Báo cáo khoa học: On the thermodynamic equilibrium between (R)-2-hydroxyacyl-CoA and 2-enoyl-CoAOn the thermodynamic equilibrium between (R)-2-hydroxyacyl-CoA and 2-enoyl-CoA doc

... solvated more strongly than the enoyl one (2b), the difference between them, and hence the associated effect on DG Ã ðaqÞ (B), is much smaller than for reaction C. The favorable contribu- tion from DG Ã s (H 2 O) ... kJÆmol )1 and K a = 1610. Given the good agreement between theory and experiment obtained for equilibria B and C, we are confident that these values provid...

Ngày tải lên: 29/03/2014, 08:20

... accumu- lation of propionyl-CoA under these conditions, as the thioester cannot be oxidized further. Addition of acetate to the glucose/propionate medium reduced the propionyl- CoA level of the cells, ... light path of the cuvette], which con siders the decrease of the concentration of oxaloacetate in equilibrium with L -malate during t he formation o f NADH (the concentratio...

Ngày tải lên: 19/02/2014, 16:20

... deter- mined their ontological classes based on the class glossary of DOLCE. Below, we only report on the member-of and sub-quantity-of meronymic relations, and on the located-in, contained-in and structural ... How- ever, these relation extraction efforts have over- looked the ontological distinctions between the different types of part-whole relations. They as- sume...

Ngày tải lên: 20/02/2014, 04:20

... satisfying the definition. Constraints on instantiation (COMPONENT2 above) are reflected in the choice of values for the instances in these propositions. Thus the KERNEL structure has the properties ... The propositions shown there are the ones whose truth is necessary and sufficient for the definition to have been met. Bindings constraints between nodes are ref...

Ngày tải lên: 21/02/2014, 20:20

... ponents (and) and synonym specification (or) become more and more blurred; c) When p reaches its lower limit of 1, the distinction between and and or operators is completely lost. and the ... value for each and- operator. The higher the p-value, the more similar • the corresponding operator will be to the com- pulsory Boolean and. Correspondingly, the smal...

Ngày tải lên: 22/02/2014, 09:20

... theoretical work has shown, the c-command condition is only an approximation to reality (cf. Stowell 1989). However, the precise definition of the c-command relation and the syntactic condition ... relation between the pronoun ~ and the host quanti- fier 7 is a syntactic one, whereas the relation between 7 and the antecedent a is a semantic relation: Up to whi...

Ngày tải lên: 22/02/2014, 10:20

... information and stress the importance of relations between text segments in discourse interpretation. In fact, the incorporation of the above types of information ties in well with the SDRT (Asher and ... its own right to show the contribution that the ATT- Meta approach can make towards the semantics of metaphor. In the somewhat simplified discussion on the within-pr...

Ngày tải lên: 08/03/2014, 03:20

... comparisons between them. We I One of the exceptions is the work by (Samuelsson and Voutilainen, 1997), in which a very strict comparison between taggers is performed. think that there are ... tend to make the same errors that appear in the test set. On the contrary, if the train- ing and test sets come from different sources -sharing only the tag set- the behav...

Ngày tải lên: 08/03/2014, 05:21

... [E] 0 the enzyme concentration, [S] the substrate concentration, [I] the inhibitor concentration, K m the Michaelis constant and K 1i , K 2i , L 1i , L 2i the dissociation constants of the different abortive ... added to the buffer compartment of the control and to the compartment containing AMY1 in the sample cell. The AMY1 concentration in the control cell was ad...

Ngày tải lên: 08/03/2014, 08:20

... the point of observation Is "vlrtual" l.e. It Is an hypothetical locatlon and direction for vlewlng: the location is coincident with the stone,, and the direction Is the direction ... and in the ~mi, whenever field or bowl contain X. One ~ay however say the dust on the ~ml, and the fertilizer on the ~eid. An adhering thln lamina brings atten...

Ngày tải lên: 08/03/2014, 18:20