3 -2 S 2 O 3 -2 , or ... S + 2 NO + 4 H 2 O MnO 2 + 4 HBr → MnBr 2 + Br 2 + 2 H 2 O +1 -2 +5 -2 +1 0 +2 -2 +1 -2 ox agred ag +4 -2 +1 -1 +2...

Ngày tải lên: 28/11/2013, 01:12

... electron-transfer pathway. The molybdop- terin cofactor contacts the nearest [2Fe-2S] cluster Fe-S I through the exocyclic NH 2 of the pyranopterin ring system and the S .c atom of one of the [Fe-S] ... % 75 A ˚ [14–17]. A single polypeptide of 907 amino-acid residues contains three redox centers: the active site, formed by a fivefold-co-ordi- nated Mo atom bound to two oxygen ligands, one sul...

Ngày tải lên: 07/03/2014, 15:20

... case: condition 1 statement 1-A; statementl-B; case: condition 2 statement2-A; statement2-B ; . . . case: condition 3 statement3-A; statement3-B; . . . end cases This statement ... Consequently, the if-statement inside that loop is performed CrZ2(n + I - i) = ~ln~')(n - i) = n(n - 1)/2 times. Asymptotically this pair of nested loops is the mo...

Ngày tải lên: 17/03/2014, 14:51

... temperature. хш materials (electrolytes, electrodes, non-aqueous electrochemistry in gene- ral), up-to-date charge transfer theory and biological aspects of electro- chemistry. On the other hand, the presentation ... Waals non-bonding interactions and dipole-dipole interactions will become impor- tant. Thus, non-ideal behaviour must be considered for electrolyte solutions at much lower con...

Ngày tải lên: 22/03/2014, 22:20

... polydimethylsiloxane (PDMS), divinylbenbenzene (DVB), PDMS/DVB and carboxen-PDMS (CAR-PDMS) and carbowax-DVB (CW-DVB), carboxen-PDMS-DVB (PDMS-DVB-CAR) and they are selected according to the characteristics ... (N-methyl-N-trimethylsilyltrifluoroacetamide), BSTFA (N,O-bis(trimethylsilyl )- trifluoracetamide), TMS (Trimethylsulfonium hydroxide solution) and MTBSTFA (N-tert- Butyldimethyl...

Ngày tải lên: 23/03/2014, 05:21

... H -_ - - ED *-& quot; - - - - - - i—C - - -& quot;".^. S - . _ . _ (b) Fig. 4-1 . Electrodes (a) partiaUy immersed and (b) completely im- mersed in an electrol3i«: ED = elec- trode; ... function of Eqn. 1-3 , as shown in Fig. 1-3 . The total concentration, n.,of electrons that occupy the allowed electron fit) - Dit) -* Fi...

Ngày tải lên: 01/04/2014, 11:36

... used: di- mensioned quantities like concentration, distance or time will be given lower- case symbols (c, x, t, etc.) and their non-dimensional equivalents will be given the corresponding upper-case ... time, as well as other variables, in the form of differ- ential equations. Fundamentally, these are transport (diffusion-, convection- and migration-) equations but may be complicated by chemica...

Ngày tải lên: 16/04/2014, 11:19